CN106398908B - A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake - Google Patents
A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake Download PDFInfo
- Publication number
- CN106398908B CN106398908B CN201610755880.2A CN201610755880A CN106398908B CN 106398908 B CN106398908 B CN 106398908B CN 201610755880 A CN201610755880 A CN 201610755880A CN 106398908 B CN106398908 B CN 106398908B
- Authority
- CN
- China
- Prior art keywords
- hydrogen peroxide
- sodium chloride
- saltcake
- sodium
- adduct
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to inorganic salts preparation technical field, in particular to a kind of method that adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake.Specific method is first to mix saltcake, hydrogen peroxide and sodium chloride, be stirred to react 30~60min under room temperature, and decompression filters after reaction, is separated by solid-liquid separation；Solid phase after separation is dried to 60~90min at 80~120 DEG C again, obtains adduct sodium sulphate-hydrogen peroxide-sodium chloride product.
Description
Technical field
The invention belongs to inorganic salts preparation technical fields, in particular to a kind of to prepare sodium sulphate-peroxide using solid waste saltcake
Change hydrogen-sodium chloride adduct method.
Background technique
Adduct sodium sulphate-hydrogen peroxide-sodium chloride is a kind of neutral, oxygen-containing washing assisant of nontoxic solid and one
The novel oxygenation agent of kind, disinfectant, bleaching assistant.Molecular formula is 4Na2SO4-2H2O2The mass fraction of-NaCl, hydrogen peroxide is
Greater than 9.2%, active o content 4.6%.Due to 4Na2SO4-2H2O2- NaCl is dissolved in the hydrogen peroxide generated after water and occurs to divide
Solution, the elemental oxygen of releasing has bleaching, sterilization, decontamination and disinfection, so the property with hydrogen peroxide；It is dissolved in simultaneously
PH value after water in aqueous solution is 6~8, close to neutrality, frequently as detergent bleach auxiliary agent.
There are mainly two types of for the production technology of traditional adduct sodium sulphate-hydrogen peroxide-sodium chloride: one is wet types
Sodium sulphate, sodium chloride, stabilizer are dissolved in hydrogen peroxide by preparation method, are controlled crystallization temperature appropriate, are dried after separation to
Product.Another is dry type preparation method, sodium sulphate, sodium chloride is stirred kneading using mixer or kneader, simultaneously
Mixture is sprayed with hydrogen peroxide, product is made.
Although adduct sodium sulphate-hydrogen peroxide-sodium chloride possesses plurality of advantages, when it is used as bleaching agent bleaching, deposit
The phenomenon that decomposition rate is too fast, decomposition, needs additionally to add synergist or stabilizer slows down its decomposition rate；Simultaneously should
Product grains are tiny, and in production, drying, storage and transportational process, crystal grain can be acted on due to crystal, are bonded to each other, out
The phenomenon that existing product agglomeration.
Saltcake, Na2SO4•10H2O content >=85%, monoclinic system is usually in pelletized form, blocky, soluble easily in water, there is moisture absorption
Property.The chlor-alkali plant etc. that chemical fibre factory or embrane method remove nitre at present has a common difficulty, and the by-product saltcake exactly produced does not have
There is market, remaining beneficial ingredient is all abandoned as waste, becomes new solid waste, in a large amount of saltcake accumulations and transportational process very
The problems such as be easy to causeing soil and underground water pollution.The saltcake of especially certain by-products contains the Hubeiwans such as cellulose, therefore
Saltcake solid waste bring environmental pollution how is reduced, turns waste into wealth, increases operation rate, make the product of higher value, at
For people's concern.
Summary of the invention
Technical problem to be solved by the present invention lies in: there are particle size distributions for adduct sodium sulphate-hydrogen peroxide-sodium chloride
Difference, easily agglomeration the disadvantages of, while when being used as bleaching assistant bleaching, the phenomenon that there are decomposition rates is too fast, decomposition, need volume
Outer addition synergist or stabilizer slow down its decomposition rate, cause the increase of cost.
The present invention uses the solid waste saltcake doped with impurity to replace raw material of traditional sodium sulphate as reaction, two-step method preparation
Adduct sodium sulphate-hydrogen peroxide-sodium chloride, when being used as bleaching assistant with the adduct product that the raw material is prepared, bleaching is steady
Qualitative decomposition that is higher, effectively inhibiting adduct product, improves bleaching utilization rate；The Granularity Distribution is equal simultaneously
Even, autonomous resistive connection block effect is good, while the problems such as solve current saltcake solid waste environmental pollution is serious, resource utilization is low, very
The good cost for reducing raw material in traditional preparation method.
In order to achieve the above object, the present invention adopts the following technical scheme:
(1) sodium sulphate, hydrogen peroxide, 1.2~2.5:2.1 of sodium chloride three's molar ratio~3.5:0.8~1.6 are pressed, by awns
Nitre, hydrogen peroxide and sodium chloride mix, and are stirred to react 30~60min under the conditions of room temperature (25 DEG C), and decompression filters after reaction,
It is separated by solid-liquid separation,
Wherein, the hybrid manipulation of saltcake, hydrogen peroxide and sodium chloride is that saltcake and sodium chloride are added to aquae hydrogenii dioxidi
In solution,
Wherein, saltcake ingredient is calculated according to weight percent, needs to control are as follows: cellulose sulfonate 2%~5%, crystallite
Cellulose 2%~3%, trithiocarbonic acid sodium 1%~2%, sodium bisulfate 0.5%~1%, sulphur 0.5%~1%, zinc sulfate
1%~2%, surplus Na2SO4•10H2O,
In the presence of cellulose sulfonate, microcrystalline cellulose, zinc sulfate are with above-mentioned content, sodium sulphate-can be utmostly improved
Hydrogen peroxide-sodium chloride adduct mobility, enhances its anti-caking performance, main reason is that cellulose sulfonate contains ester
Base, which has hydrophobicity, while the polysaccharide polymer structure of cellulose sulfonate and microcrystalline cellulose can be adsorbed in adduction
Object surface forms hydrophobic layer, hinders exchanging for adduct and moisture in air, can effectively prevent adduct agglomeration；Except this with
Outside, the synergistic effect between each ingredient and adduct, the decomposition for effectively inhibiting adduct too fast slow down it to being bleached
The radical response of object improves its effective, lasting utilization rate,
If trithiocarbonic acid sodium content is higher than 2%, hydrate is generated because it is highly soluble in water, will affect sodium sulphate-
Hydrogen peroxide-sodium chloride adduct anti-caking performance, while sodium bisulfate has hygroscopicity, content must also be controlled 1%
Within,
Wherein, the Solute mass fraction of aqueous hydrogen peroxide solution is 30%, purity >=99.7% of NaCl in sodium chloride；
(2) solid phase after step (1) separation is dried at 80~120 DEG C 60~90min, obtains sodium sulphate-peroxidating
Hydrogen-sodium chloride adduct product.
The present invention also provides a kind of answering for adduct sodium sulphate-hydrogen peroxide-sodium chloride that above-mentioned preparation method obtains
With that is, using adduct sodium sulphate-hydrogen peroxide-sodium chloride as bleaching agent.
The present invention has following advantages and effect compared with prior art:
(1) present invention provides a kind of solid waste saltcake and is used as adduct sodium sulphate-hydrogen peroxide-sodium chloride raw materials for production, system
At finished product as bleaching assistant when resolution ratio < 85%, effective rate of utilization is high, stability is preferable, the pure cotton fabric after bleaching
Brightness gain >=50%, while 35 ° of static angle < in resistive connection test, product mobility is preferable, and autonomous anti-caking performance is excellent
It is different.
(2) saltcake is replaced traditional anhydrous sodium sulfate to be applied to prepare product by the present invention, and saltcake is useless for common industrial
Gurry is turned waste into wealth in this way, realizes recycling for mirabilite resource.
(3) present invention makes full use of the particularity of raw material feature and process, significantly reduces production cost, is suitble to
It is used in heavy industrialization.
Specific embodiment
Embodiment 1
(1) hydrogenperoxide steam generator that 200L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
(each ingredient of saltcake calculates 420kg saltcake according to weight percent are as follows: cellulose sulfonate 4%, microcrystalline cellulose 2%, three are thio
Sodium carbonate 1%, sodium bisulfate 0.5%, sulphur 0.8%, zinc sulfate 1.5%, surplus Na2SO4•10H2O), 46kg sodium chloride,
It is stirred to react 60min under the conditions of room temperature (25 DEG C), decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 100 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 2
(1) hydrogenperoxide steam generator that 250L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
(each ingredient of saltcake calculates 450kg saltcake according to weight percent are as follows: cellulose sulfonate 5%, microcrystalline cellulose 2%, three is thio
Sodium carbonate 1.2%, sodium bisulfate 0.6%, sulphur 1%, zinc sulfate 1.2%, surplus Na2SO4•10H2O), 52kg sodium chloride,
It is stirred to react 50min under the conditions of room temperature (25 DEG C), decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 80min at 90 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 3
(1) hydrogenperoxide steam generator that 220L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
430kg saltcake (each ingredient of saltcake is calculated according to weight percent are as follows: cellulose sulfonate 2.5%, microcrystalline cellulose 2.5%, and three
Sodium thiocarbonate 1%, sodium bisulfate 1%, sulphur 0.7%, zinc sulfate 1.8%, surplus Na2SO4•10H2O), 50kg chlorination
Sodium is stirred to react 60min under the conditions of room temperature (25 DEG C), and decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 4
(1) hydrogenperoxide steam generator that 300L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
(each ingredient of saltcake calculates 630kg saltcake according to weight percent are as follows: cellulose sulfonate 3%, microcrystalline cellulose 2.6%, trithio
For sodium carbonate 1.1%, sodium bisulfate 0.5%, sulphur 0.5%, zinc sulfate 2%, surplus Na2SO4•10H2O), 86kg chlorination
Sodium is stirred to react 60min under the conditions of room temperature (25 DEG C), and decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 5
(1) hydrogenperoxide steam generator that 280L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
(each ingredient of saltcake calculates 588kg saltcake according to weight percent are as follows: cellulose sulfonate 4%, microcrystalline cellulose 2%, three is thio
Sodium carbonate 1.5%, sodium bisulfate 0.7%, sulphur 0.6%, zinc sulfate 1.5%, surplus Na2SO4•10H2O), 80kg chlorination
Sodium is stirred to react 60min under the conditions of room temperature (25 DEG C), and decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 80 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 6
(1) hydrogenperoxide steam generator that 280L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
588kg saltcake (each ingredient of saltcake is calculated according to weight percent are as follows: cellulose sulfonate 3.5%, microcrystalline cellulose 2.3%, and three
Sodium thiocarbonate 1.5%, sodium bisulfate 0.5%, sulphur 1%, zinc sulfate 1.6%, surplus Na2SO4•10H2O), 80kg chlorination
Sodium is stirred to react 60min under the conditions of room temperature (25 DEG C), and decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 100 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 7
(1) hydrogenperoxide steam generator that 200L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
(each ingredient of saltcake calculates 420kg saltcake according to weight percent are as follows: cellulose sulfonate 4%, microcrystalline cellulose 3%, three is thio
Sodium carbonate 1.2%, sodium bisulfate 0.9%, sulphur 0.6%, zinc sulfate 1.5%, surplus Na2SO4•10H2O), 46kg chlorination
Sodium is stirred to react 60min under the conditions of room temperature (25 DEG C), and decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 8
(1) hydrogenperoxide steam generator that 250L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
(each ingredient of saltcake calculates 450kg saltcake according to weight percent are as follows: cellulose sulfonate 4.5%, microcrystalline cellulose 2%, trithio
For sodium carbonate 1%, sodium bisulfate 0.8%, sulphur 0.7%, zinc sulfate 1.1%, surplus Na2SO4•10H2O), 52kg chlorination
Sodium is stirred to react 50min under the conditions of room temperature (25 DEG C), and decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 100 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Comparative example 1
Compared to embodiment 4, saltcake is replaced to prepare conjugate using several pure raw material:
(1) hydrogenperoxide steam generator that 300L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
The Na of 568.9kg2SO4•10H2O, 18.9kg cellulose sulfonate, 16.3kg microcrystalline cellulose, 12.6kg zinc sulfate, 86kg chlorine
Change sodium, be stirred to react 60min under the conditions of room temperature (25 DEG C), decompression filters after reaction, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Comparative example 2
Compared to embodiment 4, saltcake is replaced to prepare conjugate using several pure raw material:
(1) hydrogenperoxide steam generator that 300L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
The Na of 568.9kg2SO4•10H2O, 18.9kg cellulose sulfonate, 16.3kg microcrystalline cellulose, 86kg sodium chloride, room temperature (25
DEG C) under the conditions of be stirred to react 60min, after reaction decompression filter, be separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Comparative example 3
Compared to embodiment 4, using pure Na2SO4•10H2O replaces saltcake to prepare conjugate:
(1) hydrogenperoxide steam generator that 300L mass fraction is 30% is first added in a kettle, is sequentially added under stirring
The Na of 568.9kg2SO4•10H2O and 86kg sodium chloride is stirred to react 60min under the conditions of room temperature (25 DEG C), depressurizes after reaction
It filters, is separated by solid-liquid separation；
(2) solid phase after step (1) separation is dried into 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
The bleachability of the various embodiments described above, comparative example products obtained therefrom is tested: it is freshly prepared to accurately weigh 10.000g
Adduct sodium sulphate-hydrogen peroxide-sodium chloride sample be placed in 250mL beaker, add 100ml water dissolve, heating water bath to 90
℃；Learn from else's experience and move back pure cotton fabric 10cm × 10cm for boiling and put into heat preservation leaching drift 60min in above-mentioned beaker, take out fabric, room temperature washing,
It dries, bleaching effect is tested using WSD-III full-automatic whiteness instrument: pure cotton fabric being converted into smooth 3 layers, measurement one
Average value is converted in 3 differences of block fabric.
Compare the whiteness of the adduct sodium sulphate-hydrogen peroxide-sodium chloride bleaching front and back fabric through each embodiment, it is specific to tie
Fruit is see table 1 (the benchmark whiteness before pure cotton fabric bleaching is set as 40):
W1Whiteness after pure cotton fabric bleaching,
W0Benchmark whiteness before pure cotton fabric bleaching.
The bleaching duration of the various embodiments described above, comparative example products obtained therefrom is tested:
It accurately weighs the freshly prepd adduct sodium sulphate-hydrogen peroxide-sodium chloride sample of 10.000g and is placed in 250mL beaker
In, add 100ml water to dissolve, is titrated to sample solution pinkiness with potassium permanganate standard titration solution and does not disappear in 60s
The volume of as terminal, consumed potassium permanganate standard titration solution is denoted as V0, unit (milliliter)；
Again by identical sample solution heating water bath to 90 DEG C, the pure cotton fabric 10cm × 10cm investment beaker for moving back and boiling of learning from else's experience
Middle heat preservation leaching drift 60min, takes out fabric, with sample solution after the titration bleaching of same potassium permanganate standard titration solution in pink
Color is not disappeared in 60s as terminal simultaneously, and the volume of consumed potassium permanganate standard titration solution is denoted as V at this time1, unit
(milliliter).Be calculated resolution ratio, concrete outcome see table 1,
Resolution ratio is below 85% after the bleaching of adduct prepared by the present invention, shows the present invention compared to using pure original
Expect that prepared product under equal conditions still maintains considerable active o content after use, it is seen that the decomposition of adduct
It significantly reduces, bleaching effective rate of utilization is high, duration is strong, stability is more preferable.
Test can be carried out to the anticaking capacity of the various embodiments described above, comparative example products obtained therefrom: using composed view method of testing,
25 DEG C of temperature, relative humidity 50% environment in, the sample of moisture content≤1% is poured into test funnel and flows to leakage
Bucket bottom, the height and base diameter of the cone that measurement sample is formed in funnel bottom, calculate cone oblique line and bottom is straight
Diameter angle, included angle is smaller, and powder flowbility is better,
Judgment criteria are as follows: 45 ° of composed view >, poor fluidity；35 °~45 ° mobility of composed view are medium；Composed view
35 ° of good fluidities of <.
The result shows that equal 35 ° of < of static angle, product mobility is preferable, agglomeration resistance after product briquetting stores 3~6 months
It has excellent performance, specifically see table 1.
Table 1
Claims (6)
1. a kind of method for preparing adduct sodium sulphate-hydrogen peroxide-sodium chloride using solid waste saltcake, it is characterised in that: described
Method is,
(1) solid waste saltcake, hydrogen peroxide and sodium chloride are mixed, is stirred to react 30~60min under room temperature, after reaction
Decompression filters, and is separated by solid-liquid separation；Wherein, it is cellulose that the ingredient for controlling the solid waste saltcake is calculated according to weight percent
Sulphonic acid ester 2%~5%, microcrystalline cellulose 2%~3%, trithiocarbonic acid sodium 1%~2%, sodium bisulfate 0.5%~1%, sulphur
Sulphur 0.5%~1%, zinc sulfate 1%~2%, surplus Na2SO4·10H2O；
(2) solid phase after step (1) separation is dried at 80~120 DEG C 60~90min, obtains sodium sulphate-hydrogen peroxide-chlorine
Change sodium adduct product.
2. the method that adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake as described in claim 1,
It is characterized in that: in step (1), according to sodium sulphate, hydrogen peroxide, sodium chloride when solid waste saltcake, hydrogen peroxide and sodium chloride mix
Three's molar ratio is 1.2~2.5:2.1~3.5:0.8~1.6.
3. the method that adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake as described in claim 1,
Be characterized in that: in step (1), the hybrid manipulation of solid waste saltcake, hydrogen peroxide and sodium chloride is to add solid waste saltcake and sodium chloride
Enter into aqueous hydrogen peroxide solution.
4. the method that adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake as claimed in claim 3,
Be characterized in that: the Solute mass fraction of the aqueous hydrogen peroxide solution is 30%.
5. the method that adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake as described in claim 1,
It is characterized in that: purity >=99.7% of sodium chloride described in step (1).
6. a kind of adduct sodium sulphate-hydrogen peroxide-sodium chloride obtained such as any one of claim 1 to 5 the method is answered
With, it is characterised in that: using adduct sodium sulphate-hydrogen peroxide-sodium chloride as bleaching agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610755880.2A CN106398908B (en) | 2016-08-26 | 2016-08-26 | A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610755880.2A CN106398908B (en) | 2016-08-26 | 2016-08-26 | A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106398908A CN106398908A (en) | 2017-02-15 |
| CN106398908B true CN106398908B (en) | 2018-12-14 |
Family
ID=58002536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610755880.2A Active CN106398908B (en) | 2016-08-26 | 2016-08-26 | A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106398908B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111109289A (en) * | 2019-12-31 | 2020-05-08 | 南京福斯特牧业科技有限公司 | Stable solid hydrogen peroxide adduct and application thereof in livestock and poultry and aquaculture fields |
| CN111771905B (en) * | 2020-06-18 | 2021-09-28 | 江苏南京农大动物药业有限公司 | Solid hydrogen peroxide and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3979312A (en) * | 1974-07-12 | 1976-09-07 | Kao Soap Co., Ltd. | Detergent composition containing novel bleaching agent |
| US4323465A (en) * | 1981-04-23 | 1982-04-06 | Fmc Corporation | Stabilized sodium sulfate-hydrogen peroxide-sodium chloride adduct and alkaline bleach composition containing same |
| US4618445A (en) * | 1983-05-19 | 1986-10-21 | Lever Brothers Company | Peroxide bleach and compositions comprising said bleach |
| CN103351961A (en) * | 2013-07-19 | 2013-10-16 | 常州工程职业技术学院 | Solid hydrogen peroxide preparation technology |
-
2016
- 2016-08-26 CN CN201610755880.2A patent/CN106398908B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3979312A (en) * | 1974-07-12 | 1976-09-07 | Kao Soap Co., Ltd. | Detergent composition containing novel bleaching agent |
| US4323465A (en) * | 1981-04-23 | 1982-04-06 | Fmc Corporation | Stabilized sodium sulfate-hydrogen peroxide-sodium chloride adduct and alkaline bleach composition containing same |
| US4618445A (en) * | 1983-05-19 | 1986-10-21 | Lever Brothers Company | Peroxide bleach and compositions comprising said bleach |
| CN103351961A (en) * | 2013-07-19 | 2013-10-16 | 常州工程职业技术学院 | Solid hydrogen peroxide preparation technology |
Non-Patent Citations (3)
| Title |
|---|
| 不同合成条件对硫酸钠-过氧化氢-氯化钠加合物产品产量和质量的影响;邱自力等;《沈阳农业大学学报》;20080430;第39卷(第2期);第254-256页 * |
| 硫酸钠-过氧化氢-氯化钠加合物的制备及应用;王鸿显等;《应用化工》;20040630;第33卷(第3期);第1-2页 * |
| 硫酸钠-过氧化氢-氯化钠加合物的研究现状及前景分析;李娟等;《江苏化工》;20031031;第31卷(第5期);第26页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106398908A (en) | 2017-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108640089B (en) | Continuous preparation equipment and preparation method of potassium peroxymonosulfate composite salt | |
| CN106398908B (en) | A method of adduct sodium sulphate-hydrogen peroxide-sodium chloride is prepared using solid waste saltcake | |
| CN103922378B (en) | Method for preparing high-purity metastable vaterite calcium carbonate from gypsum | |
| CN104725283B (en) | A kind of preparation method of trifluoromethanesulfonic acid | |
| CN101640268A (en) | Preparation method of precursor iron phosphate of cathode material lithium iron phosphate of lithium ion battery | |
| CN102583266A (en) | Preparation method of nanoscale stannic oxide hollow sphere | |
| CN105819480A (en) | Semi-dry process flue gas desulfurized ash modification treatment method | |
| CN103466637A (en) | Method for producing precipitate silicon dioxide by using sodium bicarbonate to control supersaturation degree | |
| CN103626222B (en) | A kind of preparation method of micron order tin dioxide powder | |
| CN108483456A (en) | A kind of activation of swelled ground | |
| CN104263014A (en) | Preparing method of high-purity active calcium carbonate used for coating | |
| CN102502669B (en) | Preparation method of nanometer silicon dioxide | |
| US20210047201A1 (en) | Method for preparing high-valence iron salt | |
| CN105016307B (en) | Preparation method of stable quick-dissolving sodium percarbonate | |
| DE102010034392B4 (en) | Stabilized chlorite reagent and thus prepared solid mixture for CIO2 production | |
| CN109650363A (en) | Full water-soluble industrial monoammonium phosphate anticaking agent and its application method | |
| CN110776477B (en) | Method for preparing DM by oxidizing M with hydrogen peroxide | |
| JPS5879804A (en) | Hydrogen peroxide adduct, its manufacture and active oxygen carrier consisting of said adduct | |
| KR100426926B1 (en) | Composite fertilizer comprising Bordeaux mixture, boron and molybdenum and manufacturing method thereof | |
| CN106186017A (en) | A kind of purification process of aluminium hydroxide powder | |
| US2222385A (en) | Manufacture of calcium sulphate | |
| CN104628018A (en) | Methods for preparing magnesium chloride hexahydrate for producing electrolytic magnesium | |
| CN107188227B (en) | A kind of preparation method of chromic anhybride and the chromic anhybride crystal grain being prepared | |
| CN109179352B (en) | Utilization method of chlorination by-product generated in preparation of phosphorus pentachloride | |
| CN109987590A (en) | Utilize the method for chlorination Calcium treatment titanium dioxide waste acid by sulfuric acid process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |