CN106398908A - Method for preparing sodium sulfate-hydrogen peroxide-sodium chloride adduct from solid waste mirabilite - Google Patents
Method for preparing sodium sulfate-hydrogen peroxide-sodium chloride adduct from solid waste mirabilite Download PDFInfo
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- CN106398908A CN106398908A CN201610755880.2A CN201610755880A CN106398908A CN 106398908 A CN106398908 A CN 106398908A CN 201610755880 A CN201610755880 A CN 201610755880A CN 106398908 A CN106398908 A CN 106398908A
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- hydrogen peroxide
- sodium chloride
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of inorganic salts, and especially relates to a method for preparing a sodium sulfate-hydrogen peroxide-sodium chloride adduct from solid waste mirabilite. The method concretely comprises the following steps: mixing mirabilite, hydrogen peroxide and sodium chloride, stirring and reacting above materials at room temperature for 30-60 min, carrying out reduced pressure suction filtration after the above reaction ends, and carrying out solid-liquid separation; and drying the obtained separated solid phase at 80-120 DEG C for 60-90 min in order to obtain the sodium sulfate-hydrogen peroxide-sodium chloride adduct.
Description
Technical field
The invention belongs to inorganic salts preparing technical field, particularly to one kind, sodium sulphate-peroxide is prepared using solid waste saltcake
The method changing hydrogen-sodium chloride adduct.
Background technology
Adduct sodium sulphate-hydrogen peroxide-sodium chloride is a kind of oxygen-containing washing assisant of neutral, nontoxic solid, is also one
Plant new oxygenation agent, disinfectant, bleaching assistant.Molecular formula is 4Na2SO4-2H2O2- NaCl, the mass fraction of hydrogen peroxide is
More than 9.2%, active o content is 4.6%.Due to 4Na2SO4-2H2O2The hydrogen peroxide that-NaCl generates after being dissolved in water occurs to divide
Solution, the elemental oxygen of releasing has bleaching, sterilization, decontamination and disinfective action, so having the property of hydrogen peroxide;It is dissolved in simultaneously
After water, pH value in aqueous is 6~8, close to neutral, frequently as detergent bleach auxiliary agent.
The production technology of traditional adduct sodium sulphate-hydrogen peroxide-sodium chloride mainly has following two:One kind is wet type
Preparation method, sodium sulphate, sodium chloride, stabilizer are dissolved in hydrogen peroxide, control the crystallization temperature worked as, are dried after separation to product
Product.Another is dry type preparation method, is stirred mediating by sodium sulphate, sodium chloride using mixer or kneader, uses simultaneously
Hydrogen peroxide sprays to mixture, prepared product.
Although adduct sodium sulphate-hydrogen peroxide-sodium chloride has plurality of advantages, when it is used as bleaching agent bleaching, deposit
In too fast, decomposition the phenomenon of decomposition rate, extra interpolation synergist or stabilizer is needed to slow down its decomposition rate;Should simultaneously
Product grains are tiny, and in production, dry, storage and transportation, crystal grain can be acted on due to crystal, be bonded to each other, go out
The phenomenon of existing product caking.
Saltcake, NaSO4·10H2O content >=85%, monoclinic system, generally in pelletized form, block, soluble in water, there is moisture absorption
Property.Chemical fibre factory or embrane method are removed chlor-alkali plant of nitre etc. and are had a common difficulty it is simply that the accessory substance saltcake producing does not have at present
There is market, remaining beneficial composition is all abandoned as waste, become new solid waste, in a large amount of saltcake accumulations and transportation very
Easily cause the problems such as soil and underground water pollution.The saltcake of particularly some by-products contains the Hubeiwans such as cellulose, therefore
How to reduce the environmental pollution that saltcake solid waste is brought, turn waste into wealth, increase operation rate, make the product of higher value, become
For people's concern.
Content of the invention
The technical problem to be solved is:There is particle size distribution in adduct sodium sulphate-hydrogen peroxide-sodium chloride
, when being used simultaneously as bleaching assistant bleaching, there is too fast, decomposition the phenomenon of decomposition rate, need volume in the shortcomings of differ from, easily lump
Outer interpolation synergist or stabilizer slow down its decomposition rate, cause the increase of cost.
The present invention replaces traditional sodium sulphate as the raw material of reaction using the solid waste saltcake doped with impurity, prepared by two-step method
Adduct sodium sulphate-hydrogen peroxide-sodium chloride, when being used as bleaching assistant with the adduct product that this raw material is prepared, bleaching is steady
Qualitative decomposition that is higher, effectively inhibiting adduct product, improves bleaching utilization rate;This Granularity Distribution is equal simultaneously
Even, autonomous resistive connection block effect is good, solves that current saltcake solid waste environmental pollution is serious, the low problem of resource utilization, very simultaneously
The good cost reducing raw material in traditional preparation method.
In order to achieve the above object, the present invention adopts the following technical scheme that:
(1) sodium sulphate, hydrogen peroxide, sodium chloride three's mol ratio 1.2~2.5 are pressed:2.1~3.5:0.8~1.6, by awns
Nitre, hydrogen peroxide and sodium chloride mixing, stirring reaction 30~60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating,
Carry out separation of solid and liquid,
Wherein, the married operation of saltcake, hydrogen peroxide and sodium chloride is, saltcake and sodium chloride are added to aquae hydrogenii dioxidi
In solution,
Wherein, saltcake composition calculates according to percetage by weight, needs to be controlled to:Cellulose sulfonate 2%~5%, crystallite
Cellulose 2%~3%, trithiocarbonic acid sodium 1%~2%, niter cake 0.5%~1%, sulphur 0.5%~1%, zinc sulfate
1%~2%, balance of NaSO4·10H2O,
In the presence of cellulose sulfonate, microcrystalline cellulose, zinc sulfate are with above-mentioned content, can at utmost improve sodium sulphate-
The mobility of hydrogen peroxide-sodium chloride adduct, strengthens its anti-caking performance, main reason is that cellulose sulfonate contains ester
Base, this group has hydrophobicity, and the polysaccharide polymer structure of cellulose sulfonate and microcrystalline cellulose can be adsorbed in adduction simultaneously
Thing surface forms hydrophobic layer, hinders the exchange of adduct and moisture in air, can effectively prevent adduct from luming;Except this with
Outward, the synergy between each composition and adduct, effectively inhibits the too fast decomposition of adduct, slows down it to being bleached
The radical response of thing, improves its effective, lasting utilization rate,
If trithiocarbonic acid sodium content be higher than 2%, generate hydrate because it is highly soluble in water, can affect sodium sulphate-
The anti-caking performance of hydrogen peroxide-sodium chloride adduct, simultaneously niter cake there is hygroscopicity, content also must control 1%
Within,
Wherein, the Solute mass fraction of aqueous hydrogen peroxide solution is 30%, purity >=99.7% of NaCl in sodium chloride;
(2) solid phase after separating step (1) dries 60~90min at 80~120 DEG C, obtains sodium sulphate-peroxidating
Hydrogen-sodium chloride adduct product.
Present invention also offers a kind of adduct sodium sulphate-hydrogen peroxide-sodium chloride that obtains of above-mentioned preparation method should
With, will adduct sodium sulphate-hydrogen peroxide-sodium chloride as bleaching agent.
The present invention compared with prior art has following advantages and effect:
(1) present invention provides a kind of solid waste saltcake to be used as adduct sodium sulphate-hydrogen peroxide-sodium chloride raw materials for production, system
, as resolution ratio < during bleaching assistant 85%, effective rate of utilization is high, stability is preferable, through the pure cotton fabric after bleaching for the finished product becoming
Brightness gain >=50%, 35 ° of static angle < in resistive connection test simultaneously, preferably, autonomous anti-caking performance is excellent for product mobility
Different.
(2) saltcake is replaced traditional anhydrous sodium sulfate to be applied to prepare product by the present invention, and saltcake gives up for common industrial
Gurry, so turns waste into wealth it is achieved that the recycling of mirabilite resource.
(3) present invention makes full use of the particularity of raw material feature and process, significantly reduces production cost, is suitable for
Use in heavy industrialization.
Specific embodiment
Embodiment 1
(1) it is initially charged the hydrogenperoxide steam generator that 200L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 420kg saltcake:Cellulose sulfonate 4%, microcrystalline cellulose 2%, three are thio
Sodium carbonate 1%, niter cake 0.5%, sulphur 0.8%, zinc sulfate 1.5%, balance of NaSO4·10H2O), 46kg sodium chloride,
Stirring reaction 60min under the conditions of room temperature (25 DEG C), reacts the suction filtration that reduces pressure after terminating, carries out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 100 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 2
(1) it is initially charged the hydrogenperoxide steam generator that 250L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 450kg saltcake:Cellulose sulfonate 5%, microcrystalline cellulose 2%, three is thio
Sodium carbonate 1.2%, niter cake 0.6%, sulphur 1%, zinc sulfate 1.2%, balance of NaSO4·10H2O), 52kg sodium chloride,
Stirring reaction 50min under the conditions of room temperature (25 DEG C), reacts the suction filtration that reduces pressure after terminating, carries out separation of solid and liquid;
(2) solid phase after separating step (1) dries 80min at 90 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 3
(1) it is initially charged the hydrogenperoxide steam generator that 220L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 430kg saltcake:Cellulose sulfonate 2.5%, microcrystalline cellulose 2.5%, three
Sodium thiocarbonate 1%, niter cake 1%, sulphur 0.7%, zinc sulfate 1.8%, balance of NaSO4·10H2O), 50kg chlorination
Sodium, stirring reaction 60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 4
(1) it is initially charged the hydrogenperoxide steam generator that 300L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 630kg saltcake:Cellulose sulfonate 3%, microcrystalline cellulose 2.6%, trithio
For sodium carbonate 1.1%, niter cake 0.5%, sulphur 0.5%, zinc sulfate 2%, balance of NaSO4·10H2O), 86kg chlorination
Sodium, stirring reaction 60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 5
(1) it is initially charged the hydrogenperoxide steam generator that 280L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 588kg saltcake:Cellulose sulfonate 4%, microcrystalline cellulose 2%, three is thio
Sodium carbonate 1.5%, niter cake 0.7%, sulphur 0.6%, zinc sulfate 1.5%, balance of NaSO4·10H2O), 80kg chlorination
Sodium, stirring reaction 60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 80 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 6
(1) it is initially charged the hydrogenperoxide steam generator that 280L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 588kg saltcake:Cellulose sulfonate 3.5%, microcrystalline cellulose 2.3%, three
Sodium thiocarbonate 1.5%, niter cake 0.5%, sulphur 1%, zinc sulfate 1.6%, balance of NaSO4·10H2O), 80kg chlorination
Sodium, stirring reaction 60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 100 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 7
(1) it is initially charged the hydrogenperoxide steam generator that 200L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 420kg saltcake:Cellulose sulfonate 4%, microcrystalline cellulose 3%, three is thio
Sodium carbonate 1.2%, niter cake 0.9%, sulphur 0.6%, zinc sulfate 1.5%, balance of NaSO4·10H2O), 46kg chlorination
Sodium, stirring reaction 60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Embodiment 8
(1) it is initially charged the hydrogenperoxide steam generator that 250L mass fraction is 30% in a kettle., sequentially add under stirring
(each composition of saltcake calculates according to percetage by weight and is 450kg saltcake:Cellulose sulfonate 4.5%, microcrystalline cellulose 2%, trithio
For sodium carbonate 1%, niter cake 0.8%, sulphur 0.7%, zinc sulfate 1.1%, balance of NaSO4·10H2O), 52kg chlorination
Sodium, stirring reaction 50min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 100 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Comparative example 1
Compared to embodiment 4, saltcake is replaced to prepare conjugate using several pure raw material:
(1) it is initially charged the hydrogenperoxide steam generator that 300L mass fraction is 30% in a kettle., sequentially add under stirring
The NaSO of 568.9kg4·10H2O, 18.9kg cellulose sulfonate, 16.3kg microcrystalline cellulose, 12.6kg zinc sulfate, 86kg chlorine
Change sodium, stirring reaction 60min under the conditions of room temperature (25 DEG C), react the suction filtration that reduces pressure after terminating, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Comparative example 2
Compared to embodiment 4, saltcake is replaced to prepare conjugate using several pure raw material:
(1) it is initially charged the hydrogenperoxide steam generator that 300L mass fraction is 30% in a kettle., sequentially add under stirring
The NaSO of 568.9kg4·10H2O, 18.9kg cellulose sulfonate, 16.3kg microcrystalline cellulose, 86kg sodium chloride, room temperature (25
DEG C) under the conditions of stirring reaction 60min, reaction terminate after reduce pressure suction filtration, carry out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
Comparative example 3
Compared to embodiment 4, using pure NaSO4·10H2O replaces saltcake to prepare conjugate:
(1) it is initially charged the hydrogenperoxide steam generator that 300L mass fraction is 30% in a kettle., sequentially add under stirring
The NaSO of 568.9kg4·10H2O and 86kg sodium chloride, stirring reaction 60min under the conditions of room temperature (25 DEG C), reaction is reduced pressure after terminating
Suction filtration, carries out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60min at 120 DEG C, obtains sodium sulphate-hydrogen peroxide-sodium chloride
Adduct product.
The bleachability of the various embodiments described above, comparative example products obtained therefrom is tested:Accurately weigh 10.000g freshly prepared
Adduct sodium sulphate-hydrogen peroxide-sodium chloride sample be placed in 250mL beaker, plus 100ml water dissolves, heating water bath to 90
℃;Learn from else's experience and move back the pure cotton fabric 10cm that boils × 10cm and put into insulation leaching drift 60min in above-mentioned beaker, take out fabric, room temperature washing,
Dry, using WSD-III full-automatic whiteness instrument, bleaching effect is tested:Pure cotton fabric is converted into smooth 3 layers, measures one
3 differences of block fabric, convert mean value.
The whiteness of fabric, concrete knot before and after adduct sodium sulphate-hydrogen peroxide-sodium chloride bleaching relatively through each embodiment
Fruit asks for an interview table 1 (the benchmark whiteness before pure cotton fabric bleaching is set as 40):
W1Whiteness after the bleaching of-pure cotton fabric,
W0Benchmark whiteness before the bleaching of-pure cotton fabric.
The bleaching continuation of the various embodiments described above, comparative example products obtained therefrom is tested:
Accurately weigh 10.000g freshly prepd adduct sodium sulphate-hydrogen peroxide-sodium chloride sample and be placed in 250mL beaker
In, plus 100ml water dissolves, it is titrated to sample solution pinkiness with potassium permanganate standard titration solution and do not disappear in 60s
It is terminal, the volume of the potassium permanganate standard titration solution being consumed is designated as V0, unit (milliliter);
Again by identical sample solution heating water bath to 90 DEG C, learn from else's experience and move back the pure cotton fabric 10cm × 10cm input beaker boiling
Middle insulation leaching drift 60min, takes out fabric, is in pink with sample solution after same potassium permanganate standard titration solution titration bleaching
Color does not simultaneously disappear as terminal in 60s, and the volume of the potassium permanganate standard titration solution now being consumed is designated as V1, unit
(milliliter).It is calculated resolution ratio, concrete outcome asks for an interview table 1,
After adduct bleaching prepared by the present invention, resolution ratio is below 85%, shows the present invention compared to using pure former
Considerable active o content is still maintained it is seen that the decomposition of adduct after product under equal conditions uses prepared by material
Significantly reduce, bleaching effective rate of utilization is high, continuation is strong, stability is more preferable.
The anti-caking performance of the various embodiments described above, comparative example products obtained therefrom is tested:Using composed view method of testing,
In 25 DEG C of temperature, the environment of relative humidity 50%, the sample of moisture≤1% is poured in test funnel and flows to leakage
Bucket bottom, the height of cone and base diameter that measurement sample is formed in funnel bottom, calculate cone oblique line and bottom is straight
Footpath angle, angle angle is less, and powder flowbility is better,
Criterion is:45 ° of composed view >, poor fluidity;35 °~45 ° mobility of composed view are medium;Composed view
35 ° of good fluidities of <.
After result shows that product briquetting stores 3~6 months, 35 ° of the equal < of static angle, product mobility preferably, agglomeration resistance
Excellent performance, specifically asks for an interview table 1.
Table 1
Embodiment | Brightness gain (%) | Bleaching resolution ratio (%) | Composed view (°) |
1 | 50.7 | 84.3 | (after briquetting stores 3 months) 32 |
2 | 50.0 | 83.2 | (after briquetting stores 4 months) 34 |
3 | 51.4 | 83.4 | (after briquetting stores 5 months) 34 |
4 | 50.0 | 82.6 | (after briquetting stores 6 months) 29 |
5 | 50.6 | 82.1 | (after briquetting stores 3 months) 33 |
6 | 51.0 | 82.4 | (after briquetting stores 4 months) 30 |
7 | 50.4 | 82.8 | (after briquetting stores 5 months) 33 |
8 | 51.2 | 83.1 | (after briquetting stores 6 months) 32 |
Comparative example 1 | 50.0 | 98.4 | (after briquetting stores 6 months) 30 |
Comparative example 2 | 50.0 | 98.8 | (after briquetting stores 6 months) 38 |
Comparative example 3 | 50.0 | 98.6 | (after briquetting stores 6 months) 52 |
Claims (7)
1. a kind of using solid waste saltcake prepare adduct sodium sulphate-hydrogen peroxide-sodium chloride method it is characterised in that:Described
Method is,
(1) saltcake, hydrogen peroxide and sodium chloride are mixed, stirring reaction 30~60min under room temperature condition, reaction is reduced pressure after terminating
Suction filtration, carries out separation of solid and liquid;
(2) solid phase after separating step (1) dries 60~90min at 80~120 DEG C, obtains sodium sulphate-hydrogen peroxide-chlorine
Change sodium adduct product.
2. the method as claimed in claim 1 adduct sodium sulphate-hydrogen peroxide-sodium chloride being prepared using solid waste saltcake, its
It is characterised by:In step (1), according to sodium sulphate, hydrogen peroxide, sodium chloride three when saltcake, hydrogen peroxide and sodium chloride mixing
Mol ratio is 1.2~2.5:2.1~3.5:0.8~1.6.
3. the method as claimed in claim 1 adduct sodium sulphate-hydrogen peroxide-sodium chloride being prepared using solid waste saltcake, its
It is characterised by:In step (1), the composition of described saltcake is controlled to calculate according to percetage by weight and be, cellulose sulfonate 2%~
5%, microcrystalline cellulose 2%~3%, trithiocarbonic acid sodium 1%~2%, niter cake 0.5%~1%, sulphur 0.5%~
1%, zinc sulfate 1%~2%, balance of NaSO4·10H2O.
4. the method as claimed in claim 1 adduct sodium sulphate-hydrogen peroxide-sodium chloride being prepared using solid waste saltcake, its
It is characterised by:In step (1), the married operation of saltcake, hydrogen peroxide and sodium chloride is that saltcake and sodium chloride are added to peroxide
Change in aqueous solution of hydrogen.
5. the method as claimed in claim 4 adduct sodium sulphate-hydrogen peroxide-sodium chloride being prepared using solid waste saltcake, its
It is characterised by:The Solute mass fraction of described aqueous hydrogen peroxide solution is 30%.
6. the method as claimed in claim 1 adduct sodium sulphate-hydrogen peroxide-sodium chloride being prepared using solid waste saltcake, its
It is characterised by:Purity >=99.7% of sodium chloride described in step (1).
7. a kind of adduct sodium sulphate-hydrogen peroxide-sodium chloride obtaining as claim 1 to 6 any one methods described should
With it is characterised in that:Using adduct sodium sulphate-hydrogen peroxide-sodium chloride as bleaching agent.
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Cited By (2)
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CN111109289A (en) * | 2019-12-31 | 2020-05-08 | 南京福斯特牧业科技有限公司 | Stable solid hydrogen peroxide adduct and application thereof in livestock and poultry and aquaculture fields |
WO2021253598A1 (en) * | 2020-06-18 | 2021-12-23 | 江苏南京农大动物药业有限公司 | Solid hydrogen peroxide and preparation method therefor and use thereof |
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CN111109289A (en) * | 2019-12-31 | 2020-05-08 | 南京福斯特牧业科技有限公司 | Stable solid hydrogen peroxide adduct and application thereof in livestock and poultry and aquaculture fields |
WO2021253598A1 (en) * | 2020-06-18 | 2021-12-23 | 江苏南京农大动物药业有限公司 | Solid hydrogen peroxide and preparation method therefor and use thereof |
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