CN108690513A - A kind of viscous waterproof roll of HDPE reactions - Google Patents
A kind of viscous waterproof roll of HDPE reactions Download PDFInfo
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- CN108690513A CN108690513A CN201710159370.3A CN201710159370A CN108690513A CN 108690513 A CN108690513 A CN 108690513A CN 201710159370 A CN201710159370 A CN 201710159370A CN 108690513 A CN108690513 A CN 108690513A
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- hdpe
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
- C09J2301/208—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being constituted by at least two or more adjacent or superposed adhesive layers, e.g. multilayer adhesive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
- C09J2423/046—Presence of homo or copolymers of ethene in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2453/00—Presence of block copolymer
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/005—Presence of polyester in the release coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2491/00—Presence of oils, fats or waxes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of HDPE to react viscous waterproof roll, and it includes separation layer, inviscid film layer, self-adhesive glue layer and carcass successively that the HDPE reactions, which glue waterproof roll from top to bottom,;The separation layer is linear saturated polyester's resin isolation film;The inviscid film layer is made of following components according to mass percentage content:Acrylic emulsions 80%~95%, alcohol organic solvent 4%~20% and A reaction promoters 0.3%~1%;The self-adhesive glue layer is made of strong bond type hot-fusible pressure-sensitive adhesive and B reaction promoters, and the content of the B reaction promoters is 0.3%~1%;The carcass is HDPE homogeneous sheet layers;The A reaction promoters and the B reaction promoters are silane coupling agent.The peel strength that waterproof roll is glued in the HDPE reactions is much larger than common HDPE adhesive waterproof coils, and constructs and be easy, will not bond construction personnel.
Description
Technical field
The present invention relates to a kind of HDPE to react viscous waterproof roll, belongs to waterproof roll field.
Background technology
Since 21 century, subway sectional tunnel waterproof roll paving construction mostly uses pre-installed and inverted adhered construction technology.It is overlaying
When anti-viscous construction, removing surface isolation film is needed then thereon by pouring concrete after the liquid just mixed to be poured after mixed
Solidifying soil solidification.Nowadays it after tearing isolation film off, since the hot-fusible pressure-sensitive adhesive caking property of adhesive linkage is too strong, is easy to bond constructor
Member, inconvenience is caused to site operation.
It is therefore desirable to design a kind of viscous waterproof roll of HDPE reactions, to overcome the above problem.
Invention content
It is an object of the invention to overcome the defect of the prior art, provide a kind of peel strength much larger than common HDPE from
Viscous waterproof roll, and waterproof roll is glued in HDPE reactions that are easy, will not bonding construction personnel of constructing.
The invention is realized in this way:
The present invention provides a kind of viscous waterproof roll of HDPE reactions, and the HDPE reactions are glued waterproof roll and wrapped successively from top to bottom
Include separation layer, inviscid film layer, self-adhesive glue layer and carcass;
The separation layer is linear saturated polyester's resin isolation film;
The inviscid film layer is made of following components according to mass percentage content:Acrylic emulsions 80%~
95%, alcohol organic solvent 4%~20% and A reaction promoters 0.3%~1%;
The self-adhesive glue layer is made of strong bond type hot-fusible pressure-sensitive adhesive and B reaction promoters, the content of the B reaction promoters
It is 0.3%~1%, wherein the strong bond type hot-fusible pressure-sensitive adhesive is composed of the following components according to parts by weight:Diblock
21-37 parts of SDS thermoplastic elastomer (TPE)s, 2-6 parts of SIS thermoplastic elastomer (TPE)s, 35-50 parts of C 5 petroleum resin, 3-5 parts of bulking agent,
1-4 parts of 4-5 parts of tackifier, 1-15 parts of polyisobutene, 10-25 parts of naphthenic oil and antiaging agent;
The carcass is HDPE homogeneous sheet layers;
The A reaction promoters and the B reaction promoters are silane coupling agent.
Further, the acrylic emulsions are the hydrophilic monomers by hydrophobic monomer and long-chain, in initiator
Under effect, it is made by emulsion polymerization.
Further, the hydrophobic monomer is methyl methacrylate, and the hydrophilic monomer of the long-chain is acrylic acid
Butyl ester or Isooctyl acrylate monomer or esters of acrylic acid, the initiator are potassium peroxydisulfate or ammonium persulfate.
Further, the alcohol organic solvent is one kind in ethyl alcohol, propyl alcohol and ethylene glycol or arbitrary several combination.
The invention has the advantages that:
The HDPE reactions glue waterproof roll and are followed successively by separation layer, inviscid film layer, self-adhesive glue layer and tire from top to bottom
Body, the peel strength that waterproof roll is glued in HDPE reaction are much larger than common HDPE adhesive waterproof coils, and construct and be easy, will not
Bond construction personnel.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
All other embodiment that technical staff is obtained without making creative work belongs to what the present invention protected
Range.
The embodiment of the present invention provides a kind of viscous waterproof roll of HDPE reactions, and the HDPE reactions glue waterproof roll from top to bottom
Include separation layer, inviscid film layer, self-adhesive glue layer and carcass successively.
The separation layer is linear saturated polyester's resin isolation film, has wax on one side, on one side without wax.There are the one side and nothing of wax
Sticky film layer fits together.
The inviscid film layer is made of following components according to mass percentage content:Acrylic emulsions 80%~
95%, alcohol organic solvent 4%~20% and A reaction promoters 0.3%~1%, the A reaction promoters are silane coupling agent.
In this preferred embodiment, the alcohol organic solvent is one kind or arbitrary several combination in ethyl alcohol, propyl alcohol and ethylene glycol.Institute
It is the hydrophilic monomer by hydrophobic monomer and long-chain to state acrylic emulsions, under the action of initiator, by emulsion polymerization
And it is made, 50% or more manufactured acrylic emulsions solid content, lotion pH=6-8.Further, the hydrophobic monomer
For methyl methacrylate, the hydrophilic monomer of the long-chain is butyl acrylate or Isooctyl acrylate monomer or esters of acrylic acid,
The initiator is potassium peroxydisulfate or ammonium persulfate.Its bonding mechanism is:The hydroxide in carboxylate radical and concrete in lotion
Calcium reacts, and complex reaction occurs for the calcium ion in the calcium acrylate and concrete of generation, forms complexing chemical bond, A reaction promoters
Also reacted with the gel layer in concrete, formed ehter bond, larger polar group also can in concrete calcium ion, silicon from
Son reaction, forms hydrogen bond, provides a large amount of intermolecular forces, film layer is enable firmly to be adhered on concrete layer.
The self-adhesive glue layer is made of strong bond type hot-fusible pressure-sensitive adhesive and B reaction promoters, the content of the B reaction promoters
It is 0.3%~1%, the B reaction promoters are silane coupling agent.Wherein, the strong bond type hot-fusible pressure-sensitive adhesive is according to weight
Number is composed of the following components:21-37 parts of diblock SDS thermoplastic elastomer (TPE)s, 2-6 parts of SIS thermoplastic elastomer (TPE)s, light dydrocarbon oil
35-50 parts of resin, 3-5 parts of bulking agent, 4-5 parts of tackifier, 1-15 parts of polyisobutene, 10-25 parts of naphthenic oil and antiaging agent 1-4
Part.SDS refers to so that polystyrene chain segment (S) is constituted hard section, polydiene (D) is formed by triblock copolymer as soft segment
(S-D-S), soft segment is polyisoprene (I), then referred to as SIS.The shore hardness (A) >=60 of the SIS thermoplastic elastomer (TPE)s,
Can equally make strong bond type hot-fusible pressure-sensitive adhesive not only with plastics meltability and thermoplasticity, but also with rubber elasticity with it is tough
Property.The C 5 petroleum resin is No. 0 color aliphatic, and softening point is 95 DEG C~110 DEG C, and HDPE waterproof rolls can be made to have
There is good construction temperature, hot-fusible pressure-sensitive adhesive caking property is made to improve.The bulking agent is water white aliphatic petroleum resin, soft
It is 90 DEG C~125 DEG C to change point, can adjust the glass transition temperature of C 5 petroleum resin, product construction temperature is made to broaden.Institute
It is highly polar tackifying resin to state tackifier, and capable of making strong bond type hot-fusible pressure-sensitive adhesive, peel strength keeps good at normal temperatures.
The antiaging agent is by phenolic antioxidant, phosphorous acid esters auxiliary antioxidant and to absorb the anti-of 240~340nm ultraviolet lights
A kind of compound antiaging agent that aging agent is formed helps to reduce color and luster, delays yellowing and retardance loss of physical properties, protects
Double bond and carboxyl in elastomer or tackifying resin has been demonstrate,proved to be not easy to be aoxidized and changed colour.
The bonding mechanism of the self-adhesive glue layer is the hole of strong bond type hot-fusible pressure-sensitive adhesive glue penetration concrete surface
In, so that glue is reached the contact of molecular level, the oxidation generated in polar group and concrete that B reaction promoters provide with concrete
The oxides such as iron, silica react, and form covalent bond, and glue-line is made to form network structure with concrete layer, make glue-line also can jail
Solid be adhered on concrete layer.
The carcass is HDPE (high density polyethylene (HDPE)) homogeneous sheet layer, can reinforce HDPE reactions and glue the strong of waterproof roll
Degree.
The Contrast on effect table that waterproof roll and common HDPE waterproof rolls are glued in HDPE reactions provided by the invention is as follows:
In conclusion the HDPE reactions glue waterproof roll and are followed successively by separation layer, inviscid film layer, self-adhesion from top to bottom
Glue-line and carcass, the peel strength that waterproof roll is glued in the HDPE reactions is much larger than common HDPE adhesive waterproof coils, and constructs
It is easy, construction personnel will not be bonded.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (4)
1. waterproof roll is glued in a kind of HDPE reactions, which is characterized in that the HDPE reactions are glued waterproof roll and wrapped successively from top to bottom
Include separation layer, inviscid film layer, self-adhesive glue layer and carcass;
The separation layer is linear saturated polyester's resin isolation film;
The inviscid film layer is made of following components according to mass percentage content:Acrylic emulsions 80% ~ 95%, alcohols
Organic solvent 4% ~ 20% and A reaction promoters 0.3% ~ 1%;
The self-adhesive glue layer is made of strong bond type hot-fusible pressure-sensitive adhesive and B reaction promoters, and the content of the B reaction promoters is
0.3% ~ 1%, wherein the strong bond type hot-fusible pressure-sensitive adhesive is composed of the following components according to parts by weight:Diblock SDS thermoplastics
21-37 parts of elastomer of property, 2-6 parts of SIS thermoplastic elastomer (TPE)s, 35-50 parts of C 5 petroleum resin, 3-5 parts of bulking agent, tackifier 4-
1-4 parts of 5 parts, 1-15 parts of polyisobutene, 10-25 parts of naphthenic oil and antiaging agent;
The carcass is HDPE homogeneous sheet layers;
The A reaction promoters and the B reaction promoters are silane coupling agent.
2. waterproof roll is glued in HDPE reactions as described in claim 1, it is characterised in that:The acrylic emulsions are by hydrophobic
The hydrophilic monomer of property monomer and long-chain is made under the action of initiator by emulsion polymerization.
3. waterproof roll is glued in HDPE reactions as claimed in claim 2, it is characterised in that:The hydrophobic monomer is metering system
The hydrophilic monomer of sour methyl esters, the long-chain is butyl acrylate or Isooctyl acrylate monomer or esters of acrylic acid, the initiator
For potassium peroxydisulfate or ammonium persulfate.
4. waterproof roll is glued in HDPE reactions as claimed in claim 1 or 2, it is characterised in that:The alcohol organic solvent is second
One kind in alcohol, propyl alcohol and ethylene glycol or arbitrary several combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710159370.3A CN108690513A (en) | 2017-03-17 | 2017-03-17 | A kind of viscous waterproof roll of HDPE reactions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710159370.3A CN108690513A (en) | 2017-03-17 | 2017-03-17 | A kind of viscous waterproof roll of HDPE reactions |
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| Publication Number | Publication Date |
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| CN108690513A true CN108690513A (en) | 2018-10-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710159370.3A Pending CN108690513A (en) | 2017-03-17 | 2017-03-17 | A kind of viscous waterproof roll of HDPE reactions |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881359A (en) * | 2021-06-18 | 2022-01-04 | 北京东方雨虹防水技术股份有限公司 | Waterproof coiled material and preparation method and construction method thereof |
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| WO2011041263A1 (en) * | 2009-09-30 | 2011-04-07 | W.R. Grace & Co.-Conn. | Waterproofing membrane |
| CN102993946A (en) * | 2012-12-11 | 2013-03-27 | 天津灯塔涂料工业发展有限公司 | Waterborne fluorine silicone resin modified acrylic acid concrete protective coating |
| CN103214998A (en) * | 2013-04-17 | 2013-07-24 | 岳阳东方雨虹防水技术有限责任公司 | Preparation method of high-temperature resistant hot-melt pressure-sensitive adhesive |
| CN103358635A (en) * | 2013-07-19 | 2013-10-23 | 北京东方雨虹防水技术股份有限公司 | Waterproof coiled material having pre-laid anti-sticking function and preparation method thereof |
-
2017
- 2017-03-17 CN CN201710159370.3A patent/CN108690513A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011041263A1 (en) * | 2009-09-30 | 2011-04-07 | W.R. Grace & Co.-Conn. | Waterproofing membrane |
| CN102993946A (en) * | 2012-12-11 | 2013-03-27 | 天津灯塔涂料工业发展有限公司 | Waterborne fluorine silicone resin modified acrylic acid concrete protective coating |
| CN103214998A (en) * | 2013-04-17 | 2013-07-24 | 岳阳东方雨虹防水技术有限责任公司 | Preparation method of high-temperature resistant hot-melt pressure-sensitive adhesive |
| CN103358635A (en) * | 2013-07-19 | 2013-10-23 | 北京东方雨虹防水技术股份有限公司 | Waterproof coiled material having pre-laid anti-sticking function and preparation method thereof |
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| 吴毅等: "高分子防水卷材用反应型自粘胶的研制", 《中国胶粘剂》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881359A (en) * | 2021-06-18 | 2022-01-04 | 北京东方雨虹防水技术股份有限公司 | Waterproof coiled material and preparation method and construction method thereof |
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Application publication date: 20181023 |
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| RJ01 | Rejection of invention patent application after publication |