CN108690431A - A kind of multifunction green environment protection type nano paint - Google Patents

A kind of multifunction green environment protection type nano paint Download PDF

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Publication number
CN108690431A
CN108690431A CN201710102288.7A CN201710102288A CN108690431A CN 108690431 A CN108690431 A CN 108690431A CN 201710102288 A CN201710102288 A CN 201710102288A CN 108690431 A CN108690431 A CN 108690431A
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CN
China
Prior art keywords
nano
calcium carbonate
agent
titanium dioxide
environment protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710102288.7A
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Chinese (zh)
Inventor
刘从荡
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Individual
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Individual
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Publication date
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Priority to CN201710102288.7A priority Critical patent/CN108690431A/en
Publication of CN108690431A publication Critical patent/CN108690431A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of multifunction green environment protection type nano paint, main ingredient(Weight percent)For:Methacrylic acid, butyl acrylate, styrene and methyl methacrylate quadripolymer latex 20~65%;Nano-titanium dioxide 0.3~5%;Nano zine oxide 0.2~3%;Nano silicon dioxide 0.3~3%;Nano-calcium carbonate 0.5~5%;Deionized water 3~12%;Superfine talcum powder 1~3%;Calcium carbonate superfine powder 3~15%;Titanium dioxide 3~25%;The auxiliary agents such as dispersant, wetting agent, rheological agent, thickener, mill base, antifoaming agent 2~12%, this nano paint produced using this formula has the characteristics that nontoxic, pollution-free, washability, damage resistant, UV resistant, ageing-resistant, waterproof, mould proof, and also there is self-cleaning function, which is widely used in the surface anticorrosion processing of the decoration and metal material of various inner, external walls.

Description

A kind of multifunction green environment protection type nano paint
Technical field
The present invention relates to a kind of multifunction green environment protection type nano paints.
Background technology
The kind that market is coated is more, but generally there is have a single function (to be only applicable to the dress of wall for these coating Decorations) and coating not damage resistant the defects of.
Invention content
The object of the present invention is to provide a kind of waterproof, mould proof, washability, damage resistant, it is ageing-resistant, nontoxic, pollution-free and A kind of multifunction green environment protection type nanometer painting for being not only suitable for wall body decoration and being suitable for anti-corrosion of metal again with self-cleaning function Material.
In order to achieve the above object, a kind of multifunction green environment protection type nano paint of the invention is mainly by metering system Acid, butyl acrylate, styrene and methyl methacrylate quadripolymer latex be equipped with nano-titanium dioxide, nano zine oxide, Nano silicon dioxide and nano-calcium carbonate are formed.It specifically matches (weight percent):Methacrylic acid, acrylic acid fourth Ester, styrene and methyl methacrylate quadripolymer latex 20~65%;Nano-titanium dioxide 0.3~5%;It is nano oxidized Zinc 0.2~3%;Nano silicon dioxide 0.3~3%;Nano-calcium carbonate 0.5~5%;Deionized water 3~12%;Extra fine talc Powder 1~3%;Calcium carbonate superfine powder 3~15%;Titanium dioxide 3~25%;Dispersant, rheological agent, thickener, mill base, disappears at wetting agent The auxiliary agents such as infusion 2~12%.
The present invention specific method and facilities be:By deionized water, dispersant, moistening temperature agent, rheological agent, antifoaming agent (part) Equal auxiliary agents are added in dispersion machine, are opened dispersion machine, are then successively delayed superfine talcum powder and calcium carbonate superfine powder and titanium dioxide Slow to be added in dispersion machine, the material in dispersion machine was sent into grinder with pump and is ground after 30 minutes by high speed dispersion.From grinding The material flowed out in machine enters intermediate storage tank, if necessary requirement is not achieved into the material size in intermediate storage tank, uses Pump, which is sent in grinder, to be regrind, until reaching necessary requirement.
By methacrylic acid, butyl acrylate, styrene, methyl methacrylate quadripolymer latex and thickener, color Slurry and part antifoaming agent are added in blend tank, open the stirring slurry of blend tank, under stiring, successively slowly into blend tank Nano-titanium dioxide, nano zine oxide, nano silicon dioxide and nano-calcium carbonate is added, it, will be intermediate with pump after stirring 30 minutes Material in storage tank is slowly added in blend tank, continues stirring 30 minutes, then sampling and testing, if qualification can spout bag Dress.
The beneficial effects of the invention are as follows:Methacrylic acid, butyl acrylate, styrene and methyl methacrylate quaternary Copolymer emulsion has excellent film-formation result, and the coating of its coating can be made to have the effect of waterproof, damage resistant, four kinds of nanometers Material is used cooperatively, make its coating have excellent hydrophily, photocatalytic, water proofing property, stain resistance, resistance to ag(e)ing with And mildew resistance and good workability.The coating can be used not only for the decoration of various walls and can be also used for metal The surface anticorrosion of material is handled.
Embodiment 1, by deionized water 12%, dispersant 1.2%, wetting agent 0.4%, rheological agent 2.3%, antifoaming agent 0.05% is added in dispersion machine, dispersion machine is opened, then successively by superfine talcum powder 2%, calcium carbonate superfine powder 8%, titanium dioxide 14% is added in dispersion machine, and the material in dispersion machine was sent into grinder with pump and is ground after 30 minutes by high speed dispersion.From grinding The material flowed out in grinding machine enters intermediate storage tank, if necessary requirement is not achieved into the material size in intermediate storage tank, It is sent in grinder and is regrind with pump, until reaching necessary requirement.
By methacrylic acid, butyl acrylate, styrene, methyl methacrylate quadripolymer latex 50%, thickener 0.4%, mill base 1.6% and antifoaming agent 0.05% are added in blend tank, the stirring slurry of blend tank are opened, under stiring, to tune Nano-titanium dioxide 2%, nano zine oxide 1.5%, nano silicon dioxide 2%, nano-calcium carbonate are slowly added in distribution tank successively 2.5%, after stirring 30 minutes, the material in intermediate storage tank is slowly added in blend tank with pump, after continuing stirring 30 minutes Sampling and testing, if test passes, you can discharging packaging.

Claims (2)

1. a kind of multifunction green environment protection type nano paint is mainly made of lotion, water, filler and auxiliary agent etc., feature It is:It is by methacrylic acid, butyl acrylate, styrene and methyl methacrylate quadripolymer latex, nanometer titanium dioxide Titanium, nano zine oxide, nano silicon dioxide, nano-calcium carbonate, deionized water, superfine talcum powder, calcium carbonate superfine powder, titanium white The auxiliary agents such as powder, dispersant, wetting agent, rheological agent, thickener, mill base, antifoaming agent are formed.
2. a kind of multifunction green environment protection type nano paint according to claim 1, characterized in that its proportioning (weight Amount percentage) be:Methacrylic acid, butyl acrylate, styrene and methyl methacrylate quadripolymer latex 20~ 65%;Nano-titanium dioxide 0.3~5%;Nano zine oxide 0.2~3%;Nano silicon dioxide 0.3~3%;Nano-calcium carbonate Calcium 0.5~5%;Deionized water 3~12%;Superfine talcum powder 1~3%;Calcium carbonate superfine powder 3~15%;Titanium dioxide 3~25%; The auxiliary agents such as dispersant, wetting agent, rheological agent, thickener, mill base, antifoaming agent 2~12%.
CN201710102288.7A 2017-02-24 2017-02-24 A kind of multifunction green environment protection type nano paint Pending CN108690431A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710102288.7A CN108690431A (en) 2017-02-24 2017-02-24 A kind of multifunction green environment protection type nano paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710102288.7A CN108690431A (en) 2017-02-24 2017-02-24 A kind of multifunction green environment protection type nano paint

Publications (1)

Publication Number Publication Date
CN108690431A true CN108690431A (en) 2018-10-23

Family

ID=63841779

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710102288.7A Pending CN108690431A (en) 2017-02-24 2017-02-24 A kind of multifunction green environment protection type nano paint

Country Status (1)

Country Link
CN (1) CN108690431A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109251610A (en) * 2018-07-23 2019-01-22 天津市奇才防水材料有限公司 A kind of environment protection colour steel construction waterproof paint specially
CN112795255A (en) * 2020-12-30 2021-05-14 华能江阴燃机热电有限责任公司 Nanoscale water-based heavy-duty self-cleaning coating
CN113897104A (en) * 2021-09-16 2022-01-07 安徽坤涂新材料科技有限公司 Preparation method of ultraviolet-proof coating for PC glass plate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109251610A (en) * 2018-07-23 2019-01-22 天津市奇才防水材料有限公司 A kind of environment protection colour steel construction waterproof paint specially
CN112795255A (en) * 2020-12-30 2021-05-14 华能江阴燃机热电有限责任公司 Nanoscale water-based heavy-duty self-cleaning coating
CN113897104A (en) * 2021-09-16 2022-01-07 安徽坤涂新材料科技有限公司 Preparation method of ultraviolet-proof coating for PC glass plate

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Application publication date: 20181023