CN108686838A - A kind of nano-bubble generator - Google Patents

A kind of nano-bubble generator Download PDF

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Publication number
CN108686838A
CN108686838A CN201810469282.8A CN201810469282A CN108686838A CN 108686838 A CN108686838 A CN 108686838A CN 201810469282 A CN201810469282 A CN 201810469282A CN 108686838 A CN108686838 A CN 108686838A
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CN
China
Prior art keywords
copper foil
air
nano
gas
water
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Granted
Application number
CN201810469282.8A
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Chinese (zh)
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CN108686838B (en
Inventor
彭铁锋
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Southwest University of Science and Technology
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Southwest University of Science and Technology
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Application filed by Southwest University of Science and Technology filed Critical Southwest University of Science and Technology
Priority to CN201810469282.8A priority Critical patent/CN108686838B/en
Publication of CN108686838A publication Critical patent/CN108686838A/en
Application granted granted Critical
Publication of CN108686838B publication Critical patent/CN108686838B/en
Expired - Fee Related legal-status Critical Current
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/02Froth-flotation processes
    • B03D1/025Froth-flotation processes adapted for the flotation of fines

Abstract

The invention discloses a kind of nano-bubble generators, including shell, horizontal baffle, filter plate and microflow channels, microflow channels include that inner tube, outer tube and the copper foil volume being arranged between inner tube and outer tube, copper foil volume are made of the copper foil for being etched with miniature air-flow conduit on surface;Nanometer foam generator further includes the air pump that air is injected into air cavity and the water pump to gas-liquid mixed intracavitary water filling.Nano-bubble generator of the present invention, it curls into microflow channels using the copper foil for being etched with a large amount of miniature air-flow conduits, high pressure gas forms a large amount of fine air-flow by microflow channels, and fine air-flow is sheared by high-speed rotating blade, to form a large amount of nano bubble in gas-liquid mixed sap cavity.The size for the nano bubble that this nano-bubble generator generates can be controlled by the rotating speed of the diameter and motor that control miniature air-flow conduit, and the dimensionally stable of the nano bubble of generation, bubbles volume is big, can improve flotation efficiency height and mineral recovery rate is high.

Description

A kind of nano-bubble generator
Technical field
The present invention relates to mineral floating technical field, more particularly to a kind of device carrying out flotation using nano bubble.
Background technology
Foam flotation method is usually used to sorting fine particle mineral, relative to tabling, high-gradient magnetic separation and stone Oil aggregation, bubble flotation have better efficiency and lower cost.The main principle of method for floating is to be based on mineral and slag The difference of surface chemical property is carried out mineral and impurity using the hydrophobic nature of mineral particle surface and the hydrophily of slag Sorting.
As the mankind continually developing and consuming to mineral resources on the earth, rich ore and tractable ore resource subtract increasingly It is few, and the demand of metal material increasingly increases, so having to exploit and sort poor, thin, matrix.This kind of ore is necessary That to be ground carefully could make the sufficient monomer dissociation of valuable mineral, in some cases, reach monomer dissociation and be intended to very Material is milled down to the granularity less than 10 μm.However, with the reduction of ore grain size, root can occur for the flotation behavior of mineral grain This variation, conventional flotation technique fully recycle these useful micro-size fraction mines because the foam grain size of its generation is big it is difficult to meet The requirement of object.
Invention content
In view of this, the object of the present invention is to provide a kind of nano-bubble generator, produced with solving existing foam transmitter Raw foam grain size is big, can not achieve the problem of fully being recycled to subparticle grade mineral.
Nano-bubble generator of the present invention includes the shell of upper opening, horizontal baffle is provided in the middle part of the shell, Shell is separated into upper and lower two parts by the horizontal baffle, and lower part is divided into air cavity, and top is divided into gas-liquid mixed chamber, the shell Upper end be additionally provided with filter plate, the filter plate is for preventing particulate matter from falling into gas-liquid mixed chamber;
The nanometer foam generator further includes several microflow channels being evenly arranged on horizontal baffle, the microflow channels Including inner tube, outer tube and the copper foil volume being arranged between inner tube and outer tube, the copper foil volume is by being etched with miniature gas on surface The copper foil in chute road is made, and for the diameter of the miniature air-flow conduit in 10-30um, the inlet end of the copper foil volume is located at air cavity In, the exhaust end of copper foil volume is located in gas-liquid mixed chamber;The both ends of said inner tube are fixedly installed water-sealed bearing, the waterproof axis Middle setting is held by shaft, the upper end of the shaft is provided with rolls up the blade that discharge air-flow is sheared to copper foil, in the air cavity It is provided with the motor of drive shaft;
The nanometer foam generator further includes the air pump of air being injected into air cavity and to gas-liquid mixed intracavitary water filling Water pump;
The nanometer foam generator further includes water tank, is arranged on water tank water inlet pipe and drainpipe, setting are in water tank The foam stabiliser of lower part is added mouth and is arranged on water tank for foam stabiliser and water to be mixed to equal blender, institute The water inlet for stating water pump is connected with the drainpipe being arranged on water tank.
Further, the copper foil volume is made by the following method:
1) selection obverse and reverse sides roughness is in Ra0.025 copper foils below, using vacuum coated mode at the copper foil back side It is covered with protective film, then copper foil is placed on spin coater, photoresist is added on the front of copper foil, using spin coater by photoetching Glue uniformly revolves figure on the front of copper foil;
2) copper foil is dried, the solvent in photoresist is made to escape;
3) miniature air-flow conduit figure is prefabricated in photomask board, copper foil and photomask board are placed on projection aligner On, projection exposure is carried out to copper foil, it will be in the miniature air-flow conduit pattern transfer to copper foil front on photomask board;
4) copper foil after exposure is put into developer solution, the photoresist being exposed on copper foil is made to be dissolved into developer solution, from And miniature air-flow conduit figure is manifested on copper foil;
5) circuit board is put into ferric trichloride etching liquid, copper foil is performed etching, it is micro- to be made on copper foil front Type air-flow conduit;
6) copper foil after etching is put into the photoresist got rid of in sodium hydroxide ethanol solution on copper foil;
7) protective film at the removal copper foil back side;
8) copper foil volume is made in the copper foil for removing protective film on the winder.
Beneficial effects of the present invention:
Nano-bubble generator of the present invention curls into miniflow using the copper foil for being etched with a large amount of miniature air-flow conduits Pipe, high pressure gas form a large amount of fine air-flow by microflow channels, and fine air-flow is sheared by high-speed rotating blade, in gas A large amount of nano bubble is formed in liquid mixing sap cavity.The size for the nano bubble that this nano-bubble generator generates can pass through control The rotating speed control of the diameter and motor of miniature air-flow conduit, the dimensionally stable of the nano bubble of generation, bubbles volume is big, can improve floating Select efficient and mineral recovery rate high.
Description of the drawings
Fig. 1 is the structural schematic diagram of nano-bubble generator of the present invention;
Fig. 2 is the enlarged diagram in the portions P in Fig. 1.
Specific implementation mode
The invention will be further described with reference to the accompanying drawings and examples.
As shown, the present embodiment nano-bubble generator, includes the shell 1 of upper opening, is set in the middle part of the shell It is equipped with horizontal baffle 2, shell is separated into upper and lower two parts by the horizontal baffle, and lower part is divided into air cavity 3, and top is divided into gas-liquid The upper end of mixing chamber 4, the shell is additionally provided with filter plate 5, and the filter plate is for preventing particulate matter from falling into gas-liquid mixed chamber.
The nanometer foam generator further includes several microflow channels 6 being evenly arranged on horizontal baffle, the miniflow Pipe includes inner tube 61, outer tube 52 and the copper foil volume 63 being arranged between inner tube and outer tube, and the copper foil volume on surface by etching There is the copper foil of miniature air-flow conduit to be made, the diameter of the miniature air-flow conduit is in 10-30um, the inlet end position of the copper foil volume In air cavity, the exhaust end of copper foil volume is located in gas-liquid mixed chamber;The both ends of said inner tube are fixedly installed water-sealed bearing 7, institute Stating setting in water-sealed bearing, by shaft 8, the upper end of the shaft is provided with rolls up the blade 9 that discharge air-flow is sheared to copper foil, The motor 10 of drive shaft is provided in the air cavity.In the present embodiment, the motor is the height that rotating speed is more than 10000r/min Speed motor.
The nanometer foam generator further includes the air pump 11 of air being injected into air cavity and to gas-liquid mixed intracavitary water filling Water pump 12.
The nanometer foam generator further includes water tank 13, is arranged on water tank water inlet pipe 14 and drainpipe 15, setting Foam stabiliser in water tank lower part is added mouth 16 and is arranged on water tank for foam stabiliser and water to be mixed equal stir Device 17 is mixed, the water inlet of the water pump is connected with the drainpipe being arranged on water tank.
In the present embodiment, the copper foil volume is made by the following method:
1) selection obverse and reverse sides roughness is in Ra0.025 copper foils below, using vacuum coated mode at the copper foil back side It is covered with protective film, then copper foil is placed on spin coater, photoresist is added on the front of copper foil, using spin coater by photoetching Glue uniformly revolves figure on the front of copper foil;The surface of best bright finish can guarantee copper foil, and in follow-up coiling, obverse and reverse sides can be close Fitting, to form mutually disconnected miniature air-flow conduit.
2) copper foil is dried, the solvent in photoresist is made to escape.
3) miniature air-flow conduit figure is prefabricated in photomask board, copper foil and photomask board are placed on projection aligner On, projection exposure is carried out to copper foil, it will be in the miniature air-flow conduit pattern transfer to copper foil front on photomask board.
4) copper foil after exposure is put into developer solution, the photoresist being exposed on copper foil is made to be dissolved into developer solution, from And miniature air-flow conduit figure is manifested on copper foil.
5) circuit board is put into ferric trichloride etching liquid, copper foil is performed etching, it is micro- to be made on copper foil front Type air-flow conduit.
6) copper foil after etching is put into the photoresist got rid of in sodium hydroxide ethanol solution on copper foil.
7) protective film at the removal copper foil back side.
8) copper foil volume is made in the copper foil for removing protective film on the winder.
It is rolled up using copper foil made of this method, is transferred to the miniature air-flow conduit on photomask board using projection exposure On copper foil, the width of miniature air-flow conduit can reach nanoscale, while when the depth of miniature air-flow conduit can be etched by controlling Between controlled, miniature airslide road size control accuracy is high.
The present embodiment nano-bubble generator curls into miniflow using the copper foil for being etched with a large amount of miniature air-flow conduits Pipe, high pressure gas form a large amount of fine air-flow by microflow channels, and fine air-flow is sheared by high-speed rotating blade, in gas A large amount of nano bubble is formed in liquid mixing sap cavity, the flotation requirement to Separate Fine-grained Minerals can be met, improve flotation efficiency height and mine The object rate of recovery is high.
Finally illustrate, the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although with reference to compared with Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the skill of the present invention Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this In the right of invention.

Claims (2)

1. a kind of nano-bubble generator, it is characterised in that:Shell including upper opening is provided with water in the middle part of the shell Shell is separated into upper and lower two parts by flat partition board, the horizontal baffle, and lower part is divided into air cavity, and top is divided into gas-liquid mixed chamber, institute The upper end for stating shell is additionally provided with filter plate, and the filter plate is for preventing particulate matter from falling into gas-liquid mixed chamber;
The nanometer foam generator further includes several microflow channels being evenly arranged on horizontal baffle, the miniflow microflow channels Including inner tube, outer tube and the copper foil volume being arranged between inner tube and outer tube, the copper foil volume is by being etched with miniature gas on surface The copper foil in chute road is made, and for the diameter of the miniature air-flow conduit in 10-30um, the inlet end of the copper foil volume is located at air cavity In, the exhaust end of copper foil volume is located in gas-liquid mixed chamber;The both ends of said inner tube are fixedly installed water-sealed bearing, the waterproof axis Middle setting is held by shaft, the upper end of the shaft is provided with rolls up the blade that discharge air-flow is sheared to copper foil, in the air cavity It is provided with the motor of drive shaft;
The nanometer foam generator further includes the air pump that air is injected into air cavity and the water pump to gas-liquid mixed intracavitary water filling;
The nanometer foam generator further includes water tank, is arranged on water tank water inlet pipe and drainpipe, setting are in water tank lower part Foam stabiliser mouth is added and is arranged on water tank for foam stabiliser and water to be mixed to equal blender, the water The water inlet of pump is connected with the drainpipe being arranged on water tank.
2. nano-bubble generator according to claim 1, it is characterised in that:The copper foil volume is made by the following method At:
1) selection obverse and reverse sides roughness is covered with using vacuum coated mode at the copper foil back side in Ra0.025 copper foils below Then copper foil is placed on spin coater by protective film, photoresist is added on the front of copper foil, using spin coater that photoresist is equal Even rotation figure is on the front of copper foil;
2) copper foil is dried, the solvent in photoresist is made to escape;
3) copper foil and photomask board are placed in projection aligner in photomask board by miniature air-flow conduit figure is prefabricated, Projection exposure is carried out to copper foil, it will be in the miniature air-flow conduit pattern transfer to copper foil front on photomask board;
4) copper foil after exposure is put into developer solution, the photoresist being exposed on copper foil is made to be dissolved into developer solution, thus Miniature air-flow conduit figure is manifested on copper foil;
5) circuit board is put into ferric trichloride etching liquid, copper foil is performed etching, to make miniature gas on copper foil front Chute road;
6) copper foil after etching is put into the photoresist got rid of in sodium hydroxide ethanol solution on copper foil;
7) protective film at the removal copper foil back side;
8) copper foil volume is made in the copper foil for removing protective film on the winder.
CN201810469282.8A 2018-05-16 2018-05-16 Nanometer bubble generator Expired - Fee Related CN108686838B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810469282.8A CN108686838B (en) 2018-05-16 2018-05-16 Nanometer bubble generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810469282.8A CN108686838B (en) 2018-05-16 2018-05-16 Nanometer bubble generator

Publications (2)

Publication Number Publication Date
CN108686838A true CN108686838A (en) 2018-10-23
CN108686838B CN108686838B (en) 2020-01-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112170472A (en) * 2019-07-02 2021-01-05 西南科技大学 Novel emergency remediation technology for heavy metal contaminated soil

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2630837Y (en) * 2003-08-12 2004-08-04 上海交通大学 Apparatus for forming nano air bubble o nmica surface based on alcohol-water substitution
JP2007308544A (en) * 2006-05-17 2007-11-29 Hitachi Ltd Nano composite material having low dielectric constant and low refractive index
CN102010038A (en) * 2010-12-30 2011-04-13 波鹰(厦门)科技有限公司 Nano catalytic electrolysis flocculation device
CN102626560A (en) * 2012-04-24 2012-08-08 中国科学院力学研究所 Rotational flow air flotation oil-water separation device and air flotation generator
CN202519115U (en) * 2012-04-19 2012-11-07 波鹰(厦门)科技有限公司 Nano-catalysis, electrolysis, flocculation and air-floatation device
KR20130112997A (en) * 2012-04-05 2013-10-15 충남대학교산학협력단 Production appararatus of gas-phase hollow nanoparticle using non-metallic template particle and method thereof
CN205838609U (en) * 2016-06-08 2016-12-28 岳阳长岭设备研究所有限公司 A kind of modified model air floatation machine

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2630837Y (en) * 2003-08-12 2004-08-04 上海交通大学 Apparatus for forming nano air bubble o nmica surface based on alcohol-water substitution
JP2007308544A (en) * 2006-05-17 2007-11-29 Hitachi Ltd Nano composite material having low dielectric constant and low refractive index
CN102010038A (en) * 2010-12-30 2011-04-13 波鹰(厦门)科技有限公司 Nano catalytic electrolysis flocculation device
KR20130112997A (en) * 2012-04-05 2013-10-15 충남대학교산학협력단 Production appararatus of gas-phase hollow nanoparticle using non-metallic template particle and method thereof
CN202519115U (en) * 2012-04-19 2012-11-07 波鹰(厦门)科技有限公司 Nano-catalysis, electrolysis, flocculation and air-floatation device
CN102626560A (en) * 2012-04-24 2012-08-08 中国科学院力学研究所 Rotational flow air flotation oil-water separation device and air flotation generator
CN205838609U (en) * 2016-06-08 2016-12-28 岳阳长岭设备研究所有限公司 A kind of modified model air floatation machine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112170472A (en) * 2019-07-02 2021-01-05 西南科技大学 Novel emergency remediation technology for heavy metal contaminated soil

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