CN108677003B - A kind of fluidisation state calciner - Google Patents

A kind of fluidisation state calciner Download PDF

Info

Publication number
CN108677003B
CN108677003B CN201810508876.5A CN201810508876A CN108677003B CN 108677003 B CN108677003 B CN 108677003B CN 201810508876 A CN201810508876 A CN 201810508876A CN 108677003 B CN108677003 B CN 108677003B
Authority
CN
China
Prior art keywords
magnetic
gas
reduction reactor
distribution grid
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201810508876.5A
Other languages
Chinese (zh)
Other versions
CN108677003A (en
Inventor
高鹏
韩跃新
唐志东
李艳军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Northeastern University China
Original Assignee
Northeastern University China
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Northeastern University China filed Critical Northeastern University China
Priority to CN201810508876.5A priority Critical patent/CN108677003B/en
Publication of CN108677003A publication Critical patent/CN108677003A/en
Application granted granted Critical
Publication of CN108677003B publication Critical patent/CN108677003B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes
    • C22B1/10Roasting processes in fluidised form

Abstract

The present invention relates to a kind of fluidisation state calciners, belong to technical field of mineral processing.A kind of fluidisation state calciner, described device include the reduction reactor perpendicular to ground setting and the field generator for magnetic for acting on the reduction reactor, and the field generator for magnetic generates the uniform magnetic field of magnetic direction vertically upward.The main body of the reduction reactor is a cylindrical chamber container, and container bottom is equipped with gas access, and the gas distribution grid for being fixed on container bottom side wall in edge is equipped in cavity, and the cavity between gas distribution grid and gas access is gas distributing chamber;Material inlet is set on the side wall above gas distribution grid;Reduction reactor container head is equipped with gas vent, and material outlet is equipped in upper portion side wall.The present invention rationally controls the flow behavior of inside reactor magnetic-particle by the way that stabilizing magnetic field is added around reduction reactor, keeps its internal Gas-solid Two-phase Flow more stable, and gas reacts sufficiently with iron ore, improves roasting efficiency.

Description

A kind of fluidisation state calciner
Technical field
The present invention relates to a kind of fluidisation state calciners, belong to technical field of mineral processing.
Background technique
Iron ore is the protection resource of China's steel and iron industry, belongs to the Major Strategic Demand of country.China's iron ore deposit is reported Tax is poor, hardly possible utilizes, it is at high cost to pick up, and domestic iron ore is chronically at serious non-starving condition, China's imported Fe ore in 2016 10.24 hundred million t, external dependence degree are more than 86%, are recorded high.2 months 2017 iron ore imports valences rise to 90 beautiful yuan/ton, directly Connecing leads to being significantly increased for China's iron ore imports cost, this not only causes to seriously affect to China's steel industry, passes through to its people The safe operation of Ji also constitutes grave danger.In China's Refractory iron ore resource, fine- disseminated ore, siderite, limonite, Oolitic hematite belongs to typical difficult and utilizes iron ore deposit, gross reserves up to 20,000,000,000 tons or more, be distributed widely in Liaoning, Hebei, Shanxi, The ground such as Shaanxi, Hubei, Xinjiang.It is difficult using conventional technique of preparing since such iron ore mineral complicated composition, grain size number are fine To obtain preferable technical-economic index, part resource not yet obtains heavy industrialization development and utilization, though part resource is able to Exploitation, but utilization efficiency is extremely low.Thus, autonomous innovation technology is researched and developed, realizes that the Efficient Development of China's iron ore deposit utilizes, is improved The iron ore degree of self-sufficiency has important strategic importance.
In recent years, domestic many research units are around complicated difficults such as fine- disseminated ore, siderite, limonite, oolitic hematites Efficient Development and the utilization for selecting iron ore deposit, have carried out a large amount of basic research and technology development work, have reached use substantially Selecting smelting combination technique is just able to achieve the common recognition of Refractory iron ore resources effective utilization.Wherein magnetizing roast-magnetic separation is that processing is multiple The maximally efficient technology of miscellaneous refractory iron ore develops high production efficiency, the magnetizing roast equipment that stable, low energy consumption becomes mine The common ideal of industry scientific circles and industrial circle.Magnetizing roast-magnetic separation refer to by material or ore heated in corresponding atmosphere into Row chemical reaction, makes bloodstone (Fe therein2O3), siderite (FeCO3), limonite (Fe2O3·nH2The weakly magnetic iron ores such as O) Object is changed into ferromagnetic magnetic iron ore (Fe3O4) or maghemite (γ-Fe2O3), recycle mineral between magnetic contrast into Row magnetic separation.
Magnetizing roast mode has shaft roasting, rotary kiln baking, fluosolids roasting etc..Shaft furnace magnetic roasting process is mainly fitted The lump ore of processing granularity 25-75mm is closed, and that there is single machine processing capacities is low, energy consumption is high, calcining time is long, product matter for the technique Measure the problems such as uneven.It is domestic at present to only have the dressing plant Jiu Gang using 44 100m3 shaft roasting carbonate containing iron ores.Revolution Kiln magnetic roasting process is suitble to handle the following ore of granularity 25mm, and magnetizing roast quality and separation index are good compared with shaft furnace.Big Xigou ditch Dressing plant handles siderite using coal-based rotary kiln magnetizing roast-low intensity magnetic separation-reverse floatation process, obtains iron ore concentrate TFe grade 60.63%, the good industrial production index of iron recovery 75.42%.But rotary kiln technology there are still magnetic susceptibility low, Yi Jie It encloses, produce the problems such as unstable, operating rate is low and energy consumption is high.
Fluidization refers to that solid material particle is in fluid state under fluid media (medium) effect, and fluidization process has similar liquid The characteristic of body.In recent years, domestic many research units have carried out a large amount of research for fluosolids roasting technology and equipment.With remaining Research Team headed by rich academician forever, proposes the concept of circulating fluidization flash magnetization roasting, is based on fluidization and dress It sets, fine ore fluidization magnetic is carried out to carbonate containings iron ores such as the big Xigou ditch siderite in Shaanxi, Kunming Wang Jiatan mine, weight steel building sequence iron ores Change roasting, obtain 55%~60% or more concentrate Iron grade, iron recovery is China up to 70%~75% good index Refractory iron ore opens new approach.Chinese Academy Of Sciences Process Engineering Research Institute proposes low temperature fluidization magnetization Roasting technique has built up 100,000 tons/year of industrial demonstration projects, and commercial test results show 33% limonite of TFe grade, through magnetic 57% or more iron ore concentrate TFe grade, the good technique index of iron recovery 93%~95% are obtained after choosing.Xi'an division of construction Big Xigou ditch sparring miberal powder that skill university is 40~60 μm to granularity carries out suspending magnetization roasting test, can get magnetic concentrate iron product The roasted product that position is 58.21%, iron recovery is 79.39%.Wherein, the most successfully surely belong to Northeastern University's independent research Preenrichment suspension roasting magnetic separation technology, with five crest bloodstone of Hubei, change eastern Exemplary deposition type hematite-limonite, Anshan iron and steel plant east tail Mine, East Anshan iron ore and Powder ore of Jiu Steel etc. are raw material, have carried out the laboratory PSRM and the pilot plant test of system, are obtained good Roasting effect and separation index.
In conclusion being roasted although existing fluosolids roasting technology can be such that Iron grade and the rate of recovery all increases substantially If misoperation during burning, however it remains material back-mixing is serious in reduction reactor, reduction product quality is uneven, discharge is unsmooth The problems such as, therefore fluosolids roasting reaction unit is developed, meaning is achieved effective control to Gas-particle Flows, chemical reaction in reactor It is great.
Summary of the invention
It is an object of the present invention to provide a kind of fluidisation state calciner that can be improved iron ore magnetizing roast efficiency, by Stabilizing magnetic field is added around reduction reactor, rationally controls the flow behavior of inside reactor magnetic-particle, makes its internal gas-solid Two-phase flow is more stable, and gas reacts sufficiently with iron ore, improves roasting efficiency.
A kind of fluidisation state calciner, described device include the reduction reactor perpendicular to ground setting and act on this also The field generator for magnetic of former reactor, the field generator for magnetic generate the uniform magnetic field of magnetic direction vertically upward.
Field generator for magnetic of the present invention can be the uniform magnetic field generating device that the prior art provides, generated magnetic field Direction is that vertical (or near normal) faces upward in ground.Preferably, the field generator for magnetic is to be set to outside reduction reactor The several groups electromagnetic coil in portion.The electromagnetic coil as its it is self-powered control its caused by magnetic field strength.
Reduction reactor of the present invention is arranged perpendicular to ground, and the solid material being passed through in it rises with air-flow, and Persistently rise under magnetic fields, prevents material back-mixing.
Preferably, the main body of the reduction reactor is a cylindrical chamber container, and container bottom is equipped with gas access, in chamber The gas distribution grid for being fixed on container bottom side wall in edge is equipped in body, the cavity between gas distribution grid and gas access is gas Body distributing chamber;Material inlet is set on the side wall above gas distribution grid;Material inlet is connected to feed pipe, and the feed pipe is logical Cross screw(-type) feeder connection feed hopper;Reduction reactor container head is equipped with gas vent, goes out in upper portion side wall equipped with material Mouthful.
Further, heating device and the temperature control system for controlling heating device are equipped on the outside of the reduction reactor. Further, the heating device is electric heater unit, uses high purity aluminium oxide as burner hearth material, anti-for guaranteeing Temperature in device is answered, required temperature is controlled to adjust by temperature control system.
Further, described device includes water cooling dump skip, for accepting the solid material from material outlet.
Further, the gas distribution grid is cell quartz plate, is distributed several ventilation circular holes thereon, aperture be less than to Handle the diameter of iron ore particle.
Further, the reduction reactor container is made of insulating materials of the relative permeability less than 1, such as quartz Glass.
Further, the effect of the gas distributing chamber is that gas mixes place, and has buffer function simultaneously;
Further, material is continuous-feeding at the material inlet, and material accumulates self-contained lock gas at material inlet Device avoids gas from escaping from material inlet.
What device of the present invention was connected with material inlet is feed pipe, and material storing is given in feed hopper by spiral Material machine is fed in feed pipe, and controls delivery rate by screw(-type) feeder.Further, the entrance height of the feed pipe is high In reduction reactor height, the power that material flows up in reduction reactor is provided will pass through height of materials difference.
Gas vent of the present invention is used for the discharge and collection of excessive reaction gas, air conservation and harm Crowd.
Further, the gas access is passed through reducing gas CO, H2Deng, and with protective gas N2, while N2Tool There is fluidization, specific gas ratio is determined according to material properties and roasting index.
The present invention fluidizes state calciner in use, placing a certain amount of iron ore inside reduction reactor container Grain is passed through reducibility gas into reactor, and iron mineral is contacted with gas occurs reduction reaction, is changed by weak magnetism mineral Ferromagnetism iron mineral, under the collective effect in air-flow and magnetic field, gas is uniformly mixed with magnetic-particle with the movement of approximate plug flow, Until being flowed out by material outlet.
Another object of the present invention is to provide a kind of fluosolids roasting technique for handling iron ore.
Iron ore particle is continuously passed through also by a kind of fluosolids roasting technique for handling iron ore by reduction reactor lower part In former reactor, iron ore particle is carried using the reproducibility gaseous mixture air-flow entered by reduction reactor bottom and is moved upwards simultaneously It is roasted in 500 DEG C~600 DEG C, reaction is continuously discharged via reactor top material outlet in the solid material obtained after roasting Device applies magnetic field to reduction reactor at the same time, and 40~60kA/m of magnetic field strength, magnetic direction is vertically upward.
" reproducibility gaseous mixture " of the present invention be reducibility gas and inert gas mixture, be preferably CO and The mixture of nitrogen composition, further, it is preferable to which the volumetric concentration of CO is 20~40%.
Preferably, the delivery rate of the iron ore particle is 30~80kg/h;Reproducibility gaseous mixture flow velocity is 0.1m/s ~2.0m/s.
The factors such as above-mentioned reproducibility gaseous mixture flow velocity and the density of iron ore material, granularity and stickiness are related, flow velocity choosing Select the movement for making it that can remain upward.
Preferably, include the steps that magnetic separation: by the solid material water cooling being discharged by reactor, drying, be finely ground to- 0.038mm content accounts for 60~80%, and magnetic separation tube magnetic separation is carried out under conditions of magnetic field strength is 70~100kA/m, obtains iron essence Mineral products.
Preferably, when being reacted, initial iron ore particle is added into reduction reactor, addition height is entire reaction The 25%~50% of device.
It is further preferred that iron ore, which is finely ground to -0.074mm, accounts for 50%~90% fineness, it is initially added in reactor Iron ore particle, highly 25%~50% for entire reactor, setting reaction temperature are 500 DEG C~600 DEG C, iron ore particle 30~80kg/h of delivery rate is passed through the gaseous mixture of CO and nitrogen, wherein CO volumetric concentration 20~40%;Apply magnetic direction to hang down Straight upward magnetic field, sets magnetic field strength as 40~60kA/m.
A preferred technical solution of the invention are as follows: iron ore is finely ground to -0.074mm and accounts for 50%~90% fineness, instead It answers and is initially added iron ore particle in device, be highly 25%~50% (guaranteeing to be higher than to material inlet) of entire reactor, beat Electric heating is opened, it is reaction temperature that temperature setting, which is 500 DEG C~600 DEG C, is passed through N2To empty air in reactor, open to mine Valve, setting delivery rate are 30~80kg/h, and (CO volumetric concentration 20~40%) is passed through pre-heated N by a certain percentage2 And CO, spiral winding power supply is opened, direct current is passed through and obtains the upward magnetic field in direction, set magnetic field strength as 40~60kA/m. Reducibility gas is passed through into reactor, iron mineral is contacted with gas occurs reduction reaction, is changed by force by weak magnetism mineral Armco magnetic iron mineral, under the collective effect in air-flow and magnetic field, gas is uniformly mixed with the movement of approximate plug flow, directly with magnetic-particle Extremely flowed out by discharge gate.After lasting discharging a period of time, feed valve, CO valve are closed, electric heating switch and electromagnetic wire are closed Power supply is enclosed, continues to be passed through N2Continue 5 minutes, until remnants CO in emptying reactor.It is dried after the water cooled cooling of roasted product Dry, weighing, sampling, and be finely ground to -0.038mm content and account for 60~80%, in the condition that magnetic field strength is 70~100kA/m Lower progress magnetic separation tube magnetic separation test obtains the iron extract mine producation that TFe grade is greater than 60%.
The invention has the benefit that
(1) magnetic fields are relied on, roasting effect is improved.During fluosolids roasting, externally-applied magnetic field can reduce iron mineral The activation energy of reaction accelerates the progress of chemical reaction to improve roasting efficiency so that iron mineral is easier to be reduced;
(2) it is powered to the spiral winding that reduction reactor surrounding is arranged in, obtains externally-applied magnetic field.In conventional fluosolids roasting In device, reduction reactor endoparticle concentration and gas-solid speed axially distribution it is serious it is uneven, gas-solid axial backmixing is big lacks Point is generally existing, is easy the phenomenon that restoring or owing reduction occurred so that iron mineral reduction is uneven.And the fluosolids roasting fills It sets and back-mixing can be effectively controlled, under the influence of a magnetic field, the ferromagnetism magnetic iron ore for restoring generation can preferentially be flowed up by discharge gate It is discharged in bed, unreacted weak magnetic mineral and non-magnetic iron logistics are dynamic relatively slowly, and Gas-particle Flows are close to plug flow, particle It is evenly distributed, avoided (deficient) reduction;
(3) roasting can be improved by adjusting residence time of the magnitude of field intensity control iron mineral in reduction reactor Index.Applied field strengths have a direct impact the flowing velocity of magnetic-particle in reduction reactor, if magnetic field strength is big, magnetic Property Particle Velocity accelerate, the residence time is reduced in bed, and the recovery time is also reduced therewith;Conversely, then the recovery time increases.Cause This, can adjust in real time magnetic field strength by the index of roasted product, control its recovery time.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for fluidizing state calciner,
Appended drawing reference is as follows: gas access 1, gas distributing chamber 2, gas distribution grid 3, material inlet 4, reduction reactor 5, Heating device 6, material outlet 7, water cooling dump skip 8, field generator for magnetic 9, temperature control system 10, gas vent 11, feed pipe 12, Screw(-type) feeder 13, feed hopper 14;
Fig. 2 is the sectional view in Fig. 1 at A-A.
Specific embodiment
Following non-limiting embodiments can with a person of ordinary skill in the art will more fully understand the present invention, but not with Any mode limits the present invention.
Test method described in following embodiments is unless otherwise specified conventional method;The reagent and material, such as Without specified otherwise, commercially obtain.
Embodiment 1
A kind of fluidisation state calciner, described device include the reduction reactor 5 perpendicular to ground setting and act on this The field generator for magnetic 9 of reduction reactor, the field generator for magnetic 9 generate the uniform magnetic field of magnetic direction vertically upward, institute Stating field generator for magnetic 9 is the several groups electromagnetic coil being set to outside reduction reactor 5, and the electromagnetic coil is charged certainly by it Source controls its generated magnetic field strength.
The main body of the reduction reactor 5 is a cylindrical chamber container, and 5 container of reduction reactor is using quartzy glass Glass is made, and container bottom is equipped with gas access 1, and the gas distribution grid 3 for being fixed on container bottom side wall in edge is equipped in cavity, The gas distribution grid 3 is cell quartz plate, is distributed several ventilation circular holes thereon, and aperture is less than iron ore particle to be processed Diameter;Cavity between gas distribution grid 3 and gas access 1 is gas distributing chamber 2;On the side wall above gas distribution grid 3 Material inlet 4 is set;Material inlet 4 is connected to feed pipe 12, and the feed pipe 12 is connected to feed hopper 14 by screw(-type) feeder 13, The entrance height of the feed pipe 12 is higher than 5 height of reduction reactor;5 container head of reduction reactor is equipped with gas vent 11, Material outlet 7 is equipped in upper portion side wall, the lower section of material outlet is equipped with water cooling dump skip 8, comes from material outlet 7 for accepting Solid material.Heating device 6 and the temperature control system 10 for controlling heating device 6, mistake are equipped on the outside of the reduction reactor 5 The reaction of amount is discharged and is collected from gas vent 11, air conservation and harm crowd.
This fluidisation state calciner verifies it by laboratory experiment, and the iron ore used is Anshan Area choosing Factories and miness stone belongs to bloodstone-siderite mixed ore.The ore chemistry composition analysis result is shown in Table 1, and Fe clusters analysis the results are shown in Table 2.As shown in Table 1, it is 9.24%, SiO that TFe grade, which is 34.43%, FeO content, in ore2Content is 49.41%, You Haiyuan Plain phosphorus, sulfur content are lower, to be respectively 0.07%, 0.05%.Show that the main valuable element of the chats is iron, major impurity ingredient For silicon.As shown in Table 2, the iron in red (brown) iron ore is 26.01%, and iron occupation rate is 75.85%;Iron in ferric carbonate is 4.98%, iron occupation rate 14.52%, therefore, the main recycle object of the chats are as follows: bloodstone and siderite.
1 ore chemistry constituent analysis of table/%
2 iron chemical phase analysis result of table/%
Iron ore is finely ground to -0.074mm and accounts for 80% fineness, iron ore particle is initially added in reduction reactor, height For 1/4 (packed height is higher than material inlet) of entire reactor, 570 DEG C are set by the electrical heating temperature of electric heater unit (as reaction temperature), is passed through N2To empty air in reactor, the feed valve of material inlet is opened, setting delivery rate is 40kg/h is passed through and is previously heated to 570 DEG C of N2With the gaseous mixture (wherein CO volumetric concentration 25%) of CO, gas flow rate is 1.0m/s opens the power supply of helical electromagnetic coils, is passed through direct current and obtains direction magnetic field vertically upward, set magnetic field strength as 60kA/m persistently discharges after 15min, closes feed valve, the gas inlet valves of material inlet, close opening for electric heater unit Pass and electromagnetic coil power supply, continue to be passed through N2Continue 5 minutes, until remnants CO in emptying reactor.The water cooled drop of roasted product It dried, weighed, sampled after temperature, and be finely ground to -0.038mm content and account for 70%, in the item that magnetic field strength is 85kA/m Magnetic separation tube magnetic separation test is carried out under part.
Raw ore TFe grade be 34.43% bloodstone-siderite mixed ore, applied field strengths be 60kA/m, CO concentration 25% carries out continuous magnetization roasting experiment under conditions of 570 DEG C of reduction temperature, and material TFe grade is after roasting 35.49%, roasting clinker can obtain the magnetic separation of iron ore concentrate product of TFe grade 66.53%, the rate of recovery 90.35% after magnetic separation.Point Choosing the results are shown in Table 3.
Material screening test result % after table 3 roasts
Embodiment 2
This experiment carries out in the fluosolids roasting device, and the sample ore used is that factories and miness stone is selected in Yunnan Province, belongs to red iron Mine-limonite type Refractory iron ore stone.The ore chemistry composition analysis result is shown in Table 4, and Fe clusters analysis the results are shown in Table 5.By Table 4 is it is found that it is 9.24%, SiO that TFe grade, which is 35.25%, FeO content, in ore2Content is 49.41%, and harmful element phosphorus contains Measure it is lower, be 0.88%.Show that the main valuable element of the chats is iron, major impurity ingredient is silicon.As shown in Table 5, red (brown) Iron in iron ore is 34.74%, and iron occupation rate is 98.85%, therefore, the main recycle object of the chats are as follows: bloodstone and brown Iron ore.
4 ore chemistry constituent analysis of table/%
5 iron chemical phase analysis result of table/%
Iron ore is finely ground to -0.074mm and accounts for 60% fineness, iron ore particle is initially added in reduction reactor, height For 30% (packed height is higher than material inlet) of entire reactor, 570 DEG C are set by the electrical heating temperature of electric heater unit (as reaction temperature), is passed through N2To empty air in reactor, the feed valve of material inlet is opened, setting delivery rate is 50kg/h is passed through and is previously heated to 570 DEG C of N2With the gaseous mixture (wherein CO volumetric concentration 30%) of CO, gas flow rate is 1.2m/s opens the power supply of helical electromagnetic coils, is passed through direct current and obtains the upward magnetic field in direction, set magnetic field strength as 55kA/m persistently discharges after 10min, closes feed valve, the gas inlet valves of material inlet, close opening for electric heater unit Pass and electromagnetic coil power supply, continue to be passed through N2Continue 5 minutes, until remnants CO in emptying reactor.The water cooled drop of roasted product It dried, weighed, sampled after temperature, and be finely ground to -0.038mm content and account for 80%, in the item that magnetic field strength is 85kA/m Magnetic separation tube magnetic separation test is carried out under part.
Raw ore TFe grade be 35.25% bloodstone-limonite mixed ore, applied field strengths be 55kA/m, CO concentration 30% carries out continuous fluidized roasting experiment under conditions of 570 DEG C of reduction temperature, and material TFe grade is after roasting 36.49%, roasting clinker can obtain the magnetic separation of iron ore concentrate product of TFe grade 65.10%, the rate of recovery 88.11% after magnetic separation.Point Choosing the results are shown in Table 6.
Material screening test result % after table 6 roasts

Claims (7)

1. a kind of fluidisation state calciner, it is characterised in that: described device includes the reduction reactor (5) perpendicular to ground setting And the field generator for magnetic (9) of the reduction reactor is acted on, the field generator for magnetic (9) generates magnetic direction vertically upward Uniform magnetic field,
The main body of the reduction reactor (5) is a cylindrical chamber container, and container bottom is equipped with gas access (1), in cavity The gas distribution grid (3) of container bottom side wall, the chamber between gas distribution grid (3) and gas access (1) are fixed on equipped with edge Body is gas distributing chamber (2);Material inlet (4) are set on the side wall above gas distribution grid (3), material inlet (4) connection Feed pipe (12), the feed pipe (12) pass through screw(-type) feeder (13) connection feed hopper (14);Reduction reactor (5) vessel top End is equipped with gas vent (11), is equipped with material outlet (7) in upper portion side wall.
2. the apparatus according to claim 1, it is characterised in that: the field generator for magnetic (9) is to be set to reduction reaction The external several groups electromagnetic coil of device (5).
3. the apparatus according to claim 1, it is characterised in that: be equipped with heating device (6) on the outside of the reduction reactor (5) And the temperature control system (10) for controlling heating device (6).
4. the apparatus according to claim 1, it is characterised in that: described device includes water cooling dump skip (8), is come for accepting Solid material from material outlet (7).
5. the apparatus according to claim 1, it is characterised in that: the gas distribution grid (3) is cell quartz plate, thereon Several ventilation circular holes are distributed, aperture is less than the diameter of iron ore particle to be processed.
6. the apparatus according to claim 1, it is characterised in that: reduction reactor (5) container uses relative magnetic permeability Insulating materials of the rate less than 1 is made.
7. the apparatus according to claim 1, it is characterised in that: the entrance height of the feed pipe (12) is higher than reduction reaction Device height provides the power that material flows up in reduction reactor will pass through height of materials difference.
CN201810508876.5A 2018-05-24 2018-05-24 A kind of fluidisation state calciner Active CN108677003B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810508876.5A CN108677003B (en) 2018-05-24 2018-05-24 A kind of fluidisation state calciner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810508876.5A CN108677003B (en) 2018-05-24 2018-05-24 A kind of fluidisation state calciner

Publications (2)

Publication Number Publication Date
CN108677003A CN108677003A (en) 2018-10-19
CN108677003B true CN108677003B (en) 2019-10-01

Family

ID=63808492

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810508876.5A Active CN108677003B (en) 2018-05-24 2018-05-24 A kind of fluidisation state calciner

Country Status (1)

Country Link
CN (1) CN108677003B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2177528Y (en) * 1993-12-20 1994-09-21 中国科学院化工冶金研究所 Fluidized magnetic field separator
US5858060A (en) * 1995-05-04 1999-01-12 Th Engineering France S.A. Magnetic separation method for iron carbide
CN1775368A (en) * 2005-11-29 2006-05-24 武汉理工大学 Cyclone suspension flash magnetized roasting-magnetic separating method for refractory ferric oxide ore
CN106755969A (en) * 2016-11-24 2017-05-31 东北大学 A kind of method of reinforced by additive bloodstone magnetizing roast

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2177528Y (en) * 1993-12-20 1994-09-21 中国科学院化工冶金研究所 Fluidized magnetic field separator
US5858060A (en) * 1995-05-04 1999-01-12 Th Engineering France S.A. Magnetic separation method for iron carbide
CN1775368A (en) * 2005-11-29 2006-05-24 武汉理工大学 Cyclone suspension flash magnetized roasting-magnetic separating method for refractory ferric oxide ore
CN106755969A (en) * 2016-11-24 2017-05-31 东北大学 A kind of method of reinforced by additive bloodstone magnetizing roast

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
磁场流态化技术的研究及其应用;朱庆山 等;《化工冶金》;19950831;第16卷(第3期);第271-281页 *
鞍山式赤铁矿预选粗精矿悬浮态磁化焙烧-磁选试验研究;余建文 等;《中南大学学报(自然科学版)》;20180430;第49卷(第4期);第771-778页 *

Also Published As

Publication number Publication date
CN108677003A (en) 2018-10-19

Similar Documents

Publication Publication Date Title
CN108588404B (en) A kind of fluosolids roasting technique handling iron ore
CN106868292B (en) A kind of refractory iron ore multistage suspension magnetizing roast magnetic separation system device and method
CN100493724C (en) Cyclone suspension flash magnetization roasting-magnetic separation method for refractory iron oxide ore
Yu et al. Magnetizing roasting mechanism and effective ore dressing process for oolitic hematite ore
Liu et al. New understanding on separation of Mn and Fe from ferruginous manganese ores by the magnetic reduction roasting process
CN104818378B (en) Preenrichment-three segment suspension roasting-magnetic separation treatment method of complex refractory iron ores
CN104726690A (en) Hematite-siderite-limonite mixed iron ore three-stage suspension roasting-magnetic separation method
CN103381390B (en) One utilizes difficult ore dressing to prepare high-grade magnetite powder complete set of equipments and method
CN108504855A (en) A method of producing iron ore concentrate by reducing agent suspending magnetization roasting of siderite
Li et al. Phase transformation in suspension roasting of oolitic hematite ore
CN104745800A (en) Three-stage suspension roasting-magnetic separation method for hematite-limonite mixed iron ores
CN102728457A (en) Method of producing nickel-containing iron ore concentrate from siliceous iron oxide ores containing nickel
Liu et al. A further investigation on the MnO2-Fe2O3 system roasted under CO-CO2 atmosphere
Li et al. Effect of fluidized magnetizing roasting on iron recovery and transformation of weakly magnetic iron mineral phasein iron tailings
CN1945186A (en) Roasting device for reducing hematite, limonite and siderite
CN107779536A (en) One kind direct-reduction iron production method and device
CN107686886A (en) A kind of method of the suspension roasting separation ferro-aluminum of high-iron bauxite
CN101524667B (en) Process for dressing ore of powder low grade iron oxide ore
CN107119185B (en) A kind of complicated difficult selects the magnetizing roast method of mixed type iron ore
CN1776421A (en) Device for measuring reaction rateof flash magnetized calcination for refractory iron oxide ore
CN102168170A (en) Method for converting natural non-magnetic iron ore into magnetite
CN108677003B (en) A kind of fluidisation state calciner
CN102268533B (en) Move horizontally-fixed-bed type Magnetization reductive roasting technique
CN109943710A (en) A kind of Iron Ore Powder multistage suspension state reduction roasting device and method
CN108950179A (en) A kind of refractory iron ore low temperature reduction with hydrogen magnetic roasting process

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant