CN108677003A - A kind of fluidisation state calciner - Google Patents

A kind of fluidisation state calciner Download PDF

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Publication number
CN108677003A
CN108677003A CN201810508876.5A CN201810508876A CN108677003A CN 108677003 A CN108677003 A CN 108677003A CN 201810508876 A CN201810508876 A CN 201810508876A CN 108677003 A CN108677003 A CN 108677003A
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gas
magnetic
reduction reactor
reactor
distribution grid
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CN108677003B (en
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高鹏
韩跃新
唐志东
李艳军
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Northeastern University China
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/02Roasting processes
    • C22B1/10Roasting processes in fluidised form

Abstract

The present invention relates to a kind of fluidisation state calciners, belong to technical field of mineral processing.A kind of fluidisation state calciner, described device includes the reduction reactor being arranged perpendicular to ground and the field generator for magnetic for acting on the reduction reactor, the field generator for magnetic generates the uniform magnetic field of magnetic direction vertically upward, the main body of the reduction reactor is a cylindrical chamber container, container bottom is equipped with gas access, the gas distribution grid for being fixed on container bottom side wall in edge is equipped in cavity, the cavity between gas distribution grid and gas access is gas distributing chamber;Material inlet is set on the side wall above gas distribution grid;Reduction reactor container head is equipped with gas vent, and material outlet is equipped in upper portion side wall.The present invention rationally controls the flow behavior of inside reactor magnetic-particle by the way that stabilizing magnetic field is added around reduction reactor, its internal Gas-solid Two-phase Flow is made more to stablize, and gas reacts fully with iron ore, improves roasting efficiency.

Description

A kind of fluidisation state calciner
Technical field
The present invention relates to a kind of fluidisation state calciners, belong to technical field of mineral processing.
Background technology
Iron ore is the protection resource of China's steel and iron industry, belongs to the Major Strategic Demand of country.China's iron ore deposit is reported Tax is poor, hardly possible utilizes, it is of high cost to pick up, and domestic iron ore is chronically at serious non-starving condition, China's imported Fe ore in 2016 10.24 hundred million t, external dependence degree are more than 86%, are recorded high.2 months 2017 iron ore imports valences rise to 90 beautiful yuan/ton, directly Connecing leads to being significantly increased for China's iron ore imports cost, this not only causes to seriously affect to China's steel industry, is passed through to its people The safe operation of Ji also constitutes grave danger.In China's Refractory iron ore resource, fine- disseminated ore, siderite, limonite, Oolitic hematite belongs to typical difficult and utilizes iron ore deposit, gross reserves up to 20,000,000,000 tons or more, be distributed widely in Liaoning, Hebei, Shanxi, The ground such as Shaanxi, Hubei, Xinjiang.Since such iron ore mineral composition is complicated, grain size number is fine, using conventional technique of preparing hardly possible To obtain preferable technical-economic index, part resource not yet obtains heavy industrialization utilization, though part resource is able to Exploitation, but utilization ratio is extremely low.Thus, autonomous innovation technology is researched and developed, realizes that the Efficient Development of China's iron ore deposit utilizes, is improved The iron ore degree of self-sufficiency has important strategic importance.
In recent years, domestic many research units are around complicated difficults such as fine- disseminated ore, siderite, limonite, oolitic hematites Efficient Development and the utilization for selecting iron ore deposit, have carried out a large amount of basic research and technology development work, have reached use substantially Selecting smelting combination technique could realize the common recognition of Refractory iron ore resources effective utilization.Wherein magnetizing roast-magnetic separation is that processing is multiple The maximally efficient technology of miscellaneous refractory iron ore, developing the magnetizing roast equipment that production efficiency is high, stable, low energy consumption becomes mine The common ideal of industry scientific circles and industrial circle.Magnetizing roast-magnetic separation refer to by material or ore heated in corresponding atmosphere into Row chemical reaction, makes bloodstone (Fe therein2O3), siderite (FeCO3), limonite (Fe2O3·nH2The weakly magnetic iron ores such as O) Object is changed into ferromagnetic magnetic iron ore (Fe3O4) or maghemite (γ-Fe2O3), recycle the magnetic contrast between mineral to carry out Magnetic separation.
Magnetizing roast mode has shaft roasting, rotary kiln baking, fluosolids roasting etc..Shaft furnace magnetic roasting process is mainly fitted Close the lump ore of processing granularity 25-75mm, and the technique there is single machine processing capacities low, high energy consumption, roasting time are long, product matter Measure the problems such as uneven.It is domestic at present to only have wine steel ore dressing plant using 44 100m3 shaft roasting carbonate containing iron ores.Revolution Kiln magnetic roasting process is suitble to handle the following ores of granularity 25mm, and magnetizing roast quality and separation index are good compared with shaft furnace.Big Xigou ditch Ore dressing plant handles siderite using coal-based rotary kiln magnetizing roast-low intensity magnetic separation-reverse floatation process, obtains iron ore concentrate TFe grades 60.63%, the good industrial production index of iron recovery 75.42%.But rotary kiln technology there are still magnetic susceptibility low, Yi Jie It encloses, produce the problems such as low unstable, operating rate and high energy consumption.
Fluidization refers to that solid material particle is in fluid state under fluid media (medium) effect, and fluidization process has similar liquid The characteristic of body.In recent years, domestic many research units have carried out a large amount of research for fluosolids roasting technology and equipment.With remaining Research Team headed by rich academician forever, it is proposed that the concept of circulating fluidization flash magnetization roasting is based on fluidization and dress It sets, fine ore fluidization magnetic is carried out to carbonate containings iron ores such as the big Xigou ditch siderite in Shaanxi, Kunming Wang Jiatan mines, weight steel building sequence iron ores Change roasting, obtain 55%~60% or more concentrate Iron grade, iron recovery is China up to 70%~75% good index Refractory iron ore opens new approach.Chinese Academy Of Sciences Process Engineering Research Institute proposes low temperature fluidization magnetization Roasting technique has built up 100,000 tons/year of industrial demonstration projects, and commercial test results show 33% limonite of TFe grades, through magnetic 57% or more iron ore concentrate TFe grades, the good technique index of iron recovery 93%~95% are obtained after choosing.Xi'an building technology Big Xigou ditch sparring miberal powder that university is 40~60 μm to granularity carries out suspending magnetization roasting experiment, can get magnetic concentrate Iron grade The roasted product for being 79.39% for 58.21%, iron recovery.Wherein, the most successfully surely belong to the pre- of Northeastern University's independent research Be enriched with suspension roasting magnetic separation technology, with five crest bloodstone of Hubei, the eastern Exemplary deposition type hematite-limonite in Chongqing, Anshan iron and steel plant east tailing, East Anshan iron ore and Powder ore of Jiu Steel etc. are raw material, have carried out the laboratories PSRM and the pilot plant test of system, have obtained good Roasting effect and separation index.
In conclusion although existing fluosolids roasting technology can be such that Iron grade and the rate of recovery all increases substantially, roasting If misoperation during burning, however it remains material back-mixing is serious in reduction reactor, reduction product quality is uneven, discharge is unsmooth The problems such as, therefore development of new fluosolids roasting reaction unit, Gas-particle Flows, chemical reaction in reactor are achieved effective control It is significant.
Invention content
It is an object of the present invention to provide a kind of fluidisation state calciner that can improve iron ore magnetizing roast efficiency, by Stabilizing magnetic field is added around reduction reactor, rationally controls the flow behavior of inside reactor magnetic-particle, makes its internal gas-solid Two-phase flow is more stablized, and gas reacts fully with iron ore, improves roasting efficiency.
A kind of fluidisation state calciner, described device include the reduction reactor being arranged perpendicular to ground and act on this also The field generator for magnetic of former reactor, the field generator for magnetic generate the uniform magnetic field of magnetic direction vertically upward.
Field generator for magnetic of the present invention can be the uniform magnetic field generating means that the prior art provides, generated magnetic field Direction is that vertical (or near normal) faces upward in ground.Preferably, the field generator for magnetic is to be set to outside reduction reactor The several groups electromagnetic coil in portion.The electromagnetic coil is by its self-powered its generated magnetic field intensity of control.
Reduction reactor of the present invention is arranged perpendicular to ground, and the solid material being passed through in it rises with air-flow, and Persistently rise under magnetic fields, prevents material back-mixing.
Preferably, the main body of the reduction reactor is a cylindrical chamber container, and container bottom is equipped with gas access, in chamber The gas distribution grid for being fixed on container bottom side wall in edge is equipped in body, the cavity between gas distribution grid and gas access is gas Body distributing chamber;Material inlet is set on the side wall above gas distribution grid;Material inlet is connected to feed pipe, and the feed pipe is logical Cross screw(-type) feeder connection feed hopper;Reduction reactor container head is equipped with gas vent, goes out equipped with material in upper portion side wall Mouthful.
Further, heating device and the temperature control system for controlling heating device are equipped on the outside of the reduction reactor. Further, the heating device is electric heater unit, uses high purity aluminium oxide as burner hearth material, anti-for ensureing Temperature in device is answered, required temperature is controlled to adjust by temperature control system.
Further, described device includes water cooling dump skip, for accepting the solid material from material outlet.
Further, the gas distribution grid is cell quartz plate, is distributed several ventilation circular holes thereon, and aperture, which is less than, waits for Handle the diameter of iron ore particle.
Further, insulating materials of the reduction reactor container using relative permeability less than 1 is made, such as quartz Glass.
Further, the gas distributing chamber act as gas mixing place, and has cushioning effect simultaneously;
Further, material is continuous-feeding at the material inlet, and material accumulates self-contained lock gas at material inlet Device avoids gas from being escaped from material inlet.
What device of the present invention was connected with material inlet is feed pipe, and material storing is given in feed hopper by spiral Material machine is fed in feed pipe, and controls delivery rate by screw(-type) feeder.Further, the entrance height of the feed pipe is high In reduction reactor height, the power that material flows up in reduction reactor is provided will pass through height of materials difference.
Gas vent of the present invention is used for the discharge and collection of excessive reaction gas, air conservation and harm Crowd.
Further, the gas access is passed through reducing gas CO, H2Deng, and with protective gas N2, while N2Have Fluidization, specific gas ratio are determined according to material properties and roasting index.
The present invention fluidizes state calciner in use, placing a certain amount of iron ore inside reduction reactor container Grain is passed through reducibility gas into reactor, and iron mineral is contacted with gas occurs reduction reaction, is changed by weak magnetism mineral Ferromagnetism iron mineral, under the collective effect in air-flow and magnetic field, uniformly mixing is moved gas with approximate laminar flow with magnetic-particle, Until being flowed out by material outlet.
Another object of the present invention is to provide a kind of fluosolids roasting technique of processing iron ore.
A kind of fluosolids roasting technique of processing iron ore, iron ore particle is continuously passed through also by reduction reactor lower part In former reactor, carries iron ore particle using the reproducibility gaseous mixture air-flow entered by reduction reactor bottom and move upwards simultaneously It is roasted in 500 DEG C~600 DEG C, reaction is continuously discharged via reactor top material outlet in the solid material obtained after roasting At the same time device applies magnetic field to reduction reactor, 40~60kA/m of magnetic field intensity, magnetic direction is vertically upward.
" reproducibility gaseous mixture " of the present invention is the mixture of reducibility gas and inert gas, is preferably CO and nitrogen The mixture of gas composition, further, it is preferable to which the volumetric concentration of CO is 20~40%.
Preferably, the delivery rate of the iron ore particle is 30~80kg/h;Reproducibility gaseous mixture flow velocity is 0.1m/s ~2.0m/s.
The factors such as above-mentioned reproducibility gaseous mixture flow velocity and the density of iron ore material, granularity and stickiness are related, flow velocity choosing Select the movement for making it that can remain upward.
Preferably, include the steps that magnetic separation:By the solid material water cooling being discharged by reactor, drying, be finely ground to- 0.038mm contents account for 60~80%, and magnetic separation tube magnetic separation is carried out under conditions of magnetic field intensity is 70~100kA/m, obtain iron essence Mineral products.
Preferably, when being reacted, initial iron ore particle is added into reduction reactor, addition height is entire reaction The 25%~50% of device.
It is further preferred that iron ore, which is finely ground to -0.074mm, accounts for 50%~90% fineness, it is initially added in reactor Iron ore particle, highly 25%~50% for entire reactor, setting reaction temperature are 500 DEG C~600 DEG C, iron ore particle 30~80kg/h of delivery rate is passed through the gaseous mixture of CO and nitrogen, wherein CO volumetric concentrations 20~40%;Apply magnetic direction to hang down Straight upward magnetic field, sets magnetic field intensity as 40~60kA/m.
A preferred technical solution of the invention is:Iron ore is finely ground to -0.074mm and accounts for 50%~90% fineness, instead It answers and is initially added iron ore particle in device, be highly 25%~50% (ensureing higher than to material inlet) of entire reactor, beat Electrical heating is opened, it is reaction temperature that temperature setting, which is 500 DEG C~600 DEG C, is passed through N2To empty air in reactor, open to mine Valve, setting delivery rate are 30~80kg/h, and (CO volumetric concentrations 20~40%) is passed through pre-heated N by a certain percentage2 And CO, spiral winding power supply is opened, direct current is passed through and obtains the upward magnetic field in direction, set magnetic field intensity as 40~60kA/m. Reducibility gas is passed through into reactor, iron mineral is contacted with gas occurs reduction reaction, is changed by force by weak magnetism mineral Armco magnetic iron mineral, under the collective effect in air-flow and magnetic field, uniformly mixing is moved gas with approximate laminar flow with magnetic-particle, directly Extremely flowed out by discharge gate.After lasting discharging a period of time, feed valve, CO valves are closed, electrical heating switch and electromagnetic wire are closed Power supply is enclosed, continues to be passed through N2Continue 5 minutes, until remnants CO in emptying reactor.It is dried after the water cooled cooling of roasted product It does, weigh, sample, and be finely ground to -0.038mm contents and account for 60~80%, in the condition that magnetic field intensity is 70~100kA/m Lower progress magnetic separation tube magnetic separation experiment obtains the iron extract mine producation that TFe grades are more than 60%.
Beneficial effects of the present invention are:
(1) magnetic fields are relied on, roasting effect is improved.During fluosolids roasting, externally-applied magnetic field can reduce iron mineral The activation energy of reaction accelerates the progress of chemical reaction so that iron mineral is easier to be reduced, and improves roasting efficiency;
(2) to the spiral winding energization in reduction reactor surrounding is arranged, externally-applied magnetic field is obtained.In conventional fluosolids roasting In device, reduction reactor endoparticle concentration and gas-solid speed axially distribution it is serious it is uneven, gas-solid axial backmixing is big lacks Point generally existing is easy, so that iron mineral reduction is uneven, the phenomenon that restoring or owing reduction occurred.And the fluosolids roasting fills Back-mixing can effectively be controlled by setting, and under the influence of a magnetic field, restoring the ferromagnetism magnetic iron ore of generation can preferentially flow up by discharge gate It is discharged in bed, unreacted weak magnetic mineral and non-magnetic iron logistics are dynamic relatively slowly, and Gas-particle Flows are close to laminar flow, particle It is evenly distributed, avoided (deficient) reduction;
(3) roasting can be improved by adjusting residence time of the magnitude of field intensity control iron mineral in reduction reactor Index.Applied field strengths have a direct impact the flowing velocity of magnetic-particle in reduction reactor, if magnetic field intensity is big, magnetic Property Particle Velocity accelerate, in bed the residence time reduce, the recovery time is also reduced therewith;Conversely, then the recovery time increases.Cause This, can adjust magnetic field intensity in real time by the index of roasted product, control its recovery time.
Description of the drawings
Fig. 1 is the structural schematic diagram for fluidizing state calciner,
Reference numeral is as follows:Gas access 1, gas distributing chamber 2, gas distribution grid 3, material inlet 4, reduction reactor 5, Heating device 6, material outlet 7, water cooling dump skip 8, electromagnetic coil 9, temperature control system 10, gas vent 11, feed pipe 12, spiral Batcher 13, feed hopper 14;
Fig. 2 is the sectional view at A-A in Fig. 1.
Specific implementation mode
Following non-limiting embodiments can make those skilled in the art be more fully understood the present invention, but not with Any mode limits the present invention.
Test method described in following embodiments is unless otherwise specified conventional method;The reagent and material, such as Without specified otherwise, commercially obtain.
Embodiment 1
A kind of fluidisation state calciner, described device include the reduction reactor 5 being arranged perpendicular to ground and act on this The field generator for magnetic 9 of reduction reactor, the field generator for magnetic 9 generate the uniform magnetic field of magnetic direction vertically upward, institute It is the several groups electromagnetic coil being set to outside reduction reactor 5 to state field generator for magnetic 9, and the electromagnetic coil is charged certainly by it Source controls its generated magnetic field intensity.
The main body of the reduction reactor 5 is a cylindrical chamber container, and 5 container of reduction reactor is using quartzy glass Glass is made, and container bottom is equipped with gas access 1, and the gas distribution grid 3 for being fixed on container bottom side wall in edge is equipped in cavity, The gas distribution grid 3 is cell quartz plate, is distributed several ventilation circular holes thereon, and aperture is less than pending iron ore particle Diameter;Cavity between gas distribution grid 3 and gas access 1 is gas distributing chamber 2;On the side wall above gas distribution grid 3 Material inlet 4 is set;Material inlet 4 is connected to feed pipe 12, and the feed pipe 12 is connected to feed hopper 14 by screw(-type) feeder 13, The entrance height of the feed pipe 12 is higher than 5 height of reduction reactor;5 container head of reduction reactor is equipped with gas vent 11, Material outlet 7 is equipped in upper portion side wall, the lower section of material outlet is equipped with water cooling dump skip 8, and material outlet 7 is come from for accepting Solid material.5 outside of the reduction reactor is equipped with electric heater unit 6 and the temperature control system 10 for controlling heating device 6, Excessive reaction is discharged and is collected from gas vent 11, air conservation and harm crowd.
This fluidisation state calciner verifies it by laboratory experiment, and the iron ore used selects for Anshan Area Factories and miness stone belongs to bloodstone-siderite mixed ore.The ore chemistry composition analysis result is shown in Table 1, and Fe clusters analysis result is shown in Table 2.As shown in Table 1, it is 9.24%, SiO that TFe grades, which are 34.43%, FeO contents, in ore2Content is 49.41%, harmful element Phosphorus, sulfur content are relatively low, to be respectively 0.07%, 0.05%.Show that the main valuable element of the chats is iron, major impurity ingredient is Silicon.As shown in Table 2, the iron in red (brown) iron ore is 26.01%, and iron occupation rate is 75.85%;Iron in ferric carbonate is 4.98%, iron occupation rate 14.52%, therefore, the main recycle object of the chats is:Bloodstone and siderite.
1 ore chemistry constituent analysis of table/%
2 iron chemical phase analysis result of table/%
Iron ore is finely ground to -0.074mm and accounts for 80% fineness, iron ore particle is initially added in reduction reactor, height For 1/4 (packed height is higher than material inlet) of entire reactor, the electrical heating temperature of electric heater unit is set as 570 DEG C (being reaction temperature), is passed through N2To empty air in reactor, the feed valve of material inlet is opened, setting delivery rate is 40kg/h is passed through and is previously heated to 570 DEG C of N2With the gaseous mixture (wherein CO volumetric concentrations 25%) of CO, gas flow rate is 1.0m/s opens the power supply of helical electromagnetic coils, is passed through direct current and obtains direction magnetic field vertically upward, set magnetic field intensity as 60kA/m persistently discharges after 15min, closes feed valve, the gas inlet valves of material inlet, close opening for electric heater unit Pass and electromagnetic coil power supply, continue to be passed through N2Continue 5 minutes, until remnants CO in emptying reactor.The water cooled drop of roasted product It dried, weighed, sampled after temperature, and be finely ground to -0.038mm contents and account for 70%, in the item that magnetic field intensity is 85kA/m Magnetic separation tube magnetic separation experiment is carried out under part.
Bloodstone-siderite mixed ore that raw ore TFe grades are 34.43% is 60kA/m, CO in applied field strengths Continuous magnetization roasting experiment is carried out under conditions of concentration 25%, 570 DEG C of reduction temperature, material TFe grades are after roasting 35.49%, roasting clinker can obtain the magnetic separation of iron ore concentrate product of TFe grades 66.53%, the rate of recovery 90.35% after magnetic separation.Point Choosing the results are shown in Table 3.
Material screening test result % after table 3 roasts
Embodiment 2
This experiment carries out in the fluosolids roasting device, and the sample ore used is that factories and miness stone is selected in Yunnan Province, belongs to red iron Mine-limonite type Refractory iron ore stone.The ore chemistry composition analysis result is shown in Table 4, and Fe clusters analysis result is shown in Table 5.By Table 4 is it is found that it is 9.24%, SiO that TFe grades, which are 35.25%, FeO contents, in ore2Content is 49.41%, and harmful element phosphorus contains Measure it is relatively low, be 0.88%.Show that the main valuable element of the chats is iron, major impurity ingredient is silicon.As shown in Table 5, red (brown) Iron in iron ore is 34.74%, and iron occupation rate is 98.85%, and therefore, the main recycle object of the chats is:Bloodstone and brown Iron ore.
4 ore chemistry constituent analysis of table/%
5 iron chemical phase analysis result of table/%
Iron ore is finely ground to -0.074mm and accounts for 60% fineness, iron ore particle is initially added in reduction reactor, height For 30% (packed height is higher than material inlet) of entire reactor, the electrical heating temperature of electric heater unit is set as 570 DEG C (being reaction temperature), is passed through N2To empty air in reactor, the feed valve of material inlet is opened, setting delivery rate is 50kg/h is passed through and is previously heated to 570 DEG C of N2With the gaseous mixture (wherein CO volumetric concentrations 30%) of CO, gas flow rate is 1.2m/s opens the power supply of helical electromagnetic coils, is passed through direct current and obtains the upward magnetic field in direction, set magnetic field intensity as 55kA/m persistently discharges after 10min, closes feed valve, the gas inlet valves of material inlet, close opening for electric heater unit Pass and electromagnetic coil power supply, continue to be passed through N2Continue 5 minutes, until remnants CO in emptying reactor.The water cooled drop of roasted product It dried, weighed, sampled after temperature, and be finely ground to -0.038mm contents and account for 80%, in the item that magnetic field intensity is 85kA/m Magnetic separation tube magnetic separation experiment is carried out under part.
Bloodstone-limonite mixed ore that raw ore TFe grades are 35.25% is 55kA/m, CO in applied field strengths Continuous fluidized roasting experiment is carried out under conditions of concentration 30%, 570 DEG C of reduction temperature, material TFe grades are after roasting 36.49%, roasting clinker can obtain the magnetic separation of iron ore concentrate product of TFe grades 65.10%, the rate of recovery 88.11% after magnetic separation.Point Choosing the results are shown in Table 6.
Material screening test result % after table 6 roasts

Claims (8)

1. a kind of fluidisation state calciner, it is characterised in that:Described device includes the reduction reactor (5) being arranged perpendicular to ground And the field generator for magnetic (9) of the reduction reactor is acted on, the field generator for magnetic (9) generates magnetic direction vertically upward Uniform magnetic field.
2. the apparatus according to claim 1, it is characterised in that:The main body of the reduction reactor (5) is a cylindrical chamber Container, container bottom are equipped with gas access (1), and the gas distribution grid for being fixed on container bottom side wall in edge is equipped in cavity (3), the cavity between gas distribution grid (3) and gas access (1) is gas distributing chamber (2);Above gas distribution grid (3) Material inlet (4) is set on side wall, and material inlet (4) is connected to feed pipe (12), and the feed pipe (12) passes through screw(-type) feeder (13) connection feed hopper (14);Reduction reactor (5) container head is equipped with gas vent (11), and material is equipped in upper portion side wall It exports (7).
3. the apparatus according to claim 1, it is characterised in that:The field generator for magnetic (9) is to be set to reduction reaction The external several groups electromagnetic coil of device (5).
4. the apparatus according to claim 1, it is characterised in that:Heating device (6) is equipped on the outside of the reduction reactor (5) And the temperature control system (10) for controlling heating device (6).
5. the apparatus according to claim 1, it is characterised in that:Described device includes water cooling dump skip (8), is come for accepting Solid material from material outlet (7).
6. the apparatus according to claim 1, it is characterised in that:The gas distribution grid (3) is cell quartz plate, thereon Several ventilation circular holes are distributed, aperture is less than the diameter of pending iron ore particle.
7. the apparatus according to claim 1, it is characterised in that:Described reduction reactor (5) container uses relative magnetic permeability Insulating materials of the rate less than 1 is made.
8. the apparatus according to claim 1, it is characterised in that:The entrance height of the feed pipe (12) is higher than reduction reaction Device height provides the power that material flows up in reduction reactor will pass through height of materials difference.
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Publication number Priority date Publication date Assignee Title
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CN2177528Y (en) * 1993-12-20 1994-09-21 中国科学院化工冶金研究所 Fluidized magnetic field separator
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CN106755969A (en) * 2016-11-24 2017-05-31 东北大学 A kind of method of reinforced by additive bloodstone magnetizing roast

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