CN108676233A - A kind of wear resistant polyethylene plastic package material and preparation method thereof - Google Patents
A kind of wear resistant polyethylene plastic package material and preparation method thereof Download PDFInfo
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- CN108676233A CN108676233A CN201810521051.7A CN201810521051A CN108676233A CN 108676233 A CN108676233 A CN 108676233A CN 201810521051 A CN201810521051 A CN 201810521051A CN 108676233 A CN108676233 A CN 108676233A
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- wear resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of wear resistant polyethylene plastic package materials, are made of the raw material of following parts by weight:30 40 parts of polyethylene, 10 15 parts of wheat stalk powder, 5 10 parts of flax fiber, 5 12 parts of propylene-based elastomeric, 38 parts of zinc stearate, 15 parts of degradation of promoter, 24 parts of antioxidant, 24 parts of antiwear assistant, 48 parts of nano-titanium dioxide, 26 parts of coupling agent, 25 parts of zeolite with carrying silver, 25 parts of antistatic agent.The present invention ensures the obdurability of packaging material, and has good degradation effect, reduces the influence to ambient enviroment, and the degradation of promoter of addition can accelerate degradation speed;It is acted on by nano-titanium dioxide, antistatic agent coordinated so that packaging material has good antistatic property;The antiwear assistant of unique formula is added, its surface is made to have superior wear-resisting property, low-temperature impact-resistant performance good;The addition of zeolite with carrying silver, it is safe and non-toxic, antimicrobial efficiency is higher.
Description
Technical field
The present invention relates to packaging material field, specifically a kind of wear resistant polyethylene plastic package material and preparation method thereof.
Background technology
With the fast development of China's packaging industry, packaging production is promoting the development of the national economy, is improving people's object
Position and function in matter culture life increasingly shows.Packaging Industry is arranged as an independent industry system, development
Enter the national economic and social development planning.
Polyethylene is the thermoplastic resin of a kind of multiplet and performance that are produced as monomer using ethylene, and polyethylene has rigid
Property, the advantages such as modulus is relatively low, electrical property is very excellent, solvent resistant, processing performance are excellent, polyethylene be widely used in mining industry,
The fields such as pipeline, agricultural, packaging, food, chemical industry, machinery.
Currently, polythene material needs further to be promoted in wearability.
Invention content
It is above-mentioned to solve the purpose of the present invention is to provide a kind of wear resistant polyethylene plastic package material and preparation method thereof
The problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions:
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
It is 30-40 parts of polyethylene, 10-15 parts of wheat stalk powder, 5-10 parts of flax fiber, 5-12 parts of propylene-based elastomeric, hard
3-8 parts of resin acid zinc, 1-5 parts of degradation of promoter, 2-4 parts of antioxidant, 2-4 parts of antiwear assistant, 4-8 parts of nano-titanium dioxide, idol
Join 2-6 parts of agent, 2-5 parts of zeolite with carrying silver, 2-5 parts of antistatic agent.
The antiwear assistant is made of the raw material of following parts by weight:10-20 parts of carbon fiber, 11-18 parts of talcum powder, poly- four
8-18 parts of vinyl fluoride micro mist, 5-15 parts of high wear-resistant carbon black, 3-5 parts of toughener, 1-3 parts of dispersant, 1-4 parts of graphene, chlorinated wax
2-6 parts, 2-4 parts of levelling agent, 1-2 parts of friction stabilising agent.
The coupling agent is aluminium titanium composite coupler.
The antistatic agent is stearic acid-base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, dodecyl front three
Ammonium chloride, octadecyltrimethylammonium chloride, stearoylketene dimethyl-penten ammonium chloride, dodecyl trimethyl ammonium bromide, ten
Tetraalkyl trimethylammonium bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or poly alkyl alcohol
One or more combinations in ethylene oxide ether phosphate.
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
30 parts of polyethylene, 10 parts of wheat stalk powder, 5 parts of flax fiber, 5 parts of propylene-based elastomeric, 3 parts of zinc stearate, drop
It solves 1 part of accelerating agent, 2 parts of antioxidant, 2 parts of antiwear assistant, 4 parts of nano-titanium dioxide, 2 parts of coupling agent, 2 parts of zeolite with carrying silver, resist
2 parts of electrostatic agent.
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
40 parts of polyethylene, 15 parts of wheat stalk powder, 10 parts of flax fiber, 12 parts of propylene-based elastomeric, 8 parts of zinc stearate,
5 parts of degradation of promoter, 4 parts of antioxidant, 4 parts of antiwear assistant, 8 parts of nano-titanium dioxide, 6 parts of coupling agent, 5 parts of zeolite with carrying silver,
5 parts of antistatic agent.
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
36 parts of polyethylene, 13 parts of wheat stalk powder, 8 parts of flax fiber, 7 parts of propylene-based elastomeric, 5 parts of zinc stearate, drop
Solve 3 parts of accelerating agent, 3 parts of antioxidant, 3 parts of antiwear assistant, 6 parts of nano-titanium dioxide, 4 parts of coupling agent, 3.5 parts of zeolite with carrying silver,
3.5 parts of antistatic agent.
A kind of preparation method of wear resistant polyethylene plastic package material, includes the following steps:
4) part weighs polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric in parts by weight;To matching raw material
Polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric carry out drying preheating,
5) by polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric, zinc stearate, nanometer two after drying preheating
Titanium oxide, zeolite with carrying silver carry out dry-mixed;
6) degradation of promoter, antioxidant, antiwear assistant, coupling agent, anti-quiet is added in the mixed powder prepared to step 3)
Electric agent after high-speed stirred 25-35mi n, is placed in extruding pelletization in screw extruder, and the extruder operating temperature is 165 DEG C-
260℃。
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention is using polyethylene as primary raw material, cooperation wheat stalk powder, flax fiber, then adds suitable additive,
Not only ensure the obdurability of packaging material, but also there is good degradation effect, reduces the influence to ambient enviroment, the drop of addition
Solution accelerating agent can accelerate degradation speed;It is acted on by nano-titanium dioxide, antistatic agent coordinated so that packaging material has
Good antistatic property;The packaging material of the present invention makes its surface have by the antiwear assistant of addition unique formula in raw material
Superior wear-resisting property, low-temperature impact-resistant performance are good;The addition of zeolite with carrying silver, it is safe and non-toxic, antimicrobial efficiency is higher.
Specific implementation mode
Embodiment 1
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
30 parts of polyethylene, 10 parts of wheat stalk powder, 5 parts of flax fiber, 5 parts of propylene-based elastomeric, 3 parts of zinc stearate, drop
It solves 1 part of accelerating agent, 2 parts of antioxidant, 2 parts of antiwear assistant, 4 parts of nano-titanium dioxide, 2 parts of coupling agent, 2 parts of zeolite with carrying silver, resist
2 parts of electrostatic agent.
The antiwear assistant is made of the raw material of following parts by weight:10-20 parts of carbon fiber, 11-18 parts of talcum powder, poly- four
8-18 parts of vinyl fluoride micro mist, 5-15 parts of high wear-resistant carbon black, 3-5 parts of toughener, 1-3 parts of dispersant, 1-4 parts of graphene, chlorinated wax
2-6 parts, 2-4 parts of levelling agent, 1-2 parts of friction stabilising agent.
The coupling agent is aluminium titanium composite coupler.
The antistatic agent is stearic acid-base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, dodecyl front three
Ammonium chloride, octadecyltrimethylammonium chloride, stearoylketene dimethyl-penten ammonium chloride, dodecyl trimethyl ammonium bromide, ten
Tetraalkyl trimethylammonium bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or poly alkyl alcohol
One or more combinations in ethylene oxide ether phosphate.
A kind of preparation method of wear resistant polyethylene plastic package material, includes the following steps:
1) part weighs polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric in parts by weight;To matching raw material
Polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric carry out drying preheating,
2) by polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric, zinc stearate, nanometer two after drying preheating
Titanium oxide, zeolite with carrying silver carry out dry-mixed;
3) degradation of promoter, antioxidant, antiwear assistant, coupling agent, anti-quiet is added in the mixed powder prepared to step 3)
Electric agent after high-speed stirred 25-35mi n, is placed in extruding pelletization in screw extruder, and the extruder operating temperature is 165 DEG C-
260℃。
Embodiment 2
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
40 parts of polyethylene, 15 parts of wheat stalk powder, 10 parts of flax fiber, 12 parts of propylene-based elastomeric, 8 parts of zinc stearate,
5 parts of degradation of promoter, 4 parts of antioxidant, 4 parts of antiwear assistant, 8 parts of nano-titanium dioxide, 6 parts of coupling agent, 5 parts of zeolite with carrying silver,
5 parts of antistatic agent.
The antiwear assistant is made of the raw material of following parts by weight:10-20 parts of carbon fiber, 11-18 parts of talcum powder, poly- four
8-18 parts of vinyl fluoride micro mist, 5-15 parts of high wear-resistant carbon black, 3-5 parts of toughener, 1-3 parts of dispersant, 1-4 parts of graphene, chlorinated wax
2-6 parts, 2-4 parts of levelling agent, 1-2 parts of friction stabilising agent.
The coupling agent is aluminium titanium composite coupler.
The antistatic agent is stearic acid-base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, dodecyl front three
Ammonium chloride, octadecyltrimethylammonium chloride, stearoylketene dimethyl-penten ammonium chloride, dodecyl trimethyl ammonium bromide, ten
Tetraalkyl trimethylammonium bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or poly alkyl alcohol
One or more combinations in ethylene oxide ether phosphate.
A kind of preparation method of wear resistant polyethylene plastic package material, includes the following steps:
1) part weighs polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric in parts by weight;To matching raw material
Polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric carry out drying preheating,
2) by polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric, zinc stearate, nanometer two after drying preheating
Titanium oxide, zeolite with carrying silver carry out dry-mixed;
3) degradation of promoter, antioxidant, antiwear assistant, coupling agent, anti-quiet is added in the mixed powder prepared to step 3)
Electric agent after high-speed stirred 25-35mi n, is placed in extruding pelletization in screw extruder, and the extruder operating temperature is 165 DEG C-
260℃。
Embodiment 3
A kind of wear resistant polyethylene plastic package material, is made of the raw material of following parts by weight:
36 parts of polyethylene, 13 parts of wheat stalk powder, 8 parts of flax fiber, 7 parts of propylene-based elastomeric, 5 parts of zinc stearate, drop
Solve 3 parts of accelerating agent, 3 parts of antioxidant, 3 parts of antiwear assistant, 6 parts of nano-titanium dioxide, 4 parts of coupling agent, 3.5 parts of zeolite with carrying silver,
3.5 parts of antistatic agent.
The antiwear assistant is made of the raw material of following parts by weight:10-20 parts of carbon fiber, 11-18 parts of talcum powder, poly- four
8-18 parts of vinyl fluoride micro mist, 5-15 parts of high wear-resistant carbon black, 3-5 parts of toughener, 1-3 parts of dispersant, 1-4 parts of graphene, chlorinated wax
2-6 parts, 2-4 parts of levelling agent, 1-2 parts of friction stabilising agent.
The coupling agent is aluminium titanium composite coupler.
The antistatic agent is stearic acid-base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, dodecyl front three
Ammonium chloride, octadecyltrimethylammonium chloride, stearoylketene dimethyl-penten ammonium chloride, dodecyl trimethyl ammonium bromide, ten
Tetraalkyl trimethylammonium bromide, cetyl trimethylammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or poly alkyl alcohol
One or more combinations in ethylene oxide ether phosphate.
A kind of preparation method of wear resistant polyethylene plastic package material, includes the following steps:
1) part weighs polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric in parts by weight;To matching raw material
Polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric carry out drying preheating,
2) by polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric, zinc stearate, nanometer two after drying preheating
Titanium oxide, zeolite with carrying silver carry out dry-mixed;
3) degradation of promoter, antioxidant, antiwear assistant, coupling agent, anti-quiet is added in the mixed powder prepared to step 3)
Electric agent after high-speed stirred 25-35mi n, is placed in extruding pelletization in screw extruder, and the extruder operating temperature is 165 DEG C-
260℃。
Claims (8)
1. a kind of wear resistant polyethylene plastic package material, which is characterized in that be made of the raw material of following parts by weight:
30-40 parts of polyethylene, 10-15 parts of wheat stalk powder, 5-10 parts of flax fiber, 5-12 parts of propylene-based elastomeric, stearic acid
3-8 parts of zinc, 1-5 parts of degradation of promoter, 2-4 parts of antioxidant, 2-4 parts of antiwear assistant, 4-8 parts of nano-titanium dioxide, coupling agent
2-6 parts, 2-5 parts of zeolite with carrying silver, 2-5 parts of antistatic agent.
2. a kind of wear resistant polyethylene plastic package material according to claim 1, which is characterized in that the antiwear assistant,
It is made of the raw material of following parts by weight:10-20 parts of carbon fiber, 11-18 parts of talcum powder, 8-18 parts of ptfe micropowder, height are resistance to
Grind 5-15 parts of carbon black, 3-5 parts of toughener, 1-3 parts of dispersant, 1-4 parts of graphene, 2-6 parts of chlorinated wax, 2-4 parts of levelling agent, friction
1-2 parts of stabilizer.
3. a kind of wear resistant polyethylene plastic package material according to claim 1, which is characterized in that the coupling agent is aluminium
Titanium composite coupler.
4. a kind of wear resistant polyethylene plastic package material according to claim 1, which is characterized in that the antistatic agent is
Stearic acid-base trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, dodecyl trimethyl ammonium chloride, octadecyl trimethyl
Ammonium chloride, stearoylketene dimethyl-penten ammonium chloride, dodecyl trimethyl ammonium bromide, tetradecyltrimethylammonium bromide, 16
Alkyl trimethyl ammonium bromide, trihydroxyethyl methyl quaternary amine Methylsulfate or one kind in fatty alcohol polyoxyethylene ether phosphate or
Multiple combinations.
5. a kind of wear resistant polyethylene plastic package material according to claim 1, which is characterized in that by following parts by weight
Raw material is made:
30 parts of polyethylene, 10 parts of wheat stalk powder, 5 parts of flax fiber, 5 parts of propylene-based elastomeric, 3 parts of zinc stearate, degradation promote
Into 1 part of agent, 2 parts of antioxidant, 2 parts of antiwear assistant, 4 parts of nano-titanium dioxide, 2 parts of coupling agent, 2 parts of zeolite with carrying silver, antistatic
2 parts of agent.
6. a kind of wear resistant polyethylene plastic package material according to claim 1, which is characterized in that by following parts by weight
Raw material is made:
40 parts of polyethylene, 15 parts of wheat stalk powder, 10 parts of flax fiber, 12 parts of propylene-based elastomeric, 8 parts of zinc stearate, degradation
It is 5 parts of accelerating agent, 4 parts of antioxidant, 4 parts of antiwear assistant, 8 parts of nano-titanium dioxide, 6 parts of coupling agent, 5 parts of zeolite with carrying silver, anti-quiet
5 parts of electric agent.
7. a kind of wear resistant polyethylene plastic package material according to claim 1, which is characterized in that by following parts by weight
Raw material is made:
36 parts of polyethylene, 13 parts of wheat stalk powder, 8 parts of flax fiber, 7 parts of propylene-based elastomeric, 5 parts of zinc stearate, degradation promote
Into 3 parts of agent, 3 parts of antioxidant, 3 parts of antiwear assistant, 6 parts of nano-titanium dioxide, 4 parts of coupling agent, 3.5 parts of zeolite with carrying silver, anti-quiet
3.5 parts of electric agent.
8. a kind of preparation method of wear resistant polyethylene plastic package material, which is characterized in that include the following steps:
1) part weighs polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric in parts by weight;To matching the poly- second of raw material
Alkene, wheat stalk powder, flax fiber, propylene-based elastomeric carry out drying preheating,
2) by polyethylene, wheat stalk powder, flax fiber, propylene-based elastomeric, zinc stearate, nanometer titanium dioxide after drying preheating
Titanium, zeolite with carrying silver carry out dry-mixed;
3) degradation of promoter, antioxidant, antiwear assistant, coupling agent, antistatic agent is added in the mixed powder prepared to step 3),
After high-speed stirred 25-35min, it is placed in extruding pelletization in screw extruder, the extruder operating temperature is 165 DEG C -260 DEG C.
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CN109735128A (en) * | 2018-12-05 | 2019-05-10 | 湖南映宏新材料股份有限公司 | A kind of steel roll package material and preparation method thereof |
CN111533982A (en) * | 2020-06-22 | 2020-08-14 | 杭州迅美塑料制品有限责任公司 | Formula of biodegradable cosmetic plastic bottle |
CN111732774A (en) * | 2020-06-19 | 2020-10-02 | 浙江晟祺实业有限公司 | Polyethylene plastic packaging material and preparation method thereof |
CN112225975A (en) * | 2020-10-15 | 2021-01-15 | 吴江鼎泰电子材料有限公司 | Preparation method of elastic damping plastic packaging material |
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