CN108659853A - A kind of liquid-crystal composition containing fluoroalkyl liquid-crystal compounds and its application - Google Patents
A kind of liquid-crystal composition containing fluoroalkyl liquid-crystal compounds and its application Download PDFInfo
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- CN108659853A CN108659853A CN201710198166.2A CN201710198166A CN108659853A CN 108659853 A CN108659853 A CN 108659853A CN 201710198166 A CN201710198166 A CN 201710198166A CN 108659853 A CN108659853 A CN 108659853A
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Abstract
The present invention relates to a kind of liquid-crystal compositions containing fluoroalkyl liquid-crystal compounds, wherein including the compound representated by least one general formula I and the compound representated by least one general formula II.Wherein, the compound representated by general formula I contains 2,3 difluorobenzene structures, has larger negative dielectric anisotropic and high clearing point；Compound representated by general formula II contains 2,3 difluorobenzene of biphenyl of fluoroalkyl, has low rotary viscosity, larger optical anisotropy and larger negative dielectric anisotropic.Liquid-crystal composition of the present invention has low rotary viscosity, big elastic constant, good low temperature intersolubility and fast response speed, it can be used for the fast-response liquid crystal display of plurality of display modes, its use in VA/MVA/PVA/PSVA, IPS or FFS mode display can be obviously improved liquid crystal display display effect, especially highly effective to improving the response time of liquid crystal display.
Description
Technical field
The invention belongs to liquid crystal material and its application fields, are related to a kind of liquid-crystal composition, specifically a kind of nematic
Phase liquid-crystal composition, exactly liquid-crystal composition provided by the present invention is with negative dielectric anisotropy, more specifically
Liquid-crystal composition provided by the present invention has the fast response time.
Background technology
Currently, liquid crystal is widely applied in field of information display, while the application in optical communication also achieves one
Fixed progress (S.T.Wu, D.K.Yang.Reflective Liquid Crystal Displays.Wiley, 2001).It is close several
Year, the application field of liquid-crystal compounds significantly widens kinds of displays part, electro-optical device, electronic component, sensor etc.,
Nematic liquid crystal compound obtains most commonly used application in flat-panel monitor, is especially used for tft active matrix
In system.
Liquid crystal display experienced very long road for development with the discovery of liquid crystal.Austrian botanist in 1888
Friedrich Reinitzer are found that the first liquid crystal material benzoic acid cholesterol (cholesteryl benzoate).
Manguin has invented rubbing within 1917, to make single domain liquid crystal and research optical anisotropy.E.Bose in 1909
Moving (Swarm) theory is established, and (1918) are supported in the experiment for obtaining L.S.Ormstein and F.Zernike et al., after
It is discussed as statistical fluctuation through De Gennes.G.W.Oseen and H.Zocher founded continuum theory in 1933, and obtained
F.C.Frank perfect (1958).M.Born (1916) and K.Lichtennecker (nineteen twenty-six) has found and has studied liquid crystal
Dielectric anisotropy.1932, nematic phase was divided into positive and negative property two major classes by W.Kast accordingly.Nineteen twenty-seven,
V.Freedericksz and V.Zolinao has found that nematic liquid crystal under electric field or magnetic fields, deforms upon and there are voltages
Threshold value (Freederichsz transformations).This making for being found to be liquid crystal display provides foundation.
Nineteen sixty-eight RCA Corp. of U.S. R.Williams finds that nematic liquid crystal forms striped farmland under electric field action, and has
Light scattering phenomenon.With dynamic scattering display pattern is developed into and first liquid crystal in the world is made in G.H.Heilmeir
Display (LCD).Early seventies, Helfrich and Schadt have invented TN principles, and people are using TN photoelectric effect and integrate
Circuit is combined, and is made display device (TN-LCD), and wide foreground has been opened up for the application of liquid crystal.The seventies with
Come, due to the development of large scale integrated circuit and liquid crystal material, application of the liquid crystal in terms of display achieves breakthrough development,
1983~1985 years T.Scheffer et al. successively propose super-twist nematic (Super Twisred Nematic：STN) pattern
And active matrix (the Active matrix that P.Brody was proposed in 1972：AM) mode is used again.Traditional TN-
LCD technology has developed into STN-LCD and TFT-LCD technologies, although the number of scanning lines of STN up to 768 rows more than, work as temperature
The problems such as response speed, visual angle and gray scale are remained when raising, therefore large area, high information quantity, colored display are mostly
Using Active Matrix LCD At mode.TFT-LCD is widely used for direct viewing type TV, large-curtain projecting TV set, terminal
Display and certain military instrument are shown, it is believed that TFT-LCD technologies have more wide application prospect.
Wherein " active matrix " includes two types：1, the OMS on the silicon wafer as substrate (partly lead by metal oxide
Body) or other diodes.2, the thin film transistor (TFT) on the glass plate as substrate (TFT).
Monocrystalline silicon limits display size as substrate material, because each section display device even module assembled is tied at it
Occur many problems at conjunction.Thus, second of thin film transistor (TFT) is the promising active matrix type of tool, the photoelectricity effect utilized
Should be typically TN effects.TFT includes compound semiconductor, such as Cdse, or the TFT based on polycrystalline or amorphous silicon.
Negative liquid crystal is most proposed earlier than the end of the eighties in last century, is mainly used for VA patterns, major advantage is to compare
Degree is high, and major defect is that visual angle is small, and the response time is slow.With the development of display technology, the technologies such as MVA, PVA, PSVA go out in succession
It is existing, solve the problems, such as response time and visual angle.In recent years, as touch screen becomes the mobile device market mainstream, IPS and FFS
The hard panel type display of class has inborn advantage, IPS and FFS class displays that can both use positivity liquid crystal, can also use negativity
Liquid crystal, due to being bent electric field present in the class display, positivity liquid crystal is arranged along electric field line direction, curved so as to cause molecule
Song, and decline in transmitance；Negative liquid crystal is arranged perpendicular to electric field line direction, thus transmitance can be substantially improved, and be current
It promotes transmitance, reduce backlight power consumption the best way.But response time problem existing for negative liquid crystal is the weight currently encountered
Hang-up, the FFS display response times slow 50% or more using the FFS displays of negative liquid crystal relative to positivity liquid crystal.
Therefore, how to promote the response time of negative liquid crystal becomes current key problem.
Specifically, the response time of liquid crystal display, (d was thickness of liquid crystal layer, and γ 1 is depending on " (d^2 γ 1)/K " _ eff
Liquid crystal rotary viscosity, Keff are effective elastic constant), therefore, rotary viscosity is reduced, thickness of liquid crystal layer is reduced and promotes elasticity often
Number can achieve the purpose that improve the response time, and thickness of liquid crystal layer depends on the design of liquid crystal display；For liquid crystal combination
Object, reduces rotary viscosity and thickness of liquid crystal is most effective.
Liquid-crystal composition provided by the present invention has low rotary viscosity, can be effectively reduced the response of liquid crystal display
Time.
Invention content
The purpose of the present invention is overcoming the deficiencies of existing technologies, provides and containing fluoroalkyl liquid-crystal compounds containing one kind
Liquid-crystal composition, the composition has the comprehensive advantages such as fast-response time.
Specifically, liquid-crystal composition provided by the invention includes the compound and extremely representated by least one general formula I
Compound representated by a kind of few general formula II.
The general formula I is specially：
In the general formula I, R1、R2Table C each independently1~C12Straight chained alkyl, unbranched alkoxy or C2~C12Straight chain
Alkenyl；Ring A1Selected from lower structure：
The general formula II is specially：
In the general formula II, R3Represent C1~C12Straight chained alkyl, unbranched alkoxy or C2~C12Straight-chain alkenyl；L1Generation
Table H or F；The integer that n is 1~6, preferably 1~5 integer.
Compound representated by general formula I provided by the invention is the liquid-crystal compounds for containing 2,3- difluorobenzene structures, such
Compound has larger negative dielectric anisotropic and high clearing point.In liquid-crystal composition provided by the invention, each liquid crystal group
/ and be 100%；The content of compound in the composition is preferably 5~70% described in general formula I, and more preferably 8~60%, 10
~57%, 35~60%, 35~57%, 8~40%, 10~40%, 25~60%, 26~57%, 10~56%, 8~50%,
10~49%, 30~60%, 35~57%, 10~45%, 23~60% or 38%.
Preferably, the compound representated by general formula I is selected from the one or more of the compound representated by Formulas I A~Formulas I E：
In the IA~IE, R1Represent C1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl, preferably C2~C5It is straight
Alkyl group；R2Represent C1~C7Straight chained alkyl or unbranched alkoxy, preferably C1~C4Straight chained alkyl or unbranched alkoxy.
As the preferred embodiment of the present invention, the compound representated by general formula I be selected from IA1~IA24, IB1~IB24, IC1~
The one or more of compound representated by IC24, ID1~ID24, IE1~IE24：
The compound represented containing at least one general formula IA in the compound that preferred formula I of the present invention is represented, or containing extremely
The compound that the compound and at least one general formula IB that a kind of few general formula IA is represented represent, or represented containing at least one general formula IA
Compound, at least one general formula IB represent compound and at least one general formula IC represent compound.
It is further preferred that the compound that general formula IA is represented account for the liquid-crystal composition total amount 1~50%, 2~45%,
1~35%, 2~30%, 10~50% or 13~45%.
It is further preferred that the compound that general formula IB is represented account for the liquid-crystal composition total amount 3~30%, 5~25%,
3~22% or 5~19%.
It is further preferred that the compound that general formula IC is represented accounts for the 4~14% of the liquid-crystal composition total amount.
Compound representated by general formula II provided by the present invention is the biphenyl 2 containing fluoroalkyl, 3- difluoros
The liquid-crystal compounds of benzene, such compound have low rotary viscosity, larger optical anisotropy and larger negative dielectric
Anisotropy.In liquid-crystal composition provided by the invention, the sum of each liquid crystal components are 100%；Compound is in group described in general formula II
Close object in content be preferably 1~40%, more preferably 3~35%, 5~30%, 8~35%, 10~30%, 10~35%,
15~30%, 3~20%, 5~20%, 3~30%, 5~28% or 15%.
Preferably, compounds of formula II provided by the present invention is one or more in IIA and IIB：
In the IIA~IIB, R3Represent C1~C7Straight chained alkyl or unbranched alkoxy, preferably 1~4 straight chained alkyl
Or unbranched alkoxy；The integer that n is 1~5, preferably 2~5 integer.
As the present invention preferred embodiment, compounds of formula II in IIA1~IIA24, IIB1~IIB24 one
Kind is a variety of：
Liquid-crystal composition provided by the present invention can also further include one or more compounds of formula III.It is logical
Compound representated by formula III is twin nuclei, has the characteristics that low rotary viscosity and excellent intersolubility.It is provided by the invention
In liquid-crystal composition, the sum of each liquid crystal components are 100%；The content of compound described in general formula III in the composition is preferably 10
~70%, more preferably 15~65%, 19~60%, 25~55%, 30~53%, 15~55%, 19~53%, 20~
65%, 24~60%, 30~65%, 30~60%, 15~35%, 19~35%, 27~53% or 32%.
The general formula III is specially：
In the general formula III, R4、R5C is represented each independently1~C12Straight chained alkyl, unbranched alkoxy or C2~C12's
Straight-chain alkenyl；Ring A2、A3Trans- 1,4- cyclohexyl or 1,4 phenylenes are represented each independently.
Preferably, the compound representated by the general formula III is one or more in IIIA~IIIC：
In the IIIA~IIIC, R4Represent C1~C7Straight chained alkyl, preferably C2~C5Straight chained alkyl；R5Represent C1
~C7Straight chained alkyl, unbranched alkoxy or C2~C7Straight-chain alkenyl, preferably C1~C5Straight chained alkyl, unbranched alkoxy or
C2~C5Straight-chain alkenyl.
As the preferred embodiment of the present invention, the compound representated by general formula III be selected from formula III A1~IIIA34, IIIB1~
The one or more of compound representated by IIIB24, IIIC1~IIIC24：
Liquid-crystal composition provided by the present invention also can further include one or more chemical combination selected from general formula IV structures
Object.
Compound representated by general formula IV is nonpolar tricyclic compound, such monomer has high clearing point and big bullet
Property constant, be conducive to improve liquid-crystal composition elastic constant.In liquid-crystal composition provided by the invention, the sum of each liquid crystal components
It is 100%；The content of compound in the composition is preferably 0~40% described in general formula IV, more preferably 0~30%, 0~
15%, 0~11%, 0~28%, 0~25%, 0~20%, 1~30%, 3~28%, 1~25% or 3~20%.
The general formula IV is specially：
In the general formula IV, R6、R7C is represented each independently1~C12Straight chained alkyl, wherein one or more are non-conterminous
CH2It can be replaced by O or CH=CH；Ring A4Selected from lower structure：
Preferably, the compound representated by general formula IV is selected from the one or more of formula IV A~following compounds of formula IV C：
In the IVA~IVC, R6Represent C2~C10Straight chained alkyl or straight-chain alkenyl, preferably C2~C5Straight chained alkyl
Or straight-chain alkenyl；R7Represent C1~C8Straight chained alkyl, preferably C1~C5Straight chained alkyl.
As the preferred embodiment of the present invention, compound representated by general formula IV be selected from formula IV A1~IVA18, IVB1~IVB22,
It is one or more in IVC1~IVC30 structures：
Liquid-crystal composition provided by the present invention also can further include one or more selected from compounds of formula V.It is logical
Compound representated by Formula V is terphenyl compounds, such compound has big optical anisotropy, can effectively promote liquid crystal
The optical anisotropy of composition.In liquid-crystal composition provided by the invention, the sum of each liquid crystal components are 100%；Described in general formula V
The content of compound in the composition is preferably 0~30%, more preferably 0~20%, 0~15% or 15%.
The general formula V is specially：
In the general formula V, R8Represent C1~C12Straight chained alkyl or C2~C12Straight-chain alkenyl；R9Represent F, C1~C12's
Straight chained alkyl, unbranched alkoxy C2~C12Straight-chain alkenyl；L2、L3、L4H or F, preferably L are represented each independently2、L3、L4It is different
When be F.
Preferably, compounds of formula V is one or more in VA~VD；
In the VA~VD, R8Represent C1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl, preferably C2~C5It is straight
Alkyl group or straight-chain alkenyl；R9Represent C1~C7Straight chained alkyl, unbranched alkoxy or C2~C7Straight-chain alkenyl, preferably C1~
C5Straight chained alkyl, unbranched alkoxy or C2~C5Straight-chain alkenyl.
As the preferred embodiment of the present invention, the compound representated by general formula V is selected from Formula V A1~VA4, VB1~VB24, VC1
It is one or more in~VC14, VD1~VD24：
In order to ensure realizing synergistic effect between each component, the resultant effect of the liquid crystal material is improved, the present invention is into one
It walks and the dosage of the middle each component of the liquid crystal material is carried out preferably.
Specifically, liquid-crystal composition provided by the present invention includes following components：
Compound representated by (1) 5~70% general formula I；Compound representated by (2) 1~40% general formula II；(3) 10~
Compound representated by 70% general formula III；Compound representated by (4) 0~40% general formula IV；(5) 0~30% general formula V institute's generations
The compound of table.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~60% general formula I；Compound representated by (2) 3~35% general formula II；(3) 15~
Compound representated by 65% general formula III；Compound representated by (4) 0~30% general formula IV；(5) 0~20% general formula V institute's generations
The compound of table.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~57% general formula I；Compound representated by (2) 5~30% general formula II；(3) 19~
Compound representated by 60% general formula III；Compound representated by (4) 0~28% general formula IV；(5) 0~15% general formula V institute's generations
The compound of table.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 35~60% general formula I；Compound representated by (2) 3~35% general formula II；(3) 15~
Compound representated by 65% general formula III；Compound representated by (4) 0~15% general formula IV；(5) 0~20% general formula V institute's generations
The compound of table.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 35~57% general formula I；Compound representated by (2) 5~30% general formula II；(3) 19~
Compound representated by 60% general formula III；Compound representated by (4) 0~11% general formula IV；(5) 0~15% general formula V institute's generations
The compound of table.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~40% general formula I；Compound representated by (2) 8~35% general formula II；(3) 25~
Compound representated by 55% general formula III；Compound representated by (4) 0~30% general formula IV；(5) 0~20% general formula V institute's generations
The compound of table.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~40% general formula I；Compound representated by (2) 10~30% general formula II；(3)30
Compound representated by~53% general formula III；Compound representated by (4) 0~28% general formula IV；(5) 0~15% general formula V institutes
The compound of representative.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 25~60% general formula I；Compound representated by (2) 10~35% general formula II；(3)15
Compound representated by~55% general formula III；Compound representated by (4) 0~15% general formula IV；(5) 0~20% general formula V institutes
The compound of representative.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 26~57% general formula I；Compound representated by (2) 15~30% general formula II；(3)19
Compound representated by~53% general formula III；Compound representated by (4) 0~11% general formula IV；(5) 0~15% general formula V institutes
The compound of representative.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~60% general formula I；Compound representated by (2) 3~20% general formula II；(3) 20~
Compound representated by 65% general formula III；Compound representated by (4) 0~30% general formula IV；(5) 0~20% general formula V institute's generations
The compound of table.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~56% general formula I；Compound representated by (2) 5~20% general formula II；(3) 24~
Compound representated by 60% general formula III；Compound representated by (4) 0~28% general formula IV；(5) 0~15% general formula V institute's generations
The compound of table.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~50% general formula I；Compound representated by (2) 3~35% general formula II；(3) 30~
Compound representated by 65% general formula III；Compound representated by (4) 0~30% general formula IV；(5) 0~20% general formula V institute's generations
The compound of table.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~49% general formula I；Compound representated by (2) 5~30% general formula II；(3) 30~
Compound representated by 60% general formula III；Compound representated by (4) 0~28% general formula IV；(5) 0~15% general formula V institute's generations
The compound of table.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 30~60% general formula I；Compound representated by (2) 10~35% general formula II；(3)15
Compound representated by~35% general formula III；Compound representated by (4) 0~15% general formula IV；(5) 0~20% general formula V institutes
The compound of representative.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 35~57% general formula I；Compound representated by (2) 15~30% general formula II；(3)19
Compound representated by~35% general formula III；Compound representated by (4) 0~11% general formula IV；(5) 0~15% general formula V institutes
The compound of representative.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~50% general formula I；Compound representated by (2) 3~30% general formula II；(3) 25~
Compound representated by 55% general formula III；Compound representated by (4) 1~30% general formula IV.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~45% general formula I；Compound representated by (2) 5~28% general formula II；(3) 27~
Compound representated by 53% general formula III；Compound representated by (4) 3~28% general formula IV.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 23~60% general formula I；Compound representated by (2) 3~35% general formula II；(3) 15~
Compound representated by 65% general formula III；Compound representated by (4) 0~20% general formula V.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 26~57% general formula I；Compound representated by (2) 5~30% general formula II；(3) 19~
Compound representated by 60% general formula III；Compound representated by (4) 0~15% general formula V.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 1~50% general formula IA；Compound representated by (2) 3~30% general formula IB；(3) 3~
Compound representated by 30% general formula II；Compound representated by (4) 15~65% general formula IIIs；(5) 0~25% general formula IV institutes
The compound of representative；Compound representated by (6) 0~20% general formula V.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 2~45% general formula IA；Compound representated by (2) 5~25% general formula IB；(3) 5~
Compound representated by 28% general formula II；Compound representated by (4) 19~60% general formula IIIs；(5) 0~20% general formula IV institutes
The compound of representative；Compound representated by (6) 0~15% general formula V.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 1~35% general formula IA；Compound representated by (2) 3~22% general formula IB；(3) 3~
Compound representated by 30% general formula II；Compound representated by (4) 25~55% general formula IIIs；(5) 1~25% general formula IV institutes
The compound of representative.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 2~30% general formula IA；Compound representated by (2) 5~19% general formula IB；(3) 5~
Compound representated by 28% general formula II；Compound representated by (4) 31~53% general formula IIIs；(5) 3~20% general formula IV institutes
The compound of representative.
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 10~50% general formula IA；Compound representated by (2) 3~30% general formula IB；(3) 3~
Compound representated by 30% general formula II；Compound representated by (4) 15~65% general formula IIIs；(5) 0~20% general formula V institute's generations
The compound of table.
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 13~45% general formula IA；Compound representated by (2) 5~25% general formula IB；(3) 5~
Compound representated by 24% general formula II；Compound representated by (4) 19~60% general formula IIIs；(5) 0~15% general formula V institute's generations
The compound of table.
As a preferred embodiment of the present invention, the liquid-crystal composition includes following component：
Compound representated by (1) 10~57% general formula I；Preferably, contain at least one in the compound that general formula I is represented
The compound that general formula IA is represented, or the chemical combination containing at least one general formula IA compounds represented and at least one general formula IB representatives
Object, or the compound of the compound containing at least one general formula IA representatives, at least one general formula IB representative and at least one general formula
The compound that IC is represented；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs；
Compound representated by (4) 0~28% general formula IV；
Compound representated by (5) 0~15% general formula V.
As a kind of further preferred embodiment of the present invention, the liquid-crystal composition includes following component：
Compound representated by (1) 26~57% general formula I；Preferably, contain at least one in the compound that general formula I is represented
The compound that general formula IA is represented, or the chemical combination containing at least one general formula IA compounds represented and at least one general formula IB representatives
Object, or the compound of the compound containing at least one general formula IA representatives, at least one general formula IB representative and at least one general formula
The compound that IC is represented；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs.
As a kind of further preferred embodiment of the present invention, the liquid-crystal composition includes following component：
Compound representated by (1) 10~45% general formula I；Preferably, contain at least one in the compound that general formula I is represented
The compound that general formula IA is represented, or the chemical combination containing at least one general formula IA compounds represented and at least one general formula IB representatives
Object, or the compound of the compound containing at least one general formula IA representatives, at least one general formula IB representative and at least one general formula
The compound that IC is represented；
Compound representated by (2) 5~28% general formula II；
Compound representated by (3) 27~53% general formula IIIs；
Compound representated by (4) 3~28% general formula IV.
As a kind of further preferred embodiment of the present invention, the liquid-crystal composition includes following component：
Compound representated by (1) 38% general formula I；Preferably, at least one general formula is contained in the compound that general formula I is represented
The compound that IA is represented, or the compound containing at least one general formula IA compounds represented and at least one general formula IB representatives,
Or compound, the compound of at least one general formula IB representatives and at least one general formula IC generations represented containing at least one general formula IA
The compound of table；
Compound representated by (2) 15% general formula II；
Compound representated by (3) 32% general formula IIIs；
Compound representated by (4) 15% general formula V.
Compound representated by liquid-crystal composition formula of I provided by the present invention is the liquid for containing 2,3- difluorobenzene structures
Brilliant compound, the compound have larger negative dielectric anisotropic and high clearing point；Compound representated by general formula II is
Biphenyl 2 containing fluoroalkyl, the liquid-crystal compounds of 3- difluorobenzenes, such compound has low rotary viscosity, larger
Optical anisotropy and larger negative dielectric anisotropic；Compound representated by general formula III is twin nuclei, is had low
Rotary viscosity and excellent intersolubility feature are the essential component of fast-response liquid crystal display, the chemical combination representated by general formula IV
Object is nonpolar tricyclic compound, such monomer has high clearing point and big elastic constant, is conducive to improve liquid crystal combination
The elastic constant of object；Compound representated by general formula V is terphenyl compounds, such compound has big optics respectively to different
Property, it can effectively promote the optical anisotropy of liquid-crystal composition.
The preparation method of liquid-crystal composition of the present invention can be used conventional method and change two or more without specifically limited
It closes object mixing to be produced, such as be prepared by the method for mixing different component at high temperature and being soluble in one another, wherein by liquid crystal group
It closes object to be dissolved in the solvent for the compound and mix, then distills out the solvent under reduced pressure；Or it is of the present invention
Liquid-crystal composition can be prepared conventionally, and the smaller component of wherein content is such as dissolved in content at a higher temperature
In larger key component, or each affiliated component dissolved in organic solvent, such as acetone, chloroform or methanol, it then will be molten
It is obtained after liquid mixing removal solvent.
There is liquid-crystal composition provided by the present invention low rotary viscosity, big elastic constant, good low temperature to dissolve each other
Property and fast response time, can be used for plurality of display modes fast-response liquid crystal display, VA/MVA/PVA/PSVA, IPS,
There is good display effect in FFS mode liquid crystal display；It is highly effective for the response speed for improving liquid crystal display.
Specific implementation mode
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Unless otherwise indicated, percentage is weight percentage in the present invention；Temperature unit is degree Celsius；△ n represent optics
Anisotropy (25 DEG C)；△ ε represent dielectric anisotropy (25 DEG C, 1000Hz)；V10Threshold voltage is represented, is in relative permeability
Character voltage (V, 25 DEG C) when changing 10%；γ 1 represents rotary viscosity (mPa.s, 25 DEG C)；Cp represents the clear of liquid-crystal composition
Bright spot (DEG C)；K11、K22、K33Respectively represent splay, distortion and bend elastic constant (pN, 25 DEG C).
In following embodiment, unit structure code shown in table 1 indicates in liquid-crystal compounds.
Table 1：The group structure code of liquid-crystal compounds
By taking following compound structure as an example：
It is expressed as：F3OGIWO2
It is expressed as：5CCWO1
In following embodiment, the preparation of liquid-crystal composition is all made of heat of solution method, includes the following steps：It is pressed with balance
Weight percent weighs liquid-crystal compounds, wherein weighing addition sequence without particular requirement, usually with liquid-crystal compounds fusing point by height
Mixing is weighed successively to low sequence, heating stirring makes each component melt uniform at 60~100 DEG C, using filter, rotates,
It finally encapsulates up to target sample.
In following embodiment, the performance parameter of the weight percent of each component when liquid-crystal composition is shown in liquid-crystal composition
Following table.
Embodiment 1
Table 2：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 2
Table 3：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 3
Table 4：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 4
Table 5：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 5
Table 6：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 6
Table 7：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 7
Table 8：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 8
Table 9：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 9
Table 10：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 10
Table 11：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 11
Table 12：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 12
Table 13：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 13
Table 14：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 14
Table 15：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 15
Table 16：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 16
Table 17：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 17
Table 18：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 18
Table 19：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 19
Table 20：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 20
Table 21：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 21
Table 22：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 22
Table 23：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 23
Table 24：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 24
Table 25：The weight percent of each component when performance parameter in liquid-crystal composition
Embodiment 25
Table 26：The weight percent of each component when performance parameter in liquid-crystal composition
Comparative example 1
Table 27：The weight percent of each component when performance parameter in liquid-crystal composition
Compared with embodiment 1 is summarized with each performance parameter value of 1 gained liquid-crystal composition of comparative example, referring to table 28.
Table 28：The performance parameter of liquid-crystal composition compares
| △n | △ε | Cp | γ1 | K11 | K22 | K33 | |
| Embodiment 1 | 0.108 | -4.0 | 91 | 82 | 14.8 | 7.4 | 16.3 |
| Comparative example 1 | 0.108 | -3.8 | 90 | 96 | 14.7 | 7.4 | 16.5 |
Known to relatively：Compared with comparative example 1, the liquid-crystal composition that embodiment 1 provides has low rotary viscosity, that is, has
There is the faster response time.
As seen from the above embodiment, liquid-crystal composition provided by the present invention has low viscosity, high resistivity, suitable light
Anisotropy, good low temperature intersolubility, big elastic constant and excellent photostability and thermal stability are learned, liquid can be reduced
The response time of crystal display, to solve the problems, such as that liquid crystal display response speed is slow.Therefore, liquid crystal provided by the present invention
Composition is suitable for VA display patterns and IPS the and FFS type TFT liquid crystal display devices such as VA/MVA/PVA/PSVA.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (10)
1. a kind of liquid-crystal composition containing fluoroalkyl liquid-crystal compounds, which is characterized in that include at least one general formula I institutes
Compound representated by the compound of representative and at least one general formula II；
The general formula I is specially：
In the general formula I, R1、R2Table C each independently1~C12Straight chained alkyl, unbranched alkoxy or C2~C12Straight chain alkene
Base；Ring A1Selected from lower structure：
The general formula II is specially：
In the general formula II, R3Represent C1~C12Straight chained alkyl, unbranched alkoxy or C2~C12Straight-chain alkenyl；L1Represent H or
F；The integer that n is 1~6.
2. liquid-crystal composition according to claim 1, which is characterized in that the compound representated by general formula I is selected from IA~IE
The one or more of representative compound：
In the IA~IE, R1Represent C1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl；R2Represent C1~C7Straight chained alkyl
Or unbranched alkoxy；
Preferably, the compound representated by general formula I is selected from IA1~IA24, IB1~IB24, IC1~IC24, ID1~ID24, IE1
The one or more of compound representated by~IE24：
3. liquid-crystal composition according to claim 2, which is characterized in that contain at least one in the compound that general formula I is represented
The compound that kind general formula IA is represented, or the change containing at least one general formula IA compounds represented and at least one general formula IB representatives
Object is closed, or logical containing compound, the compound of at least one general formula IB representatives and at least one that at least one general formula IA is represented
The compound that Formulas I C is represented.
4. according to the liquid-crystal composition described in claims 1 to 3 any one, which is characterized in that compounds of formula II is selected from
It is one or more in IIA and IIB：
In the IIA~IIB, R3Represent C1~C7Straight chained alkyl or unbranched alkoxy, n be 1~5 integer；
Preferably, compounds of formula II is one or more in IIA1~IIA24, IIB1~IIB24：
5. according to the liquid-crystal composition described in Claims 1 to 4 any one, which is characterized in that also include one or more logical
The compound of formula III；
The general formula III is specially：
In the general formula III, R4、R5C is represented each independently1~C12Straight chained alkyl, unbranched alkoxy or C2~C12Straight chain
Alkenyl；Ring A2、A3Trans- 1,4- cyclohexyl or 1,4 phenylenes are represented each independently；
Preferably, the compound representated by the general formula III is one or more in IIIA~IIIC：
In the IIIA~IIIC, R4Represent C1~C7Straight chained alkyl；R5Represent C1~C7Straight chained alkyl, unbranched alkoxy or
C2~C7Straight-chain alkenyl；
It is highly preferred that compound representated by general formula III be selected from formula III A1~IIIA34, IIIB1~IIIB24, IIIC1~
The one or more of compound representated by IIIC24：
6. according to the liquid-crystal composition described in Claims 1 to 5 any one, which is characterized in that also include one or more choosings
The compound of self-drifting IV structures；
The general formula IV is specially：
In the general formula IV, R6、R7C is represented each independently1~C12Straight chained alkyl, wherein one or more non-conterminous CH2
It can be replaced by O or CH=CH；Ring A4Selected from lower structure：
Preferably, the compound representated by general formula IV is selected from the one or more of formula IV A~following compounds of formula IV C：
In the IVA~IVC, R6Represent C2~C10Straight chained alkyl or straight-chain alkenyl；R7Represent C1~C8Straight chained alkyl；
It is highly preferred that compound representated by general formula IV is selected from formula IV A1~IVA18, IVB1~IVB22, IVC1~IVC30 structures
In it is one or more：
7. according to the liquid-crystal composition described in claim 1~6 any one, which is characterized in that further comprise it is a kind of or
It is a variety of to be selected from compounds of formula V；
The general formula V is specially：
In the general formula V, R8Represent C1~C12Straight chained alkyl or C2~C12Straight-chain alkenyl；R9Represent F, C1~C12Straight chain
Alkyl, unbranched alkoxy C2~C12Straight-chain alkenyl；L2、L3、L4H or F is represented each independently；
Preferably, compounds of formula V is one or more in VA~VD；
In the VA~VD, R8Represent C1~C7Straight chained alkyl or C2~C7Straight-chain alkenyl, R9Represent C1~C7Straight chain alkane
Base, unbranched alkoxy or C2~C7Straight-chain alkenyl；
It is highly preferred that the compound representated by general formula V is selected from Formula V A1~VA4, VB1~VB24, VC1~VC14, VD1~VD24
In it is one or more：
8. according to the liquid-crystal composition described in claim 1~7 any one, which is characterized in that the liquid-crystal composition includes
Following components：
Compound representated by (1) 5~70% general formula I；
Compound representated by (2) 1~40% general formula II；
Compound representated by (3) 10~70% general formula IIIs；
Compound representated by (4) 0~40% general formula IV；
Compound representated by (5) 0~30% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~60% general formula I；
Compound representated by (2) 3~35% general formula II；
Compound representated by (3) 15~65% general formula IIIs；
Compound representated by (4) 0~30% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~57% general formula I；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs；
Compound representated by (4) 0~28% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 35~60% general formula I；
Compound representated by (2) 3~35% general formula II；
Compound representated by (3) 15~65% general formula IIIs；
Compound representated by (4) 0~15% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 35~57% general formula I；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs；
Compound representated by (4) 0~11% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~40% general formula I；
Compound representated by (2) 8~35% general formula II；
Compound representated by (3) 25~55% general formula IIIs；
Compound representated by (4) 0~30% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~40% general formula I；
Compound representated by (2) 10~30% general formula II；
Compound representated by (3) 30~53% general formula IIIs；
Compound representated by (4) 0~28% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 25~60% general formula I；
Compound representated by (2) 10~35% general formula II；
Compound representated by (3) 15~55% general formula IIIs；
Compound representated by (4) 0~15% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 26~57% general formula I；
Compound representated by (2) 15~30% general formula II；
Compound representated by (3) 19~53% general formula IIIs；
Compound representated by (4) 0~11% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~60% general formula I；
Compound representated by (2) 3~20% general formula II；
Compound representated by (3) 20~65% general formula IIIs；
Compound representated by (4) 0~30% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~56% general formula I；
Compound representated by (2) 5~20% general formula II；
Compound representated by (3) 24~60% general formula IIIs；
Compound representated by (4) 0~28% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~50% general formula I；
Compound representated by (2) 3~35% general formula II；
Compound representated by (3) 30~65% general formula IIIs；
Compound representated by (4) 0~30% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~49% general formula I；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 30~60% general formula IIIs；
Compound representated by (4) 0~28% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 30~60% general formula I；
Compound representated by (2) 10~35% general formula II；
Compound representated by (3) 15~35% general formula IIIs；
Compound representated by (4) 0~15% general formula IV；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 35~57% general formula I；
Compound representated by (2) 15~30% general formula II；
Compound representated by (3) 19~35% general formula IIIs；
Compound representated by (4) 0~11% general formula IV；
Compound representated by (5) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 8~50% general formula I；
Compound representated by (2) 3~30% general formula II；
Compound representated by (3) 25~55% general formula IIIs；
Compound representated by (4) 1~30% general formula IV；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 10~45% general formula I；
Compound representated by (2) 5~28% general formula II；
Compound representated by (3) 27~53% general formula IIIs；
Compound representated by (4) 3~28% general formula IV；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 23~60% general formula I；
Compound representated by (2) 3~35% general formula II；
Compound representated by (3) 15~65% general formula IIIs；
Compound representated by (4) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 26~57% general formula I；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs；
Compound representated by (4) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 1~50% general formula IA；
Compound representated by (2) 3~30% general formula IB；
Compound representated by (3) 3~30% general formula II；
Compound representated by (4) 15~65% general formula IIIs；
Compound representated by (5) 0~25% general formula IV；
Compound representated by (6) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 2~45% general formula IA；
Compound representated by (2) 5~25% general formula IB；
Compound representated by (3) 5~28% general formula II；
Compound representated by (4) 19~60% general formula IIIs；
Compound representated by (5) 0~20% general formula IV；
Compound representated by (6) 0~15% general formula V；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 1~35% general formula IA；
Compound representated by (2) 3~22% general formula IB；
Compound representated by (3) 3~30% general formula II；
Compound representated by (4) 25~55% general formula IIIs；
Compound representated by (5) 1~25% general formula IV；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 2~30% general formula IA；
Compound representated by (2) 5~19% general formula IB；
Compound representated by (3) 5~28% general formula II；
Compound representated by (4) 31~53% general formula IIIs；
Compound representated by (5) 3~20% general formula IV；
Preferably, the liquid-crystal composition includes following components：
Compound representated by (1) 10~50% general formula IA；
Compound representated by (2) 3~30% general formula IB；
Compound representated by (3) 3~30% general formula II；
Compound representated by (4) 15~65% general formula IIIs；
Compound representated by (5) 0~20% general formula V；
It is highly preferred that the liquid-crystal composition includes following components：
Compound representated by (1) 13~45% general formula IA；
Compound representated by (2) 5~25% general formula IB；
Compound representated by (3) 5~24% general formula II；
Compound representated by (4) 19~60% general formula IIIs；
Compound representated by (5) 0~15% general formula V.
9. liquid-crystal composition according to claim 1, which is characterized in that the liquid-crystal composition includes following component：
Compound representated by (1) 10~57% general formula I；Preferably, at least one general formula is contained in the compound that general formula I is represented
The compound that IA is represented, or the compound containing at least one general formula IA compounds represented and at least one general formula IB representatives,
Or compound, the compound of at least one general formula IB representatives and at least one general formula IC generations represented containing at least one general formula IA
The compound of table；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs；
Compound representated by (4) 0~28% general formula IV；
Compound representated by (5) 0~15% general formula V；
Or, the liquid-crystal composition includes following component：
Compound representated by (1) 26~57% general formula I；Preferably, at least one general formula is contained in the compound that general formula I is represented
The compound that IA is represented, or the compound containing at least one general formula IA compounds represented and at least one general formula IB representatives,
Or compound, the compound of at least one general formula IB representatives and at least one general formula IC generations represented containing at least one general formula IA
The compound of table；
Compound representated by (2) 5~30% general formula II；
Compound representated by (3) 19~60% general formula IIIs；
Or, the liquid-crystal composition includes following component：
Compound representated by (1) 10~45% general formula I；Preferably, at least one general formula is contained in the compound that general formula I is represented
The compound that IA is represented, or the compound containing at least one general formula IA compounds represented and at least one general formula IB representatives,
Or compound, the compound of at least one general formula IB representatives and at least one general formula IC generations represented containing at least one general formula IA
The compound of table；
Compound representated by (2) 5~28% general formula II；
Compound representated by (3) 27~53% general formula IIIs；
Compound representated by (4) 3~28% general formula IV；
Or, the liquid-crystal composition includes following component：
Compound representated by (1) 38% general formula I；Preferably, at least one general formula IA generations are contained in the compound that general formula I is represented
The compound of table, or the compound containing at least one general formula IA compounds represented and at least one general formula IB representatives, or contain
There are compound, the compound of at least one general formula IB representatives and at least one general formula IC that at least one general formula IA is represented to represent
Compound；
Compound representated by (2) 15% general formula II；
Compound representated by (3) 32% general formula IIIs；
Compound representated by (4) 15% general formula V.
10. application of the liquid-crystal composition in fast-response liquid crystal display device, preferably exists described in claim 1~9 any one
Application in VA/PVA/MVA/PSVA, IPS or FFS mode display.
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