CN108659793A - A kind of marble surface antilubricant - Google Patents

A kind of marble surface antilubricant Download PDF

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Publication number
CN108659793A
CN108659793A CN201810568842.5A CN201810568842A CN108659793A CN 108659793 A CN108659793 A CN 108659793A CN 201810568842 A CN201810568842 A CN 201810568842A CN 108659793 A CN108659793 A CN 108659793A
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parts
mesh
ball milling
antilubricant
rare earth
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CN201810568842.5A
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张芸
许永博
吴庆梅
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/14Anti-slip materials; Abrasives
    • C09K3/149Antislip compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Lubricants (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

The invention discloses a kind of marble surface antilubricants, belong to building material technical field.The marble surface antilubricant that the present invention develops includes metal powder, rare earth oxide, zinc oxide, magnesia, magnesium chloride, polyacrylic acid zinc, saltcake and polyvinylpyrrolidone, in process for preparation, it first presses raw material composition and weighs each component, metal powder, rare earth oxide, zinc oxide, magnesia, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone are added in ball mill again, after 4~6h of ball milling mixing, discharging, obtains ball milling material;Then gained ball milling material and saltcake are uniformly mixed, discharged to get marble surface antilubricant.Marble surface antilubricant prepared by technical solution of the present invention has the characteristics that excellent non-skid property and polishing performance, has broad prospects in the development of building material technology industry.

Description

A kind of marble surface antilubricant
Technical field
The invention discloses a kind of marble surface antilubricants, belong to building material technical field.
Background technology
The ground (such as square, part road pavement etc.) of public building uses stone material as paving structure, stone material at present Block surfaces are divided into asperities, fine flour, fine face etc..The protrusion and recess heights difference on surface are less than the surface of 0.5mm, such as polish, The surface of the formation such as polishing, diamond saw or disk processing is fine face;The protrusion on surface and the table of the poor 0.5~2mm of recess heights The surface that face, such as corase grinding, sand saw processing are formed is fine flour;The protrusion and recess heights difference on surface are more than the machined surface of 2mm, warp The texture face of the formation such as striking, bore, digging is asperities.Different surfaces has different technique, anti-skidding grade different.Ground excessively light Sliding and the unexpected events such as disable of causing injury of slipping is caused constantly to rise, ground is anti-skidding at the new problem of public safety.North America Personal accidental injury caused by daily about 2.7 ten thousand roads Jian Yin cunning is fallen down, has 50% or more case to be happened at public field Institute, injury estimation caused by tumble at least account for the 17% of employment injuries, account for 18% or more of public sector's injury.Traditional marble Antilubricant the problem of there are non-skid properties to further increase, and reagent impacts marble surface glossiness after
Therefore, how improving traditional marble antilubricant, there are non-skid properties to further increase, and reagent is right after using The shortcomings that marble surface glossiness impacts is the problem of it need to be researched and solved to obtain more high combination property.
Invention content
The present invention solves the technical problem of:For traditional marble antilubricant there are non-skid properties can not be into one Step improves, the shortcomings that reagent impacts marble surface glossiness after, provides that the invention discloses a kind of marbles Surface anti-skidding agent.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of marble surface antilubricant, includes the raw material of following parts by weight:
40~60 parts of metal powder
8~10 parts of rare earth oxide
10~20 parts of zinc oxide
8~10 parts of magnesia
4~8 parts of magnesium chloride
10~20 parts of polyacrylic acid zinc
40~50 parts of saltcake
8~10 parts of polyvinylpyrrolidone
The preparation process of the marble surface antilubricant is:
(1)It is formed by raw material and weighs each component;
(2)First by metal powder, rare earth oxide, zinc oxide, magnesia, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone It is added in ball mill, after 4~6h of ball milling mixing, discharging obtains ball milling material;
(3)Gained ball milling material and saltcake are uniformly mixed, discharged to get marble surface antilubricant.
It is 1 in mass ratio that the metal powder, which is by zinc powder and magnesium powder,:10~1:20 mix;The mesh number of the metal powder For 180~200 mesh.
The rare earth oxide is any one in cerium oxide, lanthana or scandium oxide;The rare earth oxide mesh number For 120~160 mesh.
The zinc oxide mesh number is 20~30 mesh.
The magnesia mesh number is 20~30 mesh.
The beneficial effects of the invention are as follows:
(1)The present invention to powder material further refine and crush by using mechanical ball mill, in mechanical milling processes, Mechanical pressure is easy to cause powder surface and generates defect sturcture, and makes powder material surface active, to be easy marble with And sole surface absorption, and the presence of defect sturcture, it is ratcheting to be conducive to be formed machinery between powder granule and particle, to increase Frictional force between marble and sole, in friction process, material powder can fill and lead up sole and marble surface fold and Lines increases the contact area of sole and marble surface, to keep relative friction between the two more uniform, to improve Antiskid effect, in addition, in friction process, metal-powder surface gradually aoxidizes, and oxidation process is exothermic reaction, puts thermogenetic Heat can make the crystallization water in saltcake be changed into free water, and the free water of formation can be such that metal oxide and magnesium chloride in system occurs Hydration reaction, hydration reaction are exothermic reaction, and are easy be partially formed hydrated product, and hydrated product condenses to form larger Grain, the formation of bulky grain avoid powder meticulous in system from forming dust, and the presence of bulky grain can further improve marble The antiskid effect on surface;
(2)The present invention is used as one of ingredient by adding rare earth oxide, the addition of rare earth oxide, can in use, Under the action of sole frictional force, avoid the bulky grain that the particle of marble surface, especially further hydration are formed to marble The abrasion on surface, is played from polishing effect, meanwhile, rare earth oxide from polishing process be mechanical friction and chemical breakdown simultaneously Realize polishing, and in chemical decomposition process, since rare earth oxide rare earth elements are in highest valence state, show as having stronger Oxidisability, and metallic element is 0 valence in metal powder, shows as stronger reproducibility, redox reaction easily occurs for the two, to Play the role of auxiliary polishing avoids antilubricant from making marble surface while ensureing that product has good antiskid effect At cut and damage.
The present invention is by adding zinc oxide, and in use, zinc oxide itself has good moisture pick-up properties, can absorb Moisture in air, to ensure product after use, under no sole friction condition, also can good filming, avoid product from using After form airborne dust, while reducing antiskid effect, cause dust pollution.
Specific implementation mode
It counts in parts by weight, takes 40~60 parts of metal powders successively, 8~10 parts of rare earth oxides, 10~20 parts of zinc oxide, 8 ~10 parts of magnesia, 4~8 parts of magnesium chlorides, 10~20 parts of polyacrylic acid zinc, 40~50 parts of saltcake, 8~10 parts of polyvinylpyrrolidines First metal powder, rare earth oxide, zinc oxide, magnesia, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone are added for ketone In ball grinder, and it is 20 by ball material mass ratio:1~40:1 is added ball milling pearl, and ball milling pearl is respectively 10mm using diameter, 7mm with The zirconium oxide ball milling pearl quantity ratio of 5mm is 10:20:50, control ball mill revolution rotating speed is 300~320r/min, rotation rotating speed For 500~600r/min, every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, frequency 50Hz, ball Mill mixing 4~6h after, cross 500 mesh sieve, obtain ball milling material, then gained ball milling material is transferred in batch mixer, in speed of agitator be 600~ Under the conditions of 800r/min, after being stirred 3~5h, discharge to get marble surface antilubricant.The metal powder be by zinc powder and Magnesium powder is 1 in mass ratio:10~1:20 mix;The mesh number of the metal powder is 180~200 mesh.The rare earth oxide For any one in cerium oxide, lanthana or scandium oxide;The rare earth oxide mesh number is 120~160 mesh.The zinc oxide Mesh number is 20~30 mesh.The magnesia mesh number is 20~30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 10 parts of magnesia, 8 Part magnesium chloride, 20 parts of polyacrylic acid zinc, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by metal powder, rare earth oxide, oxygen Change zinc, magnesia, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone to be added in ball grinder, and is 40 by ball material mass ratio: 1 is added ball milling pearl, and ball milling pearl is 10 using the zirconium oxide ball milling pearl quantity ratio that diameter is respectively 10mm, 7mm and 5mm:20:50, It is 320r/min to control ball mill revolution rotating speed, and rotation rotating speed is 600r/min, every the forward and reverse alternate runs of 30min, alternately Interval downtime is 0min, after frequency 50Hz, ball milling mixing 6h, crosses 500 mesh sieve, obtains ball milling material, then by gained ball milling material It is transferred in batch mixer, under the conditions of speed of agitator is 800r/min, after being stirred 5h, discharging is anti-skidding to get marble surface Agent.It is 1 in mass ratio that the metal powder, which is by zinc powder and magnesium powder,:20 mix;The mesh number of the metal powder is 200 mesh.Institute It is cerium oxide to state rare earth oxide;The rare earth oxide mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.The oxidation Magnesium mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of magnesium powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 10 parts of magnesia, 8 parts Magnesium chloride, 20 parts of polyacrylic acid zinc, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by magnesium powder, rare earth oxide, zinc oxide, Magnesia, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added Ball milling pearl, ball milling pearl are 10 using the zirconium oxide ball milling pearl quantity ratio that diameter is respectively 10mm, 7mm and 5mm:20:50, control ball Grinding machine revolves round the sun rotating speed as 320r/min, and rotation rotating speed is 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals are stopped The machine time is 0min, after frequency 50Hz, ball milling mixing 6h, crosses 500 mesh sieve, obtains ball milling material, then gained ball milling material is transferred to mixed In material machine, under the conditions of speed of agitator is 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.It is described Rare earth oxide is cerium oxide;The rare earth oxide mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.The magnesia Mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 20 parts of zinc oxide, 10 parts of magnesia, 8 parts of magnesium chlorides, 20 parts poly- Zinc acrylate resin, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by metal powder, zinc oxide, magnesia, magnesium chloride, polyacrylic acid Zinc and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added ball milling pearl, and ball milling pearl uses diameter The zirconium oxide ball milling pearl quantity ratio of respectively 10mm, 7mm and 5mm are 10:20:50, control ball mill revolution rotating speed is 320r/ Min, rotation rotating speed are 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, and frequency is After 50Hz, ball milling mixing 6h, 500 mesh sieve is crossed, ball milling material is obtained, then gained ball milling material is transferred in batch mixer, is in speed of agitator Under the conditions of 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.The metal powder is by zinc powder and magnesium Powder is 1 in mass ratio:20 mix;The mesh number of the metal powder is 200 mesh.The zinc oxide mesh number is 30 mesh.The oxygen Change magnesium mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 10 parts of magnesia, 8 parts of magnesium chlorides, 20 Part polyacrylic acid zinc, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by metal powder, rare earth oxide, magnesia, magnesium chloride, Polyacrylic acid zinc and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added ball milling pearl, ball milling pearl It is 10 using the zirconium oxide ball milling pearl quantity ratio that diameter is respectively 10mm, 7mm and 5mm:20:50, control ball mill revolution rotating speed For 320r/min, rotation rotating speed is 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, Frequency is 50Hz, after ball milling mixing 6h, crosses 500 mesh sieve, ball milling material is obtained, then gained ball milling material is transferred in batch mixer, in stirring Under the conditions of rotating speed is 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.The metal powder is by zinc Powder and magnesium powder are 1 in mass ratio:20 mix;The mesh number of the metal powder is 200 mesh.The rare earth oxide is oxidation Cerium;The rare earth oxide mesh number is 160 mesh.The magnesia mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 8 parts of magnesium chlorides, 20 Part polyacrylic acid zinc, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by metal powder, rare earth oxide, zinc oxide, magnesium chloride, Polyacrylic acid zinc and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added ball milling pearl, ball milling pearl It is 10 using the zirconium oxide ball milling pearl quantity ratio that diameter is respectively 10mm, 7mm and 5mm:20:50, control ball mill revolution rotating speed For 320r/min, rotation rotating speed is 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, Frequency is 50Hz, after ball milling mixing 6h, crosses 500 mesh sieve, ball milling material is obtained, then gained ball milling material is transferred in batch mixer, in stirring Under the conditions of rotating speed is 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.The metal powder is by zinc Powder and magnesium powder are 1 in mass ratio:20 mix;The mesh number of the metal powder is 200 mesh.The rare earth oxide is oxidation Cerium;The rare earth oxide mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 10 parts of magnesia, 20 Part polyacrylic acid zinc, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by metal powder, rare earth oxide, zinc oxide, magnesia, Polyacrylic acid zinc and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added ball milling pearl, ball milling pearl It is 10 using the zirconium oxide ball milling pearl quantity ratio that diameter is respectively 10mm, 7mm and 5mm:20:50, control ball mill revolution rotating speed For 320r/min, rotation rotating speed is 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, Frequency is 50Hz, after ball milling mixing 6h, crosses 500 mesh sieve, ball milling material is obtained, then gained ball milling material is transferred in batch mixer, in stirring Under the conditions of rotating speed is 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.The metal powder is by zinc Powder and magnesium powder are 1 in mass ratio:20 mix;The mesh number of the metal powder is 200 mesh.The rare earth oxide is oxidation Cerium;The rare earth oxide mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.The magnesia mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 10 parts of magnesia, 8 Part magnesium chloride, 50 parts of saltcake, 10 parts of polyvinylpyrrolidones, first by metal powder, rare earth oxide, zinc oxide, magnesia, chlorination Magnesium and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added ball milling pearl, and ball milling pearl uses diameter The zirconium oxide ball milling pearl quantity ratio of respectively 10mm, 7mm and 5mm are 10:20:50, control ball mill revolution rotating speed is 320r/ Min, rotation rotating speed are 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, and frequency is After 50Hz, ball milling mixing 6h, 500 mesh sieve is crossed, ball milling material is obtained, then gained ball milling material is transferred in batch mixer, is in speed of agitator Under the conditions of 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.The metal powder is by zinc powder and magnesium Powder is 1 in mass ratio:20 mix;The mesh number of the metal powder is 200 mesh.The rare earth oxide is cerium oxide;It is described Rare earth oxide mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.The magnesia mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 10 parts of magnesia, 8 Part magnesium chloride, 20 parts of polyacrylic acid zinc, 10 parts of polyvinylpyrrolidones, first by metal powder, rare earth oxide, zinc oxide, oxidation Magnesium, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone are added in ball grinder, and are 40 by ball material mass ratio:1 is added ball milling Pearl, ball milling pearl are 10 using the zirconium oxide ball milling pearl quantity ratio that diameter is respectively 10mm, 7mm and 5mm:20:50, control ball mill Revolution rotating speed is 320r/min, and rotation rotating speed is 600r/min, every the forward and reverse alternate runs of 30min, when alternate intervals are shut down Between be 0min, after frequency 50Hz, ball milling mixing 6h, cross 500 mesh sieve, obtain ball milling material, then gained ball milling material is transferred to batch mixer In, under the conditions of speed of agitator is 800r/min, after being stirred 5h, discharge to get marble surface antilubricant.The metal It is 1 in mass ratio that powder, which is by zinc powder and magnesium powder,:20 mix;The mesh number of the metal powder is 200 mesh.The rare earth oxide For cerium oxide;The rare earth oxide mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.The magnesia mesh number is 30 mesh.
It counts in parts by weight, takes 60 parts of metal powders successively, 10 parts of rare earth oxides, 20 parts of zinc oxide, 10 parts of magnesia, 8 Part magnesium chloride, 20 parts of polyacrylic acid zinc, 50 parts of saltcake, first by metal powder, rare earth oxide, zinc oxide, magnesia, magnesium chloride, Polyacrylic acid zinc is added in ball grinder, and is 40 by ball material mass ratio:1 is added ball milling pearl, and ball milling pearl is respectively using diameter The zirconium oxide ball milling pearl quantity ratio of 10mm, 7mm and 5mm are 10:20:50, control ball mill revolution rotating speed is 320r/min, rotation Rotating speed is 600r/min, and every the forward and reverse alternate runs of 30min, alternate intervals downtime is 0min, frequency 50Hz, ball milling Mix 6h after, cross 500 mesh sieve, obtain ball milling material, then gained ball milling material is transferred in batch mixer, in speed of agitator be 800r/min items Under part, after being stirred 5h, discharge to get marble surface antilubricant.The metal powder be by zinc powder and magnesium powder in mass ratio It is 1:20 mix;The mesh number of the metal powder is 200 mesh.The rare earth oxide is cerium oxide;The rare earth oxide Mesh number is 160 mesh.The zinc oxide mesh number is 30 mesh.The magnesia mesh number is 30 mesh.
Comparative example:The marble antilubricant of Shanghai City architectural engineering Co., Ltd production.
The marble surface antilubricant and comparative example product of example 1 to 9 gained of example are subjected to performance detection, it is specific to detect Method is as follows:
Non-skid property:Testing friction coefficient
In identical marble, glossiness is 100 person-times of soles to be carried out anti-skidding processing, to trampling row under 90 surface condition The marble surface passed by carries out glossiness detection.
Specific testing result is as shown in table 1:
The 1 specific testing result of marble surface antilubricant of table
By 1 testing result of table it is found that marble surface antilubricant prepared by technical solution of the present invention has excellent non-skid property And the characteristics of polishing performance, it has broad prospects in the development of building material technology industry.

Claims (5)

1. a kind of marble surface antilubricant, which is characterized in that include the raw material of following parts by weight:
40~60 parts of metal powder
8~10 parts of rare earth oxide
10~20 parts of zinc oxide
8~10 parts of magnesia
4~8 parts of magnesium chloride
10~20 parts of polyacrylic acid zinc
40~50 parts of saltcake
8~10 parts of polyvinylpyrrolidone
The preparation process of the marble surface antilubricant is:
(1)It is formed by raw material and weighs each component;
(2)First by metal powder, rare earth oxide, zinc oxide, magnesia, magnesium chloride, polyacrylic acid zinc and polyvinylpyrrolidone It is added in ball mill, after 4~6h of ball milling mixing, discharging obtains ball milling material;
(3)Gained ball milling material and saltcake are uniformly mixed, discharged to get marble surface antilubricant.
2. a kind of marble surface antilubricant according to claim 1, which is characterized in that the metal powder be by zinc powder and Magnesium powder is 1 in mass ratio:10~1:20 mix;The mesh number of the metal powder is 180~200 mesh.
3. a kind of marble surface antilubricant according to claim 1, which is characterized in that the rare earth oxide is oxidation Any one in cerium, lanthana or scandium oxide;The rare earth oxide mesh number is 120~160 mesh.
4. a kind of marble surface antilubricant according to claim 1, which is characterized in that the zinc oxide mesh number be 20~ 30 mesh.
5. a kind of marble surface antilubricant according to claim 1, which is characterized in that the magnesia mesh number be 20~ 30 mesh.
CN201810568842.5A 2018-06-05 2018-06-05 A kind of marble surface antilubricant Pending CN108659793A (en)

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CN201810568842.5A CN108659793A (en) 2018-06-05 2018-06-05 A kind of marble surface antilubricant

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CN108659793A true CN108659793A (en) 2018-10-16

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN113429934A (en) * 2021-07-06 2021-09-24 上海世卿防滑防护科技有限公司郑州分公司 Long-acting brightening anti-slip agent for floor and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN113429934A (en) * 2021-07-06 2021-09-24 上海世卿防滑防护科技有限公司郑州分公司 Long-acting brightening anti-slip agent for floor and preparation method thereof
CN113429934B (en) * 2021-07-06 2022-12-13 丽水市一懿工业设计有限责任公司 Long-acting brightening anti-slip agent for floor and preparation method thereof

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