CN108651457A - Application of the isoamyl alcohol in luring mythimna separata - Google Patents

Application of the isoamyl alcohol in luring mythimna separata Download PDF

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Publication number
CN108651457A
CN108651457A CN201810394886.0A CN201810394886A CN108651457A CN 108651457 A CN108651457 A CN 108651457A CN 201810394886 A CN201810394886 A CN 201810394886A CN 108651457 A CN108651457 A CN 108651457A
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CN
China
Prior art keywords
isoamyl alcohol
attractant
mythimna separata
alcohol
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810394886.0A
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Chinese (zh)
Other versions
CN108651457B (en
Inventor
吴孔明
何莉梅
周亚涛
郭江龙
付晓伟
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Institute of Plant Protection of Chinese Academy of Agricultural Sciences
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Institute of Plant Protection of Chinese Academy of Agricultural Sciences
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Priority to CN201810394886.0A priority Critical patent/CN108651457B/en
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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02Acyclic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/02Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/14Catching by adhesive surfaces
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M2200/00Kind of animal
    • A01M2200/01Insects
    • A01M2200/012Flying insects

Abstract

The application that the present invention relates to isoamyl alcohol in luring mythimna separata.The invention discloses a kind of mythimna separata attractant for belonging to insect attractant preparing technical field, the active constituent of the attractant is isoamyl alcohol, phytol or 2 methylbutanoic acid leaf-alcohol esters.Mythimna separata attractant of the present invention have the characteristics that it is micro efficiently, cheap, nontoxic to people and animals, environmental-friendly, pests are not easy to produce resistance.

Description

Application of the isoamyl alcohol in luring mythimna separata
Technical field
The application that the present invention relates to isoamyl alcohol in luring mythimna separata belongs to insect attractant preparing technical field.
Background technology
Mythimna separata Mythimna separate Walker belong to Lepidoptera Noctuidae (Lepidoptera:Noctuidae), it is A kind of typical pest that migrates at a distance, and seriously threaten the important pests of China's grain-production safety.
The behavior manipulation of mythimna separata is acted on according to plant volatile, discovery, preparation mythimna separata attractant are comprehensive for promoting mythimna separata The pest injurious loss closed in horizontal improvement, agricultural product quality and reduction grain-production is of great significance.
Invention content
The application that the purpose of the present invention is to provide isoamyl alcohol in luring mythimna separata.The isoamyl alcohol is used for the prevention and control of mythimna separata With improvement, the pest injurious loss of objective crop is reduced.
The structural formula of the isoamyl alcohol is:
The preferably female mythimna separata of the mythimna separata, attractant effect are more notable.
A concentration of 0.01-0.6mg/m of use of the isoamyl alcohol2;It is preferred that 0.25-0.4mg/m2.Placement location is from the ground A height of 60-120cm is suitable, preferably 100cm.
The present invention also provides a kind of attractants for mythimna separata, including:It is individually for active component with isoamyl alcohol, or with different Amylalcohol, phytol are active component, either using isoamyl alcohol, 2-Methyl Butyric Acid leaf-alcohol ester as active component or with isoamyl alcohol, leaf Green alcohol, 2-Methyl Butyric Acid leaf-alcohol ester are active component.
The structural formula of the phytol is:
The structural formula of the 2-Methyl Butyric Acid leaf-alcohol ester is:
Specifically, the mass percent of active constituent is 40-100% in the attractant.
When the active constituent of the attractant is isoamyl alcohol, phytol, the mass ratio of isoamyl alcohol and phytol is 1-3:1- 3, preferably 1:1.
When the active constituent of the attractant is isoamyl alcohol, 2-Methyl Butyric Acid leaf-alcohol ester, isoamyl alcohol and 2-Methyl Butyric Acid leaf The mass ratio of alcohol ester is 1-3:1-3, preferably 1:1.
The active constituent of the attractant be isoamyl alcohol, phytol, 2-Methyl Butyric Acid leaf-alcohol ester when, isoamyl alcohol, phytol, The mass ratio of 2-Methyl Butyric Acid leaf-alcohol ester is 4-8:1-6:1-6, preferably 2:1:1.
The attractant is in addition to active component, and also packet solvent and carrier, solvent are selected from dichloromethane, it is also possible to n-hexane generation It replaces.
As one of embodiment of the present invention, the attractant includes:Active component, carrier;This may be selected in the carrier Each rubber-like materials carrier that field technology personnel are grasped.Specifically, contain 10-40mg in each rubber material carrier Active component, as lure.
The preparation of the attractant can be used the conventional attractant agent preparation method that those skilled in the art are grasped and be made.
The present invention also provides a kind of preparation methods of the attractant for mythimna separata, including:
(1) active component is added in carrier, prepares lure;
(2) solvent is added for the first time into carrier, dissolves active component;
(3) after waiting for solvent volatilization, second of addition solvent makes active component be fully infiltrated into carrier;
(4) after waiting for that solvent volatilizees again, lure is put into insect trap device.
Wherein, active component is selected from isoamyl alcohol either isoamyl alcohol and phytol or isoamyl alcohol and and 2-Methyl Butyric Acid leaf Alcohol ester or isoamyl alcohol and phytol, 2-Methyl Butyric Acid leaf-alcohol ester.
Wherein, the carrier is rubber material carrier, and isoamyl alcohol content is 10-40mg in carrier.
Wherein, the solvent is selected from dichloromethane or n-hexane, and each addition is advisable with 50-150 μ l.
The occupation mode of the attractant is:Concentration 0.01-0.6mg/m2, preferably 0.25-0.4mg/m2.The placement of lure Position is suitable, preferably 100cm away from ground 60-120cm.
The present invention also provides application of the above-mentioned attractant in preparing mythimna separata and luring drug.
Beneficial effects of the present invention are as follows:
The present invention is the active constituent for luring mythimna separata with plant volatile isoamyl alcohol, phytol, 2-Methyl Butyric Acid leaf-alcohol ester, Above-mentioned active constituent has very strong attracting action, lures agent method simple using the preparation of above-mentioned active constituent, condition is feasible, tool There is the features such as efficient, cheap, nontoxic to people and animals, environmental-friendly, to be not easy to produce resistance.
Specific implementation mode
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
The preparation of 1 mythimna separata attractant lure of embodiment
The standard specimen of isoamyl alcohol, phytol and 2-Methyl Butyric Acid leaf-alcohol ester is added to rubber carrier (each rubber carrier Content of dispersion 10-40mg), lure is prepared, 50-150ul dichloromethane dissolved compound in rubber carrier is then added, waits for solvent The dichloromethane that 50-150ul cleanings are added after volatilization makes compound object ingredient be fully infiltrated into rubber.Wait for solvent again Volatilization finishes, and lure is put into the device that insect trap places lure.
Compliance test result 1 lures experiment to the outdoor of mythimna separata
Time, place:27 days to 2013 Septembers of August in 2015 14 days, in the town and country Bei Huang of Yantai City Changdao County Academy of Agricultural Sciences of state plant protection postgraduate proving ground carries out the trapping experiment to the mythimna separata that migrates.
It tests and is carried out on the playground in base.
Concrete mode:A high-altitude searchlighting trap lamp is placed in playground center, the lure prepared in embodiment 1 is put into In insect trap, 3 repetitions of each processing setting, random alignment, while being with the rubber carrier of the clean dichloromethane of infiltration Control.At interval of 5-15m, one insect trap is set.The lure of insect trap high 100cm from the ground.Every two days after setting Investigate the ovarian development and number of copulations of mythimna separata quantity, female-male proportion and the female moth lured.The results are shown in Table 1.
Attracting action of 1 compound of table to mythimna separata
Test result shows that inventive compound isoamyl alcohol is apparently higher than phytol, 2- to the amount of trapping that is averaged of mythimna separata Methylbutanoic acid leaf-alcohol ester and control.The ovarian development of female moth is level-one, and is not all mated, illustrates the work of the present invention Property ingredient isoamyl alcohol there is extremely strong attractive activity to the mythimna separata adult that just sprouts wings.
Compliance test result 2 measures the attractive activity of mythimna separata
Using the mythimna separata adult (indoor raising) of 1-2 ages in days as experiment insect, using Y-shaped smell sensing apparatus to the compounds of this invention The active compound of isoamyl alcohol and different ratio has carried out attractive activity test.Wherein, it compares as clean dichloromethane.
By untested compound isoamyl alcohol be configured to 0.1mol/L for reagent liquid.The air-flow velocity of Y-shaped smell sensing apparatus is set as 0.4L/min.Single head mythimna separata adult is released into the observation of Y-piece base arm, is opened when mythimna separata adult is at Y-piece base arm pipe range 1/2 Beginning timing.At mythimna separata adult crosses left or right arm 3cm and when stopping 10s or more in this area, it is denoted as the reaction that makes a choice; Tend to without apparent selection after being put into mythimna separata adult 5min, is then denoted as reactionless.
59-65 mythimna separatas of each processing test, calculate the reactivity of mythimna separata and the selection rate to untested compound, formula is such as Shown in lower, test result is shown in Table 2.
The sum of reactivity (%)=100 × (test mythimna separata sum-nonreactive mythimna separata number)/test mythimna separata
2 compound of mythimna separata count table of mythimna separata number/test of selection rate (%)=100 × selection compound to be tested/no With the active compound matched to the attractive activity of mythimna separata
Table 2 the result shows that, active compound such as isoamyl alcohol, 1 of the compound of the present invention isoamyl alcohol and different ratio:1 Isoamyl alcohol and phytol and 1:1 isoamyl alcohol lures work to the mythimna separata just to sprout wings with 2-Methyl Butyric Acid leaf-alcohol ester with extremely strong Property, the selection rate of mythimna separata is 60% or more.Therefore, mythimna separata attractant is made using the active constituent of the present invention to carry out mythimna separata Trapping is convened, the pest injurious loss in horizontal, agricultural product quality and reduction grain-production to the prevention and control for improving mythimna separata is had Significance.
Although above the present invention is described in detail with a general description of the specific embodiments, On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (10)

1. application of the isoamyl alcohol in luring mythimna separata.
2. application according to claim 1, which is characterized in that the mythimna separata is female mythimna separata.
3. application according to claim 1 or 2, which is characterized in that a concentration of 0.01-0.6mg/ of use of the isoamyl alcohol m2, preferably 0.25-0.4mg/m2
4. according to any applications of claim 1-3, which is characterized in that the isoamyl alcohol placement location is apart from ground height 60-120cm。
5. a kind of attractant for mythimna separata, which is characterized in that include active constituent, the active constituent is:
It is individually for active component with isoamyl alcohol;
Alternatively, using isoamyl alcohol, phytol as active component;
Alternatively, using isoamyl alcohol, 2-Methyl Butyric Acid leaf-alcohol ester as active component;
Or using isoamyl alcohol, phytol, 2-Methyl Butyric Acid leaf-alcohol ester as active component.
6. attractant according to claim 5, which is characterized in that the mass percent of active constituent is in the attractant 40-100%.
7. attractant according to claim 5 or 6, which is characterized in that the active constituent of the attractant is isoamyl alcohol, leaf When green alcohol, the mass ratio of isoamyl alcohol and phytol is 1-3:1-3, preferably 1:1;
When the active constituent of the attractant is isoamyl alcohol, 2-Methyl Butyric Acid leaf-alcohol ester, isoamyl alcohol and 2-Methyl Butyric Acid leaf-alcohol ester Mass ratio be 1-3:1-3, preferably 1:1;
When the active constituent of the attractant is isoamyl alcohol, phytol, 2-Methyl Butyric Acid leaf-alcohol ester, isoamyl alcohol, phytol, 2- first The mass ratio of base butyric acid leaf-alcohol ester is 4-8:1-6:1-6, preferably 2:1:1.
8. according to any attractants of claim 5-7, which is characterized in that the attractant also includes solvent, carrier.
9. attractant according to claim 5, which is characterized in that the attractant includes:Active component, carrier;It is described Carrier is rubber material carrier;Contain 10-40mg active components in each rubber material carrier.
10. a kind of preparation method of attractant for mythimna separata, which is characterized in that including:
(1) active component is added in carrier, prepares lure;
(2) solvent is added for the first time into carrier, dissolves active component;
(3) after waiting for solvent volatilization, second of addition solvent makes active component be fully infiltrated into carrier;
(4) after waiting for that solvent volatilizees again, lure is put into insect trap device.
CN201810394886.0A 2018-04-27 2018-04-27 Application of isoamylol in attracting armyworms Active CN108651457B (en)

Priority Applications (1)

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CN201810394886.0A CN108651457B (en) 2018-04-27 2018-04-27 Application of isoamylol in attracting armyworms

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Application Number Priority Date Filing Date Title
CN201810394886.0A CN108651457B (en) 2018-04-27 2018-04-27 Application of isoamylol in attracting armyworms

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022124915A1 (en) * 2020-12-09 2022-06-16 Landcare Research New Zealand Limited Mammalian attractant

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105028424A (en) * 2015-06-23 2015-11-11 潍坊友容实业有限公司 Armyworm and spica parallelangula alpheraky attractant and application thereof to planting of buckwheat in saline-alkali soil
CN105613495A (en) * 2016-02-02 2016-06-01 深圳百乐宝生物农业科技有限公司 Noctuidae pest attractant and preparation method and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105028424A (en) * 2015-06-23 2015-11-11 潍坊友容实业有限公司 Armyworm and spica parallelangula alpheraky attractant and application thereof to planting of buckwheat in saline-alkali soil
CN105613495A (en) * 2016-02-02 2016-06-01 深圳百乐宝生物农业科技有限公司 Noctuidae pest attractant and preparation method and application thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KAIMEI LIHUANG 等: ""Antennal and behavioral responses of Mythimna se pa ra ta (Walker) to three plant volatiles"", 《ENVIRON SCI POLLUT RES》 *
宋亚茹等: "粘虫雌蛾性信息素特征成分鉴定及其不同配比的室内引诱效果", 《植物保护学报》 *
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022124915A1 (en) * 2020-12-09 2022-06-16 Landcare Research New Zealand Limited Mammalian attractant

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