CN108641445A - A kind of adhesive composition of Anti-bacteria hot melt - Google Patents

A kind of adhesive composition of Anti-bacteria hot melt Download PDF

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Publication number
CN108641445A
CN108641445A CN201810492170.4A CN201810492170A CN108641445A CN 108641445 A CN108641445 A CN 108641445A CN 201810492170 A CN201810492170 A CN 201810492170A CN 108641445 A CN108641445 A CN 108641445A
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parts
resin
hot melt
adhesive composition
dienol
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CN201810492170.4A
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Chinese (zh)
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陆永
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Individual
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/04Printing inks based on proteins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/06Printing inks based on fatty oils
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/08Printing inks based on natural resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Epoxy Resins (AREA)

Abstract

The invention discloses a kind of adhesive compositions of Anti-bacteria hot melt, are made of following raw material according to parts by weight:59 parts of butyl rubber,0.6 1 parts of isocyanate group,37 parts of castor oil hydrogenated mixture,49 parts of water-soluble polyethylene second dienol wax,0.6 1 parts of acrylamide,15 20 parts of aliphatic polyester resinoid,37 parts of toughener,0.3 0.7 parts of isopropanol,10 15 parts of tackifying resin,59 parts of quality,5 15 parts of tert butyl phenolic resin,0.3 0.7 parts of alkoxy,0.3 0.7 parts of cyclohexanone,27 parts of carboxymethyl cellulose,0.3 0.9 parts of magnesia,48 parts of silicones,5 10 parts of attapulgite,0.3 0.8 parts of lactobionic acid,10 18 parts of 44 epoxy resin of E,38 parts of silylation hydrophober,0.3 0.8 parts of isoflavones,38 parts of 37 parts of cineole and coumarone indene resin.The present invention has many advantages, such as that advantages of nontoxic raw materials is pollution-free, reaches environmentally protective requirement.

Description

A kind of adhesive composition of Anti-bacteria hot melt
Technical field
The present invention relates to building shell mold plate correlative technology field more particularly to a kind of combinations of the adhesive of Anti-bacteria hot melt Object.
Background technology
Adhesive is Modern Fine Chemical Industry product, and since 21st century, adhesive and adhesive technology have shown that incomparable Vigor and vitality, importance is growing day by day, and the practicality attracts people's attention, and popularity is promising, it should widely popularize and answer With creating considerable economic benefit and social benefit [1-5].It is higher than national product in the growth rate of American-European countries, adhesive The growth rate of total value, average growth rate are 3% or so.World's adhesive annual turnover is at present more than 10,000,000 tons, entirely Ball composite adhesives sales volume is more than 26,000,000,000 dollars.China's adhesive industry maintains sustained and rapid growth, and is put down over nearly 5 years Equal development speed reaches 11.6%, and production technology level is had taken great strides in one's progress, and new technology is continued to bring out with new product, it is contemplated that 2005 Year adhesive and sealant yield are presented sales volume and increase pattern higher than increase of production up to 3,650,000 t.Expert is pre- It surveys, forthcoming generations adhesive industry will enter the period of a recombination, modern towards scale of operation, technologically advancedization, production Change, the direction of product environmental protection is developed.It is wood-processing industry that China's adhesive, which consumes largest industry, at present, accounts for entirety about 60%;Followed by construction industry accounts for about 22%;It is packing business, shoe industry again, accounts for 6.2%, 4% respectively.Insider point Analysis, 5~10 years following, adhesive consumption in China's will be increased with faster speed, and adhesive industry is by there are one larger Development, industry promise well.Now study it is a kind of efficiently, the wood adhesive of environmental protection, can keep for a long time timber and timber it Between bonding force.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of Anti-bacteria hot melt proposed Adhesive composition.
To achieve the goals above, present invention employs following technical solutions:
A kind of adhesive composition of Anti-bacteria hot melt is made of according to parts by weight following raw material:It is 5-9 parts of butyl rubber, different 0.6-1 parts of cyanic acid ester group, 3-7 parts of castor oil hydrogenated mixture, 4-9 parts of water-soluble polyethylene second dienol wax, acrylamide 0.6-1 parts, 15-20 parts of aliphatic polyester resinoid, 3-7 parts of toughener, wooden 5-10 parts of the more phenolic tetraglycidel ether epoxy resins, two 0.2-0.6 parts of titanium oxide, 0.3-0.8 parts of dimethylbenzene, 0.4-0.8 parts of alkylidene, 0.3-0.8 parts of polyhydroxy alkyl, polyamide acyl 0.6-1 parts of imines, 0.2-0.7 parts of dihydroxyalkyl, 0.3-0.7 parts of isopropanol, 10-15 parts of tackifying resin, 5-9 parts of quality, uncle 5-15 parts of butyl phenolic resin, 0.3-0.7 parts of alkoxy, 0.3-0.7 parts of cyclohexanone, 2-7 parts of carboxymethyl cellulose, magnesia 0.3-0.9 parts, 4-8 parts of silicones, 5-10 parts of attapulgite, 0.3-0.8 parts of lactobionic acid, 10-18 parts of E-44 epoxy resin, silane 3-8 parts of 3-8 parts of base hydrophober, 0.3-0.8 parts of isoflavones, 3-7 parts of cineole and coumarone indene resin.
A kind of adhesive composition of above-mentioned Anti-bacteria hot melt is made of according to parts by weight following raw material:Butyl rubber 5-8 parts of glue, 0.6-0.9 parts of isocyanate group, 3-6 parts of castor oil hydrogenated mixture, water-soluble polyethylene second dienol wax 4-8 Part, 0.6-0.9 parts of acrylamide, 15-19 parts of aliphatic polyester resinoid, 3-6 parts of toughener, the wooden polyphenol type diglycidyl ether epoxy 5-9 parts of resin, 0.2-0.5 parts of titanium dioxide, 0.3-0.7 parts of dimethylbenzene, 0.4-0.7 parts of alkylidene, polyhydroxy alkyl 0.3-0.7 Part, 0.6-0.9 parts of polyamidoimide, 0.2-0.6 parts of dihydroxyalkyl, 0.3-0.6 parts of isopropanol, 10-14 parts of tackifying resin, 5-8 parts of quality, 5-14 parts of tert butyl phenolic resin, 0.3-0.6 parts of alkoxy, 0.3-0.6 parts of cyclohexanone, carboxymethyl cellulose 2- 6 parts, 0.3-0.8 parts of magnesia, 4-7 parts of silicones, 5-9 parts of attapulgite, 0.3-0.7 parts of lactobionic acid, E-44 epoxy resin 10- 3-7 parts of 17 parts, 3-7 parts of silylation hydrophober, 0.3-0.7 parts of isoflavones, 3-6 parts of cineole and coumarone indene resin.
A kind of adhesive composition of above-mentioned Anti-bacteria hot melt is made of according to parts by weight following raw material:Butyl rubber 6-8 parts of glue, 0.7-0.9 parts of isocyanate group, 4-6 parts of castor oil hydrogenated mixture, water-soluble polyethylene second dienol wax 5-8 Part, 0.7-0.9 parts of acrylamide, 16-19 parts of aliphatic polyester resinoid, 4-6 parts of toughener, the wooden polyphenol type diglycidyl ether epoxy 6-9 parts of resin, 0.3-0.5 parts of titanium dioxide, 0.5-0.7 parts of dimethylbenzene, 0.4-0.7 parts of alkylidene, polyhydroxy alkyl 0.4-0.7 Part, 0.7-0.9 parts of polyamidoimide, 0.3-0.6 parts of dihydroxyalkyl, 0.4-0.6 parts of isopropanol, 11-14 parts of tackifying resin, 6-8 parts of quality, 6-14 parts of tert butyl phenolic resin, 0.4-0.6 parts of alkoxy, 0.4-0.6 parts of cyclohexanone, carboxymethyl cellulose 3- 6 parts, 0.4-0.8 parts of magnesia, 5-7 parts of silicones, 6-9 parts of attapulgite, 0.4-0.7 parts of lactobionic acid, E-44 epoxy resin 11- 4-7 parts of 17 parts, 4-7 parts of silylation hydrophober, 0.4-0.7 parts of isoflavones, 4-6 parts of cineole and coumarone indene resin.
A kind of adhesive composition of above-mentioned Anti-bacteria hot melt is made of according to parts by weight following raw material:Butyl rubber 7 parts of glue, 0.8 part of isocyanate group, 5 parts of castor oil hydrogenated mixture, 6.5 parts of water-soluble polyethylene second dienol wax, acryloyl 0.8 part of amine, 17.5 parts of aliphatic polyester resinoid, 5 parts of toughener, wooden 7.5 parts of the more phenolic tetraglycidel ether epoxy resins, titanium dioxide 0.4 part of titanium, 0.55 part of dimethylbenzene, 0.6 part of alkylidene, 0.55 part of polyhydroxy alkyl, 0.8 part of polyamidoimide, dihydroxy alkane 0.45 part of base, 0.5 part of isopropanol, 12.5 parts of tackifying resin, 7 parts of quality, 10 parts of tert butyl phenolic resin, 0.5 part of alkoxy, ring 0.5 part of hexanone, 4.5 parts of carboxymethyl cellulose, 0.6 part of magnesia, 6 parts of silicones, 7.5 parts of attapulgite, 0.55 part of lactobionic acid, 14 parts of E-44 epoxy resin, 5.5 parts of silylation hydrophober, 0.55 part of isoflavones, 5 parts of cineole and coumarone indene resin 5.5 part.
Compared with prior art, beneficial effects of the present invention are:
A kind of adhesive composition of Anti-bacteria hot melt of the present invention equally has due to the equal asepsis environment-protecting of various raw materials after compounding The characteristic of standby environment-friendly and green;The present invention can reach very strong bonding force when usage amount is less, and the duration relatively waits so long and has Beneficial effect.
Specific implementation mode
Embodiment 1
A kind of adhesive composition of Anti-bacteria hot melt is made of according to parts by weight following raw material:5 parts of butyl rubber, isocyanide 0.6 part of perester radical, 3 parts of castor oil hydrogenated mixture, 4 parts of water-soluble polyethylene second dienol wax, 0.6 part of acrylamide, aliphatic series 15 parts of polyester resin, 3 parts of toughener, wooden 5 parts of the more phenolic tetraglycidel ether epoxy resins, 0.2 part of titanium dioxide, dimethylbenzene 0.3 part, 0.4 part of alkylidene, 0.3 part of polyhydroxy alkyl, 0.6 part of polyamidoimide, 0.2 part of dihydroxyalkyl, isopropanol 0.3 Part, 10 parts of tackifying resin, 5 parts of quality, 5 parts of tert butyl phenolic resin, 0.3 part of alkoxy, 0.3 part of cyclohexanone, carboxymethyl cellulose 2 parts of element, 0.3 part of magnesia, 4 parts of silicones, 5 parts of attapulgite, 0.3 part of lactobionic acid, 10 parts of E-44 epoxy resin, silylation are hated 3 parts of 3 parts of aqua, 0.3 part of isoflavones, 3 parts of cineole and coumarone indene resin.
Embodiment 2
A kind of adhesive composition of above-mentioned Anti-bacteria hot melt is made of according to parts by weight following raw material:Butyl rubber 9 Part, 1 part of isocyanate group, 7 parts of castor oil hydrogenated mixture, 9 parts of water-soluble polyethylene second dienol wax, 1 part of acrylamide, fat 20 parts of adoption esters resin, 7 parts of toughener, wooden 10 parts of the more phenolic tetraglycidel ether epoxy resins, 0.6 part of titanium dioxide, diformazan 0.8 part of benzene, 0.8 part of alkylidene, 0.8 part of polyhydroxy alkyl, 1 part of polyamidoimide, 0.7 part of dihydroxyalkyl, isopropanol 0.7 Part, 15 parts of tackifying resin, 9 parts of quality, 15 parts of tert butyl phenolic resin, 0.7 part of alkoxy, 0.7 part of cyclohexanone, carboxymethyl cellulose 7 parts of element, 0.9 part of magnesia, 8 parts of silicones, 10 parts of attapulgite, 0.8 part of lactobionic acid, 18 parts of E-44 epoxy resin, silylation 8 parts of 8 parts of hydrophober, 0.8 part of isoflavones, 7 parts of cineole and coumarone indene resin.
Embodiment 3
A kind of adhesive composition of above-mentioned Anti-bacteria hot melt is made of according to parts by weight following raw material:Butyl rubber 7 Part, 0.8 part of isocyanate group, 5 parts of castor oil hydrogenated mixture, 6.5 parts of water-soluble polyethylene second dienol wax, acrylamide 0.8 part, 17.5 parts of aliphatic polyester resinoid, 5 parts of toughener, wooden 7.5 parts of the more phenolic tetraglycidel ether epoxy resins, titanium dioxide 0.4 part, 0.55 part of dimethylbenzene, 0.6 part of alkylidene, 0.55 part of polyhydroxy alkyl, 0.8 part of polyamidoimide, dihydroxyalkyl 0.45 part, 0.5 part of isopropanol, 12.5 parts of tackifying resin, 7 parts of quality, 10 parts of tert butyl phenolic resin, 0.5 part of alkoxy, hexamethylene 0.5 part of ketone, 4.5 parts of carboxymethyl cellulose, 0.6 part of magnesia, 6 parts of silicones, 7.5 parts of attapulgite, 0.55 part of lactobionic acid, E- 44 14 parts of epoxy resin, 5.5 parts of silylation hydrophober, 0.55 part of isoflavones, 5 parts of cineole and coumarone indene resin 5.5 Part.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of adhesive composition of Anti-bacteria hot melt, which is characterized in that be made of following raw material according to parts by weight:Butyl 5-9 parts of rubber, 0.6-1 parts of isocyanate group, 3-7 parts of castor oil hydrogenated mixture, water-soluble polyethylene second dienol wax 4-9 Part, 0.6-1 parts of acrylamide, 15-20 parts of aliphatic polyester resinoid, 3-7 parts of toughener, the wooden polyphenol type diglycidyl ether epoxy tree 5-10 parts of fat, 0.2-0.6 parts of titanium dioxide, 0.3-0.8 parts of dimethylbenzene, 0.4-0.8 parts of alkylidene, polyhydroxy alkyl 0.3-0.8 Part, 0.6-1 parts of polyamidoimide, 0.2-0.7 parts of dihydroxyalkyl, 0.3-0.7 parts of isopropanol, 10-15 parts of tackifying resin, matter 5-9 parts plain, 5-15 parts of tert butyl phenolic resin, 0.3-0.7 parts of alkoxy, 0.3-0.7 parts of cyclohexanone, carboxymethyl cellulose 2-7 Part, 0.3-0.9 parts of magnesia, 4-8 parts of silicones, 5-10 parts of attapulgite, 0.3-0.8 parts of lactobionic acid, E-44 epoxy resin 10- 3-8 parts of 18 parts, 3-8 parts of silylation hydrophober, 0.3-0.8 parts of isoflavones, 3-7 parts of cineole and coumarone indene resin.
2. a kind of adhesive composition of Anti-bacteria hot melt according to claim 1, which is characterized in that according to parts by weight It is made of following raw material:5-8 parts of butyl rubber, 0.6-0.9 parts of isocyanate group, 3-6 parts of castor oil hydrogenated mixture, water solubility 4-8 parts of polyethylene second dienol wax, 0.6-0.9 parts of acrylamide, 15-19 parts of aliphatic polyester resinoid, 3-6 parts of toughener, wood 5-9 parts of more phenolic tetraglycidel ether epoxy resins, 0.2-0.5 parts of titanium dioxide, 0.3-0.7 parts of dimethylbenzene, alkylidene 0.4-0.7 Part, 0.3-0.7 parts of polyhydroxy alkyl, 0.6-0.9 parts of polyamidoimide, 0.2-0.6 parts of dihydroxyalkyl, isopropanol 0.3- 0.6 part, 10-14 parts of tackifying resin, 5-8 parts of quality, 5-14 parts of tert butyl phenolic resin, 0.3-0.6 parts of alkoxy, cyclohexanone 0.3-0.6 parts, 2-6 parts of carboxymethyl cellulose, 0.3-0.8 parts of magnesia, 4-7 parts of silicones, 5-9 parts of attapulgite, lactobionic acid 0.3-0.7 parts, 10-17 parts of E-44 epoxy resin, 3-7 parts of silylation hydrophober, 0.3-0.7 parts of isoflavones, cineole 3-6 parts and 3-7 parts of coumarone indene resin.
3. a kind of adhesive composition of Anti-bacteria hot melt according to claim 1, which is characterized in that according to parts by weight It is made of following raw material:6-8 parts of butyl rubber, 0.7-0.9 parts of isocyanate group, 4-6 parts of castor oil hydrogenated mixture, water solubility 5-8 parts of polyethylene second dienol wax, 0.7-0.9 parts of acrylamide, 16-19 parts of aliphatic polyester resinoid, 4-6 parts of toughener, wood 6-9 parts of more phenolic tetraglycidel ether epoxy resins, 0.3-0.5 parts of titanium dioxide, 0.5-0.7 parts of dimethylbenzene, alkylidene 0.4-0.7 Part, 0.4-0.7 parts of polyhydroxy alkyl, 0.7-0.9 parts of polyamidoimide, 0.3-0.6 parts of dihydroxyalkyl, isopropanol 0.4- 0.6 part, 11-14 parts of tackifying resin, 6-8 parts of quality, 6-14 parts of tert butyl phenolic resin, 0.4-0.6 parts of alkoxy, cyclohexanone 0.4-0.6 parts, 3-6 parts of carboxymethyl cellulose, 0.4-0.8 parts of magnesia, 5-7 parts of silicones, 6-9 parts of attapulgite, lactobionic acid 0.4-0.7 parts, 11-17 parts of E-44 epoxy resin, 4-7 parts of silylation hydrophober, 0.4-0.7 parts of isoflavones, cineole 4-6 parts and 4-7 parts of coumarone indene resin.
4. a kind of adhesive composition of Anti-bacteria hot melt according to claim 1, which is characterized in that according to parts by weight It is made of following raw material:7 parts of butyl rubber, 0.8 part of isocyanate group, 5 parts of castor oil hydrogenated mixture, water-soluble polyethylene second 6.5 parts of dienol wax, 0.8 part of acrylamide, 17.5 parts of aliphatic polyester resinoid, 5 parts of toughener, the wooden polyphenol type glycidol ether 7.5 parts of epoxy resin, 0.4 part of titanium dioxide, 0.55 part of dimethylbenzene, 0.6 part of alkylidene, 0.55 part of polyhydroxy alkyl, polyamide 0.8 part of acid imide, 0.45 part of dihydroxyalkyl, 0.5 part of isopropanol, 12.5 parts of tackifying resin, 7 parts of quality, tertiary butyl phenolic aldehyde tree 10 parts of fat, 0.5 part of alkoxy, 0.5 part of cyclohexanone, 4.5 parts of carboxymethyl cellulose, 0.6 part of magnesia, 6 parts of silicones, concave convex rod 7.5 parts of soil, 0.55 part of lactobionic acid, 14 parts of E-44 epoxy resin, 5.5 parts of silylation hydrophober, 0.55 part of isoflavones, folium eucalypti 5.5 parts of 5 parts of oily element and coumarone indene resin.
CN201810492170.4A 2018-05-22 2018-05-22 A kind of adhesive composition of Anti-bacteria hot melt Withdrawn CN108641445A (en)

Priority Applications (1)

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CN201810492170.4A CN108641445A (en) 2018-05-22 2018-05-22 A kind of adhesive composition of Anti-bacteria hot melt

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Application Number Priority Date Filing Date Title
CN201810492170.4A CN108641445A (en) 2018-05-22 2018-05-22 A kind of adhesive composition of Anti-bacteria hot melt

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Publication Number Publication Date
CN108641445A true CN108641445A (en) 2018-10-12

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Application publication date: 20181012