CN107384264A - A kind of preparation method of mould proof color inhibition skin shoes-used glue - Google Patents
A kind of preparation method of mould proof color inhibition skin shoes-used glue Download PDFInfo
- Publication number
- CN107384264A CN107384264A CN201710753123.6A CN201710753123A CN107384264A CN 107384264 A CN107384264 A CN 107384264A CN 201710753123 A CN201710753123 A CN 201710753123A CN 107384264 A CN107384264 A CN 107384264A
- Authority
- CN
- China
- Prior art keywords
- parts
- mould proof
- color inhibition
- adhesive
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention discloses a kind of preparation method of mould proof color inhibition skin shoes-used glue, including following operating procedure：（1）After ethyl acrylate, cyclohexyl methacrylate, chain extender HER, lauryl amine, water are mixed, add into reactor, adhesive A is made；（2）By weight, after cornstarch, konjak starch, insect wax, water being mixed, after heating the mixture to 80 90 DEG C, ketone acid anhydride, two molybdic acid hydrate sodium are added thereto, and after continuing stirring reaction 23 hours using 300r/min rotating speed, adhesive B is made；（3）By adhesive A and adhesive B according to mass ratio be 35:After 1 ratio mixing, 40 60min are persistently stirred using 400r/min rotating speed, mould proof color inhibition skin shoes-used glue is made.A kind of preparation method of mould proof color inhibition skin shoes-used glue provided by the invention, simple to operate, cost is cheap, and the three wastes are few in production process, and glue is green, has no irritating odor, and bond effect is notable, and especially it has excellent mould proof anti-yellowing property.
Description
Technical field
The invention belongs to skin shoes-used glue preparing technical field, and in particular to a kind of preparation side of mould proof color inhibition skin shoes-used glue
Method.
Background technology
, it is necessary to use a certain amount of glue in the preparation process of leather shoes, because the use environment of shoes is more severe,
In daily life, it is frequently found to have used the shoes of 1 year or so that the phenomenon of glue flavescence on footwear just occurs, or even have
The mouldy phenomenon in bonding place, the appearance of these phenomenons, due to caused by the effect of the glue that uses without mould proof color inhibition.
In order to extend the service life of leather shoes, the quality of leather shoes is lifted, is badly in need of a kind of preparation method of mould proof color inhibition skin shoes-used glue.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of preparation method of mould proof color inhibition skin shoes-used glue.
The present invention is achieved by the following technical solutions.
A kind of preparation method of mould proof color inhibition skin shoes-used glue, including following operating procedure：
（1）By weight, by ethyl acrylate 60-70 parts, cyclohexyl methacrylate 8-10 parts, chain extender HER 1-2 parts,
After lauryl amine 5-7 parts, the mixing of water 20-25 parts, add into reactor, after reacting 120-140min at 90-95 DEG C, gluing is made
Agent A；
（2）By weight, by cornstarch 58-65 parts, konjak starch 30-40 parts, insect wax 10-13 parts, water 140-160 parts
After mixing, stir, after heating the mixture to 80-90 DEG C, add ketone acid anhydride 5-7 parts, two molybdic acid hydrate sodium 1-3 thereto
Part, after continuing stirring reaction 2-3 hours using 300r/min rotating speed, adhesive B is made；
（3）According to mass ratio it is 3-5 by adhesive A and adhesive B:After 1 ratio mixing, continued using 400r/min rotating speed
40-60min is stirred, mould proof color inhibition skin shoes-used glue is made.
Specifically, above-mentioned steps（1）In, above-mentioned steps（1）Middle chain extender HER purity is 99.0%.
Specifically, above-mentioned steps（2）The Average Particle Diameters of middle cornstarch and konjak starch are 200 mesh.
Specifically, above-mentioned steps（2）In, the ester mixture content of aliphatic monobasic acid is 93% in insect wax, and resin contains
Measure as 1%, heptacosane content is 3%.
Specifically, above-mentioned steps（2）In, the active constituent content of ketone acid anhydride is 99-99.5%.
Technical scheme more than, the beneficial effects of the invention are as follows：
A kind of preparation method of mould proof color inhibition skin shoes-used glue provided by the invention, simple to operate, cost is cheap, in production process
The three wastes are few, and glue is green, have no irritating odor, and bond effect is notable, and especially it has excellent mould proof yellowing resistance
Energy.Wherein, the lauryl amine in adhesive A can not only lift intermolecular adhesion in glue, the effective bonding for strengthening glue
Performance, and there is extremely excellent fungicidal properties, it can effectively avoid mould from being bred in glue superficial growth；Insect wax and ketone
The addition of acid anhydride, cornstarch and konjak starch adhesive property can be effectively lifted, and the fungicidal properties of glue can be increased；Adhesive
Compatibility between A and adhesive B is good, after being mixed using two kinds of compositions, can effectively lift the densification on glue surface after drying
Property, the water resistance of glue is improved, and the cost of glue is reduced, glue is made has excellent yellowing resistance simultaneously
Energy.
Embodiment
In order that those skilled in the art can be further understood that the feature and technology contents of the present invention, referring to following has
Close detailed description of the invention.
Embodiment 1
A kind of preparation method of mould proof color inhibition skin shoes-used glue, including following operating procedure：
（1）By weight, by 60 parts of ethyl acrylate, 8 parts of cyclohexyl methacrylate, 1 part of chain extender HER, lauryl amine 5
After 20 parts of part, water mixing, add into reactor, after reacting 120min at 90 DEG C, adhesive A is made；
（2）By weight, by after 140 parts of 58 parts of cornstarch, 30 parts of konjak starch, 10 parts of insect wax, water mixing, stirring is equal
It is even, after heating the mixture to 80 DEG C, 5 parts of ketone acid anhydride, 1 part of two molybdic acid hydrate sodium are added thereto, using 300r/min rotating speed
Continue stirring reaction after 2 hours, adhesive B is made；
（3）By adhesive A and adhesive B according to mass ratio be 3:After 1 ratio mixing, persistently stirred using 400r/min rotating speed
40min is mixed, mould proof color inhibition skin shoes-used glue is made.
Specifically, above-mentioned steps（1）In, above-mentioned steps（1）Middle chain extender HER purity is 99.0%.
Specifically, above-mentioned steps（2）The Average Particle Diameters of middle cornstarch and konjak starch are 200 mesh.
Specifically, above-mentioned steps（2）In, the ester mixture content of aliphatic monobasic acid is 93% in insect wax, and resin contains
Measure as 1%, heptacosane content is 3%.
Specifically, above-mentioned steps（2）In, the active constituent content of ketone acid anhydride is 99%.
Embodiment 2
A kind of preparation method of mould proof color inhibition skin shoes-used glue, including following operating procedure：
（1）By weight, by 65 parts of ethyl acrylate, 9 parts of cyclohexyl methacrylate, 1 part of chain extender HER, lauryl amine 6
After 23 parts of part, water mixing, add into reactor, after reacting 130min at 93 DEG C, adhesive A is made；
（2）By weight, by after 150 parts of 62 parts of cornstarch, 35 parts of konjak starch, 12 parts of insect wax, water mixing, stirring is equal
It is even, after heating the mixture to 85 DEG C, 6 parts of ketone acid anhydride, 2 parts of two molybdic acid hydrate sodium are added thereto, using 300r/min rotating speed
Continue stirring reaction after 2.5 hours, adhesive B is made；
（3）By adhesive A and adhesive B according to mass ratio be 4:After 1 ratio mixing, persistently stirred using 400r/min rotating speed
50min is mixed, mould proof color inhibition skin shoes-used glue is made.
Specifically, above-mentioned steps（1）In, above-mentioned steps（1）Middle chain extender HER purity is 99.0%.
Specifically, above-mentioned steps（2）The Average Particle Diameters of middle cornstarch and konjak starch are 200 mesh.
Specifically, above-mentioned steps（2）In, the ester mixture content of aliphatic monobasic acid is 93% in insect wax, and resin contains
Measure as 1%, heptacosane content is 3%.
Specifically, above-mentioned steps（2）In, the active constituent content of ketone acid anhydride is 99.3%.
Embodiment 3
A kind of preparation method of mould proof color inhibition skin shoes-used glue, including following operating procedure：
（1）By weight, by 70 parts of ethyl acrylate, 10 parts of cyclohexyl methacrylate, 2 parts of chain extender HER, lauryl amine 7
After 25 parts of part, water mixing, add into reactor, after reacting 140min at 95 DEG C, adhesive A is made；
（2）By weight, by after 160 parts of 65 parts of cornstarch, 40 parts of konjak starch, 13 parts of insect wax, water mixing, stirring is equal
It is even, after heating the mixture to 90 DEG C, 7 parts of ketone acid anhydride, 3 parts of two molybdic acid hydrate sodium are added thereto, using 300r/min rotating speed
Continue stirring reaction after 3 hours, adhesive B is made；
（3）By adhesive A and adhesive B according to mass ratio be 5:After 1 ratio mixing, persistently stirred using 400r/min rotating speed
60min is mixed, mould proof color inhibition skin shoes-used glue is made.
Specifically, above-mentioned steps（1）In, above-mentioned steps（1）Middle chain extender HER purity is 99.0%.
Specifically, above-mentioned steps（2）The Average Particle Diameters of middle cornstarch and konjak starch are 200 mesh.
Specifically, above-mentioned steps（2）In, the ester mixture content of aliphatic monobasic acid is 93% in insect wax, and resin contains
Measure as 1%, heptacosane content is 3%.
Specifically, above-mentioned steps（2）In, the active constituent content of ketone acid anhydride is 99.5%.
Respectively by glue made from obtained adhesive A, adhesive B in embodiment 1 and each embodiment and control group
After commercially available common glue is applied to same block leather, after its drying, used 120W/cm UV photo-irradiation treatments 96 small
When, check whether a glue occurs Yellowing, result of the test is as shown in table 1：
The glue anti-yellowing property of table 1
| Project | Yellowing |
| Adhesive A | Slight xanthochromia |
| Adhesive B | Serious xanthochromia |
| Embodiment 1 | Without xanthochromia |
| Embodiment 2 | Without xanthochromia |
| Embodiment 3 | Without xanthochromia |
| Control group | Serious xanthochromia |
As shown in Table 1, mould proof color inhibition skin shoes-used glue produced by the present invention, there is extremely excellent anti-yellowing property.
Above-described embodiment is the preferable embodiment of the present invention, but is not merely restricted to the described embodiments, other
Any Spirit Essence without departing from the present invention with made under principle change, modification, replacement, combine, simplification, should be equivalent
Substitute mode, it is all contained within protection scope of the present invention.
Claims (5)
1. a kind of preparation method of mould proof color inhibition skin shoes-used glue, it is characterised in that including following operating procedure：
（1）By weight, by ethyl acrylate 60-70 parts, cyclohexyl methacrylate 8-10 parts, chain extender HER 1-2 parts,
After lauryl amine 5-7 parts, the mixing of water 20-25 parts, add into reactor, after reacting 120-140min at 90-95 DEG C, gluing is made
Agent A；
（2）By weight, by cornstarch 58-65 parts, konjak starch 30-40 parts, insect wax 10-13 parts, water 140-160 parts
After mixing, stir, after heating the mixture to 80-90 DEG C, add ketone acid anhydride 5-7 parts, two molybdic acid hydrate sodium 1-3 thereto
Part, after continuing stirring reaction 2-3 hours using 300r/min rotating speed, adhesive B is made；
（3）According to mass ratio it is 3-5 by adhesive A and adhesive B:After 1 ratio mixing, continued using 400r/min rotating speed
40-60min is stirred, mould proof color inhibition skin shoes-used glue is made.
2. according to a kind of preparation method of mould proof color inhibition skin shoes-used glue described in claim 1, it is characterised in that above-mentioned step
Suddenly（1）In, above-mentioned steps（1）Middle chain extender HER purity is 99.0%.
3. according to a kind of preparation method of mould proof color inhibition skin shoes-used glue described in claim 1, it is characterised in that above-mentioned step
Suddenly（2）The Average Particle Diameters of middle cornstarch and konjak starch are 200 mesh.
4. according to a kind of preparation method of mould proof color inhibition skin shoes-used glue described in claim 1, it is characterised in that above-mentioned step
Suddenly（2）In, the ester mixture content of aliphatic monobasic acid is 93% in insect wax, resin content 1%, and heptacosane content is
3%。
5. according to a kind of preparation method of mould proof color inhibition skin shoes-used glue described in claim 1, it is characterised in that above-mentioned step
Suddenly（2）In, the active constituent content of ketone acid anhydride is 99-99.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710753123.6A CN107384264A (en) | 2017-08-29 | 2017-08-29 | A kind of preparation method of mould proof color inhibition skin shoes-used glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710753123.6A CN107384264A (en) | 2017-08-29 | 2017-08-29 | A kind of preparation method of mould proof color inhibition skin shoes-used glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107384264A true CN107384264A (en) | 2017-11-24 |
Family
ID=60346012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710753123.6A Pending CN107384264A (en) | 2017-08-29 | 2017-08-29 | A kind of preparation method of mould proof color inhibition skin shoes-used glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107384264A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112335998A (en) * | 2020-10-22 | 2021-02-09 | 广州晨骐鞋业有限公司 | Method for preparing women's shoes capable of maintaining three-dimensional state for a long time by using natural leather |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084154A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | The footwear preparation method of aqueous adhesive |
-
2017
- 2017-08-29 CN CN201710753123.6A patent/CN107384264A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084154A (en) * | 2016-06-30 | 2016-11-09 | 嘉兴市哈妮鞋业有限公司 | The footwear preparation method of aqueous adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 苗明三 主编: "《法定中药药理与临床》", 31 October 1998 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112335998A (en) * | 2020-10-22 | 2021-02-09 | 广州晨骐鞋业有限公司 | Method for preparing women's shoes capable of maintaining three-dimensional state for a long time by using natural leather |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102031078B (en) | Starch-based wood adhesive and preparation method and application thereof | |
| CN102391797B (en) | Corn starch adhesive for building and preparation method thereof | |
| CN103122228B (en) | Bio-oil starch adhesive for wood and preparation method | |
| CN103031095A (en) | Adhesive for veneering of artificial board and preparation method of adhesive | |
| CN103788904A (en) | Organic silicon-vinyl acetate-acrylic copolymerized and modified starch-based wood adhesive and preparation process thereof | |
| CN103265909B (en) | High-solid content quick-drying modified starch lap adhesive and preparation method thereof | |
| CN107384264A (en) | A kind of preparation method of mould proof color inhibition skin shoes-used glue | |
| CN104893629B (en) | A kind of timber normal temperature cure bio oil starch adhesive and preparation method thereof | |
| CN100567430C (en) | With the W-Gum is Wood substance material adhesion agent and the manufacture method thereof that major ingredient is made | |
| CN102911385A (en) | Preparation method of high-strength degradable composite film | |
| CN106079016A (en) | A kind of artificial board containing powder of straw | |
| CN106272843B (en) | A kind of Eucalyptus floor base material | |
| CN107868631A (en) | A kind of environment-friendly wood assembling glue and preparation method thereof | |
| CN103540283A (en) | Urea-formaldehyde glue adhesive and preparation method thereof | |
| CN106363732A (en) | Furfuryl alcohol-added and phenolic resin-compounded fast-growing wood modifying agent | |
| CN107938434B (en) | Preparation method of gold foil cigarette paper | |
| CN107629725A (en) | A kind of Glutinous rice wet glue of high bond strength | |
| CN102358831A (en) | Preparation method for polyurethane adhesive | |
| CN102295903A (en) | Production method for rapidly-precured white latex | |
| CN106272837A (en) | The method being raw material production wardrobe moulding with Eucalyptus core | |
| CN102490217A (en) | Thin board veneering method for bamboo floor | |
| CN107236345A (en) | A kind of excellent white glue with vinyl of health environment-friendly and preparation method thereof | |
| CN109929260A (en) | A method of environment-friendly degradable polymerization sheet is manufactured using agriculture and forestry organic waste material | |
| CN107325753A (en) | A kind of preparation method of corrugated paper high-strength adhesive | |
| CN107936875A (en) | A kind of based Wood Adhesives and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171124 |