CN108610971A - A kind of ceramic insulation coating - Google Patents
A kind of ceramic insulation coating Download PDFInfo
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- CN108610971A CN108610971A CN201611145345.1A CN201611145345A CN108610971A CN 108610971 A CN108610971 A CN 108610971A CN 201611145345 A CN201611145345 A CN 201611145345A CN 108610971 A CN108610971 A CN 108610971A
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- vinyl acetate
- insulation coating
- ceramic insulation
- coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of ceramic insulation coating, weigh turpentine oil, rosin, ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] chlordene metatitanic acid (IV) salt, vinyl acetate ethylene copolymer emulsion, vinylacetate latex of butyl acrylate copolymer adhesive, waterglass, Ludox, polyvinyl alcohol, carbon black, titanium dioxide, sodium hypochlorite, isobutanol and Boratexes, the coating smooth coating, with high glaze, wearability is good, 8 12min of surface drying, does solid work 18 22h；50 90J of impact strength, 12 grades of adhesive force；4 8H of hardness, heat-insulation and heat-preservation inhibiting rate 92 96%；Anti-scratch load is high, and the 8mm coatings are coated on the ceramics of 1200 DEG C of high temperature, and the outer temperature of coating is down to 50 90 DEG C, and antibacterial effect 99.9% can produce and constantly replace current material extensively.
Description
Technical field
The present invention relates to paint field more particularly to a kind of ceramic insulation coating.
Background technology
Global heat-barrier material just develops towards effectively insulating, energy saving thin layer, the integrated direction of outer protection.According to space travel
Device heat-transfer mechanism, according to material technology, Chemical Engineering Technology, information technology, biotechnology, energy technology, nanotechnology, environmental protection
The modern high technologies such as technology, space technology, computer technology, ocean engineering technology, engineering and technique, logistics and its industry are whole
The mating support of body, experience research and development in how many years, successfully develops ZS-1 ceramic high-temperature resistant heat insulating coatings.This type is resistance to
High temperature insulating thermal insulation coatings using nano-hollow ceramic microsphere there is efficient heat-barrier material to finish, and coating has low lead
Hot coefficient, effectively insulating, heatproof is high, fire protection flame retarding, insulation pressure resistance, the epoch-making heat-barrier material of sound insulation environment-friendly novel.
The high temperature resistant heat insulation coating of High Performance Thin has widely applied space flight, military project, metallurgy, electric power, petrochemical industry, traffic etc.
Key areas, excellent performance in heat-barrier material can not replace, play conclusive by the technological improvement for applying brush material
Effect, energy saving, stability, science and technology are unprecedented, are really epoch-making heat-insulated for the development of entire society
Material helps the energy saving economy of enterprise to create greater achievements.
Ceramic coating weatherability and processing performance are excellent, bear dirty and resistant to damage.Although previous ceramic coating resistant to damage,
But if carrying out bending machining to the component after application, crackle, and fluorine resin paints and organic coating are easy tod produce, hold
Easily by damages such as sandstone, dusts.
Insulating moulding coating has been developed in recent years a kind of, reflection thermal-optical type, short time limit, quick functional coating.
There are mainly three types of thermal insulating coating is classified from characteristic principle, isolation conduction type insulating moulding coating, reflective insulation coating and radiation type heat-insulation
Coating.In addition to above-mentioned three types insulating moulding coating, has there are a kind of heat insulating coatings in external heat insulating function coating, in addition to tool
Other than the advantages of standby above-mentioned insulating moulding coating, more for peculiar heat insulation effect.
With social city, technicalization, hommization development, design a kind of fast drying, strong adhesive force, glossiness it is high,
Hardness height and the good ceramic insulation coating of wearability are very important with meeting the market demand.
Invention content
The technical issues of solution：
The application for existing coating heat insulation is poor, wear no resistance, hardness is low, the slow technical problem low with adhesive force of drying,
A kind of ceramic insulation coating is provided.
Technical solution：
A kind of ceramic insulation coating, raw material match as follows in parts by weight：100 parts of turpentine oil, 50-90 parts of rosin, ethyl alcohol 20-60
Part, bis- [three (acetylacetonate) titaniums (IV)] 10-30 parts of chlordene metatitanic acid (IV) salt, vinyl acetate-ethylene copolymerization emulsions 20-40
Part, 5-25 parts of vinyl acetate-acrylic butyl ester copolymer emulsion adhesive, 1-5 parts of waterglass, 10-30 parts of Ludox, polyethylene
6-10 parts of alcohol, 2-6 parts of carbon black, 15-35 parts of titanium dioxide, 3-7 parts of sodium hypochlorite, 4-8 parts of isobutanol, 1.5-5.5 parts of Boratex.
As a preferred technical solution of the present invention：The raw material of the ceramic insulation coating is matched such as in parts by weight
Under：100 parts of turpentine oil, 60-80 parts of rosin, 30-50 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] chlordene metatitanic acid (IV) salt
15-25 parts, 25-35 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion adhesive 10-20
Part, 2-4 parts of waterglass, 15-25 parts of Ludox, 7-9 parts of polyvinyl alcohol, 3-5 parts of carbon black, 20-30 parts of titanium dioxide, sodium hypochlorite 4-
6 parts, 5-7 parts of isobutanol, 2.5-4.5 parts of Boratex.
As a preferred technical solution of the present invention：The raw material of the ceramic insulation coating is matched such as in parts by weight
Under：100 parts of turpentine oil, 60 parts of rosin, 30 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] 15 parts of chlordene metatitanic acid (IV) salt,
25 parts of vinyl acetate-ethylene copolymerization emulsions, 10 parts of vinyl acetate-acrylic butyl ester copolymer emulsion adhesive, 2 parts of waterglass,
15 parts of Ludox, 7 parts of polyvinyl alcohol, 3 parts of carbon black, 20 parts of titanium dioxide, 4 parts of sodium hypochlorite, 5 parts of isobutanol, 2.5 parts of Boratex.
As a preferred technical solution of the present invention：The raw material of the ceramic insulation coating is matched such as in parts by weight
Under：100 parts of turpentine oil, 80 parts of rosin, 50 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] 25 parts of chlordene metatitanic acid (IV) salt,
35 parts of vinyl acetate-ethylene copolymerization emulsions, 20 parts of vinyl acetate-acrylic butyl ester copolymer emulsion adhesive, 4 parts of waterglass,
25 parts of Ludox, 9 parts of polyvinyl alcohol, 5 parts of carbon black, 30 parts of titanium dioxide, 6 parts of sodium hypochlorite, 7 parts of isobutanol, 4.5 parts of Boratex.
As a preferred technical solution of the present invention：The raw material of the ceramic insulation coating is matched such as in parts by weight
Under：100 parts of turpentine oil, 70 parts of rosin, 40 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] 20 parts of chlordene metatitanic acid (IV) salt,
30 parts of vinyl acetate-ethylene copolymerization emulsions, 15 parts of vinyl acetate-acrylic butyl ester copolymer emulsion adhesive, 3 parts of waterglass,
20 parts of Ludox, 8 parts of polyvinyl alcohol, 4 parts of carbon black, 25 parts of titanium dioxide, 5 parts of sodium hypochlorite, 6 parts of isobutanol, 3.5 parts of Boratex.
Advantageous effect：
A kind of ceramic insulation coating of the present invention compared to the prior art using above technical scheme has following technology effect
Fruit：1, smooth coating has high glaze, and wearability is good, and surface drying 8-12min does solid work 18-22h；2, impact strength 50-90J, it is attached
Put forth effort 1-2 grades；3, hardness 4-8H, heat-insulation and heat-preservation inhibiting rate 92-96%；4, anti-scratch load is high, on the ceramics of 1200 DEG C of high temperature
The 8mm coatings are coated, the outer temperature of coating is down to 50-90 DEG C, and antibacterial effect 99.9% can be produced and constantly be replaced existing extensively
Material.
Specific implementation mode
Embodiment 1
Proportioning weighs 100 parts of turpentine oil in parts by weight, 50 parts of rosin, and 20 parts of ethyl alcohol is bis- [three (acetylacetonate) titaniums (IV)]
10 parts of chlordene metatitanic acid (IV) salt, 20 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion glue
Glutinous 5 parts of agent, 1 part of waterglass, 10 parts of Ludox, 6 parts of polyvinyl alcohol, 2 parts of carbon black, 15 parts of titanium dioxide, 3 parts of sodium hypochlorite, isobutyl
4 parts of alcohol, 1.5 parts of Boratex.
By turpentine oil and rosin input in the reaction kettle equipped with blender and thermometer, 60 DEG C are warming up to, 30min is stirred,
Mixing speed is 800 revs/min.
90 DEG C are warming up to, surplus stock is added, mixes 80min, 20min is ground in grinder, with sieve mistake after cooling
Filter.
Obtained insulating moulding coating, smooth coating have high glaze, and wearability is good, and surface drying 12min does solid work 22h；Impact
Intensity 50J, 2 grades of adhesive force；Hardness 4H, heat-insulation and heat-preservation inhibiting rate 92%；Anti-scratch load is high, on the ceramics of 1200 DEG C of high temperature
The 8mm coatings are coated, the outer temperature of coating is down to 90 DEG C, and antibacterial effect 99.9% can produce and constantly replace existing material extensively
Material.
Embodiment 2
Proportioning weighs 100 parts of turpentine oil, 50-90 parts of rosin, 60 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums in parts by weight
(IV)] 30 parts of chlordene metatitanic acid (IV) salt, 40 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymerization breast
25 parts of liquid adhesive, 5 parts of waterglass, 30 parts of Ludox, 10 parts of polyvinyl alcohol, 6 parts of carbon black, 35 parts of titanium dioxide, sodium hypochlorite 7
Part, 8 parts of isobutanol, 5.5 parts of Boratex.
By turpentine oil and rosin input in the reaction kettle equipped with blender and thermometer, 80 DEG C are warming up to, 70min is stirred,
Mixing speed is 1200 revs/min.
110 DEG C are warming up to, surplus stock is added, mixes 120min, 40min is ground in grinder, sieve is used after cooling
Filtering.
Obtained insulating moulding coating, smooth coating have high glaze, and wearability is good, and surface drying 11min does solid work 21h；Impact
Intensity 60J, 2 grades of adhesive force；Hardness 5H, heat-insulation and heat-preservation inhibiting rate 93%；Anti-scratch load is high, on the ceramics of 1200 DEG C of high temperature
The 8mm coatings are coated, the outer temperature of coating is down to 80 DEG C, and antibacterial effect 99.9% can produce and constantly replace existing material extensively
Material.
Embodiment 3
Proportioning weighs 100 parts of turpentine oil in parts by weight, 60 parts of rosin, and 30 parts of ethyl alcohol is bis- [three (acetylacetonate) titaniums (IV)]
15 parts of chlordene metatitanic acid (IV) salt, 25 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion glue
Glutinous 10 parts of agent, 2 parts of waterglass, 15 parts of Ludox, 7 parts of polyvinyl alcohol, 3 parts of carbon black, 20 parts of titanium dioxide, 4 parts of sodium hypochlorite, isobutyl
5 parts of alcohol, 2.5 parts of Boratex.
By turpentine oil and rosin input in the reaction kettle equipped with blender and thermometer, 60 DEG C are warming up to, 30min is stirred,
Mixing speed is 800 revs/min.
90 DEG C are warming up to, surplus stock is added, mixes 80min, 20min is ground in grinder, with sieve mistake after cooling
Filter.
Obtained insulating moulding coating, smooth coating have high glaze, and wearability is good, and surface drying 10min does solid work 20h；Impact
Intensity 70J, 2 grades of adhesive force；Hardness 6H, heat-insulation and heat-preservation inhibiting rate 94%；Anti-scratch load is high, on the ceramics of 1200 DEG C of high temperature
The 8mm coatings are coated, the outer temperature of coating is down to 70 DEG C, and antibacterial effect 99.9% can produce and constantly replace existing material extensively
Material.
Embodiment 4
Proportioning weighs 100 parts of turpentine oil in parts by weight, 80 parts of rosin, and 50 parts of ethyl alcohol is bis- [three (acetylacetonate) titaniums (IV)]
25 parts of chlordene metatitanic acid (IV) salt, 35 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion glue
Glutinous 20 parts of agent, 4 parts of waterglass, 25 parts of Ludox, 9 parts of polyvinyl alcohol, 5 parts of carbon black, 30 parts of titanium dioxide, 6 parts of sodium hypochlorite, isobutyl
7 parts of alcohol, 4.5 parts of Boratex.
By turpentine oil and rosin input in the reaction kettle equipped with blender and thermometer, 80 DEG C are warming up to, 70min is stirred,
Mixing speed is 1200 revs/min.
110 DEG C are warming up to, surplus stock is added, mixes 120min, 40min is ground in grinder, sieve is used after cooling
Filtering.
Obtained insulating moulding coating, smooth coating have high glaze, and wearability is good, and surface drying 9min does solid work 19h；Impact is strong
Spend 80J, adhesion 1 grade；Hardness 7H, heat-insulation and heat-preservation inhibiting rate 95%；Anti-scratch load is high, is applied on the ceramics of 1200 DEG C of high temperature
The upper 8mm coatings, the outer temperature of coating are down to 60 DEG C, and antibacterial effect 99.9% can produce and constantly replace current material extensively.
Embodiment 5
Proportioning weighs 100 parts of turpentine oil in parts by weight, 70 parts of rosin, and 40 parts of ethyl alcohol is bis- [three (acetylacetonate) titaniums (IV)]
20 parts of chlordene metatitanic acid (IV) salt, 30 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion glue
Glutinous 15 parts of agent, 3 parts of waterglass, 20 parts of Ludox, 8 parts of polyvinyl alcohol, 4 parts of carbon black, 25 parts of titanium dioxide, 5 parts of sodium hypochlorite, isobutyl
6 parts of alcohol, 3.5 parts of Boratex.
By turpentine oil and rosin input in the reaction kettle equipped with blender and thermometer, 70 DEG C are warming up to, 50min is stirred,
Mixing speed is 1000 revs/min.
100 DEG C are warming up to, surplus stock is added, mixes 100min, 30min is ground in grinder, sieve is used after cooling
Filtering.
Obtained insulating moulding coating, smooth coating have high glaze, and wearability is good, and surface drying 8min does solid work 18h；Impact is strong
Spend 90J, adhesion 1 grade；Hardness 8H, heat-insulation and heat-preservation inhibiting rate 96%；Anti-scratch load is high, is applied on the ceramics of 1200 DEG C of high temperature
The upper 8mm coatings, the outer temperature of coating are down to 50 DEG C, and antibacterial effect 99.9% can produce and constantly replace current material extensively.
All components in above example can be commercially available.
The above embodiments are merely intended to illustrate the present invention rather than to limit it, therefore with the present invention's
Any change in the comparable meaning and scope of claims, should be construed as being included in the scope of the claims.
Claims (5)
1. a kind of ceramic insulation coating, it is characterised in that：The raw material of the ceramic insulation coating matches as follows in parts by weight：Pine
100 parts of fuel-economizing, 50-90 parts of rosin, 20-60 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] chlordene metatitanic acid (IV) salt 10-30
Part, 20-40 parts of vinyl acetate-ethylene copolymerization emulsions, 5-25 parts of vinyl acetate-acrylic butyl ester copolymer emulsion adhesive, water
1-5 parts of glass, 10-30 parts of Ludox, 6-10 parts of polyvinyl alcohol, 2-6 parts of carbon black, 15-35 parts of titanium dioxide, 3-7 parts of sodium hypochlorite,
4-8 parts of isobutanol, 1.5-5.5 parts of Boratex.
2. a kind of ceramic insulation coating according to claim 1, it is characterised in that：The raw material of the ceramic insulation coating is pressed
Parts by weight proportioning is as follows：100 parts of turpentine oil, 60-80 parts of rosin, 30-50 parts of ethyl alcohol are bis- [three (acetylacetonate) titaniums (IV)]
15-25 parts of chlordene metatitanic acid (IV) salt, 25-35 parts of vinyl acetate-ethylene copolymerization emulsions, the copolymerization of vinyl acetate-acrylic butyl ester
10-20 parts of lotion adhesive, 2-4 parts of waterglass, 15-25 parts of Ludox, 7-9 parts of polyvinyl alcohol, 3-5 parts of carbon black, titanium dioxide 20-
30 parts, 4-6 parts of sodium hypochlorite, 5-7 parts of isobutanol, 2.5-4.5 parts of Boratex.
3. a kind of ceramic insulation coating according to claim 1, it is characterised in that：The raw material of the ceramic insulation coating is pressed
Parts by weight proportioning is as follows：100 parts of turpentine oil, 60 parts of rosin, 30 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] chlordene titaniums
Sour 15 parts of (IV) salt, 25 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion adhesive 10
Part, 2 parts of waterglass, 15 parts of Ludox, 7 parts of polyvinyl alcohol, 3 parts of carbon black, 20 parts of titanium dioxide, 4 parts of sodium hypochlorite, 5 parts of isobutanol,
2.5 parts of Boratex.
4. a kind of ceramic insulation coating according to claim 1, it is characterised in that：The raw material of the ceramic insulation coating is pressed
Parts by weight proportioning is as follows：100 parts of turpentine oil, 80 parts of rosin, 50 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] chlordene titaniums
Sour 25 parts of (IV) salt, 35 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion adhesive 20
Part, 4 parts of waterglass, 25 parts of Ludox, 9 parts of polyvinyl alcohol, 5 parts of carbon black, 30 parts of titanium dioxide, 6 parts of sodium hypochlorite, 7 parts of isobutanol,
4.5 parts of Boratex.
5. a kind of ceramic insulation coating according to claim 1, it is characterised in that：The raw material of the ceramic insulation coating is pressed
Parts by weight proportioning is as follows：100 parts of turpentine oil, 70 parts of rosin, 40 parts of ethyl alcohol, bis- [three (acetylacetonate) titaniums (IV)] chlordene titaniums
Sour 20 parts of (IV) salt, 30 parts of vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-acrylic butyl ester copolymer emulsion adhesive 15
Part, 3 parts of waterglass, 20 parts of Ludox, 8 parts of polyvinyl alcohol, 4 parts of carbon black, 25 parts of titanium dioxide, 5 parts of sodium hypochlorite, 6 parts of isobutanol,
3.5 parts of Boratex.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611145345.1A CN108610971A (en) | 2016-12-13 | 2016-12-13 | A kind of ceramic insulation coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611145345.1A CN108610971A (en) | 2016-12-13 | 2016-12-13 | A kind of ceramic insulation coating |
Publications (1)
| Publication Number | Publication Date |
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| CN108610971A true CN108610971A (en) | 2018-10-02 |
Family
ID=63643749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611145345.1A Withdrawn CN108610971A (en) | 2016-12-13 | 2016-12-13 | A kind of ceramic insulation coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN108610971A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060100A (en) * | 1991-01-19 | 1992-04-08 | 铁道部大连机车车辆工厂 | Water-based insulation damping painting |
| CN101037562A (en) * | 2007-04-29 | 2007-09-19 | 王林山 | Inner wall mouldproof coating |
| CN104109477A (en) * | 2014-07-29 | 2014-10-22 | 陆佩 | Gloss paint for decorative porcelain |
-
2016
- 2016-12-13 CN CN201611145345.1A patent/CN108610971A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060100A (en) * | 1991-01-19 | 1992-04-08 | 铁道部大连机车车辆工厂 | Water-based insulation damping painting |
| CN101037562A (en) * | 2007-04-29 | 2007-09-19 | 王林山 | Inner wall mouldproof coating |
| CN104109477A (en) * | 2014-07-29 | 2014-10-22 | 陆佩 | Gloss paint for decorative porcelain |
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Application publication date: 20181002 |