CN108609990A - A kind of anti-fracture thermal insulation material of impact resistance resistance to compression - Google Patents

A kind of anti-fracture thermal insulation material of impact resistance resistance to compression Download PDF

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Publication number
CN108609990A
CN108609990A CN201810577253.3A CN201810577253A CN108609990A CN 108609990 A CN108609990 A CN 108609990A CN 201810577253 A CN201810577253 A CN 201810577253A CN 108609990 A CN108609990 A CN 108609990A
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parts
thermal insulation
insulation material
impact resistance
agent
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CN201810577253.3A
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Chinese (zh)
Inventor
刘榄
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County Huashun Casting Co Ltd
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County Huashun Casting Co Ltd
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Priority to CN201810577253.3A priority Critical patent/CN108609990A/en
Publication of CN108609990A publication Critical patent/CN108609990A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials
    • C04B2111/503Elastic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to thermal insulation material technical fields, and in particular to a kind of anti-fracture thermal insulation material of impact resistance resistance to compression.The raw material of the thermal insulation material includes:Expanded perlite, bentonite, lime, attapulgite clay, polyurethane rubber elastomer, gypsum, inorganic mineral fiber, rock wool, polyacrylamide, bonding agent, fire retardant, organic silicon water-proofing curing agent and water.Wherein, polyurethane rubber elastomer is prepared by raw materials such as organic silicon modified polyurethane, ethylene propylene diene rubber, epoxy resin, white carbons;Expanded perlite is closed-cell expanded perlite, and inorganic mineral fiber includes one kind in alumina silicate fibre, brucite fiber, sepiolite fibre, and bonding agent is aluminum phosphate;Fire retardant is aluminium hydroxide.The thermal and insulating performance of the thermal insulation material is outstanding, and production cost is relatively low, also has outstanding resistance to compression, impact resistance, and toughness is strong, elasticity is good, it is not easy to be broken.

Description

A kind of anti-fracture thermal insulation material of impact resistance resistance to compression
Technical field
The present invention relates to thermal insulation material technical fields, and in particular to a kind of anti-fracture thermal insulation material of impact resistance resistance to compression.
Background technology
Thermal insulation board is a kind of construction material for building energy conservation heat insulation engineering construction, which can significantly improve building Energy-conserving and environment-protective performance, foreign countries there is very long history for the use of building thermal insulation material, develop porcelain tendre thermal insulating material Material, aluminum silicate insulation material, phenolic foam material, polyurethane foamed material, glue powder polyphenyl particle, rock wool, foam cement etc. are more The organic and inorganic heat insulation material of kind.
Wherein, the thermal insulation material used in China's building process of construction is mainly inorganic heat insulation material, inorganic heat insulation material Low with production cost, material anti-aging property is outstanding, the small advantage of thermal deformation degree, but the impact resistance of inorganic heat insulation material Performance is poor, is easy cracking in a compressed state, and the thermal insulation material after cracking is easy to fall off, and loses practical value.
Invention content
For problems of the prior art, the present invention provides a kind of anti-fracture thermal insulation materials of impact resistance resistance to compression, should The thermal and insulating performance of type thermal insulation material is outstanding, and production cost is relatively low, also has outstanding resistance to compression, an impact resistance, toughness is strong, Elasticity is good, it is not easy to be broken.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of anti-fracture thermal insulation material of impact resistance resistance to compression, according to mass fraction, the raw material of the thermal insulation material includes:Expanded perlite 70-75 parts, 25-30 parts of bentonite, 8-10 parts of lime, 10-15 parts of attapulgite clay, 17-22 parts of polyester-rubber elastomer, 8-15 parts of gypsum, 4-6 parts of inorganic mineral fiber, 15-20 parts of rock wool, 2-5 parts of polyacrylamide, 10-13 parts of bonding agent, fire retardant 8-10 parts, 7-8 parts of organic silicon water-proofing curing agent, 60-65 parts of water.
Preferably, according to mass fraction, the raw material of the thermal insulation material includes:72-73 parts of expanded perlite, bentonite 27- 28 parts, 9-10 parts of lime, 12-13 parts of attapulgite clay, 18-20 parts of polyester-rubber elastomer, 12-13 parts of gypsum, inorganic mine 4-5 parts of fibres, 17-18 parts of rock wool, 3-4 parts of polyacrylamide, 12-13 parts of bonding agent, 9-10 parts of fire retardant, organic silicon water-proofing 7.5-7.7 parts of curing agent, 63-64 parts of water.
In the present invention, polyester-rubber method for producing elastomers is:Prepare raw material according to mass fraction:Organosilicon changes 55 parts of polyurethane of property, 18 parts of ethylene propylene diene rubber, 7 parts of epoxy resin, white carbon 8,13 parts of silica flour, 4 parts of zinc oxide, 3,3 ,- Two chloro- 4,4,4 parts of-diamino-diphenyl methane, 2 parts of silane coupling agent, 3 parts of anti-aging agent;By organic silicon modified polyurethane, three First EP rubbers, epoxy resin and 3,3 ,-two chloro- 4,4 ,-diamino-diphenyl methane is added in batch mixer, with 80-95 DEG C temperature batch mixing stir 1-1.5h, then white carbon, silica flour, zinc oxide, silane coupling agent and anti-aging agent are added to mixed In material machine, continue to mix 15-20min, feeds the mixture into extruding pelletization in double screw extruder, institute is obtained after cooling drying Need polyester-rubber elastomer.Anti-aging agent is antioxidant D or anti-aging agent 4040 in raw material.
Preferably, expanded perlite is closed-cell expanded perlite.
Preferably, inorganic mineral fiber includes one kind in alumina silicate fibre, brucite fiber, sepiolite fibre.
Preferably, bonding agent is aluminum phosphate;Fire retardant is aluminium hydroxide.
The preparation method of thermal insulation material provided by the invention is as follows:According to mass fraction, by expanded perlite, bentonite, Lime, attapulgite clay, polyester-rubber elastomer, gypsum, inorganic mineral fiber, rock wool, polyacrylamide, bonding agent, resistance It is uniform that combustion agent is pre-added to stirrer for mixing, and water is then added into mixture, stirs into slurry, slurry is put into mould It is press-formed in tool, molding heat preservation plate material is sent in drying box, dried to water content and dropped with 80-85 DEG C of high-temperature To original 4 one-tenth, then take out cooled to room temperature, then surface press polish processing carried out to heat preservation plate material, after press polish processing Heat preservation plate material press polish layer surface smears organosilicon water-proof solidifying agent, obtains required thermal insulation material.
The present invention has following advantageous effect:
The main body thermal insulation material of the type thermal insulation board is that inorganic material is being kept by adding inorganic mineral fiber and rock wool fibers While good thermal and insulating performance, the strength of materials and toughness are improved so that the bending strength of material and anti-fracture performance More preferably.Wherein, polyester-rubber elastomer is also added in thermal insulation material, which uses the heat preservation for not only making material Performance is more outstanding, and makes the elasticity of material and flexibility more preferable, further promotes the impact resistance of thermal insulation material.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of anti-fracture thermal insulation material of impact resistance resistance to compression, according to mass fraction, the raw material of the thermal insulation material includes:Expanded perlite 70 parts, 25 parts of bentonite, 8 parts of lime, 10 parts of attapulgite clay, 17 parts of polyester-rubber elastomer, 8 parts of gypsum, inorganic mineral 4 parts of fiber, 15 parts of rock wool, 2 parts of polyacrylamide, 10 parts of bonding agent, 8 parts of fire retardant, 7 parts of organic silicon water-proofing curing agent, water 60 Part.
In the present embodiment, polyester-rubber method for producing elastomers is:Prepare raw material according to mass fraction:Organosilicon 55 parts of modified polyurethane, 18 parts of ethylene propylene diene rubber, 7 parts of epoxy resin, white carbon 8,13 parts of silica flour, 4 parts of zinc oxide, 3, 3 ,-two chloro- 4,4,4 parts of-diamino-diphenyl methane, 2 parts of silane coupling agent, 3 parts of anti-aging agent;By organic silicon modified polyurethane, Ethylene propylene diene rubber, epoxy resin and 3,3 ,-two chloro- 4,4 ,-diamino-diphenyl methane is added in batch mixer, with 80 DEG C Temperature batch mixing stir 1h, then white carbon, silica flour, zinc oxide, silane coupling agent and anti-aging agent are added in batch mixer, Continue to mix 15min, feeds the mixture into extruding pelletization in double screw extruder, required polyurethane-is obtained after cooling drying Rubber elastomer.Anti-aging agent is antioxidant D in raw material.
Wherein, expanded perlite is closed-cell expanded perlite;Inorganic mineral fiber is alumina silicate fibre;Bonding agent is phosphoric acid Aluminium;Fire retardant is aluminium hydroxide.
The preparation method of thermal insulation material provided in this embodiment is as follows:According to mass fraction, by expanded perlite, swelling Soil, lime, attapulgite clay, polyester-rubber elastomer, gypsum, inorganic mineral fiber, rock wool, polyacrylamide, bonding It is uniform that agent, fire retardant are pre-added to stirrer for mixing, and water is then added into mixture, stirs into slurry, slurry is thrown Enter and be press-formed into mold, molding heat preservation plate material is sent in drying box, is dried to aqueous with 80 DEG C of high-temperature Amount is down to original 4 one-tenth, then takes out cooled to room temperature, then carry out surface press polish processing, press polish processing to heat preservation plate material Organosilicon water-proof solidifying agent is smeared in heat preservation plate material press polish layer surface afterwards, obtains required thermal insulation material.
Embodiment 2
A kind of anti-fracture thermal insulation material of impact resistance resistance to compression, according to mass fraction, the raw material of the thermal insulation material includes:Expanded perlite 75 parts, 30 parts of bentonite, 10 parts of lime, 15 parts of attapulgite clay, 22 parts of polyester-rubber elastomer, 15 parts of gypsum, inorganic mine 6 parts of fibres, 20 parts of rock wool, 5 parts of polyacrylamide, 13 parts of bonding agent, 10 parts of fire retardant, 8 parts of organic silicon water-proofing curing agent, water 65 parts.
In the present embodiment, polyester-rubber method for producing elastomers is:Prepare raw material according to mass fraction:Organosilicon 55 parts of modified polyurethane, 18 parts of ethylene propylene diene rubber, 7 parts of epoxy resin, white carbon 8,13 parts of silica flour, 4 parts of zinc oxide, 3, 3 ,-two chloro- 4,4,4 parts of-diamino-diphenyl methane, 2 parts of silane coupling agent, 3 parts of anti-aging agent;By organic silicon modified polyurethane, Ethylene propylene diene rubber, epoxy resin and 3,3 ,-two chloro- 4,4 ,-diamino-diphenyl methane is added in batch mixer, with 95 DEG C Temperature batch mixing stir 1.5h, white carbon, silica flour, zinc oxide, silane coupling agent and anti-aging agent are then added to batch mixer In, continue to mix 20min, feeds the mixture into extruding pelletization in double screw extruder, required poly- ammonia is obtained after cooling drying Ester-rubber elastomer.Anti-aging agent is anti-aging agent 4040 in raw material.
Wherein, expanded perlite is closed-cell expanded perlite;Inorganic mineral fiber is brucite fiber;Bonding agent is phosphoric acid Aluminium;Fire retardant is aluminium hydroxide.
The preparation method of thermal insulation material provided in this embodiment is as follows:According to mass fraction, by expanded perlite, swelling Soil, lime, attapulgite clay, polyester-rubber elastomer, gypsum, inorganic mineral fiber, rock wool, polyacrylamide, bonding It is uniform that agent, fire retardant are pre-added to stirrer for mixing, and water is then added into mixture, stirs into slurry, slurry is thrown Enter and be press-formed into mold, molding heat preservation plate material is sent in drying box, is dried to aqueous with 85 DEG C of high-temperature Amount is down to original 4 one-tenth, then takes out cooled to room temperature, then carry out surface press polish processing, press polish processing to heat preservation plate material Organosilicon water-proof solidifying agent is smeared in heat preservation plate material press polish layer surface afterwards, obtains required thermal insulation material.
Embodiment 3
A kind of anti-fracture thermal insulation material of impact resistance resistance to compression, according to mass fraction, the raw material of the thermal insulation material includes:Expanded perlite 73 parts, 28 parts of bentonite, 9 parts of lime, 13 parts of attapulgite clay, 19 parts of polyester-rubber elastomer, 11 parts of gypsum, inorganic mine 5 parts of fibres, 18 parts of rock wool, 4 parts of polyacrylamide, 12 parts of bonding agent, 9 parts of fire retardant, 7.5 parts of organic silicon water-proofing curing agent, 63 parts of water.
In the present embodiment, polyester-rubber method for producing elastomers is:Prepare raw material according to mass fraction:Organosilicon 55 parts of modified polyurethane, 18 parts of ethylene propylene diene rubber, 7 parts of epoxy resin, white carbon 8,13 parts of silica flour, 4 parts of zinc oxide, 3, 3 ,-two chloro- 4,4,4 parts of-diamino-diphenyl methane, 2 parts of silane coupling agent, 3 parts of anti-aging agent;By organic silicon modified polyurethane, Ethylene propylene diene rubber, epoxy resin and 3,3 ,-two chloro- 4,4 ,-diamino-diphenyl methane is added in batch mixer, with 90 DEG C Temperature batch mixing stir 1.2h, white carbon, silica flour, zinc oxide, silane coupling agent and anti-aging agent are then added to batch mixer In, continue to mix 18min, feeds the mixture into extruding pelletization in double screw extruder, required poly- ammonia is obtained after cooling drying Ester-rubber elastomer.Anti-aging agent is antioxidant D in raw material.
Wherein, expanded perlite is closed-cell expanded perlite;Inorganic mineral fiber is sepiolite fibre;Bonding agent is phosphoric acid Aluminium;Fire retardant is aluminium hydroxide.
The preparation method of thermal insulation material provided in this embodiment is as follows:According to mass fraction, by expanded perlite, swelling Soil, lime, attapulgite clay, polyester-rubber elastomer, gypsum, inorganic mineral fiber, rock wool, polyacrylamide, bonding It is uniform that agent, fire retardant are pre-added to stirrer for mixing, and water is then added into mixture, stirs into slurry, slurry is thrown Enter and be press-formed into mold, molding heat preservation plate material is sent in drying box, is dried to aqueous with 83 DEG C of high-temperature Amount is down to original 4 one-tenth, then takes out cooled to room temperature, then carry out surface press polish processing, press polish processing to heat preservation plate material Organosilicon water-proof solidifying agent is smeared in heat preservation plate material press polish layer surface afterwards, obtains required thermal insulation material.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (8)

1. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression, it is characterised in that:According to mass fraction, the raw material of the thermal insulation material Including:70-75 parts of expanded perlite, 25-30 parts of bentonite, 8-10 parts of lime, 10-15 parts of attapulgite clay, polyester-rubber 17-22 parts of elastomer, 8-15 parts of gypsum, 4-6 parts of inorganic mineral fiber, 15-20 parts of rock wool, 2-5 parts of polyacrylamide, bonding agent 10-13 parts, 8-10 parts of fire retardant, 7-8 parts of organic silicon water-proofing curing agent, 60-65 parts of water.
2. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 1, it is characterised in that:According to mass parts Number, the raw material of the thermal insulation material include:72-73 parts of expanded perlite, 27-28 parts of bentonite, 9-10 parts of lime, concave convex rod are viscous It is 12-13 parts native, 18-20 parts of polyester-rubber elastomer, 12-13 parts of gypsum, 4-5 parts of inorganic mineral fiber, 17-18 parts of rock wool, 3-4 parts of polyacrylamide, 12-13 parts of bonding agent, 9-10 parts of fire retardant, 7.5-7.7 parts of organic silicon water-proofing curing agent, water 63-64 Part.
3. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 1, which is characterized in that the polyurethane- The preparation method of rubber elastomer is:Prepare raw material according to mass fraction:55 parts of organic silicon modified polyurethane, ethylene propylene diene rubber 18 parts, 7 parts of epoxy resin, white carbon 8,13 parts of silica flour, 4 parts of zinc oxide, 3,3 ,-two chloro- 4,4 ,-diamino-diphenylmethyl 4 parts of alkane, 2 parts of silane coupling agent, 3 parts of anti-aging agent;By organic silicon modified polyurethane, ethylene propylene diene rubber, epoxy resin and 3,3 ,- Two chloro- 4,4 ,-diamino-diphenyl methane is added in batch mixer, stirs 1-1.5h with 80-95 DEG C of temperature batch mixing, then White carbon, silica flour, zinc oxide, silane coupling agent and anti-aging agent are added in batch mixer, continues to mix 15-20min, will mix It closes material and is sent to extruding pelletization in double screw extruder, required polyester-rubber elastomer is obtained after cooling drying.
4. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 3, it is characterised in that:Prevent in the raw material Old agent is antioxidant D or anti-aging agent 4040.
5. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 1, it is characterised in that:The expanded pearlite Rock is closed-cell expanded perlite.
6. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 1, it is characterised in that:The inorganic mineral Fiber includes one kind in alumina silicate fibre, brucite fiber, sepiolite fibre.
7. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 1, it is characterised in that:The bonding agent is Aluminum phosphate;Fire retardant is aluminium hydroxide.
8. a kind of anti-fracture thermal insulation material of impact resistance resistance to compression according to claim 1, it is characterised in that:The thermal insulation material Preparation method it is as follows:According to mass fraction, by expanded perlite, bentonite, lime, attapulgite clay, polyester-rubber bullet Property body, gypsum, inorganic mineral fiber, rock wool, polyacrylamide, bonding agent, that fire retardant is pre-added to stirrer for mixing is equal It is even, water is then added into mixture, stirs into slurry, slurry is put into mold and is press-formed, by molding thermal insulation board Material is sent in drying box, is dried to water content with 80-85 DEG C of high-temperature and is down to original 4 one-tenth, it is cold to then take out nature But to room temperature, then surface press polish processing is carried out to heat preservation plate material, it is organic in heat preservation plate material press polish layer surface smearing after press polish processing Silicon water-proof solidifying agent obtains required thermal insulation material.
CN201810577253.3A 2018-06-07 2018-06-07 A kind of anti-fracture thermal insulation material of impact resistance resistance to compression Pending CN108609990A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN111574241A (en) * 2020-05-15 2020-08-25 江苏银辉生态科技有限公司 HKS modified polypropylene heat preservation sound insulation board
CN111960786A (en) * 2020-08-25 2020-11-20 泰山石膏(涡阳)有限公司 Compression-resistant and breakage-resistant gypsum product and preparation method thereof
CN113968713A (en) * 2021-11-15 2022-01-25 江阴市维沃保温材料有限公司 Inorganic silicon crystal material for smoke prevention and exhaust air duct and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111574241A (en) * 2020-05-15 2020-08-25 江苏银辉生态科技有限公司 HKS modified polypropylene heat preservation sound insulation board
CN111960786A (en) * 2020-08-25 2020-11-20 泰山石膏(涡阳)有限公司 Compression-resistant and breakage-resistant gypsum product and preparation method thereof
CN113968713A (en) * 2021-11-15 2022-01-25 江阴市维沃保温材料有限公司 Inorganic silicon crystal material for smoke prevention and exhaust air duct and preparation method thereof
CN113968713B (en) * 2021-11-15 2022-06-28 江阴市维沃保温材料有限公司 Inorganic silicon crystal material for smoke prevention and exhaust air pipe and preparation method thereof

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Application publication date: 20181002