CN108603071A - Coating resin combination - Google Patents
Coating resin combination Download PDFInfo
- Publication number
- CN108603071A CN108603071A CN201780010374.3A CN201780010374A CN108603071A CN 108603071 A CN108603071 A CN 108603071A CN 201780010374 A CN201780010374 A CN 201780010374A CN 108603071 A CN108603071 A CN 108603071A
- Authority
- CN
- China
- Prior art keywords
- coating
- resin combination
- base material
- film
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention provides a kind of coating resin combination, has the storage stability used and the rapid-drying properties being resistant in the production line, and the Physical properties of coating film such as the adaptation of film and chemical-resistant are excellent.It is the composition for being coated on resin base material, which is characterized in that the composition contains the present invention relates to coating resin combination：(A) the multifunctional reactive compounds with 2~15 epoxy groups and/or halogenated alcohol radical in a molecule；The amino resins that (B) number-average molecular weight is 250~10,000.
Description
Technical field
The present invention relates to coating resin combinations.
Background technology
In the past, using the industrial product with the presence of resin base material in the shell of such as PC or the shape of various films etc.
Difference, but it is widely available.As aspect common in these manufacturing methods, it can enumerate and be filled to drying from painting in the production line
It is carried out continuously.It is carried out continuously in the production line from when being applied to dry as described above, the time needed for the process is direct
It is related to productivity.Therefore, in order to improve productivity ratio, need to complete above-mentioned operation with the short time.
As the method being dried in a short time, it can be cited for example that the acrylic resin system using one-pack-type applies
The method of material.But as understood as basic technical information, although one-pack-type coating can be compared it is short
Drying in time, but the Physical properties of coating film such as adaptation or chemical-resistant may not be abundant.As the method for improving this aspect, it is known that
There is the dual liquid type coating for for example making acrylic resin be reacted with isocyanate resin, although in this case, Physical properties of coating film is good
It is good, but when dry need that acrylic resin is made to react with isocyanate resin, therefore drying time is long, and making
Standby coating is also reacted between being coated with, therefore there are problems that the storage stability of gelation or the like occurs, therefore real
The use on border is restricted.
As with the short time make dual liquid type coating dry method, have make drying temperature be high temperature method or will be reactive
The method that relatively high resin is combined with each other.But the problem of due to the heat resistance of resin base material, although because of the material of resin base material
Matter or drying time and exist different, but be generally difficult to carry out the processing under high temperature.Therefore, by selecting institute in coating in reality
Resin types solve.As resin types, the widely known group for having the curing agent such as epoxy resin and amine compounds
It closes, but rapid-drying properties and storage stability are generally difficult to have both both there are shifting relationship.As solving the project
Method, report have for example by using particle cover curing agent surface come improve storage stability method (such as patent text
It offers 1,2), but there is microparticle residue in the method in the problems in film, use scope is restricted.As other sides
Method reports the side being favorably modified as curing agent to novolac resin with the compound with amino triazine ring structure
Method (such as patent document 3), but curing agent is complicated, and the solvent or epoxy resin type to mix is restricted, therefore its
Use scope is restricted.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2015-203033 bulletins
Patent document 2：Japanese Unexamined Patent Publication 9-87364 bulletins
Patent document 3：Japanese Unexamined Patent Publication 2002-226556 bulletins
Invention content
Problems to be solved by the invention
The purpose of the present invention is to provide a kind of coating resin combinations, have the use being resistant on production line
Storage stability and rapid-drying properties, and the Physical properties of coating film such as the adaptation of film and chemical-resistant are excellent.
Means for solving the problems
The present inventor has made intensive studies in order to solve the above problems, as a result, it has been found that containing having certain amount of epoxy
The multifunctional reactive compounds of base and/or halogenated alcohol radical and the amino resins with specific number-average molecular weight as it is necessary at
The storage stability and rapid-drying properties of the composition epoxy resin of the dual liquid type divided are excellent, and the feature as dual liquid type coating
The Physical properties of coating film such as the adaptation of film and chemical-resistant are excellent, are suitable as the coating for being coated on resin base material and combine
Object, so as to complete the present invention.
That is, the coating of the present invention composition that resin combination is for being coated on resin base material, which is characterized in that should
Composition contains：
(A) the multifunctional reactive compounds with 2~15 epoxy groups and/or halogenated alcohol radical in a molecule；With
(B) amino resins that number-average molecular weight is 250~10,000.
In the coating resin combination of the present invention, preferably (B) amino resins is melmac.
In the coating resin combination of the present invention, preferably with respect to 100 parts by weight of (A) ingredient, the content of (B) ingredient
For 10~10,000 parts by weight.
In the coating resin combination of the present invention, preferably (A) multifunctional reactive compounds have in a molecule
There are 2~10 epoxy groups and/or halogenated alcohol radical.
The present invention component be characterized in that, with resin base material and use the present invention coating resin combination
And it is formed in the film on resin base material.
In the component of the present invention, the material of preferred resin base material is polyester.
The manufacturing method of the component of the present invention is the method for component for manufacturing the present invention, which is characterized in that this method
Including：
Process (1)：The coating of the present invention is coated on at least one face of resin base material with resin combination；With
Process (2)：The coating resin combination that will be coated in process (1) heats 5~300 seconds at 60~250 DEG C
And make its solidification.
Invention effect
The coating resin combination of the present invention contains multifunctional with certain amount of epoxy group and/or halogenated alcohol radical
Reactive compounds and amino resins with specific number-average molecular weight, therefore storage stability and rapid-drying properties are excellent, and
The adaptation and good chemical resistance of film, are suitable as the coating composition for being coated on resin base material.
Specific implementation mode
<<Coating resin combination>>
The coating of the present invention composition that resin combination is for being coated on resin base material, which is characterized in that the group
Object is closed to contain：
(A) the multifunctional reactive compounds with 2~15 epoxy groups and/or halogenated alcohol radical in a molecule；With
(B) amino resins that number-average molecular weight is 250~10,000.
<(A) multifunctional reactive compounds>
As (A) multifunctional reactive compounds (hereinafter also referred to as (A) ingredient), if in a molecule have 2~
15 epoxy groups and/or halogenated alcohol radical, then there is no particular limitation as to it, as the compound with epoxy group, can enumerate example
As d-sorbite polyglycidyl ether, bisphenol A diglycidyl ether, glycerine polyglycidyl ether, polyglycereol polyglycidyl ether,
Trimethylolpropane polyglycidyl ether, pentaerythrite polyglycidyl ether, resorcinolformaldehyde resin, isobide two
Glycidol ether, isomannite diglycidyl ether, different iditol diglycidyl ether, hydrogenated bisphenol A diglycidyl ether,
Cresol novolac polyglycidyl ether etc..As halohydrin compound, it can be cited for example that making halogen and water and there is double bond
Compound reaction obtained from compound, make epihalohydrin class and alcoholic compound reacted in the presence of lewis acid catalyst and
Obtained compound (halogenated ether compound).It can be cited for example that the poly- halohydrin of D-sorbite, the poly- halohydrin of glycerine, diglycerol
Poly- chlorhydrin, ethylene glycol dihalo alcohol, propylene glycol dichlorohydrins etc..They can be used alone or in combination with two or more.
For (A) ingredient in a molecule possessed epoxy group and/or the quantity of halogenated alcohol radical, as long as be 2~15
A, then there is no particular limitation as to it, preferably 2~10, more preferably 2~6, further preferably 2~4.(A) ingredient
It, can not be solid into resin combination is exercised when possessed epoxy group and/or the quantity of halogenated alcohol radical are less than 2 in a molecule
Change and form the cross-linking reaction needed for film, when more than 15, storage stability reduces sometimes.
(A) in the case that ingredient is epoxide, epoxide equivalent is not particularly limited, preferably 100~1000,
More preferably 120~700.When epoxide equivalent is less than 100, it is bad to occasionally result in solidification, when more than 1000, storage stability sometimes
It is deteriorated.(A) in the case that ingredient is the compound with halogenated alcohol radical, water-disintegrable chlorine is not particularly limited, usually
10%~30%.
In the coating resin combination of the present invention, the content of (A) ingredient is not particularly limited, preferably 1~
90 weight %, more preferably 1~50 weight %.When content is less than 1 weight %, sometimes due to (A) ingredient is insufficient and is unable to fully
Carry out cross-linking reaction, cause to cure it is bad, when more than 90 weight %, sometimes due to (B) ingredient deficiency and be unable to fully be handed over
Connection reaction, causes to cure bad.
<(B) amino resins>
(B) amino resins (hereinafter also referred to as (B) ingredient) the coating of the present invention use in resin combination as (A) at
The curing agent divided carries out mixture.The reason of as storage stability is improved by using (B) ingredient, it is believed that be because of (B)
The number-average molecular weight of ingredient is bigger, with the three-dimensional knot for reacting relevant amino and being present in (B) ingredient at normal temperatures of (A) ingredient
The inside of structure, therefore be less likely to occur to react with (A) ingredient.In addition, making its solidification as by (B) ingredient to improve heating
When rapid-drying properties the reason of, it is believed that be because amino originally and the reactivity of (A) ingredient is high, makes (B) ingredient by heating
Stereochemical structure changes, and carries out reacting with (A) ingredient immediately when amino appears in surface.
As (B) ingredient, as long as number-average molecular weight is 250~10,000, then there is no particular limitation as to it, can enumerate example
Such as include melmac, carbamide resin, the glyoxal resin of benzoguano amine resin.They can be used alone, and can also close
With two or more.Among them, from the viewpoint of applying film strength, adaptation, preferred melmac.Melamine tree
Fat refers to the condensation polymer of melamine or derivatives thereof and aldehyde compound, as the monomer for constituting melmac, can be made
Use such as melamine or derivatives thereof melamine methylol, benzoguanamine, can be used as aldehyde compound
Formaldehyde etc..Each monomer of these melamines or derivatives thereof and aldehyde compound can be used alone, can also share two kinds with
On.
(B) as long as the number-average molecular weight of ingredient is 250~10,000, then there is no particular limitation as to it, and preferably 500~2,
000, more preferably 700~1,300.When number-average molecular weight is less than 250, rapid-drying properties become inadequate sometimes, when more than 10,000,
Sometimes the compatibility with (A) ingredient becomes inadequate.
In the coating resin combination of the present invention, the content of (B) ingredient is not particularly limited, relative to (A)
100 parts by weight of ingredient, preferably 10~10,000 parts by weight, more preferably 10~500 parts by weight.(B) content of ingredient is less than
In the case of in the case of 10 parts by weight or more than 10,000 parts by weight, rapid-drying properties become inadequate sometimes.
Other than (A) ingredient and (B) ingredient, coating of the invention can not damage the present invention's with resin combination
Arbitrarily contain other ingredients in the range of purpose.It as other ingredients, is not particularly limited, it can be cited for example that solvent, solidification
Accelerating agent, antifoaming agent, levelling agent, organic thickening agent, antioxidant, light stabilizer, cementability enhancer, antitack agent, strengthening material
Material, softening agent, colorant, fire retardant, antistatic agent, Ricinate etc..
<Solvent>
It as solvent, is not particularly limited, can be properly used any solvent of water system or organic solvent system, can enumerate
Such as the aromatic hydrocarbon series solvents such as toluene, ethylbenzene, trimethylbenzene, dimethylbenzene；The aliphatic hydrocarbon system such as pentane, hexane, hexamethylene is molten
Agent；The ketone series solvents such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), cyclohexanone；Methanol, ethyl alcohol, isopropanol, ethylene glycol, diethyl
The alcohol series solvents such as glycol, triethylene glycol, propylene glycol；Methyl cellosolve, ethyl cellosolve, butyl cellosolve, diethylene glycol dimethyl ether,
The glycol ether series solvent such as diethylene glycol ether, butyl, propylene glycol monomethyl ether；Ethyl acetate, butyl acetate, propylene glycol
The ester series solvents such as monomethyl ether acetate；Water etc..In addition, as the commercially available product that can be used as aromatic hydrocarbon series solvent, Ke Yiju
Go out Solvesso100, Solvesso150, Solvesso200 etc..They can be used alone or in combination with two or more.
In the case that the coating resin combination of the present invention contains solvent, the content of solvent is according to coating method, institute's phase
The film thickness of the cured coating film of prestige is selected, and there is no particular limitation as to it, relative to 100 parts by weight of (A) ingredient, preferably
10~5000 parts by weight, more preferably 20~2000 parts by weight.Content be less than 10 parts by weight when, sometimes viscosity get higher, Wu Fajun
It is coated with evenly, when more than 5000 parts by weight, is unable to get the film of abundant film thickness sometimes, in addition to this, cut from economy, VOC
From the perspective of subtracting, also not preferably.
<Curing accelerator>
It as curing accelerator, is not particularly limited, it can be cited for example that formic acid, acetic acid, lactic acid, glycolic, butyric acid, different
The aliphatic carboxylic acids class such as butyric acid, propionic acid, caproic acid, octanoic acid, enanthic acid, monoxone, dichloroacetic acid, trichloroacetic acid and thioacetic acid；Apple
The polybasic carboxylic acids class such as tartaric acid, oxalic acid, succinic acid, malonic acid, fumaric acid, maleic acid, tartaric acid and citric acid；Benzoic acid, to first
The benzoic acid derivatives such as yl benzoic acid, p-aminobenzoic acid, parachlorobenzoic-acid, 2,4 dichloro benzene formic acid；Phthalic acid, isophthalic
The aromatic carboxylic acids such as the phthalic acid derivatives such as dioctyl phthalate and terephthalic acid (TPA) and salicylic acid；Phenol, metacresol, to chlorobenzene
The phenols such as phenol, p-nitrophenol, 2,4 dichloro phenol, o-aminophenol, para-aminophenol and 2,4,5- trichlorophenol, 2,4,6,-Ts；Isophthalic two
The Polyphenols such as phenol, quinhydrones, catechol and phloroglucin；The phenol resin class such as novolaks；Methanol, ethyl alcohol, propyl alcohol, isopropanol,
The aliphatic alcohols such as butanol, isobutanol, tert-butyl alcohol；The glycols such as ethylene glycol, propylene glycol, polyethylene glycol, polypropylene glycol；Glycerine,
The glycerols such as polyglycereol；Sulphonic acids such as toluenesulfonic acid, methanesulfonic acid etc..They can be used alone or in combination with two or more.
In the case that the coating resin combination of the present invention contains curing accelerator, do not have for the content of curing accelerator
It is particularly limited to, relative to 100 parts by weight of (A) ingredient, preferably 0.01~2000 parts by weight, more preferably 0.1~2000 weight
Measure part.When content is less than 0.01 parts by weight, it is unable to get the effect of addition curing accelerator sometimes, when more than 2000 parts by weight,
Sometimes appearance of film is impaired, sometimes also not preferred from the viewpoint of economy.
<<Component>>
The present invention component be characterized in that, with resin base material and use the present invention coating resin combination
The film being formed on resin base material.
<Resin base material>
The material of resin base material is not particularly limited, polyethylene terephthalate, poly- naphthalene diformazan can be enumerated
The polyester such as sour glycol ester；The polyolefin such as polyethylene, polypropylene, polymethylpentene；The polyamide such as nylon 6, nylon66 fiber；Poly- carbonic acid
Ester, polyvinyl acetate, polyimides, ABS resin etc..It is excellent from the viewpoint of economy, ease of processing among them
Select polyester.
The thickness of resin base material is not particularly limited, film, sheet material, plate, laminate etc. can be used to add by molding
The product for being shaped to various molded products manufactured by work etc. is as resin base material.
<Film>
Film is formed on resin base material using the coating resin combination of the present invention.As use the present invention
The method that coating resin combination forms film on resin base material, is not particularly limited, and can enumerate in resin base material
After the coating resin combination of at least one face coating present invention, carrying out heating makes its cured method etc..It is right later
It is coated with the method for the coating resin combination of the present invention and carrying out heating makes its cured method be described.
The thickness of film is not particularly limited, preferably 0.1~30 μm, more preferably 0.3~20 μm.Thickness is less than
At 0.1 μm, the flatness of film becomes inadequate sometimes, when more than 30 μm, sometimes due to the increase of internal stress and make closely sealed
Property becomes inadequate.
<<The manufacturing method of component>>
The manufacturing method of the component of the present invention is the method for component for manufacturing the present invention, which is characterized in that this method
Including：
Process (1)：The coating of the present invention is coated on at least one face of resin base material with resin combination；With
Process (2)：The coating resin combination that will be coated in process (1) heats 5~300 seconds at 60~250 DEG C
And make its solidification.
<Process (1)>
In this process, the coating of the present invention is coated on at least one face of resin base material with resin combination.As
The method for being coated with the coating resin combination of the present invention, is not particularly limited, it can be cited for example that stick coating method, spin-coating method, spray
Coating, dip coating, nozzle rubbing method, gravure coating method, reverse roll coating method, die coating method, air doctor blade method, scraper plate rubbing method,
Bar coating, curtain coating method, scraper for coating method, transfer rolling method, extrusion coated method, infiltration rubbing method, kiss-coating method, calendering coating
Method, extrusion coating methods etc..
<Process (2)>
In this process, the coating being coated in process (1) is heated with resin combination and makes its solidification.
In process (2), heating temperature is not particularly limited, preferably 60~250 DEG C, more preferably 60~150
℃.Heating temperature be less than 60 DEG C when, occasionally result in solidification it is bad, when more than 250 DEG C, the shape of base material is because of resin base material sometimes
Material and be damaged.In addition, as long as heating time is 5~300 seconds, then there is no particular limitation as to it, preferably 20~120 seconds.Add
The hot time be less than 5 seconds when, occasionally result in solidification it is bad, when more than 300 seconds, the shape of base material is due to the material of resin base material sometimes
It is impaired, and the time needed for process is elongated, therefore from the viewpoint of productivity, also not preferably.
Embodiment
Hereinafter, enumerating, examples illustrate the present invention, but the present invention is not limited to embodiments below.Hereinafter, for
" part " or " % " then refers respectively to " parts by weight " or " weight % " as long as no special declaration.
(synthesis example 1)
D-sorbite 50g is dispersed in toluene 20g, butter of tin 0.18g is added, exists while stirring 95 DEG C or more
2 hours used times added epichlorohydrin 62g within the scope of 100 DEG C or less of temperature, made its reaction.Utilize the drop recorded in JIS K 7236
Determine the disappearance that method confirms epichlorohydrin, the toluene used as solvent is removed using reduced pressure.Obtained concentrate is dissolved
In water 100g, aqueous solution (total solid content concentration 52.5%) of the D-sorbite polychlorostyrene for alcoholic compound is obtained.
(using material)
In following embodiments and comparative example, material below is used.
(A) multifunctional reactive compounds
D-sorbite polyglycidyl ether (manufacture of Nagase chemtex Co., Ltd., Denacol EX-614B, epoxy
Equivalent：173, the quantity of the epoxy group of each molecule：3~4)
Bisphenol A diglycidyl ether (Mitsubishi chemical Co., Ltd's manufacture, 828, epoxide equivalent：188, each molecule
The quantity of epoxy group：2)
The poly- chlorhydrin of D-sorbite (synthesis example 1, each molecule halogenated alcohol radical quantity：2~4)
(B) amino resins
Melmac (Dainippon Ink Chemicals's manufacture, SUPER BECKAMIN L-145-60, number-average molecular weight：1073、
Solid component concentration：55%)
Amine compounds
Trien (Tokyo Chemical Industry Co., Ltd's manufacture, molecular weight：146)
Curing accelerator
Toluenesulfonic acid
Solvent
Toluene (Wako Pure Chemical Industries, Ltd.'s manufacture)
Resin base material
Polyester (PET) film (Dongli Ltd.'s manufacture, Lumiror, 50 μm of film thickness)
(Examples 1 to 3, comparative example 1~4)
Each ingredient is mixed with weight ratio shown in following table 1, obtains coating resin combination.Use obtained coating
With resin combination, the evaluation of storage stability is carried out using aftermentioned method.In addition, will be acquired using bar coater (No.2)
Coating be coated on resin base material with resin combination, using air drier, heated 60 seconds at 130 DEG C, thus make it solid
Change and form film, obtains component.Using the component for being cooled to room temperature as test film, rapid-curing cutback is carried out using aftermentioned method
The evaluation of property, adaptation and chemical-resistant.These results are shown in table 1.
(evaluation method)
Storage stability
Coating is stood with resin combination under the conditions of 23 DEG C, confirms the time until muddiness occurs.Confirm most
It is long to carry out to 12 hours.
Rapid-drying properties
With finger contact just make after test film film, confirmation have it is inviscid, based on following benchmark with two etc.
Grade is evaluated.
○：It is inviscid
×：Toughness
Adaptation
The film that the test film after just making is wiped 10 times with finger confirms whether there is or not the stripping of film, is based on following bases
Standard is evaluated with two grades.
○：Without stripping
×：There is stripping
Chemical-resistant
Chemical-resistant experiment is carried out using the test film after rigid make.Specifically, using Friction tester, will soak
There is the gauze of methyl ethyl ketone to press on the film coated surface of test film under conditions of load 300g, in this state reciprocal 30
It is secondary, friction test is carried out, confirms that whether there is or not the strippings of film, are evaluated based on following benchmark with two grades.
○：Without stripping
×：There is stripping
Even if the coating resin combination of the present invention is under low temperature, the drying condition of short time as 130 DEG C, 60 seconds
Also it can fully dry, the adaptation of film, chemical-resistant are also good.On the other hand, in the comparison as the prior art
In example 1~4, it is unable to fully drying under low temperature, the drying condition of short time, as a result, adaptation, chemical-resistant
It is insufficient.
Claims (7)
1. a kind of coating resin combination is the composition for being coated on resin base material, which is characterized in that the composition
Contain：
(A) the multifunctional reactive compounds with 2~15 epoxy groups and/or halogenated alcohol radical in a molecule；With
(B) amino resins that number-average molecular weight is 250~10,000.
2. coating resin combination as described in claim 1, wherein
(B) amino resins is melmac.
3. coating resin combination as claimed in claim 1 or 2, wherein
Relative to 100 parts by weight of (A) ingredient, the content of (B) ingredient is 10 parts by weight~10,000 parts by weight.
4. coating resin combination according to any one of claims 1 to 3, wherein
(A) multifunctional reactive compounds have 2~10 epoxy groups and/or halogenated alcohol radical in a molecule.
5. a kind of component, which is characterized in that it is with the coating described in any one of resin base material and use Claims 1 to 44
The film being formed in resin combination on resin base material.
6. component as claimed in claim 5, wherein
The material of resin base material is polyester.
7. a kind of manufacturing method of component is the method for the component described in manufacturing claims 5 or 6, which is characterized in that
This method includes：
Process (1)：Coating according to any one of claims 1 to 4 is coated on resin base material at least with resin combination
One face；With
Process (2)：The coating resin combination that will be coated in process (1) heats 5 seconds~300 seconds at 60 DEG C~250 DEG C
And make its solidification.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016055473 | 2016-03-18 | ||
| JP2016-055473 | 2016-03-18 | ||
| PCT/JP2017/010395 WO2017159732A1 (en) | 2016-03-18 | 2017-03-15 | Coating resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108603071A true CN108603071A (en) | 2018-09-28 |
Family
ID=59851580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780010374.3A Pending CN108603071A (en) | 2016-03-18 | 2017-03-15 | Coating resin combination |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6874236B2 (en) |
| CN (1) | CN108603071A (en) |
| WO (1) | WO2017159732A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113004242A (en) * | 2021-03-01 | 2021-06-22 | 中国林业科学研究院林产化学工业研究所 | Sorbitol-based aqueous cyclic carbonate, and preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102476929B1 (en) * | 2020-11-30 | 2022-12-14 | 주식회사 제일화성 | Biomass-based epoxy resin composition with excellent yellowing resistance |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60163937A (en) * | 1984-02-07 | 1985-08-26 | Dainippon Ink & Chem Inc | Resin composition for coating plastic |
| JP2000063739A (en) * | 1998-08-17 | 2000-02-29 | Kansai Paint Co Ltd | Coating composition and coated metallic plate using the same |
| JP2001026749A (en) * | 1999-03-03 | 2001-01-30 | Kansai Paint Co Ltd | Overcoating composition and laminated film for adhesion |
| JP2001271026A (en) * | 2000-03-28 | 2001-10-02 | Kawakami Paint Mfg Co Ltd | Coating resin composition |
| JP4365007B2 (en) * | 2000-06-20 | 2009-11-18 | 関西ペイント株式会社 | Overcoat composition for laminated film of packaging material |
| JP2003206362A (en) * | 2002-01-11 | 2003-07-22 | Toyo Ink Mfg Co Ltd | Resin composition for overcoat for plastic film and its use |
| JP3938020B2 (en) * | 2002-11-25 | 2007-06-27 | 東洋インキ製造株式会社 | Exterior coating composition for drawn cans excellent in high-speed paintability and use of the composition |
| JP5645462B2 (en) * | 2010-04-28 | 2014-12-24 | 三菱樹脂株式会社 | Laminated polyester film |
| KR20120068624A (en) * | 2010-12-17 | 2012-06-27 | 아크조노벨코팅스인터내셔널비.브이. | Organic-inorganic hybrid paint composition |
| JP2012162636A (en) * | 2011-02-07 | 2012-08-30 | Kansai Paint Co Ltd | Water dispersion, and aqueous coating composition |
| JPWO2013077307A1 (en) * | 2011-11-22 | 2015-04-27 | 日本ペイントホールディングス株式会社 | Hard coating composition |
| JP6255626B2 (en) * | 2014-03-18 | 2018-01-10 | Dic株式会社 | Coating composition and article coated with the coating composition |
-
2017
- 2017-03-15 JP JP2018505977A patent/JP6874236B2/en active Active
- 2017-03-15 WO PCT/JP2017/010395 patent/WO2017159732A1/en active Application Filing
- 2017-03-15 CN CN201780010374.3A patent/CN108603071A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113004242A (en) * | 2021-03-01 | 2021-06-22 | 中国林业科学研究院林产化学工业研究所 | Sorbitol-based aqueous cyclic carbonate, and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6874236B2 (en) | 2021-05-19 |
| JPWO2017159732A1 (en) | 2019-01-24 |
| WO2017159732A1 (en) | 2017-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2637715A (en) | Epoxy resin-polycarboxylic acid-dicyandiamide reaction products | |
| KR101579363B1 (en) | Coating compositions with improved adhesion to containers | |
| KR101779271B1 (en) | Coating compositions for food and beverage containers | |
| CN106832224A (en) | The hardener composition of epoxy resin | |
| CN100379831C (en) | Polymerization of a reactive diluent in the presence of an epoxy-amine material, and coating compositions prepared thereby | |
| CN103403110A (en) | Cargo tank coating | |
| CN108603071A (en) | Coating resin combination | |
| CA1076280A (en) | Process for preparing water-dilutable, heat-curing coating compositions | |
| DE60128118T2 (en) | POLYPHENOL RESIN, METHOD FOR THE PRODUCTION THEREOF, EPOXY RESIN COMPOSITION AND ITS USE | |
| KR100559055B1 (en) | Cardanol-modified epoxy resin composition | |
| RU2686919C1 (en) | Epoxide adhesive binder, film adhesive and adhesive prepreg on its basis | |
| CN102971356A (en) | Phosphazene blocked azole compounds as latent catalysts for epoxy resins | |
| JP4500990B2 (en) | Binder and method of using it as coating material for metal containers | |
| JP6217064B2 (en) | Resin composition and resin molded body | |
| CN110484117A (en) | Blade coating type aqueous double-component gage mark coating and preparation method thereof | |
| CN103865365B (en) | coating system | |
| US20050176884A1 (en) | Water soluble thermosetting polyester resin composition and method of preparing the same | |
| EP2999757B1 (en) | Coating composition | |
| EP0387454B1 (en) | Coating processes and curable compositions | |
| TWI509034B (en) | Biomass epoxy resin paint and method of preparing a biomass epoxy coating | |
| CN105793368A (en) | Aqueous-based coating composition containing hydroxy-terminated polybutadiene | |
| US20160160099A1 (en) | Adhesive for hydrophobic or water-repellent substrate and manufacturing method thereof | |
| US9605190B2 (en) | Adhesive for hydrophobic or water-repellent substrate and manufacturing method thereof | |
| KR101111526B1 (en) | Two component epoxy under coating paint and method of forming the same | |
| JP2017082077A (en) | Halohydrin compound and resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180928 |