CN108598164A - GaN-based enhanced power electronic device and manufacturing method thereof - Google Patents
GaN-based enhanced power electronic device and manufacturing method thereof Download PDFInfo
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- CN108598164A CN108598164A CN201810471447.5A CN201810471447A CN108598164A CN 108598164 A CN108598164 A CN 108598164A CN 201810471447 A CN201810471447 A CN 201810471447A CN 108598164 A CN108598164 A CN 108598164A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 230000004888 barrier function Effects 0.000 claims abstract description 62
- 238000002161 passivation Methods 0.000 claims abstract description 16
- 229910002704 AlGaN Inorganic materials 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 6
- 229910052733 gallium Inorganic materials 0.000 claims description 23
- 229910052738 indium Inorganic materials 0.000 claims description 23
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 5
- 229910004205 SiNX Inorganic materials 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 238000004518 low pressure chemical vapour deposition Methods 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000000231 atomic layer deposition Methods 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 230000012010 growth Effects 0.000 claims description 3
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 claims description 3
- 238000001451 molecular beam epitaxy Methods 0.000 claims description 3
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 75
- 239000000463 material Substances 0.000 description 6
- 229910002058 ternary alloy Inorganic materials 0.000 description 6
- 238000005036 potential barrier Methods 0.000 description 5
- 230000005533 two-dimensional electron gas Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229910002059 quaternary alloy Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
- H01L29/7782—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET
- H01L29/7783—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/20—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
- H01L29/201—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys
- H01L29/205—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds including two or more compounds, e.g. alloys in different semiconductor regions, e.g. heterojunctions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66446—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET]
- H01L29/66462—Unipolar field-effect transistors with an active layer made of a group 13/15 material, e.g. group 13/15 velocity modulation transistor [VMT], group 13/15 negative resistance FET [NERFET] with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Ceramic Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Junction Field-Effect Transistors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
A GaN-based enhancement type power electronic device and a manufacturing method thereof are provided, the electronic device comprises a substrate, a GaN epitaxial layer, a back barrier layer, a GaN channel layer and a barrier layer from bottom to top in sequence, a source electrode, a grid electrode and a drain electrode are formed on the barrier layer, and a passivation layer is deposited on the barrier layer among the source electrode, the grid electrode and the drain electrode; wherein the back barrier layer and barrier layer are independently selected from AlGaN, AlInN, or AlInGaN. The invention can obviously improve the threshold voltage of the GaN-based enhanced device and improve the yield and the threshold uniformity of the large-size enhanced GaN-based power electronic device.
Description
Technical field
The invention belongs to technical field of semiconductors, and in particular to a kind of GaN base enhanced power electronic device and its making
Method.
Background technology
Enhanced is the core requirement of power electronic device trouble free service.There are mainly four types of technologies to realize in the world at present
AlGaN/GaN base enhancement devices:1) the groove etched thinned AlGaN potential barrier of grid;2) it is injected in AlGaN potential barrier electronegative
Fluorine ion;3) P- (Al) GaN cap layers are grown in potential barrier layer surface;4) InGaN or thickness GaN contrapolarizations are grown in potential barrier layer surface
Layer.By the above technology although can realize enhanced, the threshold value of device is confined to+3V or less.In order to break through GaN base power electricity
The threshold value bottleneck of sub- device expands its application in high-voltage power electronic field, there is an urgent need for by design novel enhancement type material and
The threshold value of GaN base enhancement device is increased to+3V or more by device architecture.
Invention content
In order to solve the problems in the existing technology, the present invention proposes a kind of GaN base enhanced power electronic device
And production method, the threshold voltage for improving GaN base enhancement device.
In order to achieve the above object, on the one hand, the present invention proposes a kind of GaN base enhanced power electronic device, under
Include substrate, GaN epitaxial layer, back of the body barrier layer, GaN channel layers and barrier layer successively on and, formed on the barrier layer source,
Grid and drain electrode, deposition has passivation layer on the barrier layer between the source electrode, grid and drain electrode;
The wherein described back of the body barrier layer and barrier layer are independently selected from AlGaN, AlInN or AlInGaN.
Preferably, the back of the body barrier layer is AlGaN or AlInN, and wherein Al components are fixed, and the content of Al components is situated between
Between 0-100mol.%.
Preferably, the back of the body barrier layer is AlGaN or AlInN, and wherein Al components are gradually reduced or gradually from bottom to top
Increase, reduced from y mol.% or be increased to x mol.%, wherein x, y is between 0-100.
Preferably, the back of the body barrier layer is AlInGaN, and Al, In and Ga components are fixed with thickness, or are gradually increased
Or reduce.
Preferably, the thickness of the back of the body barrier layer is 1-1000nm.
Preferably, the thickness of the barrier layer is 0-10nm.
Preferably, the passivation layer is selected from AlN, SiO2Or SiNx.
Preferably, gate dielectric layer or no gate dielectric layer are formed between the grid and the barrier layer.On the other hand,
The present invention proposes a kind of production method of GaN base enhanced power electronic device, including:
In the GaN epitaxial layer growth back of the body barrier layer of substrate;
The GaN channel layers of high-crystal quality are grown on the back of the body barrier layer;
Barrier layer is grown on the GaN channel layers;
Passivation layer is formed on the barrier layer;
The passivation layer is etched, source electrode, grid and drain electrode are then made;
Passivation layer is formed on the barrier layer between the source electrode, grid and drain electrode.
Preferably, the back of the body barrier layer uses MOCVD, MBE or HVPE methods to prepare.
Preferably, the passivation layer is prepared by MOCVD, LPCVD, PECVD or ALD.
Preferably, the production method further includes the steps that rectangular at gate dielectric layer under the gate.
Compared with prior art, using the invention has the advantages that:
1, the present invention raises the conduction bands of GaN channel layers using the reversed polarization effect of Al (In, Ga) N back of the body barrier layers, with into one
Step exhausts the two-dimensional electron gas in Al (In, Ga) N/GaN hetero-junctions raceway grooves, to significantly improve the threshold of GaN base enhancement device
Threshold voltage;
2, the present invention realizes the enhanced grid structure of no etching using thin potential barrier Al (In, Ga) N/GaN heterojunction structures, carries
The high yield and threshold value uniformity of the enhanced GaN base power electronic device of large scale, has pushed GaN base power electronic device
Application process.
Description of the drawings
Fig. 1 is the GaN base enhanced power electronic device structure schematic diagram of one embodiment of the invention;
Fig. 2 is the GaN base enhanced power electronic device structure schematic diagram of another embodiment of the present invention.
Specific implementation mode
To make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, and reference
Attached drawing, the present invention is described in further detail.
The invention discloses a kind of GaN base enhanced power electronic device structures for carrying on the back barrier structure with Al (In, Ga) N
And production method.Production method therein includes:A thin layer Al (In, Ga) N Back are first grown in thicker GaN epitaxial layer
Barrier (back of the body barrier layer), and then grows a floor height crystal quality GaN layer, finally grows the ultra-thin barrier layers of Al (In, Ga) N,
To form enhanced Al (In, Ga) N/GaN heterogeneous structure materials, source electrode, gate medium, grid are finally prepared on the material structure
Pole and drain electrode and passivation layer form transistor arrangement.
Al (In, Ga) N back of the body barrier layer is to use MOCVD, prepared by MBE or HVPE methods, thickness between 1nm extremely
1000nm。
It can be AlGaN or AlInN ternary alloy layers or AlInGaN quaternary alloys that Al (In, Ga) N, which carries on the back barrier layer,.
Al (In, Ga) is if N carries on the back barrier layer AlGaN ternary alloy layers, and Al components are between 0 and 100%.
Al (In, Ga) is if N carries on the back barrier layer AlGaN ternary alloy layers, and Al components can be fixed, between 0 He
Some numerical value between 100%;It can also be gradually to successively decrease or increase from bottom to up, reduced from y% or be increased to x%, wherein
X, y are between 0 and 100.
Al (In, Ga) is if N carries on the back barrier layer AlInN ternary alloy layers, and Al components are between 0% and 100%.
Al (In, Ga) is if N carries on the back barrier layer AlInN ternary alloy layers, and Al components can be fixed, between 0 He
Some numerical value between 100%;It can also be gradually to successively decrease or increase from bottom to up, reduced from y% or be increased to x%, wherein
X, y are between 0 and 100.
Al (In, Ga) if N carry on the back barrier layer AlInGaN quaternary alloy layers, Al, In, Ga components between 0 and 100% it
Between, they can be fixed with thickness, can also gradually change, and can gradually increase, can also be to be gradually reduced.
Al (In, Ga) N barrier layers can be AlGaN or AlInN in barrier layer Al (In, Ga) the N/GaN heterojunction structures
Ternary alloy layer or AlInGaN quaternary alloys, thickness is between 0nm to 10nm.
The passivation layer uses AlN, SiO2Or SiNxMaterial preparation, can by MOCVD, LPCVD, PECVD or
Prepared by ALD growths, the passivation layer can go out highdensity positive charge in Al (In, Ga) N barrier layer spatial inductions, significantly improve Al
In (In, Ga) N barrier layers/GaN hetero-junctions raceway grooves two-dimensional electron gas (i.e. between grid and source electrode, grid and drain electrode
Between two-dimensional electron gas), to effectively reduce device conducting resistance.
The present invention raises the conduction band of GaN channel layers by the reversed polarization effect of Al (In, Ga) N back of the body barrier layers, with further
The two-dimensional electron gas in Al (In, Ga) N back of the body barrier layer/GaN hetero-junctions raceway grooves is exhausted, to significantly improve the enhanced device of GaN base
The threshold voltage of part has pushed applications of the GaN in high threshold, high-power electric and electronic system.
In one embodiment of the invention, a thin layer is first grown using MOCVD in the thicker GaN epitaxial layer 2 of substrate 1
AlInN carries on the back barrier layer 3, and thickness 100nm grows a floor height crystal quality GaN channel layers 4, most on AlInN back of the body barrier layers 3
The ultra-thin barrier layers 5 of AlGaN are grown afterwards, and thickness 5nm first passes through to form enhanced AlGaN/GaN heterogeneous structure materials
LPCVD forms SiNxThen passivation layer 9 prepares source electrode 6, grid 7 and drain electrode 8 on the material structure, forms transistor arrangement,
As shown in Figure 1, in figure 10 be two-dimensional electron gas.
In another embodiment, gate dielectric layer 11 is also formed between grid and barrier layer, as shown in Figure 2.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical solution and advantageous effect
Describe in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the protection of the present invention
Within the scope of.
Claims (10)
1. a kind of GaN base enhanced power electronic device, which is characterized in that from bottom to top successively include substrate, GaN epitaxial layer,
Carry on the back barrier layer, GaN channel layers and barrier layer, form source, grid and drain electrode on the barrier layer, the source electrode, grid and
Deposition has passivation layer on the barrier layer between drain electrode;
The wherein described back of the body barrier layer and barrier layer are independently selected from AlGaN, AlInN or AlInGaN.
2. GaN base enhanced power electronic device according to claim 1, wherein the back of the body barrier layer be AlGaN or
AlInN, wherein Al components are fixed, and the content of Al components is between 0-100mol.%, alternatively, Al components are from bottom to top
It is gradually reduced or gradually increases, reduced from y mol.% or be increased to x mol.%, wherein x, y is between 0-100.
3. GaN base enhanced power electronic device according to claim 1, wherein the back of the body barrier layer is AIInGaN,
Al, In and Ga component are fixed with thickness, or gradually increase or reduce.
4. GaN base enhanced power electronic device according to claim 1, wherein the thickness of the back of the body barrier layer is 1-
1000nm, it is preferable that the thickness of the barrier layer is 0-10nm.
5. GaN base enhanced power electronic device according to claim 1, wherein the passivation layer is selected from AlN, SiO2Or
SiNx。
6. GaN base enhanced power electronic device according to claim 1, wherein the grid and the barrier layer it
Between be formed with gate dielectric layer or no gate dielectric layer.
7. a kind of production method of any one of claim 1-6 GaN base enhanced power electronic devices, including:
In the GaN epitaxial layer growth back of the body barrier layer of substrate;
The GaN channel layers of high-crystal quality are grown on the back of the body barrier layer;
Barrier layer is grown on the GaN channel layers;
Passivation layer is formed on the barrier layer;
The passivation layer is etched, source electrode, grid and drain electrode are then made.
8. production method according to claim 7, wherein the back of the body barrier layer uses MOCVD, MBE or HVPE method systems
It is standby.
9. production method according to claim 7, wherein the passivation layer passes through MOCVD, LPCVD, PECVD or ALD
It prepares.
10. production method according to claim 7, wherein the production method further includes rectangular at grid under the gate
The step of dielectric layer.
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JP2005086102A (en) * | 2003-09-10 | 2005-03-31 | Univ Nagoya | Field effect transistor and method of manufacturing field effect transistor |
US20080203430A1 (en) * | 2007-02-23 | 2008-08-28 | Grigory Simin | Enhancement mode insulated gate heterostructure field-effect transistor |
CN101916773A (en) * | 2010-07-23 | 2010-12-15 | 中国科学院上海技术物理研究所 | Double-channel MOS-HEMT (Metal Oxide Semiconductor-High Electron Mobility Transistor) device and manufacturing method |
-
2018
- 2018-05-17 CN CN201810471447.5A patent/CN108598164A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1599960A (en) * | 2001-12-03 | 2005-03-23 | 克里公司 | Strain balanced nitride heterojunction transistors and methods of fabricating strain balanced nitride heterojunction transistors |
JP2005086102A (en) * | 2003-09-10 | 2005-03-31 | Univ Nagoya | Field effect transistor and method of manufacturing field effect transistor |
US20080203430A1 (en) * | 2007-02-23 | 2008-08-28 | Grigory Simin | Enhancement mode insulated gate heterostructure field-effect transistor |
CN101916773A (en) * | 2010-07-23 | 2010-12-15 | 中国科学院上海技术物理研究所 | Double-channel MOS-HEMT (Metal Oxide Semiconductor-High Electron Mobility Transistor) device and manufacturing method |
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