CN108590819A - Effectively remove the catalyst converter of vehicle launch stage tail gas pollution - Google Patents

Effectively remove the catalyst converter of vehicle launch stage tail gas pollution Download PDF

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Publication number
CN108590819A
CN108590819A CN201810560309.4A CN201810560309A CN108590819A CN 108590819 A CN108590819 A CN 108590819A CN 201810560309 A CN201810560309 A CN 201810560309A CN 108590819 A CN108590819 A CN 108590819A
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CN
China
Prior art keywords
catalyst
vehicle
tail gas
electric heating
vehicle launch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810560309.4A
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Chinese (zh)
Inventor
李言钦
关雪丰
李自凡
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Zhengzhou University
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Zhengzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhengzhou University filed Critical Zhengzhou University
Priority to CN201810560309.4A priority Critical patent/CN108590819A/en
Publication of CN108590819A publication Critical patent/CN108590819A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • F01N3/2013Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/101Three-way catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/40Engine management systems

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

Traditional vehicle catalyst converter is within a period of time of vehicle launch, and since catalyst is not yet by flue gas to active temperature, the flue gas in the stage cannot be cleaned processing, and the hazardous contaminants such as a large amount of NOx and hydrocarbon HC are discharged.The invention discloses a kind of Vehicular exhaust catalytic cleaner, including catalytic unit that can utmostly eliminate vehicle launch stage exhaust emissions itself and catalyst preheating systems.The carrier of the catalytic unit coats electro-thermal coatings first, and the electro-thermal coatings are coated with catalyst coat outside using the excellent electric heating materials such as carbon fiber, the electrothermal layer.Before internal combustion engine start the catalyst coat of the appearance is heated rapidly to its active temperature range in advance using electrothermal layer by being remotely controlled induction, allow to start vehicle internal combustion engine again, and stop heating of the exterior source of energy to catalyst, thus the combustion tail gas in the stage is able to effectively be catalyzed reaction, to remove the pollutants such as NOx therein.

Description

Effectively remove the catalyst converter of vehicle launch stage tail gas pollution
Technical field
The present invention relates to a kind of tail gas disposal technique fields effectively removing vehicle launch stage tail gas pollution, especially relate to And one kind can pre-warmed Vehicular exhaust catalytic cleaner, it is the various vehicles of power and mechanical dress to be suitable for use internal combustion engine It sets.
Background technology
Catalytic cleaner refers to that the pernicious gases such as NOx, CO that Vehicular exhaust is discharged and hydrocarbon HC are passed through oxidation It is changed into the catalytic unit of harmless nitrogen gas and water and carbon dioxide with reduction.Three-way catalyst is minimum Celsius 250 It reacts when spending, when temperature is too low, transfer efficiency drastically declines, and the active best operating temperature of catalyst is 400 DEG C to 800 DEG C or so.Conventional catalyst clarifier is generally seated in from about 1.2 m of engine export at present, is started in engine In preceding 200 s of work, the bed temperature of catalyst is below 250 DEG C, the initiation temperature without reaching catalyst, therefore nothing Method plays catharsis to the pollutant discharged during cold start, especially in north cold area.The vehicle launch stage due to Internal combustion engine is needed to provide the combustion power more much bigger than the normally travel stage to obtain corresponding acceleration, the burning of fuel is less filled Point, so the pollutant of its discharge is more, toxicity bigger.
Invention content
The purpose of the present invention is that solve the above-mentioned problems and provides one kind and effectively removing vehicle launch stage tail gas The catalyst converter of pollution.
The present invention is achieved through the following technical solutions above-mentioned purpose.
A kind of Vehicular exhaust catalytic cleaner effectively removing vehicle launch stage tail gas pollution, the design of catalyst converter carrier For honeycomb, pore surface is catalyst layer, and electric heating layer is added between catalyst layer and carrier, uses carbon fiber Etc. excellent thermo electric material;Meanwhile as the honeycomb structure carrier of carrier be poor conductive insulating materials.The electricity of entire catalyst converter Heating layer is connected, and is connected to vehicle-mounted electric-heating source by unified interface, controls its break-make by central processing unit, sees principle Schematic diagram.Wherein specific honeycomb skeleton structure and can be with the general industrial design that is coupled as of electric heating layer and catalyst layer It realizes, the engineers and technicians that usually obtain employment are understood that and complete, and scheme is such as according to current industrial coating technology, Ke Yi Suitably increase its honeycomb porosity on the basis of existing catalyst converter carrier framework, first covers electric heating coating on basic skeleton, then The catalyst layer on electrothermal layer;Can also be newly added in the tail portion of former catalyst converter such a has intermediate electrical heating interlayer Netted catalyst converter can be used multilayer and be combined together.Conceptual design forms different in this way does not affect the protection model of the present invention It encloses.
Before the internal combustion engine start of vehicle, the remote control of carrying is first turned on the switch energization by vehicle driver, works as entrance After the active induction range of vehicle remote control inductor, remote control inductor sends instruction by corresponding central processing unit, makes catalysis Device electric heating layer electrified regulation catalyst layer is catalyzed by being embedded in the temperature sensor measurement of the catalyst layer heating process The temperature change of oxidant layer, when its temperature is more than catalyst activity temperature certain value, such as up to 300 DEG C or more, catalyst has enough Catalytic activity, then allowed by central processing unit to start vehicle internal combustion engine, cut off external heat source to electric heating simultaneously after internal combustion engine start The heating of layer.In this way, the pollutions such as NOx, CO and hydrocarbon HC in the startup stage of vehicle can just make combustion product gases Object reacts removing in time.And traditional vehicle catalytic cleaner as previously mentioned, starting stage after vehicle internal combustion engine startup by Active temperature has not yet been reached in catalyst and makes in a large amount of toxic pollutants discharge environment in flue gas.The catalyst of the present invention Traditional three-way catalyst can be used, using different catalysts, control the temperature for cutting off heating in the central processing unit of electric heating layer It spends depending on active temperature range of the limit value by used catalyst.
The connection encapsulation of the wherein elements such as central processing unit, remote signal inductor, catalyst layer temperature sensor is same The common operation for belonging to industrial design in related field is not difficult to realize, different designs is also for correlation engineering technical staff Do not influence protection scope of the present invention.
The beneficial effects of the present invention are:It can carry out catalyst warm-up in advance prior to the startup of vehicle internal combustion engine, it made to reach Restart internal combustion engine after to enough active temperatures, utmostly to reduce or eliminate a large amount of dirts of vehicle launch stage emission Dye, efficiently solves the associated disadvantages of current vehicle mounted tail gas catalytic cleaner, the catalyst converter excellent catalytic effect of respective design, structure Simply, high catalytic efficiency.
Description of the drawings
Fig. 1 is a kind of structural principle signal letter of catalyst converter effectively removing vehicle launch stage tail gas pollution of the present invention Figure.
Fig. 2 is setting for " sandwich " structure of the base material of honeycomb catalyst converter of the present invention, electric heating layer and catalyst layer Count schematic diagram.
Specific implementation mode
The invention will be further described below in conjunction with the accompanying drawings.
As shown in Figure 1, a kind of catalyst converter effectively removing vehicle launch stage tail gas pollution, including central processing unit, packet Flue gas honeycomb catalyst converter containing electric heating layer, the vehicle power supply for heating electro-thermal coatings, the temperature for measuring catalyst layer temperature Sensor(To prevent a sensor fault, it is arranged in different location two or more), induction for receiving remote signal Device etc..Matching remote control is carried in vehicle operator(Energized state)Into the induction range of aforementioned inductor, sense Answer device electric heating layer can be made to begin to warm up catalyst layer by central processing unit startup power supply.When catalyst layer temperature rises to Enough catalytic activity(The present invention is referred to as critical catalytic temperature)Afterwards, such as 300 DEG C, central processing unit, which sends out instruction, can start internal combustion Machine burns, while breaking heating of the power supply to electrothermal layer.Wherein internal combustion engine is lighted by vehicle console and catalyst converter centre Manage the series control of device, as long as and can only catalyst layer temperature can start higher than set critical catalytic temperature internal combustion engine.
In above structure, when preparing to start vehicle, first it is powered to the electric heating layer of catalyst converter by vehicle power supply, with heating External catalyst layer allows startup internal combustion engine when catalyst temperature is increased to enough active temperatures, then by central processing unit Burning, the flue gas that such internal combustion engine start stage generates, can be by institutes because catalyst is heated to activated state in advance Aforementioned pernicious gas is subjected to catalytic treatment in time when stating honeycomb catalyst converter and is converted into the gases such as harmless CO2, H2O, N2 To eliminate or effectively reduce the pollution of internal combustion engine start stage exhaust emissions.And current Vehicular exhaust catalyst converter is not because being catalyzed The preheating of agent, a large amount of above-mentioned toxic and harmful gas and soot particles caused by several minutes of internal combustion engine start stage cannot be by It decomposes removal and is discharged into air, cause the pollution that can not ignore.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe the originals of the present invention Reason, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes and improvements It both falls in the scope of protection of present invention.

Claims (5)

1. a kind of catalytic cleaner effectively removing vehicle launch stage tail gas pollution, it is characterised in that:In catalyst layer and Electric heating layer is set between its carrier, can before vehicle internal combustion engine works by catalyst layer rapidly pre-warming to its activation temperature, Catalyst is enable to decompose the pollutants such as internal combustion engine start stage NOx and hydrocarbon HC.
2. a kind of catalytic cleaner effectively removing vehicle launch stage tail gas pollution according to claim 1, special Sign is:Electric heating layer is using excellent thermo electric materials such as carbon fibers.
3. a kind of catalytic cleaner effectively removing vehicle launch stage tail gas pollution according to claim 1, special Sign is:The work of electric heating layer is controlled by a central processing unit, which is powered by on-vehicle battery;Central processing unit controls Energization and power-off of the vehicle power supply to electric heating layer.
4. a kind of catalytic cleaner effectively removing vehicle launch stage tail gas pollution according to claim 1, special Sign is:Temperature sensor is buried in catalyst layer, temperature parameter is reached into central processing unit, reaches it in catalyst layer temperature When abundant active temperature range, about 300 DEG C or more, central processing unit, which sends out instruction, to be allowed to start internal combustion engine, and cuts off outer heat The heating in source.
5. a kind of catalytic cleaner effectively removing vehicle launch stage tail gas pollution according to claim 1, special Sign is:In the range of the remote control of driver's carrying energized state enters vehicle certain distance, the remote control on vehicle Inductor can actively incude, and start electric heating layer heating catalyst layer by central processing unit;If catalyst is in above-mentioned work More than warm-natured angle value, even if remote control is powered and in the induction range of inductor, electric heating layer heating will not be started.
CN201810560309.4A 2018-06-03 2018-06-03 Effectively remove the catalyst converter of vehicle launch stage tail gas pollution Pending CN108590819A (en)

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Application Number Priority Date Filing Date Title
CN201810560309.4A CN108590819A (en) 2018-06-03 2018-06-03 Effectively remove the catalyst converter of vehicle launch stage tail gas pollution

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Application Number Priority Date Filing Date Title
CN201810560309.4A CN108590819A (en) 2018-06-03 2018-06-03 Effectively remove the catalyst converter of vehicle launch stage tail gas pollution

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110486125A (en) * 2019-08-20 2019-11-22 北京汽车集团越野车有限公司 A kind of fuel engines catalyst light-off control method and system
CN112412584A (en) * 2019-08-23 2021-02-26 上海汽车集团股份有限公司 Method for reducing engine emission, VCU, and control system and vehicle with VCU
CN112570035A (en) * 2020-12-14 2021-03-30 艾蓝腾新材料科技(上海)有限公司 Manufacturing method of alloy material as catalyst carrier and application of alloy material in automobile exhaust treatment
CN114776416A (en) * 2022-04-01 2022-07-22 浙江吉利控股集团有限公司 Internal combustion engine emission control system, control method, and vehicle

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2718228Y (en) * 2004-07-16 2005-08-17 上海比亚迪有限公司 Electric heatable vehicle tail gas catalytic purifier
CN205744068U (en) * 2016-05-07 2016-11-30 中国人民解放军装甲兵工程学院 A kind of heavy-duty vehicle device for purifying and treating tail gas
CN106762043A (en) * 2015-11-20 2017-05-31 排放方案先进技术股份有限公司 Emission control system with controlled sensing heating and the method using the system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2718228Y (en) * 2004-07-16 2005-08-17 上海比亚迪有限公司 Electric heatable vehicle tail gas catalytic purifier
CN106762043A (en) * 2015-11-20 2017-05-31 排放方案先进技术股份有限公司 Emission control system with controlled sensing heating and the method using the system
CN205744068U (en) * 2016-05-07 2016-11-30 中国人民解放军装甲兵工程学院 A kind of heavy-duty vehicle device for purifying and treating tail gas

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110486125A (en) * 2019-08-20 2019-11-22 北京汽车集团越野车有限公司 A kind of fuel engines catalyst light-off control method and system
CN110486125B (en) * 2019-08-20 2021-05-07 北京汽车集团越野车有限公司 Method and system for controlling ignition of fuel engine catalyst
CN112412584A (en) * 2019-08-23 2021-02-26 上海汽车集团股份有限公司 Method for reducing engine emission, VCU, and control system and vehicle with VCU
CN112412584B (en) * 2019-08-23 2022-03-25 上海汽车集团股份有限公司 Method for reducing engine emission, VCU, and control system and vehicle with VCU
CN112570035A (en) * 2020-12-14 2021-03-30 艾蓝腾新材料科技(上海)有限公司 Manufacturing method of alloy material as catalyst carrier and application of alloy material in automobile exhaust treatment
CN114776416A (en) * 2022-04-01 2022-07-22 浙江吉利控股集团有限公司 Internal combustion engine emission control system, control method, and vehicle
CN114776416B (en) * 2022-04-01 2023-12-05 浙江吉利控股集团有限公司 Internal combustion engine emission control system, control method, and vehicle

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Application publication date: 20180928

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