CN108587685A - A kind for the treatment of process of solid waste - Google Patents

A kind for the treatment of process of solid waste Download PDF

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Publication number
CN108587685A
CN108587685A CN201810315257.4A CN201810315257A CN108587685A CN 108587685 A CN108587685 A CN 108587685A CN 201810315257 A CN201810315257 A CN 201810315257A CN 108587685 A CN108587685 A CN 108587685A
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CN
China
Prior art keywords
solid waste
treatment
processing
cracking
gasification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810315257.4A
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Chinese (zh)
Inventor
章志明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huzhou Informed Technology Service Co Ltd
Original Assignee
Huzhou Informed Technology Service Co Ltd
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Filing date
Publication date
Application filed by Huzhou Informed Technology Service Co Ltd filed Critical Huzhou Informed Technology Service Co Ltd
Priority to CN201810315257.4A priority Critical patent/CN108587685A/en
Publication of CN108587685A publication Critical patent/CN108587685A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • C10J2300/0996Calcium-containing inorganic materials, e.g. lime

Abstract

The invention discloses a kind for the treatment of process of solid waste, include the following steps:(1)Pretreatment;(2)Pyrolytic gasification;(3)Cracking is reformed;(4)Post-processing.The present invention provides a kind for the treatment of process of solid waste, and the organic contamination factor in organic solid waste is eliminated, achievees the purpose that environmental protection.

Description

A kind for the treatment of process of solid waste
Technical field
The present invention relates to organic matter technical field of energy utilization more particularly to a kind for the treatment of process of solid waste.
Background technology
Burning is the integrated disposal processing of organic solid waste pyrolytic and deep oxidation greatly, and benefit is a large amount of harmful Scrap digestion and become harmless substance.With such processing method, solid waste is taken up an area less, treating capacity is big, but is burned There is disadvantage, the smoke evacuation of existing common burning method can cause secondary pollution, and equipment corrosion phenomena is serious.Pyrolysismethod is to utilize The thermal instability of organic matter in organic solid waste is carrying out heating distillation to it, so that organic matter is generated cracking, after condensed Various new gases, liquid and solid are formed, the process of fuel oil, combustible gas is therefrom extracted.With such processing method, will produce The substances such as tar, processing are complicated.
Invention content
The object of the present invention is to provide a kind for the treatment of process of solid waste, by organic dirt in organic solid waste It contaminates the factor to eliminate, achievees the purpose that environmental protection.
Technical scheme of the present invention:A kind for the treatment of process of solid waste, which is characterized in that include the following steps:
(1)Pretreatment:Organic solid castoff is dried, is crushed, deodorizing process;
(2)Pyrolytic gasification:Pretreated organic solid castoff is subjected to pyrolysis processing, at the laggard promoting the circulation of qi of pyrolysis processing Reason, is passed through vapor and quartz sand during gasification, and solid waste becomes high-temperature flue gas or ash content after pyrolytic gasification, High-temperature flue gas is discharged from the top vent of solid waste pyrolysis gasifying device, and ash content and quartz sand are pyrolyzed from solid waste The discharge gate of gasification installation is discharged, after cooling screening detaches ash content, quartz sand circulating and recovering;
(3)Cracking is reformed:To the high-temperature flue gas after pyrolytic gasification, cracking reformation is carried out under the effect of the catalyst;
(4)Post-processing:Gas cooling, the purification generated after cracking is reformed.
A kind for the treatment of process of solid waste above-mentioned, which is characterized in that the step(1)In, by solid waste Drying to moisture content is 5-20%, and it is 0.5-5mm to be crushed to particle size range.
A kind for the treatment of process of solid waste above-mentioned, which is characterized in that the step(2)In, the mistake of pyrolysis processing Oxygen content in journey<5%, the temperature of pyrolysis processing is 500-1000 DEG C, and the time of pyrolysis processing is 60-120min.
A kind for the treatment of process of solid waste above-mentioned, which is characterized in that the step(3)In, crack the temperature of reformation Degree is 1000-1200 DEG C, reformation time 10-30s.
A kind for the treatment of process of solid waste above-mentioned, which is characterized in that the step(3)In, catalyst is nickel salt At least one of catalyst and iron salt catalyst.
Beneficial effects of the present invention:It, will be organic in pyrolytic process to the technique of organic solid waste progress harmless treatment The organic contamination factor contained by solid waste is eliminated, while material reaction environment is reduction-state, evades the generation of bioxin, keeps away Secondary pollution of the disposal process to environment, obvious environment benefit are exempted from.
Specific implementation mode
The present invention is further illustrated for following example, but is not intended as the foundation limited the present invention.
Embodiment:A kind for the treatment of process of solid waste, includes the following steps:
(1)Pretreatment:Organic solid castoff is dried, is crushed, deodorizing process;
(2)Pyrolytic gasification:Pretreated organic solid castoff is subjected to pyrolysis processing, at the laggard promoting the circulation of qi of pyrolysis processing Reason, is passed through vapor and quartz sand during gasification, and solid waste becomes high-temperature flue gas or ash content after pyrolytic gasification, High-temperature flue gas is discharged from the top vent of solid waste pyrolysis gasifying device, and ash content and quartz sand are pyrolyzed from solid waste The discharge gate of gasification installation is discharged, after cooling screening detaches ash content, quartz sand circulating and recovering;
(3)Cracking is reformed:To the high-temperature flue gas after pyrolytic gasification, cracking reformation is carried out under the effect of the catalyst;
(4)Post-processing:Gas cooling, the purification generated after cracking is reformed.
The step(1)In, it is 5-20% that solid waste, which is dried to moisture content, and it is 0.5- to be crushed to particle size range 5mm。
The step(2)In, oxygen content during pyrolysis processing<5%, the temperature of pyrolysis processing is 500-1000 DEG C, the time of pyrolysis processing is 60-120min.
The step(3)In, the temperature for cracking reformation is 1000-1200 DEG C, reformation time 10-30s.
The step(3)In, catalyst is at least one of nickel salt catalyst and iron salt catalyst.

Claims (5)

1. a kind for the treatment of process of solid waste, which is characterized in that include the following steps:
(1)Pretreatment:Organic solid castoff is dried, is crushed, deodorizing process;
(2)Pyrolytic gasification:Pretreated organic solid castoff is subjected to pyrolysis processing, at the laggard promoting the circulation of qi of pyrolysis processing Reason, is passed through vapor and quartz sand during gasification, and solid waste becomes high-temperature flue gas or ash content after pyrolytic gasification, High-temperature flue gas is discharged from the top vent of solid waste pyrolysis gasifying device, and ash content and quartz sand are pyrolyzed from solid waste The discharge gate of gasification installation is discharged, after cooling screening detaches ash content, quartz sand circulating and recovering;
(3)Cracking is reformed:To the high-temperature flue gas after pyrolytic gasification, cracking reformation is carried out under the effect of the catalyst;
(4)Post-processing:Gas cooling, the purification generated after cracking is reformed.
2. a kind for the treatment of process of solid waste according to claim 1, which is characterized in that the step(1)In, it will It is 5-20% that solid waste, which is dried to moisture content, and it is 0.5-5mm to be crushed to particle size range.
3. a kind for the treatment of process of solid waste according to claim 1, which is characterized in that the step(2)In, heat Oxygen content during solution processing<5%, the temperature of pyrolysis processing is 500-1000 DEG C, and the time of pyrolysis processing is 60- 120min。
4. a kind for the treatment of process of solid waste according to claim 1, which is characterized in that the step(3)In, it splits The temperature that solution is reformed is 1000-1200 DEG C, reformation time 10-30s.
5. a kind for the treatment of process of solid waste according to claim 1, which is characterized in that the step(3)In, it urges Agent is at least one of nickel salt catalyst and iron salt catalyst.
CN201810315257.4A 2018-04-10 2018-04-10 A kind for the treatment of process of solid waste Withdrawn CN108587685A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810315257.4A CN108587685A (en) 2018-04-10 2018-04-10 A kind for the treatment of process of solid waste

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810315257.4A CN108587685A (en) 2018-04-10 2018-04-10 A kind for the treatment of process of solid waste

Publications (1)

Publication Number Publication Date
CN108587685A true CN108587685A (en) 2018-09-28

Family

ID=63621458

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810315257.4A Withdrawn CN108587685A (en) 2018-04-10 2018-04-10 A kind for the treatment of process of solid waste

Country Status (1)

Country Link
CN (1) CN108587685A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109897673A (en) * 2019-03-23 2019-06-18 南京大学常高新国际环保产业技术研究院 It is a kind of to handle high COD chemical industry dangerous waste technique with high salt using hydropyrolysis process harmless resource

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109897673A (en) * 2019-03-23 2019-06-18 南京大学常高新国际环保产业技术研究院 It is a kind of to handle high COD chemical industry dangerous waste technique with high salt using hydropyrolysis process harmless resource

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Application publication date: 20180928

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