CN108587574A - A kind of oil electric heater specific complex heat carrier - Google Patents
A kind of oil electric heater specific complex heat carrier Download PDFInfo
- Publication number
- CN108587574A CN108587574A CN201711256417.4A CN201711256417A CN108587574A CN 108587574 A CN108587574 A CN 108587574A CN 201711256417 A CN201711256417 A CN 201711256417A CN 108587574 A CN108587574 A CN 108587574A
- Authority
- CN
- China
- Prior art keywords
- parts
- electric heater
- nano
- heat carrier
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/14—Solid materials, e.g. powdery or granular
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D13/00—Electric heating systems
- F24D13/04—Electric heating systems using electric heating of heat-transfer fluid in separate units of the system
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Paints Or Removers (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
The invention discloses a kind of oil electric heater specific complex heat carriers, belong to Heat Conduction Material technical field.The oil electric heater specific complex heat carrier that the present invention develops is by compounding base oil, Organic Selenium, aromatic alcohol, polyallylamine, complex solvent, polyamide wax dispersion liquid, nano-oxide is starched, potassium nitrate and sodium nitrite composition, wherein compounding base oil is by MethylethoxylsiliconFluid Fluid, trifluoro propyl methyl-silicone oil and isopropyl naphthalene composition, complex solvent is made of fatty alcohol and N methyl pyrrolidones, and polyamide wax dispersion liquid is by polyamide wax, butyl ether, dimethylethanolamine and water are made, in addition, contain nano oxidized boron in nano-oxide slurry, copper oxide and magnesia；When configuring product, first compounding base oil, complex solvent and polyallylamine are stirred, sequentially add Organic Selenium, aromatic alcohol etc., then be passed through carbon dioxide gas, is discharged, it is filling, you can.Oil electric heater specific complex heat carrier of the present invention has the characteristics that excellent high-temperature stability.
Description
Technical field
The invention discloses a kind of oil electric heater specific complex heat carriers, belong to Heat Conduction Material technical field.
Background technology
Organic heat carrier (heat transfer fluids) is the general designation of the organic substance used as a heat transfer medium,
Referred to as heat transfer oil (heat transfer fluids), conduction oil (hot oils), organic heating medium (organic heat
Transfer carriers), heating agent (heating media) etc. be used for all organic medias of indirect heat transfer purpose.According to change
Synthesis type organic heat carrier and mineral oil origin organic heat carrier can be divided by learning composition;The organic heat of gas phase can be classified as according to boiling range to carry
Body and liquid phase organic heat carrier.Mineral oil origin organic heat carrier is mostly the petroleum cuts of weight, has safe, small toxicity, original
Expect the features such as wide, at low cost, but temperature in use is relatively low.Mineral oil origin organic heat carrier is substantially all as cycloalkane and alkane
Mixture.Such conduction oil has long, straight chain chemical constitution, is easy to happen fracture, and thermal stability is poor, and low component is volatile,
Additive amount is big, different degrees of oxygenolysis is will produce in the high temperature lower short time, so as to cause coking knot carbon.But because its is at low cost
Honest and clean, processing technology is simple, and boiling point is high, without pressurizeing to expansion slot, is often used and is wanted to thermal stability and technological temperature accuracy
Not high heating system is sought, usually using temperature at 250 DEG C or less.Simultaneously compared with synthesizing conduction oil, mineral oil low temperature viscosity
Very big, in winter when very cold, pump start is difficult, and energy consumption is big, and heat transfer efficiency is relatively low, and cost of equipment maintenance increases, mineral
It cannot be regenerated after oil deterioration, waste oil can be used as fuel treatment.And synthesis type organic heat carrier can overcome mine to a certain extent
The deficiency of object oil type organic heat carrier, but with the raising of production and quality of the life, it is steady to the heat of traditional organic heat carrier
Qualitative more stringent requirements are proposed, especially applies to the organic heat carrier of oil electric heater.Due to traditional organic heat carrier height
Temperature stability is poor, and heat-conducting effect is caused not keep for a long time, is also easy to produce deposition during use, leads to pipeline blockage, influence to make
Use effect.
Therefore, how to improve traditional organic heat carrier poor high temperature stability, heat-conducting effect is caused not keep for a long time, use
It is also easy to produce deposition in the process, the shortcomings that leading to pipeline blockage, influence using effect, organic heat to obtain more high combination property carries
Body is that it is promoted and applies, meets industrial production demand urgent problem to be solved.
Invention content
The present invention solves the technical problem of：For traditional organic heat carrier poor high temperature stability, heat conduction is caused to be imitated
Fruit can not keep for a long time, be also easy to produce deposition during use, the shortcomings that leading to pipeline blockage, influence using effect, provide one
Kind oil electric heater specific complex heat carrier.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of oil electric heater specific complex heat carrier, is made of the raw material of following parts by weight：80~90 parts of compounding bases
Oil, 4~6 parts of Organic Seleniums, 3~5 parts of aromatic alcohols, 4~6 parts of polyallylamines, 10~20 parts of complex solvents, 8~10 parts of polyamide waxes
Dispersion liquid, 8~10 parts of nano-oxide slurries, 4~6 parts of potassium nitrate, 3~5 parts of sodium nitrites；
The oil electric heater specific complex heat carrier configuration process is：
（1）It is formed by raw material and weighs each component；
（2）Compounding base oil, complex solvent and polyallylamine are first sequentially added into batch mixer, after being stirred, sequentially added
Organic Selenium, aromatic alcohol, polyamide wax dispersion liquid, nano-oxide slurry, potassium nitrate and sodium nitrite, continue high-speed stirred mixing,
Carbon dioxide gas is passed through into batch mixer again, is discharged, it is filling to get oil electric heater specific complex heat carrier.
The compounding base oil is compounded by following parts by weight raw material：10~15 parts of MethylethoxylsiliconFluid Fluids, 8~
10 parts of trifluoro propyl methyl-silicone oils, 40~60 parts of isopropyl naphthalenes.
The Organic Selenium is any one in two selenium of hexichol selenide or hexichol.
The aromatic alcohol is any one in terephthalyl alcohol, benzyl carbinol or benzyl alcohol.
It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：8~1：10 compound；Institute
It is any one in lauryl alcohol, tridecanol, tetradecyl alchohol or pentadecanol to state fatty alcohol.
The polyamide wax dispersion liquid configuration process is：It counts in parts by weight, takes 20~30 parts of polyamide wax AQ- successively
600,20~30 parts of butyl ether, 3~5 parts of dimethylethanolamines, 10~12 parts of water are first high by polyamide wax AQ-600, butyl ether and water
Speed is stirred, then dimethylethanolamine is added dropwise, ultrasonic disperse, obtains polyamide wax dispersion liquid.
The nano-oxide starches configuration process：It counts in parts by weight, takes 8~10 parts of nano oxidized boron successively, 10~
15 parts of nano cupric oxides, 10~15 parts of nano magnesias, 60~80 parts of propylene glycol monomethyl ethers, 3~5 parts of wetting dispersing agent BYK-190,
After stirring at low speed mixing, 24~36h is stood, obtains nano-oxide slurry.
The beneficial effects of the invention are as follows：
（1）Technical solution of the present invention in system by adding Organic Selenium class compound, and in use, such compound can
The metallicses such as the iron under relatively lower temp and on container tube wall react, and generate corresponding metal selenide, thus
Selenide thin film is formed on container tube wall, avoids active metal substance in tube wall from being contacted with substances such as base oils, to reduce pipe
The deposition of carbon distribution on wall keeps pipeline unobstructed, heat-transfer effect is made to keep for a long time；In addition, aromatic alcohol in technical solution of the present invention
It is added, in use, the fracture of c h bond can occur at high temperature for aromatic alcohol, generate hydroperoxyl radical and remaining group, hydrogen is certainly
The Active Radicals Produced that the cracking of the organic matters such as base oil generates can be captured by base, the transmission of its cracking reaction chain is terminated, to play
Inhibit cracking, reduce the effect of after polymerization reaction, while improving the organic matters stability such as base oil, effectively prevents pipe
The deposition of substance in road enables the permanently effective holding of heat-conducting effect；
（2）By adding polyallylamine in technical solution of the present invention, and carbon dioxide is passed through into system in configuration process,
In configuration process, polyallylamine absorbing carbon dioxide, and three-dimensional crosslinked network is formed inside system, thus by nanometer in system
The absorption of the substances such as oxide is fixed in three-dimensional crosslinked network, its sedimentation is avoided, to improve nano-oxide in storage process
In dispersion stabilization in system, in use, polyallylamine adsorbs fixed carbon dioxide and slowly overflows from system
Go out, the flowing of promotion system, realizes quick conductive, and partial CO 2 is scattered in the form of micro-bubble in system, and inhale
Nano-oxide surface is invested, makes it in use, remains to suspended dispersed in system, further increases the heat conduction of system
Effect.
Specific implementation mode
It counts in parts by weight, takes 20~30 parts of polyamide wax AQ-600,20~30 parts of butyl ether, 3~5 parts of dimethyl second successively
Hydramine, 10~12 parts of water first pour into polyamide wax AQ-600, butyl ether and water in No. 1 beaker, with blender with 1400~
1600r/min rotating speed high-speed stirreds mix 45~60min, under stirring, with 3~5mL/min rates into No. 1 beaker
Be added dropwise dimethylethanolamine, wait being added dropwise, material in No. 1 beaker be transferred to ultrasonic disperse instrument, in supersonic frequency be 45~
Under the conditions of 50kHz, 45~60min of ultrasonic disperse, discharging obtains polyamide wax dispersion liquid；It counts in parts by weight, in No. 2 beakers
Sequentially add 8~10 parts of nano oxidized boron, 10~15 parts of nano cupric oxides, 10~15 parts of nano magnesias, 60~80 parts the third two
Alcohol methyl ether, 3~5 parts of wetting dispersing agent BYK-190, with blender with 120~150r/min rotating speed stirring at low speed mixing 45~
After 60min, by No. 2 beakers under room temperature, 24~36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
80~90 parts of compounding base oils, 4~6 parts of Organic Seleniums, 3~5 parts of aromatic alcohols, 4~6 parts of polyallylamines, 10~20 parts of complex solvents,
8~10 parts of polyamide wax dispersion liquids, 8~10 parts of nano-oxide slurries, 4~6 parts of potassium nitrate, 3~5 parts of sodium nitrites will first answer
It is sequentially added in batch mixer with base oil, complex solvent and polyallylamine, 2~4h is stirred with 500~600r/min rotating speeds
Afterwards, under stirring, Organic Selenium, aromatic alcohol, polyamide wax dispersion liquid, nano-oxide are sequentially added into batch mixer
Slurry, potassium nitrate and sodium nitrite, continue under the conditions of 1200~1400r/min, after high-speed stirred mixes 2~4h, stop stirring,
And carbon dioxide gas is passed through into batch mixer with 60~80mL/min rates in material, it is continually fed into 10~15min, is discharged,
It is filling to get oil electric heater specific complex heat carrier.The compounding base oil is compounded by following parts by weight raw material：
10~15 parts of MethylethoxylsiliconFluid Fluids, 8~10 parts of trifluoro propyl methyl-silicone oils, 40~60 parts of isopropyl naphthalenes.The Organic Selenium is
Any one in two selenium of hexichol selenide or hexichol.The aromatic alcohol is arbitrary in terephthalyl alcohol, benzyl carbinol or benzyl alcohol
It is a kind of.It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：8~1：10 compound；The fat
Fat alcohol is any one in lauryl alcohol, tridecanol, tetradecyl alchohol or pentadecanol.
Example 1
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 15 parts
Nano magnesia, 80 parts of propylene glycol monomethyl ethers, 5 parts of wetting dispersing agent BYK-190, with blender with 150r/min rotating speed stirring at low speed
After mixing 60min, by No. 2 beakers under room temperature, 36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
90 parts of compounding base oils, 6 parts of Organic Seleniums, 5 parts of aromatic alcohols, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersions
Liquid, 10 parts of nano-oxides slurry, 6 parts of potassium nitrate, 5 parts of sodium nitrites, first will compounding base oil, complex solvent and polyallylamine according to
In secondary addition batch mixer, after being stirred 4h with 600r/min rotating speeds, under stirring, sequentially added into batch mixer
Machine selenium, aromatic alcohol, polyamide wax dispersion liquid, nano-oxide slurry, potassium nitrate and sodium nitrite, continue at 1400r/min conditions
Under, after high-speed stirred mixes 4h, stop stirring, and carbon dioxide gas is passed through into batch mixer with 80mL/min rates in material
Body is continually fed into 15min, discharging, filling to get oil electric heater specific complex heat carrier.The compounding base oil be by with
Lower parts by weight raw material compounds：15 parts of MethylethoxylsiliconFluid Fluids, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.
The Organic Selenium is hexichol selenide.The aromatic alcohol is terephthalyl alcohol.The complex solvent is by fatty alcohol and N- methyl pyrroles
Pyrrolidone is 1 in mass ratio：10 compound；The fatty alcohol is lauryl alcohol.
Example 2
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 15 parts
Nano magnesia, 80 parts of propylene glycol monomethyl ethers, 5 parts of wetting dispersing agent BYK-190, with blender with 150r/min rotating speed stirring at low speed
After mixing 60min, by No. 2 beakers under room temperature, 36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
90 parts of compounding base oils, 5 parts of aromatic alcohols, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersion liquids, 10 parts of nanometers
Oxide is starched, 6 parts of potassium nitrate, 5 parts of sodium nitrites, and compounding base oil, complex solvent and polyallylamine are first sequentially added batch mixing
In machine, after being stirred 4h with 600r/min rotating speeds, under stirring, aromatic alcohol, polyamides are sequentially added into batch mixer
Amine wax dispersion, nano-oxide slurry, potassium nitrate and sodium nitrite, continue under the conditions of 1400r/min, high-speed stirred mixes 4h
Afterwards, stop stirring, and carbon dioxide gas is passed through into batch mixer with 80mL/min rates in material, be continually fed into 15min, go out
Material, it is filling to get oil electric heater specific complex heat carrier.The compounding base oil be by following parts by weight raw material compounding and
At：15 parts of MethylethoxylsiliconFluid Fluids, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.The aromatic alcohol is terephthaldehyde
Alcohol.It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：10 compound；The fatty alcohol is
Lauryl alcohol.
Example 3
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 15 parts
Nano magnesia, 80 parts of propylene glycol monomethyl ethers, 5 parts of wetting dispersing agent BYK-190, with blender with 150r/min rotating speed stirring at low speed
After mixing 60min, by No. 2 beakers under room temperature, 36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
90 parts of compounding base oils, 6 parts of Organic Seleniums, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersion liquids, 10 parts of nanometers
Oxide is starched, 6 parts of potassium nitrate, 5 parts of sodium nitrites, and compounding base oil, complex solvent and polyallylamine are first sequentially added batch mixing
In machine, after being stirred 4h with 600r/min rotating speeds, under stirring, Organic Selenium, polyamides are sequentially added into batch mixer
Amine wax dispersion, nano-oxide slurry, potassium nitrate and sodium nitrite, continue under the conditions of 1400r/min, high-speed stirred mixes 4h
Afterwards, stop stirring, and carbon dioxide gas is passed through into batch mixer with 80mL/min rates in material, be continually fed into 15min, go out
Material, it is filling to get oil electric heater specific complex heat carrier.The compounding base oil be by following parts by weight raw material compounding and
At：15 parts of MethylethoxylsiliconFluid Fluids, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.The Organic Selenium is hexichol selenide.
It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：10 compound；The fatty alcohol is 12
Alcohol.
Example 4
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 15 parts
Nano magnesia, 80 parts of propylene glycol monomethyl ethers, 5 parts of wetting dispersing agent BYK-190, with blender with 150r/min rotating speed stirring at low speed
After mixing 60min, by No. 2 beakers under room temperature, 36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
90 parts of compounding base oils, 6 parts of Organic Seleniums, 5 parts of aromatic alcohols, 20 parts of complex solvents, 10 parts of polyamide wax dispersion liquids, 10 parts of nano oxygens
Compound is starched, 6 parts of potassium nitrate, 5 parts of sodium nitrites, is first sequentially added compounding base oil, complex solvent in batch mixer, with 600r/
After min rotating speeds are stirred 4h, under stirring, Organic Selenium, aromatic alcohol, polyamide wax point are sequentially added into batch mixer
Dispersion liquid, nano-oxide slurry, potassium nitrate and sodium nitrite, continue under the conditions of 1400r/min, after high-speed stirred mixes 4h, stop
It only stirs, and carbon dioxide gas is passed through into batch mixer with 80mL/min rates in material, be continually fed into 15min, discharge, fill
Dress is to get oil electric heater specific complex heat carrier.The compounding base oil is compounded by following parts by weight raw material：15
Part MethylethoxylsiliconFluid Fluid, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.The Organic Selenium is hexichol selenide.It is described
Aromatic alcohol is terephthalyl alcohol.It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：10 compounding and
At；The fatty alcohol is lauryl alcohol.
Example 5
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 15 parts
Nano magnesia, 80 parts of propylene glycol monomethyl ethers, 5 parts of wetting dispersing agent BYK-190, with blender with 150r/min rotating speed stirring at low speed
After mixing 60min, by No. 2 beakers under room temperature, 36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
90 parts of compounding base oils, 6 parts of Organic Seleniums, 5 parts of aromatic alcohols, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersions
Liquid, 10 parts of nano-oxides slurry, 6 parts of potassium nitrate, 5 parts of sodium nitrites, first will compounding base oil, complex solvent and polyallylamine according to
In secondary addition batch mixer, after being stirred 4h with 600r/min rotating speeds, under stirring, sequentially added into batch mixer
Machine selenium, aromatic alcohol, polyamide wax dispersion liquid, nano-oxide slurry, potassium nitrate and sodium nitrite, continue at 1400r/min conditions
Under, after high-speed stirred mixes 4h, stops stirring, and nitrogen gas is passed through into batch mixer with 80mL/min rates in material, hold
It is continuous to be passed through 15min, it discharges, it is filling to get oil electric heater specific complex heat carrier.The compounding base oil is by following weight
Number raw material compounds：15 parts of MethylethoxylsiliconFluid Fluids, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.It is described to have
Machine selenium is hexichol selenide.The aromatic alcohol is terephthalyl alcohol.The complex solvent is by fatty alcohol and N-Methyl pyrrolidone
It is 1 in mass ratio：10 compound；The fatty alcohol is lauryl alcohol.
Example 6
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 15 parts of nano cupric oxides in No. 2 beakers, 15 parts of nano magnesias, 80 parts
Propylene glycol monomethyl ether, 5 parts of wetting dispersing agent BYK-190, after mixing 60min with blender with 150r/min rotating speed stirring at low speed, by 2
Number beaker stands 36h under room temperature, obtains nano-oxide slurry；Count in parts by weight, take successively 90 parts compounding base oils, 6
Part Organic Selenium, 5 parts of aromatic alcohols, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersion liquids, 10 parts of nano-oxides
Slurry, 6 parts of potassium nitrate, 5 parts of sodium nitrites first sequentially add compounding base oil, complex solvent and polyallylamine in batch mixer, with
After 600r/min rotating speeds are stirred 4h, under stirring, Organic Selenium, aromatic alcohol, polyamides are sequentially added into batch mixer
Amine wax dispersion, nano-oxide slurry, potassium nitrate and sodium nitrite, continue under the conditions of 1400r/min, high-speed stirred mixes 4h
Afterwards, stop stirring, and carbon dioxide gas is passed through into batch mixer with 80mL/min rates in material, be continually fed into 15min, go out
Material, it is filling to get oil electric heater specific complex heat carrier.The compounding base oil be by following parts by weight raw material compounding and
At：15 parts of MethylethoxylsiliconFluid Fluids, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.The Organic Selenium is hexichol selenide.
The aromatic alcohol is terephthalyl alcohol.It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：10 is multiple
With into；The fatty alcohol is lauryl alcohol.
Example 7
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 80 parts
Propylene glycol monomethyl ether, 5 parts of wetting dispersing agent BYK-190, after mixing 60min with blender with 150r/min rotating speed stirring at low speed, by 2
Number beaker stands 36h under room temperature, obtains nano-oxide slurry；Count in parts by weight, take successively 90 parts compounding base oils, 6
Part Organic Selenium, 5 parts of aromatic alcohols, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersion liquids, 10 parts of nano-oxides
Slurry, 6 parts of potassium nitrate, 5 parts of sodium nitrites first sequentially add compounding base oil, complex solvent and polyallylamine in batch mixer, with
After 600r/min rotating speeds are stirred 4h, under stirring, Organic Selenium, aromatic alcohol, polyamides are sequentially added into batch mixer
Amine wax dispersion, nano-oxide slurry, potassium nitrate and sodium nitrite, continue under the conditions of 1400r/min, high-speed stirred mixes 4h
Afterwards, stop stirring, and carbon dioxide gas is passed through into batch mixer with 80mL/min rates in material, be continually fed into 15min, go out
Material, it is filling to get oil electric heater specific complex heat carrier.The compounding base oil be by following parts by weight raw material compounding and
At：15 parts of MethylethoxylsiliconFluid Fluids, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.The Organic Selenium is hexichol selenide.
The aromatic alcohol is terephthalyl alcohol.It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：10 is multiple
With into；The fatty alcohol is lauryl alcohol.
Example 8
It counts in parts by weight, takes 30 parts of polyamide wax AQ-600,30 parts of butyl ether, 5 parts of dimethylethanolamines, 12 parts of water, elder generation successively
Polyamide wax AQ-600, butyl ether and water are poured into No. 1 beaker, mixed with 1600r/min rotating speed high-speed stirreds with blender
60min is added dropwise dimethylethanolamine into No. 1 beaker with 5mL/min rates, waits being added dropwise, by 1 under stirring
Material is transferred to ultrasonic disperse instrument in number beaker, and under the conditions of supersonic frequency is 50kHz, ultrasonic disperse 60min, discharging obtains polyamides
Amine wax dispersion；It counts in parts by weight, sequentially adds 10 parts of nano oxidized boron in No. 2 beakers, 15 parts of nano cupric oxides, 15 parts
Nano magnesia, 80 parts of propylene glycol monomethyl ethers, 5 parts of wetting dispersing agent BYK-190, with blender with 150r/min rotating speed stirring at low speed
After mixing 60min, by No. 2 beakers under room temperature, 36h is stood, obtains nano-oxide slurry；It counts, takes successively in parts by weight
90 parts of compounding base oils, 6 parts of Organic Seleniums, 5 parts of aromatic alcohols, 6 parts of polyallylamines, 20 parts of complex solvents, 10 parts of polyamide wax dispersions
Liquid, 10 parts of nano-oxide slurries, first sequentially adds compounding base oil, complex solvent and polyallylamine in batch mixer, with 600r/
After min rotating speeds are stirred 4h, under stirring, Organic Selenium, aromatic alcohol, polyamide wax point are sequentially added into batch mixer
Dispersion liquid, nano-oxide slurry, continue under the conditions of 1400r/min, after high-speed stirred mixes 4h, stop stirring, and with 80mL/
Min rates are passed through carbon dioxide gas into batch mixer in material, be continually fed into 15min, discharging, filling to get oil heater electric heating
Device specific complex heat carrier.The compounding base oil is compounded by following parts by weight raw material：15 parts of methyl ethoxy silicon
Oil, 10 parts of trifluoro propyl methyl-silicone oils, 60 parts of isopropyl naphthalenes.The Organic Selenium is hexichol selenide.The aromatic alcohol is to benzene two
Methanol.It is 1 in mass ratio that the complex solvent, which is by fatty alcohol and N-Methyl pyrrolidone,：10 compound；The fatty alcohol
For lauryl alcohol.
Comparative example：The heat carrier of Shandong Chemical Industry Science Co., Ltd production.
The oil electric heater specific complex heat carrier of 1 to 8 gained of example and comparative example product are subjected to performance detection, specifically
Detection method is as follows：
High-temperature stability：Test specimen maximum permissible service temperature is detected according to GB/T23800.
Specific testing result is as shown in table 1：
Table 1
| Detection project | Maximum permissible service temperature/DEG C |
| Example 1 | 410 |
| Example 2 | 385 |
| Example 3 | 393 |
| Example 4 | 376 |
| Example 5 | 362 |
| Example 6 | 354 |
| Example 7 | 349 |
| Example 8 | 332 |
| Comparative example | 310 |
By 1 testing result of table it is found that the oil electric heater specific complex heat carrier of technical solution of the present invention preparation is with excellent
High-temperature stability can achieve the effect that long-term heat conduction, and deposition is not likely to produce during use, and the smooth feature of pipeline is carried in heat
It has broad prospects in the development of body industry.
Claims (7)
1. a kind of oil electric heater specific complex heat carrier, it is characterised in that：It is made of the raw material of following parts by weight：80~
90 parts of compounding base oils, 4~6 parts of Organic Seleniums, 3~5 parts of aromatic alcohols, 4~6 parts of polyallylamines, 10~20 parts of complex solvents, 8~
10 parts of polyamide wax dispersion liquids, 8~10 parts of nano-oxide slurries, 4~6 parts of potassium nitrate, 3~5 parts of sodium nitrites；
The oil electric heater specific complex heat carrier configuration process is：
（1）It is formed by raw material and weighs each component；
（2）Compounding base oil, complex solvent and polyallylamine are first sequentially added into batch mixer, after being stirred, sequentially added
Organic Selenium, aromatic alcohol, polyamide wax dispersion liquid, nano-oxide slurry, potassium nitrate and sodium nitrite, continue high-speed stirred mixing,
Carbon dioxide gas is passed through into batch mixer again, is discharged, it is filling to get oil electric heater specific complex heat carrier.
2. a kind of oil electric heater specific complex heat carrier according to claim 1, it is characterised in that：The compounding basis
Oil is compounded by following parts by weight raw material：10~15 parts of MethylethoxylsiliconFluid Fluids, 8~10 parts of trifluoro propyl methyl silicon
Oil, 40~60 parts of isopropyl naphthalenes.
3. a kind of oil electric heater specific complex heat carrier according to claim 1, it is characterised in that：The Organic Selenium is
Any one in two selenium of hexichol selenide or hexichol.
4. a kind of oil electric heater specific complex heat carrier according to claim 1, it is characterised in that：The aromatic alcohol is
Any one in terephthalyl alcohol, benzyl carbinol or benzyl alcohol.
5. a kind of oil electric heater specific complex heat carrier according to claim 1, it is characterised in that：The complex solvent
Be by fatty alcohol and N-Methyl pyrrolidone it is 1 in mass ratio：8~1：10 compound；The fatty alcohol is lauryl alcohol, 13
Any one in alcohol, tetradecyl alchohol or pentadecanol.
6. a kind of oil electric heater specific complex heat carrier according to claim 1, it is characterised in that：The polyamide wax
Dispersion liquid configuration process is：It counts in parts by weight, takes 20~30 parts of polyamide wax AQ-600 successively, 20~30 parts of butyl ether, 3~5
Polyamide wax AQ-600, butyl ether and water high-speed stirred are first mixed, then diformazan are added dropwise by part dimethylethanolamine, 10~12 parts of water
Ethylethanolamine, ultrasonic disperse obtain polyamide wax dispersion liquid.
7. a kind of oil electric heater specific complex heat carrier according to claim 1, it is characterised in that：It is described nano oxidized
Object starches configuration process：It counts in parts by weight, takes 8~10 parts of nano oxidized boron successively, 10~15 parts of nano cupric oxides, 10~15
Part nano magnesia, 60~80 parts of propylene glycol monomethyl ethers, 3~5 parts of wetting dispersing agent BYK-190 stand 24 after stirring at low speed mixing
~36h obtains nano-oxide slurry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711256417.4A CN108587574A (en) | 2017-12-04 | 2017-12-04 | A kind of oil electric heater specific complex heat carrier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711256417.4A CN108587574A (en) | 2017-12-04 | 2017-12-04 | A kind of oil electric heater specific complex heat carrier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108587574A true CN108587574A (en) | 2018-09-28 |
Family
ID=63633048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711256417.4A Withdrawn CN108587574A (en) | 2017-12-04 | 2017-12-04 | A kind of oil electric heater specific complex heat carrier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108587574A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110042014A (en) * | 2019-02-25 | 2019-07-23 | 陈太师 | A kind of kitchen pipeline mild dredging agent |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531082A (en) * | 2014-11-25 | 2015-04-22 | 冯智勇 | Novel nanoscale copper-aluminum-alloy particle heat-conduction fluid material |
-
2017
- 2017-12-04 CN CN201711256417.4A patent/CN108587574A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531082A (en) * | 2014-11-25 | 2015-04-22 | 冯智勇 | Novel nanoscale copper-aluminum-alloy particle heat-conduction fluid material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110042014A (en) * | 2019-02-25 | 2019-07-23 | 陈太师 | A kind of kitchen pipeline mild dredging agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105647502B (en) | Thick oil viscosity reducer and preparation method thereof | |
| CN102489049B (en) | Mineral oil type antifoaming agent and preparation method thereof | |
| CN102382554B (en) | Heat preservation and insulation heavy duty anti-corrosion coating with low thermal conductivity and preparation method thereof | |
| CN202105611U (en) | Heating and mixing paddle of polymerization reactor | |
| CN101153239A (en) | Compound sulphonic acid albany grease and method for producing the same | |
| CN105273741B (en) | Ethylene device gasoline stripping tower scale inhibitor, preparation method and usage method | |
| CN103952225B (en) | For water-based free abrasive cutting liquid cutting solar silicon wafers and preparation method thereof | |
| CN101798781A (en) | Silicone defoaming agent for papermaking and pulping and preparation method thereof | |
| CN110452762B (en) | Multi-linear flaked silicon wafer cutting fluid and preparation method thereof | |
| CN105802599A (en) | Efficient compound-type hydrate dynamics inhibitor | |
| CN108587574A (en) | A kind of oil electric heater specific complex heat carrier | |
| CN101721843A (en) | Solid particle foam inhibitor and preparation method thereof | |
| CN103980246A (en) | Production method for preparing propylene (ethylene) carbonate from carbon dioxide and propylene oxide (ethylene oxide) through tubular reaction | |
| CN104232246A (en) | Lubricating oil composite type antifoaming agent and application thereof | |
| CN107987805A (en) | A kind of engine cool liquid complexing agent and preparation method thereof | |
| CN101838544A (en) | Scale inhibitor of ethylene device gasoline stripping tower and using method thereof | |
| CN110747036A (en) | High-quality micro-emulsified cutting fluid for metal processing | |
| Fujita et al. | Clathrate‐hydrate formation by water spraying onto a porous metal plate exuding a hydrophobic liquid coolant | |
| CN105084447B (en) | Defoaming agent for foam drainage gas production and preparation method thereof | |
| CN104326905A (en) | Aryl alkyl carboxylic polyoxyethylene ester and preparation method and application thereof | |
| CN108276437A (en) | A kind of low-foam wetting agents and preparation method thereof | |
| CN101230212A (en) | White carbon black surface recombination modified preparation method | |
| CN106978223B (en) | A kind of nano combined pour point reducer composition and preparation method thereof | |
| CN105315983B (en) | Aqueous fracturing fluid drag reducer and its preparation method and application | |
| CN107267274B (en) | A kind of environmental protection wire cutting liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180928 |