CN107267274B - A kind of environmental protection wire cutting liquid and preparation method thereof - Google Patents
A kind of environmental protection wire cutting liquid and preparation method thereof Download PDFInfo
- Publication number
- CN107267274B CN107267274B CN201710507497.XA CN201710507497A CN107267274B CN 107267274 B CN107267274 B CN 107267274B CN 201710507497 A CN201710507497 A CN 201710507497A CN 107267274 B CN107267274 B CN 107267274B
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- wire cutting
- cutting liquid
- environment
- friendly type
- type wire
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- 238000005520 cutting process Methods 0.000 title claims abstract description 70
- 239000007788 liquid Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 230000007613 environmental effect Effects 0.000 title description 6
- 239000000126 substance Substances 0.000 claims abstract description 14
- 239000003921 oil Substances 0.000 claims abstract description 11
- 235000019198 oils Nutrition 0.000 claims abstract description 11
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 9
- 239000008158 vegetable oil Substances 0.000 claims abstract description 9
- 239000013556 antirust agent Substances 0.000 claims abstract description 6
- 238000007127 saponification reaction Methods 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000003242 anti bacterial agent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003599 detergent Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 3
- 238000005070 sampling Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- -1 triethanolamine boric acid Ester Chemical class 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
- 239000002202 Polyethylene glycol Substances 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 abstract description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005859 coupling reaction Methods 0.000 abstract description 2
- 239000012847 fine chemical Substances 0.000 abstract description 2
- 239000003208 petroleum Substances 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000008399 tap water Substances 0.000 abstract 1
- 235000020679 tap water Nutrition 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000010730 cutting oil Substances 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000006061 abrasive grain Substances 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000004377 microelectronic Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000002210 silicon-based material Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000012224 working solution Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HJVAFZMYQQSPHF-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;boric acid Chemical group OB(O)O.OCCN(CCO)CCO HJVAFZMYQQSPHF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical group CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/081—Inorganic acids or salts thereof containing halogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/20—Rosin acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention belongs to intermetallic composite coating and fine chemical product preparation fields, it is related to a kind of wire cutting liquid without coupling reaction, more particularly to a kind of environmentally friendly wire cutting liquid and preparation method thereof, each substance including following mass parts: 1~14 part of rosin, 1~14 part of vegetable oil acid, 10~30 parts of lye, 20~50 parts of tap water, 1~5 part of antirust agent, 5~10 parts of petroleum sodium sulfonate, 2~5 parts of synthetic oil, 1~15 part of polyethylene glycol, 3~8 parts of alcohol, 0.1 part of anti-foaming agent, wherein, the mass concentration of lye is 50%.Its heat resistance having had, light fastness, and can be suitably used for cold district use；Also it is able to satisfy higher wire cutting speed.
Description
Technical field
The invention belongs to intermetallic composite coating and fine chemical product preparation fields, are related to a kind of wire cutting without coupling reaction
A kind of liquid, and in particular to environmental protection wire cutting liquid and preparation method thereof.
Background technique
Wire cutting liquid is used primarily in numerically controlled wire cutting machine, generally has the function of good cooling, lubrication, cleaning and antirust
Can, also there are other properties: having certain dielectric strength, go to dissociate, arc extinguishing, prevent fracture of wire and long service life, peace
Atoxic etc..It can get ideal processing finish and processing efficiency with suitable wire cutting liquid, and the use of lathe can be extended
Service life.
In the past, wire cutting liquid is mainly used in the Precision Machining of the hard materials such as metal；Now with global solar and
The rapid development of microelectronic industry, the demand rapid growth to silicon wafer, wire cutting silicon wafer have become solar energy and microelectronic industry
Master operation.But the wire cutting of either metal or the wire cutting of silicon wafer can cause certain remnants to answer to product
Power, surface layer and surface damage.
It is numerous studies have shown that in the case where cutting on line process stabilizing, the performance of cutting liquid is to influence silicon wafer cutting efficiency
And one of key factor of quality.In cutting process, the double action being machined with mechanically and chemically of cutting liquid to machined part,
Lubricating action can be played, the intermolecular interior friction of lubricating film is converted by the strong mechanical friction between molybdenum filament, abrasive grain and silicon material, makes
The secondary motion that rubs is steady, reduces damage and stress, while taking away the heat of cutting process generation in time；But also it can play
Cleaning action, and under the premise of environmental protection improve lathe rust resistance and corrosion resistance performance.Cutting liquid of good performance requires its ingredient
Nontoxic, soluble easily in water, easy cleaning, volatility are small, energy is biodegradable and performance in terms of permeating, disperse in lubrication
Well.It is uniformly dispersed with seeing through property of good lubrication, abrasive grain, the cutting liquid for the characteristics such as pH value is appropriate can greatly reduce silicon material
Loss in cutting, is effectively reduced the surface damage stress of workpiece to be added, reduces cutting damage layer, improves adding for workpiece to be added
Work precision and quality.
But the wire cutting liquid mainly sold on existing market mainly includes potassium hydroxide, mineral oil, oleic acid, lye, second
Alcohol, butyl etc., existing defect have: one, must use base oil (mineral when existing wire cutting oil emulsion produces
Oil) as its must can not be small raw materials for production, and the waste oil environmental pollution of base oil (mineral oil) is quite serious.Root
It transfers to according to the waste mineral oil needs that clear stipulaties in " National Hazard waste register " are not suitable for original purposes at waste mineral oil
The unit for setting business licence is disposed.The production-operation unit of wire cutting oil emulsion is used now, and only fraction can incite somebody to action
Its discarded wire cutting oil emulsion transfers to the recovery processing unit with concerned countries qualification to be disposed.However it is many private
Medium and small micro- enterprise or small intermetallic composite coating workshop, not will do it in accordance in the disposition of national regulation, What is more will directly give up
Emulsion direct emission is in natural environment or urban sewage pipeline.It is very serious for environmental disruption.Second is that, existing line cuts
The production energy consumption for cutting oil emulsion is big, and raw material need to be warming up to 130~140 DEG C by production.Since present ecological requirements have been forbidden firing
Burning heavy oil, coal, biomass fuel, so continuing to be unfavorable for production cost control with old technology production.Third is that, existing product is watered
Working solution is milky turbidity liquid afterwards, unfriendly to environment, its is thermo-labile, light fugitive.Fourth is that, existing product warp in wire cutting
Machine on-the-spot test, wire cutting liquid are able to satisfy practical cutting efficiency up to 100mm2/Min, cutting speed need to be improved to adapt to city
The trend of field.Fifth is that, existing product concentrate cloud point be≤- 10 DEG C, used in cold district limited.
Summary of the invention
In order to improve the performance of wire cutting liquid, the application provides a kind of environment-friendly type wire cutting liquid and preparation method thereof, tool
The heat resistance that has had, light fastness, and can be suitably used for cold district use；Also it is able to satisfy higher wire cutting speed.
To realize the above-mentioned technical purpose, the specific technical solution that the present invention takes is a kind of environment-friendly type wire cutting liquid, including
Each substance of following mass parts:
Wherein, the mass concentration of lye is 50%.
As the improved technical solution of the present invention, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
It further include antibacterial agent as the improved technical solution of the present invention, the mass parts of antibacterial agent are 0.1~10 part.
As the improved technical solution of the present invention, antirust agent is triethanolamine borate.
It further include detergent as the improved technical solution of the present invention, the mass parts of detergent are 10~20 parts.
Another object of the present invention is to provide a kind of preparation methods of environment-friendly type wire cutting liquid, include the following steps:
Step 1: weighing rosin and vegetable oil acid by formulation content, heating melting after the two is mixed is uniformly mixed
Molten liquid；
It is saponified Step 2: lye is at the uniform velocity added dropwise into molten liquid while stirring, after being added dropwise to complete, timesharing
Between section sample, sample water is detected whether into oil slick；The time that saponification terminates, which is subject to, examines no oil slick；
Step 3: other compositions in formula are added into the solution after saponification, and stir evenly after saponification.
As the improved technical solution of the present invention, the temperature of heating melting is 70 DEG C~90 DEG C in step 1.
As the improved technical solution of the present invention, 75~80 DEG C of temperature of heating melting in step 1.
As the improved technical solution of the present invention, the time for starting to sample in step 2 is 5~8h after being added dropwise to complete.
Beneficial effect
The present invention realizes the water solubility for improving each ingredient in cutting liquid by being saponified to rosin and vegetable oil acid；Its
In, in order to improve the saponification efficiency of rosin, buffered here using vegetable oil acid；Rosin after saponification becomes with vegetable oil acid
Aqueous colloidal shape, the heat resistance having had, light resistance；After being mixed with synthetic oil, petroleum sodium sulfonate, polyethylene glycol etc.,
The wire cutting liquid for being under synergistic effect has heat resistance, light resistance, lower temperature resistance, while having good dispersion performance and resisting
Static behaviour ability effectively expands the working environment of wire cutting；In addition, due to rosin, vegetable oil acid saponification and with synthetic oil, stone
It is also equipped with certain electronegativity after the mixing such as oily sodium sulfonate, polyethylene glycol, in practical application, the cutting during wire cutting is considered to be worth doing
It will not be suspended in wire cutting liquid, sink to bottom.The clean level of wire cutting liquid during wire cutting, Jin Eryou has been effectively ensured
Effect improves wire cutting speed.
Further more, wire cutting liquid has been effectively ensured uses the longevity due to containing the substances such as alcohol, antibacterial agent in wire cutting liquid
Life, and improve the utilization rate of wire cutting liquid.
Rosin, vegetable oil acid are first saponified by wire cutting liquid preparation method provided by the present application, then mix each component by formula
Merging stirring can be obtained product, and in whipping process, wire cutting liquid passes through the mutual synergistic effect of each component, impart the line
The excellent cooling performance of cutting liquid, greasy property, wettability, while ensure that the low characteristic of spumescence.With preparation method
Simple process, condition is easily-controllable, low in cost, feature low for equipment requirements, is suitable for industrialized production.
Specific embodiment
To keep purpose and the technical solution of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention to this hair
The technical solution of bright embodiment is clearly and completely described.Obviously, described embodiment is that a part of the invention is implemented
Example, instead of all the embodiments.Based on described the embodiment of the present invention, those of ordinary skill in the art are without creating
Property labour under the premise of every other embodiment obtained, shall fall within the protection scope of the present invention.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology art
Language and scientific term) there is meaning identical with the general understanding of those of ordinary skill in fields of the present invention.Should also
Understand, those terms such as defined in the general dictionary, which should be understood that, to be had and the meaning in the context of the prior art
The consistent meaning of justice, and unless defined as here, it will not be explained in an idealized or overly formal meaning.
A kind of preparation method of environment-friendly type wire cutting liquid, includes the following steps:
Step 1: weighing rosin and vegetable oil acid by formulation content, heating melting after the two is mixed is uniformly mixed
Molten liquid；In order to control saponification effect, the temperature of heating melting is 70 DEG C~90 DEG C, the preferably temperature 75~80 of heating melting
℃；
It is saponified Step 2: lye is at the uniform velocity added dropwise into molten liquid while stirring, after being added dropwise to complete, timesharing
Between section sample, sample water is detected whether into oil slick；The time that saponification terminates, which is subject to, examines no oil slick；In order to guarantee sampling
Validity, the time for starting to sample are 5~8h after being added dropwise to complete；
Step 3: other compositions in formula are added into the solution after saponification, and stir evenly after saponification.
Embodiment 1
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%,
Wherein, antirust agent derives from the aqueous omnipotent antirust agent of family Shanghai Jia Hui cleaning agent Trade Co., Ltd..
Embodiment 2
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%；
In the present embodiment, antirust agent includes each substance of following parts by weight:
Embodiment 3
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
Embodiment 4
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
Embodiment 5
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
Embodiment 6
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
Embodiment 7
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
Embodiment 8
A kind of environment-friendly type wire cutting liquid, each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
Implementation result
Wherein, foaming properties are used is tested using dynamic foam tester；
Greasy property test, is tested using OCA20 video contact angle measuring instrument；
By implementation result it is found that the application enables to each performance such as lubrication, foam, wetting by the compounding of formula
It can play and maximize, to realize that provide a kind of cooling performance, greasy property, wettability relatively good, while there is foam
The low carborundum line cutting liquid of property, meets curstomer's site demand purpose.
The present invention relative to existing product the first big advantage this be: it is entirely free of mineral oil component, will not pollute
Environment, product meet RoSH standard, are free of lead, cadmium, mercury, Cr VI, multi-joint bromobenzene, polybrominated diphenyl ethers.Using unit can in order to avoid
It goes to consider the problems of that devil liquor recovery discharges.The second largest advantage be the present invention only need to heat the raw material to 80 DEG C or so can stop plus
Production can be completed in heat, then the stirring carried out 30 minutes, greatly reduces in terms of energy consumption and is conducive to the bigger profit of enterprise's acquisition
It is also beneficial to the effective use of resource.And it is safer when producing.The third-largest advantage be the present invention be watered rear working solution be it is clear
Clear prescribed liquid gives people a kind of impression that Environmental Safety is nontoxic, directly enhances the use confidence of user.The fourth-largest advantage
It is the practical cutting efficiency of this product fast wire winding up to 8000mm2/ h, cutting speed can be improved 10% compared with existing product.It is the fifth-largest excellent
Gesture is reachable -15 DEG C of concentrate cloud point of the present invention, is more advantageous under cryogenic conditions and cold district and uses.
The above is only embodiments of the present invention, and the description thereof is more specific and detailed, and but it cannot be understood as right
The limitation of the invention patent range.It should be pointed out that for those of ordinary skill in the art, not departing from the present invention
Under the premise of design, various modifications and improvements can be made, these are all belonged to the scope of protection of the present invention.
Claims (9)
1. a kind of environment-friendly type wire cutting liquid, which is characterized in that each substance including following mass parts:
Wherein, the mass concentration of lye is 50%.
2. a kind of environment-friendly type wire cutting liquid according to claim 1, which is characterized in that each object including following mass parts
Matter:
Wherein, the mass concentration of lye is 50%.
3. a kind of environment-friendly type wire cutting liquid according to claim 1, which is characterized in that it further include antibacterial agent, antibacterial agent
Mass parts are 0.1~10 part.
4. a kind of environment-friendly type wire cutting liquid according to claim 1, which is characterized in that antirust agent is triethanolamine boric acid
Ester.
5. a kind of environment-friendly type wire cutting liquid according to claim 1, which is characterized in that it further include detergent, detergent
Mass parts are 10~20 parts.
6. a kind of preparation method of environment-friendly type wire cutting liquid a method as claimed in any one of claims 1 to 5, which is characterized in that including as follows
Step:
Step 1: weighing rosin and vegetable oil acid by formulation content, heating melting after the two is mixed obtains uniformly mixed melt
Melt liquid；
It is saponified Step 2: lye is at the uniform velocity added dropwise into molten liquid while stirring, after being added dropwise to complete, time segment
Sampling, detects whether oil slick for sample water；The time that saponification terminates, which is subject to, examines no oil slick；
Step 3: other compositions in formula are added into the solution after saponification, and stir evenly after saponification.
7. a kind of preparation method of environment-friendly type wire cutting liquid according to claim 6, which is characterized in that heated in step 1
The temperature of melting is 70 DEG C~90 DEG C.
8. a kind of preparation method of environment-friendly type wire cutting liquid according to claim 6, which is characterized in that heated in step 1
75~80 DEG C of the temperature of melting.
9. a kind of preparation method of environment-friendly type wire cutting liquid according to claim 6, which is characterized in that start in step 2
The time of sampling is 5~8h after being added dropwise to complete.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1035193A1 (en) * | 1997-10-24 | 2000-09-13 | Sadao Futahashi | Metal working water and metal working composition |
| CN102433210A (en) * | 2011-10-27 | 2012-05-02 | 姜堰市华润化工厂 | Water-based working liquid for electrical discharge wire cutting and preparation method thereof |
| CN103184094A (en) * | 2011-12-29 | 2013-07-03 | 辽宁奥克化学股份有限公司 | Cooling liquid for diamond wire cutting technology |
| CN104164295A (en) * | 2014-06-23 | 2014-11-26 | 通懋自动化设备襄阳有限责任公司 | Cutting working fluid of numerically controlled line-cutting machine, and preparation method thereof |
| CN104818105A (en) * | 2015-05-07 | 2015-08-05 | 黄乐 | Working fluid for wire cutting |
-
2017
- 2017-06-28 CN CN201710507497.XA patent/CN107267274B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1035193A1 (en) * | 1997-10-24 | 2000-09-13 | Sadao Futahashi | Metal working water and metal working composition |
| CN102433210A (en) * | 2011-10-27 | 2012-05-02 | 姜堰市华润化工厂 | Water-based working liquid for electrical discharge wire cutting and preparation method thereof |
| CN103184094A (en) * | 2011-12-29 | 2013-07-03 | 辽宁奥克化学股份有限公司 | Cooling liquid for diamond wire cutting technology |
| CN104164295A (en) * | 2014-06-23 | 2014-11-26 | 通懋自动化设备襄阳有限责任公司 | Cutting working fluid of numerically controlled line-cutting machine, and preparation method thereof |
| CN104818105A (en) * | 2015-05-07 | 2015-08-05 | 黄乐 | Working fluid for wire cutting |
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