CN108587433A - A kind of water milk coating - Google Patents
A kind of water milk coating Download PDFInfo
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- CN108587433A CN108587433A CN201810555594.0A CN201810555594A CN108587433A CN 108587433 A CN108587433 A CN 108587433A CN 201810555594 A CN201810555594 A CN 201810555594A CN 108587433 A CN108587433 A CN 108587433A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized waters.Preferably, chloral hydrate, hexamethylene diisocyanate and silicol are sufficiently mixed, stir, is reacted 2 hours in the case of 80~100 DEG C, obtain Primary product;Pyridine and methyl silanol potassium are added into Primary product, continues to stir, and be cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Dispersant, wetting agent, filler, lotion and deionized water are added into intermediate product, at room temperature, reacts 1~2 hour, obtains water milk coating.A kind of water milk coating of the present invention and preparation method thereof, compared with traditional coating, water resistance is more preferable, and environmentally protective, and coating uses more preferable, reliable in quality, safety, convenient transportation.
Description
Technical field
The present invention relates to a kind of technical field of coatings, and in particular to a kind of water milk coating.
Background technology
Coating, in the entitled paint of Chinese tradition, so-called coating be coated in the body surface being protected or decorated, and
The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or lotion, add or do not add face
Material, filler add corresponding additive, the thick liquid being formulated with organic solvent or water.Chinese coating circle is more authoritative《It applies
Material technique》What one book was defined as:" coating is a kind of material, and this material can be coated in object with different construction technologies
Part surface forms and adheres to securely, with some strength, continuous solid film.The film common name film formed in this way, also known as paint film
Or coating." easy peeling falls off after the time of coating smeared under normal circumstances used at present has been grown, and influences beauty,
And viscosity is not high.
Invention content
It is an object of the invention to provide a kind of water milk coatings, solve one or more of the above-mentioned prior art problem.
A kind of water milk coating according to the present invention, including following component, chloral hydrate, hexa-methylene diisocyanate
Ester, silicol, pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water.
Preferably, include the component of following parts by weight, 20~40 parts of chloral hydrate, hexamethylene diisocyanate 10
~20 parts, 8~12 parts of silicol, 6~12 parts of pyridine, 4~8 parts of methyl silanol potassium, 2~4 parts of dispersant, wetting agent 4~6
100~200 parts of part, 2~4 parts of filler and deionized water.
Preferably, include the component of following parts by weight, 30 parts of chloral hydrate, 15 parts of hexamethylene diisocyanate,
10 parts of silicol, 9 parts of pyridine, 6 parts of methyl silanol potassium, 3 parts of dispersant, 5 parts of wetting agent, 3 parts of filler and deionized water 150
Part.
Preferably, the dispersant is polyether polyurethane-acrylate, polyester polyurethane acrylate or terminal hydroxy group
One kind in polybutadiene-based polyurethane acrylate.
Preferably, the wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
Preferably, the weight part ratio of the composition of the hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:
1。
Preferably, the filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Preferably, the lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
Preferably, further include fluorescent whitening agent.Brightening agent is 1- (to methanesulfonylphenYl) -3- (to chlorophenyl) pyrazoles
Quinoline.
A kind of water milk coating of the present invention and preparation method thereof, compared with traditional coating, water resistance is more preferable, and
Environmentally protective, for coating using more preferable, reliable in quality, coating viscosities height is not easily to fall off.
Specific implementation mode
The present invention is described in more detail below.
Embodiment 1
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes
20 parts of aldehyde, 10 parts of hexamethylene diisocyanate, 8 parts of silicol, 6 parts of pyridine, 4 parts of methyl silanol potassium, 2 parts of dispersant, profit
100 parts of 4 parts of humectant, 2 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 80 DEG C, obtain Primary product;Pyridine and methyl silicon are added into Primary product
Potassium alcoholate continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Dispersant, profit are added into intermediate product
Humectant, filler, lotion and deionized water react 1 hour at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly-
One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 2
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes
30 parts of aldehyde, 15 parts of hexamethylene diisocyanate, 10 parts of silicol, 9 parts of pyridine, 6 parts of methyl silanol potassium, 3 parts of dispersant, profit
150 parts of 5 parts of humectant, 3 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 90 DEG C, obtain Primary product;Pyridine and methyl silicon are added into Primary product
Potassium alcoholate continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Dispersant, profit are added into intermediate product
Humectant, filler, lotion and deionized water react 1.5 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly-
One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 3
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes
40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant,
200 parts of 6 parts of wetting agent, 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product
Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant,
Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly-
One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 4
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes
40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 6 parts of wetting agent,
200 parts of 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product
Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant,
Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 5
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes
40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant,
200 parts of 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product
Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant,
Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly-
One kind in urethane acrylate.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 6
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, deionized water, parts by weight of component is as follows, chloral hydrate 40
Part, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant, wetting
200 parts of 6 parts of agent, 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product
Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant,
Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly-
One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
It further include fluorescent whitening agent.
Embodiment 7
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole
Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes
40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant,
200 parts of 6 parts of wetting agent, 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled
Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product
Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant,
Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly-
One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
Experimental data compares:General paint adhesion intensity is 0.6-0.75MPa
Embodiment 1, adhesion strength 0.95MPa;Embodiment 2, adhesion strength 0.98MPa;
Embodiment 3, adhesion strength 0.94MPa;Embodiment 4, adhesion strength 0.81MPa;
Embodiment 5, adhesion strength 0.78MPa;Embodiment 6, adhesion strength 0.79MPa;
Embodiment 7, adhesion strength 0.96MPa, the coating yellowish in embodiment 7.
It is compared by above-mentioned experimental data it is found that embodiment 1, embodiment 2 and embodiment 3 are strong more than general paint adhesion
Degree, and also greater than the adhesion strength in 3~embodiment of embodiment 6, and lack fluorescent whitening agent in embodiment 7, in adhesion strength
On have no effect on, only influence color.
The above is only the preferred embodiment of the present invention, it is noted that those skilled in the art, not
Under the premise of being detached from the invention design, several similar modification and improvement can also be made, these also should be regarded as the present invention
Protection domain within.
Claims (9)
1. a kind of water milk coating, which is characterized in that including following component, chloral hydrate, hexamethylene diisocyanate, hydroxyl
Base silane, pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water.
2. a kind of water milk coating according to claim 1 and, which is characterized in that include the component of following parts by weight, be hydrated trichlorine
20~40 parts of acetaldehyde, 10~20 parts of hexamethylene diisocyanate, 8~12 parts of silicol, 6~12 parts of pyridine, methyl silanol
100~200 parts of 4~8 parts of potassium, 2~4 parts of dispersant, 4~6 parts of wetting agent, 2~4 parts of filler and deionized water.
3. according to a kind of water milk coating shown in claim 2, which is characterized in that include the component of following parts by weight, hydration three
30 parts of chloroacetaldehyde, 15 parts of hexamethylene diisocyanate, 10 parts of silicol, 9 parts of pyridine, 6 parts of methyl silanol potassium, dispersant 3
Part, 5 parts of wetting agent, 3 parts of filler and 150 parts of deionized water.
4. according to a kind of water milk coating shown in claim 3, which is characterized in that the dispersant is polyether polyurethane propylene
One kind in acid esters, polyester polyurethane acrylate or Hydroxyl-terminated Polybutadiene Polyurethane acrylate.
5. according to a kind of water milk coating shown in claim 3, which is characterized in that the wetting agent is hydroxyethyl cellulose, three
The composition of poly cyanamid and methacrylic acid.
6. according to a kind of water milk coating shown in claim 3, which is characterized in that the hydroxyethyl cellulose, melamine and
The weight part ratio of the composition of methacrylic acid is 1:2:1.
7. according to a kind of water milk coating shown in claim 3, which is characterized in that the filler be Paris white, talcum powder,
At least one of kaolin, barium sulfate and mica powder.
8. according to a kind of water milk coating shown in claim 3, which is characterized in that the lotion is pure-acrylic emulsion or phenylpropyl alcohol breast
Liquid.
9. a kind of water milk coating according to claim 1, which is characterized in that further include fluorescent whitening agent.
Priority Applications (1)
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CN201810555594.0A CN108587433A (en) | 2018-06-01 | 2018-06-01 | A kind of water milk coating |
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CN201810555594.0A CN108587433A (en) | 2018-06-01 | 2018-06-01 | A kind of water milk coating |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103614032A (en) * | 2013-12-10 | 2014-03-05 | 广州富美奥涂料有限公司 | Water-based paint |
CN104293152A (en) * | 2013-03-22 | 2015-01-21 | 吴小再 | Preparation method of paint |
-
2018
- 2018-06-01 CN CN201810555594.0A patent/CN108587433A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104293152A (en) * | 2013-03-22 | 2015-01-21 | 吴小再 | Preparation method of paint |
CN103614032A (en) * | 2013-12-10 | 2014-03-05 | 广州富美奥涂料有限公司 | Water-based paint |
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Application publication date: 20180928 |