CN108587433A - A kind of water milk coating - Google Patents

A kind of water milk coating Download PDF

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Publication number
CN108587433A
CN108587433A CN201810555594.0A CN201810555594A CN108587433A CN 108587433 A CN108587433 A CN 108587433A CN 201810555594 A CN201810555594 A CN 201810555594A CN 108587433 A CN108587433 A CN 108587433A
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China
Prior art keywords
parts
filler
water
dispersant
water milk
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Withdrawn
Application number
CN201810555594.0A
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Chinese (zh)
Inventor
虞保海
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Haian Dongyyang Tongda Auto Accessories Co Ltd
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Haian Dongyyang Tongda Auto Accessories Co Ltd
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Priority to CN201810555594.0A priority Critical patent/CN108587433A/en
Publication of CN108587433A publication Critical patent/CN108587433A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized waters.Preferably, chloral hydrate, hexamethylene diisocyanate and silicol are sufficiently mixed, stir, is reacted 2 hours in the case of 80~100 DEG C, obtain Primary product;Pyridine and methyl silanol potassium are added into Primary product, continues to stir, and be cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Dispersant, wetting agent, filler, lotion and deionized water are added into intermediate product, at room temperature, reacts 1~2 hour, obtains water milk coating.A kind of water milk coating of the present invention and preparation method thereof, compared with traditional coating, water resistance is more preferable, and environmentally protective, and coating uses more preferable, reliable in quality, safety, convenient transportation.

Description

A kind of water milk coating
Technical field
The present invention relates to a kind of technical field of coatings, and in particular to a kind of water milk coating.
Background technology
Coating, in the entitled paint of Chinese tradition, so-called coating be coated in the body surface being protected or decorated, and The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or lotion, add or do not add face Material, filler add corresponding additive, the thick liquid being formulated with organic solvent or water.Chinese coating circle is more authoritative《It applies Material technique》What one book was defined as:" coating is a kind of material, and this material can be coated in object with different construction technologies Part surface forms and adheres to securely, with some strength, continuous solid film.The film common name film formed in this way, also known as paint film Or coating." easy peeling falls off after the time of coating smeared under normal circumstances used at present has been grown, and influences beauty, And viscosity is not high.
Invention content
It is an object of the invention to provide a kind of water milk coatings, solve one or more of the above-mentioned prior art problem.
A kind of water milk coating according to the present invention, including following component, chloral hydrate, hexa-methylene diisocyanate Ester, silicol, pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water.
Preferably, include the component of following parts by weight, 20~40 parts of chloral hydrate, hexamethylene diisocyanate 10 ~20 parts, 8~12 parts of silicol, 6~12 parts of pyridine, 4~8 parts of methyl silanol potassium, 2~4 parts of dispersant, wetting agent 4~6 100~200 parts of part, 2~4 parts of filler and deionized water.
Preferably, include the component of following parts by weight, 30 parts of chloral hydrate, 15 parts of hexamethylene diisocyanate, 10 parts of silicol, 9 parts of pyridine, 6 parts of methyl silanol potassium, 3 parts of dispersant, 5 parts of wetting agent, 3 parts of filler and deionized water 150 Part.
Preferably, the dispersant is polyether polyurethane-acrylate, polyester polyurethane acrylate or terminal hydroxy group One kind in polybutadiene-based polyurethane acrylate.
Preferably, the wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
Preferably, the weight part ratio of the composition of the hydroxyethyl cellulose, melamine and methacrylic acid is 1:2: 1。
Preferably, the filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Preferably, the lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
Preferably, further include fluorescent whitening agent.Brightening agent is 1- (to methanesulfonylphenYl) -3- (to chlorophenyl) pyrazoles Quinoline.
A kind of water milk coating of the present invention and preparation method thereof, compared with traditional coating, water resistance is more preferable, and Environmentally protective, for coating using more preferable, reliable in quality, coating viscosities height is not easily to fall off.
Specific implementation mode
The present invention is described in more detail below.
Embodiment 1
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes 20 parts of aldehyde, 10 parts of hexamethylene diisocyanate, 8 parts of silicol, 6 parts of pyridine, 4 parts of methyl silanol potassium, 2 parts of dispersant, profit 100 parts of 4 parts of humectant, 2 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 80 DEG C, obtain Primary product;Pyridine and methyl silicon are added into Primary product Potassium alcoholate continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Dispersant, profit are added into intermediate product Humectant, filler, lotion and deionized water react 1 hour at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly- One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 2
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes 30 parts of aldehyde, 15 parts of hexamethylene diisocyanate, 10 parts of silicol, 9 parts of pyridine, 6 parts of methyl silanol potassium, 3 parts of dispersant, profit 150 parts of 5 parts of humectant, 3 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 90 DEG C, obtain Primary product;Pyridine and methyl silicon are added into Primary product Potassium alcoholate continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Dispersant, profit are added into intermediate product Humectant, filler, lotion and deionized water react 1.5 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly- One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 3
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes 40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant, 200 parts of 6 parts of wetting agent, 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant, Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly- One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 4
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes 40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 6 parts of wetting agent, 200 parts of 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant, Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 5
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes 40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant, 200 parts of 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant, Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly- One kind in urethane acrylate.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
It further include fluorescent whitening agent.
Embodiment 6
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, deionized water, parts by weight of component is as follows, chloral hydrate 40 Part, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant, wetting 200 parts of 6 parts of agent, 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant, Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly- One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
It further include fluorescent whitening agent.
Embodiment 7
A kind of water milk coating, including following component, chloral hydrate, hexamethylene diisocyanate, silicol, pyrrole Pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water, parts by weight of component is as follows, is hydrated three chloroethenes 40 parts of aldehyde, 20 parts of hexamethylene diisocyanate, 12 parts of silicol, 12 parts of pyridine, 8 parts of methyl silanol potassium, 4 parts of dispersant, 200 parts of 6 parts of wetting agent, 4 parts of filler and deionized water.
The preparation method of water milk coating is as follows:Chloral hydrate, hexamethylene diisocyanate and silicol are filled Mixing, stirring is divided to be reacted 2 hours in the case of 100 DEG C, obtain Primary product;Pyridine and methyl are added into Primary product Silanol potassium continues to stir, and is cooled at 60 DEG C, reacts 1 hour, obtains intermediate product;Into intermediate product be added dispersant, Wetting agent, filler, lotion and deionized water react 2 hours at room temperature, obtain water milk coating.
Dispersant is that polyether polyurethane-acrylate, polyester polyurethane acrylate or end hydroxy butadiene type are poly- One kind in urethane acrylate.
Wetting agent is the composition of hydroxyethyl cellulose, melamine and methacrylic acid.
The weight part ratio of the composition of hydroxyethyl cellulose, melamine and methacrylic acid is 1:2:1.
Filler is at least one of Paris white, talcum powder, kaolin, barium sulfate and mica powder.
Lotion is pure-acrylic emulsion or styrene-acrylic emulsion.
Experimental data compares:General paint adhesion intensity is 0.6-0.75MPa
Embodiment 1, adhesion strength 0.95MPa;Embodiment 2, adhesion strength 0.98MPa;
Embodiment 3, adhesion strength 0.94MPa;Embodiment 4, adhesion strength 0.81MPa;
Embodiment 5, adhesion strength 0.78MPa;Embodiment 6, adhesion strength 0.79MPa;
Embodiment 7, adhesion strength 0.96MPa, the coating yellowish in embodiment 7.
It is compared by above-mentioned experimental data it is found that embodiment 1, embodiment 2 and embodiment 3 are strong more than general paint adhesion Degree, and also greater than the adhesion strength in 3~embodiment of embodiment 6, and lack fluorescent whitening agent in embodiment 7, in adhesion strength On have no effect on, only influence color.
The above is only the preferred embodiment of the present invention, it is noted that those skilled in the art, not Under the premise of being detached from the invention design, several similar modification and improvement can also be made, these also should be regarded as the present invention Protection domain within.

Claims (9)

1. a kind of water milk coating, which is characterized in that including following component, chloral hydrate, hexamethylene diisocyanate, hydroxyl Base silane, pyridine, methyl silanol potassium, dispersant, wetting agent, filler, lotion and deionized water.
2. a kind of water milk coating according to claim 1 and, which is characterized in that include the component of following parts by weight, be hydrated trichlorine 20~40 parts of acetaldehyde, 10~20 parts of hexamethylene diisocyanate, 8~12 parts of silicol, 6~12 parts of pyridine, methyl silanol 100~200 parts of 4~8 parts of potassium, 2~4 parts of dispersant, 4~6 parts of wetting agent, 2~4 parts of filler and deionized water.
3. according to a kind of water milk coating shown in claim 2, which is characterized in that include the component of following parts by weight, hydration three 30 parts of chloroacetaldehyde, 15 parts of hexamethylene diisocyanate, 10 parts of silicol, 9 parts of pyridine, 6 parts of methyl silanol potassium, dispersant 3 Part, 5 parts of wetting agent, 3 parts of filler and 150 parts of deionized water.
4. according to a kind of water milk coating shown in claim 3, which is characterized in that the dispersant is polyether polyurethane propylene One kind in acid esters, polyester polyurethane acrylate or Hydroxyl-terminated Polybutadiene Polyurethane acrylate.
5. according to a kind of water milk coating shown in claim 3, which is characterized in that the wetting agent is hydroxyethyl cellulose, three The composition of poly cyanamid and methacrylic acid.
6. according to a kind of water milk coating shown in claim 3, which is characterized in that the hydroxyethyl cellulose, melamine and The weight part ratio of the composition of methacrylic acid is 1:2:1.
7. according to a kind of water milk coating shown in claim 3, which is characterized in that the filler be Paris white, talcum powder, At least one of kaolin, barium sulfate and mica powder.
8. according to a kind of water milk coating shown in claim 3, which is characterized in that the lotion is pure-acrylic emulsion or phenylpropyl alcohol breast Liquid.
9. a kind of water milk coating according to claim 1, which is characterized in that further include fluorescent whitening agent.
CN201810555594.0A 2018-06-01 2018-06-01 A kind of water milk coating Withdrawn CN108587433A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810555594.0A CN108587433A (en) 2018-06-01 2018-06-01 A kind of water milk coating

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Application Number Priority Date Filing Date Title
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103614032A (en) * 2013-12-10 2014-03-05 广州富美奥涂料有限公司 Water-based paint
CN104293152A (en) * 2013-03-22 2015-01-21 吴小再 Preparation method of paint

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104293152A (en) * 2013-03-22 2015-01-21 吴小再 Preparation method of paint
CN103614032A (en) * 2013-12-10 2014-03-05 广州富美奥涂料有限公司 Water-based paint

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Application publication date: 20180928