CN108587359A - A kind of water-repellent paint and preparation method thereof with long-acting killing mosquito worm's ovum function - Google Patents

A kind of water-repellent paint and preparation method thereof with long-acting killing mosquito worm's ovum function Download PDF

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Publication number
CN108587359A
CN108587359A CN201810729842.9A CN201810729842A CN108587359A CN 108587359 A CN108587359 A CN 108587359A CN 201810729842 A CN201810729842 A CN 201810729842A CN 108587359 A CN108587359 A CN 108587359A
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parts
water
long
repellent paint
mosquito worm
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CN201810729842.9A
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Chinese (zh)
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曹迈宇
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CHANGSHA DAYU BUILDING MATERIALS TECHNOLOGY Co Ltd
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CHANGSHA DAYU BUILDING MATERIALS TECHNOLOGY Co Ltd
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Priority to CN201810729842.9A priority Critical patent/CN108587359A/en
Publication of CN108587359A publication Critical patent/CN108587359A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of water-repellent paint with long-acting killing mosquito worm's ovum function, including liquid material and powder, wherein liquid material include following components in parts by weight:400 500 parts of pure third polymer emulsion, 300 400 parts of vinyl acetate ethylene copolymer emulsion, 100 200 parts of water, 35 parts of dispersant, 12 parts of preservative, 37 parts of antifoaming agent;Wherein powder includes following components in parts by weight:30 40 parts of temperature sensitive Microencapsulated Slow insecticide, 100 200 parts of high alumina cement, 300 450 parts of Portland cement, 100 200 parts of calcium carbonate, 200 300 parts of quartz sand, 13 parts of water-reducing agent.There is the present invention following advantageous effect to be:When environment temperature is 20 DEG C 35 DEG C(22 DEG C 32 DEG C are suitble to survival temperature section for mosquito worm's ovum), the present invention contained by temperature sensitive capsule sustained release insecticide continue into ponding discharge deinsectization component, be automatically stopped release insect disinfestation component beyond above-mentioned temperature range microcapsules.

Description

A kind of water-repellent paint and preparation method thereof with long-acting killing mosquito worm's ovum function
Technical field
The present invention relates to water-repellent paint technical fields, and in particular to a kind of with the long-acting waterproof for killing mosquito worm's ovum function Coating and preparation method thereof.
Background technology
" city have water is then elegant, occupy have water then clever ", various water landscapes, roof in modern architecture group(It is indoor)Garden etc. obtains It fully and is widely applied, meets the phychology that people pursue nature, back to nature, but ponding also becomes in water landscape simultaneously Such as mosquito pest oviposition procreation and spread the disease(Such as:The various acutes heavy type infectious disease such as dengue fever, encephalitis malaria)Temperature Bed, and the method for administering landscape ponding disease now mostly manually refreshes the water periodically, launches insecticide, liquid fumicants etc., these are only Only it is short-term deinsectization, does not have and permanently effective to mosquito ovum in ponding kill function.Therefore a kind of i.e. tool water proofing property is provided, again The water-repellent paint for having long-acting mosquito-killing disease becomes urgent problem in the industry.
It is energy as Chinese patent application discloses a kind of revealed technologies that deinsectization coating mainly solves of CN102863830A Enough mould proof, deinsectizations, free from extraneous odour are primarily adapted for use in the ground such as fermentation plant and metope, do not have water resistance.
If Chinese patent application discloses a kind of revealed Antibacterial waterproof deinsectization coatings of CN103613969A, do not have long-term Impregnate property, be not suitable for for a long time water landscape etc. be immersed in water for a long time or humidity environment in use.
It is suitable for water-based paint class coating industry as Chinese patent application discloses the revealed one kind of CN105038461A, no Has water resistance.
Invention content
The purpose of the present invention is to provide a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function and its preparation side Method, to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides the following technical solutions:
A kind of water-repellent paint with long-acting killing mosquito worm's ovum function, including liquid material and powder, wherein liquid material are in parts by weight Including following components:400-500 parts of pure third polymer emulsion, 300-400 parts of vinyl acetate-ethylene copolymerization emulsions, water 100-200 Part, 3-5 parts of dispersant, 1-2 parts of preservative, 3-7 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:30-40 parts of temperature sensitive Microencapsulated Slow insecticide, high alumina cement 100- 200 parts, 300-450 parts of Portland cement, 100-200 parts of calcium carbonate, 200-300 parts of quartz sand, 1-3 parts of water-reducing agent.
It is as further technical solution of the invention:Including liquid material and powder, wherein liquid material include in parts by weight with Lower component:450 parts of pure third polymer emulsion, 350 parts of vinyl acetate-ethylene copolymerization emulsions, 150 parts of water, 4 parts of dispersant, anti-corrosion 1.5 parts of agent, 5 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:It is 35 parts of temperature sensitive Microencapsulated Slow insecticide, 150 parts of high alumina cement, general Logical 375 parts of portland cement, 150 parts of calcium carbonate, 250 parts of quartz sand, 2 parts of water-reducing agent.
It is as further technical solution of the invention:In pure third polymer emulsion polymer content be more than 50%, Minimum film formation temperature is 10 DEG C.
It is as further technical solution of the invention:Polymer content is more than in the vinyl acetate-ethylene lotion 50%。
It is as further technical solution of the invention:The dispersant is polyurethane-type dispersant.
It is as further technical solution of the invention:The antifoaming agent is organic silicon antifoaming agent.
It is as further technical solution of the invention:The temperature sensitive temperature sensitive temperature of Microencapsulated Slow insecticide environment is 20 DEG C -35 DEG C, temperature sensitive Microencapsulated Slow insecticide is modified juvenile hormone insecticides.
It is as further technical solution of the invention:The high alumina cement is 525 high alumina white cements, the ordinary silicon Acid salt cement is 42.5 Portland cements.
It is as further technical solution of the invention:The water-reducing agent is powdery polycarboxylic acid high-performance water reducer.
A kind of preparation method with the long-acting water-repellent paint for killing mosquito worm's ovum function, includes the following steps:
(One)By pure third polymer emulsion, vinyl acetate-ethylene copolymerization emulsions, dispersant, antifoaming agent, preservative, water, thickener Mixing is stirred 20 minutes with the rotating speed of 300-400r/min and obtains uniform liquid material;
(Two)Temperature sensitive Microencapsulated Slow insecticide, high alumina cement, ordinary portland cement, calcium carbonate, quartz sand, water-reducing agent are mixed Obtain powder;
(Three)It is 1 by the mass ratio of liquid material and powder:The electric blender that 1.5-2 is added to stirs that obtain no particle within 5 minutes uniform Slurries.
There is the present invention following advantageous effect to be:
1, when environment temperature is 20 DEG C -35 DEG C(22 DEG C -32 DEG C are suitble to survival temperature section for mosquito worm's ovum), institute of the present invention The temperature sensitive capsule sustained release insecticide contained continues to discharge deinsectization component into ponding, is automatically stopped beyond above-mentioned temperature range microcapsules Discharge insect disinfestation component;
2, when environment temperature is 20 DEG C -35 DEG C, in 3 millimeters of coatings of the invention microcapsules sustainable insecticide release time be - 14400 hours 12000 hours;
3, temperature sensitive Microencapsulated Slow insecticide in the present invention, release 100% medicament required time is 120-168 hours;
4, temperature sensitive Microencapsulated Slow insecticide is juvenile hormone insecticides in the present invention, which being capable of effective killing mosquito Larva, and have the advantages that it is free from environmental pollution, to person poultry harmless.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.
Embodiment 1:
A kind of water-repellent paint with long-acting killing mosquito worm's ovum function, including liquid material and powder, wherein liquid material are in parts by weight Including following components:400 parts of pure third polymer emulsion, 300 parts of vinyl acetate-ethylene copolymerization emulsions, 100 parts of water, dispersant 3 Part, 1 part of preservative, 3 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:It is 30 parts of temperature sensitive Microencapsulated Slow insecticide, 100 parts of high alumina cement, general Logical 300 parts of portland cement, 100 parts of calcium carbonate, 200 parts of quartz sand, 1 part of water-reducing agent.
A kind of preparation method with the long-acting water-repellent paint for killing mosquito worm's ovum function, includes the following steps:
(One)By pure third polymer emulsion, vinyl acetate-ethylene copolymerization emulsions, dispersant, antifoaming agent, preservative, water, thickener Mixing is stirred 20 minutes with the rotating speed of 300-400r/min and obtains uniform liquid material;
(Two)Temperature sensitive Microencapsulated Slow insecticide, high alumina cement, ordinary portland cement, calcium carbonate, quartz sand, water-reducing agent are mixed Obtain powder;
(Three)It is 1 by the mass ratio of liquid material and powder:1.5 are added to electric blender stirring obtains without evengranular for 5 minutes Slurries.
By the water-repellent paint with long-acting killing mosquito worm's ovum function according to liquid powder weight/power ratio than 1:After 1.5 mixing, according to GB/T23445-2009《Polymer cement waterproof paint》Middle experimental method is detected, and is obtained specific targets and is:Solid content >=70%, tensile strength >=1.8MPa, elongation at break >=80%, adhesion strength >=0.7MPa.
Embodiment 2:
A kind of water-repellent paint with long-acting killing mosquito worm's ovum function, including liquid material and powder, wherein liquid material are in parts by weight Including following components:500 parts of pure third polymer emulsion, 400 parts of vinyl acetate-ethylene copolymerization emulsions, 200 parts of water, dispersant 5 Part, 2 parts of preservative, 7 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:It is 40 parts of temperature sensitive Microencapsulated Slow insecticide, 200 parts of high alumina cement, general Logical 450 parts of portland cement, 200 parts of calcium carbonate, 300 parts of quartz sand, 3 parts of water-reducing agent.
A kind of preparation method with the long-acting water-repellent paint for killing mosquito worm's ovum function, includes the following steps:
(One)By pure third polymer emulsion, vinyl acetate-ethylene copolymerization emulsions, dispersant, antifoaming agent, preservative, water, thickener Mixing is stirred 20 minutes with the rotating speed of 300-400r/min and obtains uniform liquid material;
(Two)Temperature sensitive Microencapsulated Slow insecticide, high alumina cement, ordinary portland cement, calcium carbonate, quartz sand, water-reducing agent are mixed Obtain powder;
(Three)It is 1 by the mass ratio of liquid material and powder:2 are added to electric blender stirring obtains without evengranular slurry for 5 minutes Liquid.
Liquid powder will be pressed than 1 with the long-acting water-repellent paint for killing mosquito worm's ovum function:2 after mixing, in 1m*1m*1m With 3 millimeters of thick coatings of hairbrush brushing in volume concrete experimental box, 800 kilograms of ponding are filled with after 48 hours dry, and put It is placed in 20 DEG C of environment of mosquito more than -35 DEG C 240 hours, checks worm's ovum number and survival number in ponding, obtaining specific targets is: Worm's ovum death rate > 96%.
Embodiment 3:
A kind of water-repellent paint with long-acting killing mosquito worm's ovum function, including liquid material and powder, wherein liquid material are in parts by weight Including following components:450 parts of pure third polymer emulsion, 350 parts of vinyl acetate-ethylene copolymerization emulsions, 150 parts of water, dispersant 4 Part, 1.5 parts of preservative, 5 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:It is 35 parts of temperature sensitive Microencapsulated Slow insecticide, 150 parts of high alumina cement, general Logical 375 parts of portland cement, 150 parts of calcium carbonate, 250 parts of quartz sand, 2 parts of water-reducing agent.
A kind of preparation method with the long-acting water-repellent paint for killing mosquito worm's ovum function, includes the following steps:
(One)By pure third polymer emulsion, vinyl acetate-ethylene copolymerization emulsions, dispersant, antifoaming agent, preservative, water, thickener Mixing is stirred 20 minutes with the rotating speed of 300-400r/min and obtains uniform liquid material;
(Two)Temperature sensitive Microencapsulated Slow insecticide, high alumina cement, ordinary portland cement, calcium carbonate, quartz sand, water-reducing agent are mixed Obtain powder;
(Three)It is 1 by the mass ratio of liquid material and powder:1.8 are added to electric blender stirring obtains without evengranular for 5 minutes Slurries.
By the water-repellent paint with long-acting killing mosquito ovum function according to liquid powder than 1:1.8 after mixing, according to GB/ T23445-2009《Polymer cement waterproof paint》Middle experimental method is made 3 piece of 10 ㎝ * 10cm*3mm and tests sample film, by 3 pieces of realities Test sample film be separately immersed in water and be respectively placed in 10 DEG C, 26 DEG C, stand 3 hours in 40 DEG C of environment temperatures, detect in 3 sample films The quality of insecticide contained by water obtains specific targets:0.1 micrograms of Pesticide content </m3 in 10 DEG C and 40 DEG C of containers, 26 DEG C Water Pesticide content is >=10 micrograms/m3 in container.
Patent of the present invention discloses a kind of water-repellent paint with harmful mosquito worm's ovum function in long-acting killing ponding, not only Has water-proof function, under specific temperature conditions, the present invention can discharge nontoxic, pollution-free slow-release pesticide as ponding for a long time In, to achieve the purpose that long-acting to kill mosquito worm's ovum in ponding.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (10)

1. a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that including liquid material and powder, wherein liquid Material includes following components in parts by weight:400-500 parts of pure third polymer emulsion, vinyl acetate-ethylene copolymerization emulsions 300-400 Part, 100-200 parts of water, 3-5 parts of dispersant, 1-2 parts of preservative, 3-7 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:30-40 parts of temperature sensitive Microencapsulated Slow insecticide, high alumina cement 100- 200 parts, 300-450 parts of Portland cement, 100-200 parts of calcium carbonate, 200-300 parts of quartz sand, 1-3 parts of water-reducing agent.
2. according to claim 1 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that packet Liquid material and powder are included, wherein liquid material includes following components in parts by weight:450 parts of pure third polymer emulsion, vinyl acetate-ethylene 350 parts of copolymer emulsion, 150 parts of water, 4 parts of dispersant, 1.5 parts of preservative, 5 parts of antifoaming agent;
Wherein powder includes following components in parts by weight:It is 35 parts of temperature sensitive Microencapsulated Slow insecticide, 150 parts of high alumina cement, general Logical 375 parts of portland cement, 150 parts of calcium carbonate, 250 parts of quartz sand, 2 parts of water-reducing agent.
3. a kind of water-repellent paint with long-acting killing mosquito worm's ovum function according to claim 1 or 2, feature exist In it is 10 DEG C that polymer content, which is more than 50%, minimum film formation temperature, in pure third polymer emulsion.
4. according to claim 3 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that institute It states polymer content in vinyl acetate-ethylene lotion and is more than 50%.
5. according to claim 1 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that institute It is polyurethane-type dispersant to state dispersant.
6. according to claim 5 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that institute It is organic silicon antifoaming agent to state antifoaming agent.
7. according to claim 1 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that institute It is 20 DEG C -35 DEG C to state the temperature sensitive temperature sensitive temperature of Microencapsulated Slow insecticide environment, and temperature sensitive Microencapsulated Slow insecticide is modified guarantor children Hormone insecticides.
8. according to claim 7 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that institute It is 525 high alumina white cements to state high alumina cement, and the Portland cement is 42.5 Portland cements.
9. according to claim 1 a kind of with the long-acting water-repellent paint for killing mosquito worm's ovum function, which is characterized in that institute It is powdery polycarboxylic acid high-performance water reducer to state water-reducing agent.
10. a kind of preparing the method as described in claim 1 with the long-acting water-repellent paint for killing mosquito worm's ovum function, spy Sign is, includes the following steps:
(1) by pure third polymer emulsion, vinyl acetate-ethylene copolymerization emulsions, dispersant, antifoaming agent, preservative, water, thickener Mixing is stirred 20 minutes with the rotating speed of 300-400r/min and obtains uniform liquid material;
(2) temperature sensitive Microencapsulated Slow insecticide, high alumina cement, ordinary portland cement, calcium carbonate, quartz sand, water-reducing agent are mixed Obtain powder;
(3) it is 1 by the mass ratio of liquid material and powder:The electric blender that 1.5-2 is added to stirs that obtain no particle within 5 minutes uniform Slurries.
CN201810729842.9A 2018-07-05 2018-07-05 A kind of water-repellent paint and preparation method thereof with long-acting killing mosquito worm's ovum function Pending CN108587359A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1144243A (en) * 1996-03-19 1997-03-05 陈秋竹 Multifunctional health-care latex paint with insectifuge
CN101392109A (en) * 2008-11-07 2009-03-25 董庆华 Long acting sustained-release insect prevention additive agent for inner wall paint and preparation method thereof
CN101429401A (en) * 2007-11-06 2009-05-13 董善刚 High-performance waterproof coating material of cement based polymer
CN104231867A (en) * 2014-08-12 2014-12-24 海南红杉科创实业有限公司 Anti-termite inorganic flake waterborne epoxy resin coating
CN105062281A (en) * 2015-08-17 2015-11-18 惠州东方雨虹建筑材料有限责任公司 I-type environment-friendly two-component polymer cement waterproof paint and preparation method
CN107686297A (en) * 2016-08-04 2018-02-13 立邦涂料(中国)有限公司 A kind of net taste type bicomponent cement base waterproof material of environmental protection

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1144243A (en) * 1996-03-19 1997-03-05 陈秋竹 Multifunctional health-care latex paint with insectifuge
CN101429401A (en) * 2007-11-06 2009-05-13 董善刚 High-performance waterproof coating material of cement based polymer
CN101392109A (en) * 2008-11-07 2009-03-25 董庆华 Long acting sustained-release insect prevention additive agent for inner wall paint and preparation method thereof
CN104231867A (en) * 2014-08-12 2014-12-24 海南红杉科创实业有限公司 Anti-termite inorganic flake waterborne epoxy resin coating
CN105062281A (en) * 2015-08-17 2015-11-18 惠州东方雨虹建筑材料有限责任公司 I-type environment-friendly two-component polymer cement waterproof paint and preparation method
CN107686297A (en) * 2016-08-04 2018-02-13 立邦涂料(中国)有限公司 A kind of net taste type bicomponent cement base waterproof material of environmental protection

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
甘肃农业大学: "《草原保护学 第二分册》", 30 November 1984, 农业出版社 *

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Application publication date: 20180928

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