CN108587128A - A kind of 3D printing pen consumptive material with special-effect - Google Patents
A kind of 3D printing pen consumptive material with special-effect Download PDFInfo
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- CN108587128A CN108587128A CN201810494060.1A CN201810494060A CN108587128A CN 108587128 A CN108587128 A CN 108587128A CN 201810494060 A CN201810494060 A CN 201810494060A CN 108587128 A CN108587128 A CN 108587128A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
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Abstract
The invention discloses a kind of 3D printing pen consumptive material with special-effect, raw material are made of following material：Oligomer, photoinitiator, aided initiating, surfactant, antiplastering aid, suspending agent, light spread powder, special-effect agent.Its material includes according to weight percent：Oligomer 63%~90%, photoinitiator 1%~12%, aided initiating 0.8%~6%, surfactant 1%~7%, antiplastering aid 1%~5%, suspending agent 0.1%~2%, light spread powder 0.5%~2%, special-effect agent 1%~16%.The special-effect agent that the present invention uses makes the consumptive material after solidification that pearly-lustre, bright sudden strain of a muscle, fluorescence, chance temperature discoloration and other effects be presented, it can also be combined with fragrance, there is the consumptive material of specific fragrance again as existing particular color, different exposition needs of the user to this field consumptive material in vision and the sense of taste are met, make product that color diversity, interest and attraction be presented.This is that traditional similar product is not achieved.
Description
Technical field
The invention belongs to 3D printers field more particularly to a kind of 3D printing pen consumptive materials with special-effect.
Background technology
3D printing pen technology is a kind of revolutionary industrial forming technique, for traditional drawing, more lively shape
As increasing children's manipulative ability.Raw material by 3D printers just can straight forming, it is that a kind of digital model file is base
Plinth constructs the technology of object by layer-by-layer printing with adhesive materials such as powdery metal or plastics, be not required to through
The manufacture for crossing mold saves time and the cost of mold manufacturing, with the rapid development of 3D printing techniques, to material
It is required that also rapid improve.Our company has developed that a kind of temperature in use is low, curing rate is fast, the dry and comfortable tack-free safety of cured article
Type 3D printing pen consumptive material.This consumptive material is mixed colours using color/toner to product, but the color unicity of color/toner limits
Expression of the product in vision and the sense of taste is made, usually only common color cannot reach fluorescence, bright sudden strain of a muscle, meet temperature discoloration, tool
There is specific fragrance and other effects, limits the expression of user on the creation in cured article.
In conclusion how inventing a kind of fluorescence, bright dodging, meet temperature discoloration, the 3D printing pen with specific fragrance and other effects
It is a problem to be solved with consumptive material.
Invention content：
The present invention proposes a kind of 3D printing pen consumptive material with special-effect, is formulated by rationalizing, obtaining product has
Fluorescence, meets temperature discoloration, haveing excellent performance with specific fragrance and other effects at bright sudden strain of a muscle.
1. a kind of 3D printing pen consumptive material with special-effect proposed by the present invention, raw material are made of following material：
Oligomer, photoinitiator, aided initiating, surfactant, antiplastering aid, suspending agent, light spread powder, special-effect agent.Its feature
It is, material includes according to weight percent：Oligomer 63%~90%, photoinitiator 1%~12%, aided initiating 0.8%~
6%, surfactant 1%~7%, antiplastering aid 1%~5%, suspending agent 0.1%~2%, light spread powder 0.5%~2%, special-effect agent 1%
~16%.
Preferably, oligomer is polyurethane acrylic resin.
Oligomer is light-cured resin, it is the substrate of photocuring reaction, the year-on-year market price of oligomer that this material uses
Low 20%, reduce product cost.
Photoinitiator is 2,4,6- trimethylbenzoyl phenyl phosphinic acid ethyl esters.
Photoinitiator is the double bond fracture caused inside oligomer, forms free radical, and the use of solidified resin makes finally admittedly
It is big to change toughness of products, is not easily broken.
Aided initiating is ethyl 4-dimethylaminobenzoate.
The use of ethyl 4-dimethylaminobenzoate can help photoinitiator to accelerate the fracture of double bond, accelerate solidification speed
Degree, curing rate control in 20s, meanwhile, the use of aided initiating contributes to the dosage for reducing photoinitiator, since light draws
The product that agent is most expensive in this product dispensing is sent out, the reduction of his dosage makes this product cost further decrease 30%.
Antiplastering aid is palm acid ethyl ester.
The use of antiplastering aid can reduce system viscosity, increase mobility so that product surface after solidification is dry and comfortable not to be glued
Hand.
Inherently a kind of low-viscosity grease of ester, low greasy feeling, surface are clearly not glutinous greasy for palm acid ethyl；It effectively contains
Amount up to 90% is the submissive raw material of ideal for substituting dioctadecyl dimethyl ammonium chloride D1821；It only needs to add water, nothing when preparation
Other raw materials and auxiliary agent need to be compounded, it is easy, quick, it is cost-effective；The salubrious performance of excellent softness, bactericidal property and antistatic property
Energy；Corresponding compatibility, yellowing resistance, dispersibility and rewettability etc.；Biodegradability outstanding, safety and environmental protection.
Surfactant is cocounut oil acid methyl single ethanol amide.
Cocounut oil acid methyl single ethanol amide is nontoxic, irritation is extremely low, with good stability；With various surfactants
There is good compatibility, there is fabulous collaboration tackifying effect, good foaming characteristic and foam stability.Even if higher containing grease
In system, also there is good Efficient Adhesive Promotion；It is skin friendly with tax fat effect；Can prevent under low temperature occur crystallization be precipitated and
Color burn phenomenon under high temperature；High/low temperature viscosity change is steady, and low temperature is not " jelly ", small by pH value variation system viscosity fluctuation；
This product is liquid condition, in water easy dispersing and dissolving, and production operation is easy to use, and surface-active can be also quickly dissolved in without heating
In agent system；Suspending agent is lithium magnesium silicate.
Lithium magnesium silicate has nano microcrystalline structure, and dispersion in water forms nanometer water white transparency thixotropy gel, light transmittance
Up to 99.5% or more, hydration rate is fast, and viscosity moment rises, and situation is thickened after not will produce, and lithium magnesium silicate has thixotropy.Silicon
Sour magnesium lithium gel has the characteristic of this good suspended substance under external force and the unlimited reversible transition of gelinite, while also assigning
Give gelinite excellent spread and film forming.Also there is the ability for transmitting yield value at a low viscosity, therefore dispersed phase is to steady
It is fixed, it can be uniformly distributed in wash.
The colloform texture of lithium magnesium silicate dispersion liquid also provides best suspension for other fine particles in same system
Property, anti-settling agent use is done in the present invention, prevents particle sedimentation caking, it is ensured that system ingredients improve the screening of product pigment
Lid rate.Lithium magnesium silicate compatibility is good negatively charged, with most of anion surfactants and nonionic agent compatibility
It is good, it is good with the nonionic surface active agent cocounut oil acid methyl single ethanol amide compatibility in the present invention.
Light spread powder is to reflect the ultraviolet light of absorption, preferably to cure.Special-effect agent is that system is allowed to have
There are certain color, fragrance so as to attract the attention of people, becoming existing particular color again has the consumptive material of specific fragrance,
Different exposition needs of the user to this field consumptive material in vision and the sense of taste are met, make product that color diversity, entertaining be presented
Property and attraction.
Special-effect agent can be any one in pearl powder, glitter powder, fluorescent powder, temperature change powder.
Pearl powder
Similar to the physical arrangement of pearl；It is the sandwich type piece that natural mica thin slice is cladded with titanium dioxide, di-iron trioxide composition
It is brilliant.Form and aspect and gloss are created by refraction, the transmission to light.Face coat, plastic products can be assigned with deep level
Sense and special reflecting feel can reproduce graceful gloss and color possessed by nature pearl, shell, butterfly, swimming fish and metal,
Its nontoxic, high temperature resistant, light shine, acid and alkali-resistance, it is non-discolouring, do not migrate, be non-conductive.With traditional optical absorption type organic-inorganic face
The metallic pigments of material and optical reflection type compare, and the color production theory of pearlescent pigment is entirely different, so its effect is also only
Special.Pearlescent pigment is the main representative of the optical interference pigment on your kind effort tripodia.
Pearlescent pigment is mixed with more transparent material, more can generate graceful pearly luster, also can with it is saturating in the present invention
Bright resin mixes, and to obtain suitable coloured light, the pearlescent pigment of color series can be various not according to the generation of the mixing principle of color
Same pearly luster.
Pearlescent pigment is nonmetallic functional environment-friendly pigment, and pearly-lustre dry powder is used in the present invention, easily evenly dispersed.
Pearlescent pigment shows different effects in use with the of different sizes of its particle.Generally speaking, particle is got over
Greatly, flicker effect is stronger, and weaker to the covering power of background color；Otherwise particle is smaller, and stronger to the covering power of background color, gloss is more soft
With.
The chemical property of pearlescent pigment is stablized, and is non-metallic pigments, and safety can ensure.And pearlescent pigment is several
Can be applied to all thermoplastics and a part thermosetting plastics, therefore with the present invention resin material compatibility
It is good.
Glitter powder
As a kind of unique finish materials of effect, feature is to enhance the visual effect of product glitter powder, makes surface
Part bumps have levels, more three-dimensional sense；The characteristic of its height flash of light, more so that ornament is dazzlingly beautiful, adds brilliance doubly.It is free of
Metal component, but the optical characteristics of the polymeric membrane due to forming the product, thus the product has change and the light of metal color
There is apparent color change in pool.
It is cut through precision machinery by the high import PET mylars of smart brightness.Shape have hexagon, quadrangle,
Strip and irregular shape.And there are many color is available.
Material：There are tri- kinds of aluminum, PET and PVC using material.High temperature modification glitter powder is produced by aluminum or PET material, different
Material can bear different degrees of high temperature（It is differed by 80 DEG C, 180 DEG C, 300 DEG C）.It is assorted to add protective layer, bright in color, to day
Gas, the variation of temperature and mild corrosion chemicals, have certain resilience.Material can make color plus sealer
Glory is bright, also has certain resistance and temperature tolerance, ep-type material to the mild corrosion of amblent air temperature, temperature.
Aluminum material matter glitter powder is used in the present invention, can be 300 degree with high temperature resistant, acid and alkali-resistance, suitable for the present invention
Resin material.
Fluorescent powder
Fluorescent powder in the present invention uses novel light-storing fluorescence powder, and model MHG-4D is good with resin compatible degree, is suitable for the present invention
Base material.To absorb various visible light 10-20 minutes, you can continuous illumination 10 more than hour, is photic storage in the dark
Light type self-luminescent material realizes self light emission function by absorbing various visible lights, has after-glow brightness height, persistence long, suitable
The advantages that wide, nontoxic, harmless, "dead" with range, and can recycle infinitely.The product can be used as a kind of additive,
It is even to be distributed in various transparent mediums, realize the self light emission function of medium, and can show the color that becomes clear possessed by luminescent powder,
Good low emergency lighting, sign and decoration effect is presented.The various light emitting articles made of the luminescent powder, can
It is applied in daily necessities with being perfectly safe.It is nontoxic without radiating, do not burn, not exploding, be free of other harmful heavy metals
Element or chemical substance.
Luminescent powder is irradiated through 10 minutes, can generate high brightness twilight sunset, is 30-50 times of traditional luminescent powder brightness；Its
Persistence is in human viewable's brightness（≥0.32 mcd/m2）In the case of, it is 20 hours or more, considerably beyond fluorescent brightness
Requirement.Shooting condition is low（Excitation wavelength range 200-450nm）, excitation light source is easy to get, and sunlight, general lighting, environment are spuious
Light all can be used as excitation light source；Do not need power supply support, can any light source of automatic absorption, bright place's extinction, dark place shine.It inhales at bright place
It automatic continuous can shine at the various visible lights such as receipts daylight, light, environment stray light, dark, to more in people's dark
Information indicates.Preferable physics and chemical characteristic.It can be used outdoors or under adverse circumstances, and stronger ultraviolet light spoke can be resisted
It penetrates, is irradiated thousand hours under 300W high-pressure sodium lamps, performance is basically unchanged.Shine it is soft, brightness is high, physical and chemical index safety and stability,
Anti-aging property is excellent, and chemical resistance is good, and use temperature range is wide（-50~1300℃）.Extremely long service life（≥20
Year）,-storage-can be absorbed repeatedly emits visible light, safety coefficient 100%.Luminescent powder has good anti-after color film process
Aging, corrosion resistance, heat resistance have certain anti-flammability and adhesion strength.Luminescent color great variety of goods has yellowish green
Color, blue-green, sky blue, purple, pink, white.
Temperature change powder
Heat discoloration pigment makes the molecular structure of the organic matter change because of electronics transfer at a certain temperature, to realize face
Color changes.This electrochromic substance is not only bright-colored, but also the color change from " coloured===colourless " state may be implemented, this
It is not available for heavy metal double salt Complex Type and liquid crystal type reversible temperature-sensitive electrochromic substance.Microencapsulation reversible temperature-sensitive discoloration object
Matter is known as reversible temperature-sensitive camouflage paint and (is commonly called as:Warm variable pigments, temperature-sensitive powder or temperature change powder).The particle of this pigment is spherical,
Average diameter is 2 ~ 7 microns (one micron is equal to one thousandth millimeter).Electrochromic substance inside it, outside be a thickness about 0.2 ~
0.5 micron can neither dissolve the transparent outer cover that will not melt, and exactly it protects electrochromic substance from other chemical substances
It corrodes.1, heat discoloration basic colors:Heat discoloration cardinal temperature:-5℃、0℃、5℃、10℃、16℃、21℃、31℃、
33℃、38℃、43℃、45℃、50℃、65℃、70℃、78℃.Heat discoloration can must become repeatedly with the up and down of temperature
Color.(by taking 31 DEG C of red as an example, discoloration form is 31 DEG C of presented above colourless, 31 DEG C of red presented below).
Microencapsulation reversible temperature-sensitive alternating temperature powder, alternating temperature temperature is used to select 43 DEG C, 45 DEG C, 50 DEG C of 3 values in the present invention.This
Heating temperature is worth within 45 DEG C when selecting 43 DEG C, 45 DEG C, 50 DEG C this 3 when the 3D printing pen of invention is finally used with consumptive material
Temperature change powder after, according to the change temp effect of material, user can be allowed intuitively to observe 3D heating temperatures, be convenient for creating
Make, without touching material sense temperature with hand, more securely and reliably, children can operate.
Special-effect material further includes essence, and material is made to distribute specific fragrance.
It is any in pearl powder, glitter powder, fluorescent powder, temperature change powder to be combined with essence, become existing particular color again
The consumptive material for having specific fragrance meets different exposition needs of the user to this field consumptive material in vision and the sense of taste, makes the product be in
Existing color diversity, interest and attraction.
The additive amount of special-effect agent is respectively by weight percentage：Pearl powder 1%~3% or glitter powder 2%~16% or glimmering
Light powder 1%~5% or temperature change powder 0.1%~2%.
It is fragrant according to weight percent when any one of essence and pearl powder, glitter powder, fluorescent powder, temperature change powder are used cooperatively
Essence additive amount be:1%~4%.
By weight percentage, the additive amount of special-effect agent be pearl powder 1.1% or glitter powder 8.3% or fluorescent powder 2.3% or
Temperature change powder 0.9%.When any one of essence and pearl powder, glitter powder, fluorescent powder, temperature change powder are used cooperatively, according to weight hundred
Divide and compare, the additive amount of essence is:2.5%.
Preferably, by weight percentage, the additive amount of special-effect agent is pearl powder 1.1% or glitter powder 8.3% or fluorescence
Powder 2.3% or temperature change powder 0.9%.When any one of essence and pearl powder, glitter powder, fluorescent powder, temperature change powder are used cooperatively, press
According to weight percent, the additive amount of essence is:2.5%.
The present invention does not use reactive diluent by independent research, for conventional curing technology, can eliminate because
The problems such as pollution caused by component volatilization, stimulation.
Illumination wavelength of the present invention belongs to visible light photocuring, avoids using ultraviolet curing to human body in 400nm or more
The injury of skin eyes.
The advantage of the invention is that：
（1）The special-effect agent that the present invention uses makes the consumptive material after solidification that pearly-lustre, bright sudden strain of a muscle, fluorescence, the warm discoloration of chance, essence etc. be presented
Effect compares the unicity of conventional color so that more ornamental after the completion of works, color diversification, or there is fragrance；
（2）Aluminum material matter glitter powder is used in the present invention, can be 300 degree with high temperature resistant, acid and alkali-resistance, the oligomer phase with the present invention
Capacitive is good；
（3）Works artistic conception can also be presented at night in iridescent, meet the different works of client and demand is presented；Fluorescence in the present invention
Powder uses novel light-storing fluorescence powder, model MHG-4D good with the oligomer compatible degree of the invention used；
（4）The 3D printing pen of the present invention when finally being used with consumptive material heating temperature within 45 DEG C, when select 43 DEG C, 45 DEG C, 50
After the temperature change powders of DEG C of this 3 values, according to the change temp effect of material, user can be allowed intuitively to observe 3D heating temperatures, just
In being created, without touching material sense temperature with hand, more securely and reliably, children can operate；
（5）It can also be combined with fragrance, becoming existing particular color again has the consumptive material of specific fragrance, meets user and is consumed to this field
Different exposition needs of the material in vision and the sense of taste make product that color diversity, interest and attraction be presented.With significant
Performance advantage.
Below by way of specific embodiment, the present invention is further explained, but is not limited to following embodiments.
Specific implementation mode
Embodiment 1
1, the 3D printing pen consumptive material raw material with special-effect is configured according to the following ratio：
Polyurethane acrylic resin 74.5%
2,4,6- trimethylbenzoyl phenyls phosphinic acid ethyl ester 9.5%
Ethyl 4-dimethylaminobenzoate 2%
Palm acid ethyl ester 3%
Cocounut oil acid methyl single ethanol amide 6.5%
Lithium magnesium silicate 1%
Light spread powder 1.5
In pearl powder or glitter powder or fluorescent powder or temperature change powder any one 2%
2, preparation method
Weigh polyurethane acrylic resin, 2,4,6- trimethylbenzoyl phenyls phosphinic acid ethyl ester, 4- dimethyl respectively according to the ratio
Benzocaine.Above-mentioned material is mixed evenly to be prepared into intermediate product A for use.
Weigh palmitic acid hexyl acetate, lithium magnesium silicate, cocounut oil acid methyl single ethanol amide, light spread powder respectively according to the ratio.
Above-mentioned material is mixed evenly to be prepared into intermediate product B for use.
It is for use that A and B is uniformly mixed to product C among preparing.
Into intermediate product C, it is added arbitrary in weighted according to the ratio pearl powder or glitter powder or fluorescent powder or temperature change powder
One kind being heated up to 30 DEG C, at the uniform velocity stirs 30min, until being evenly distributed.Finished product D is obtained, is sealed.
Finished product D is added in 3D and is used as 3D pigment, paying attention to must not be light-exposed in adition process.
Embodiment 2
2, the 3D printing pen consumptive material raw material with special-effect is configured according to the following ratio：
Polyurethane acrylic resin 63%
2,4,6- trimethylbenzoyl phenyls phosphinic acid ethyl ester 12%
Ethyl 4-dimethylaminobenzoate 6%
Palm acid ethyl ester 5%
Cocounut oil acid methyl single ethanol amide 7%
Lithium magnesium silicate 2%
Light spread powder 2%
Essence surplus
2, preparation method
Weigh polyurethane acrylic resin, 2,4,6- trimethylbenzoyl phenyls phosphinic acid ethyl ester, 4- dimethyl respectively according to the ratio
Benzocaine.Above-mentioned material is mixed evenly to be prepared into intermediate product A for use.
Weigh palm acid ethyl ester, lithium magnesium silicate, cocounut oil acid methyl single ethanol amide, light spread powder respectively according to the ratio.
Above-mentioned material is mixed evenly to be prepared into intermediate product B for use.
It is for use that A and B is uniformly mixed to product C among preparing.
Into intermediate product C, essence weighted according to the ratio is added, is heated up to 30 DEG C, at the uniform velocity stirs 30min, until uniformly.
Finished product D is obtained, is sealed.
Finished product D is added in 3D and is used as 3D pigment, paying attention to must not be light-exposed in adition process.
Embodiment 3
3, the 3D printing pen consumptive material raw material with special-effect is configured according to the following ratio：
Polyurethane acrylic resin 90%
2,4,6- trimethylbenzoyl phenyls phosphinic acid ethyl ester 1%
Ethyl 4-dimethylaminobenzoate 0.8%
Palm acid ethyl ester 1%
Cocounut oil acid methyl single ethanol amide 1%
Lithium magnesium silicate 0.1%
Light spread powder 0.5%
Essence 1.5%
Any one surplus in pearl powder or glitter powder or fluorescent powder or temperature change powder
2, preparation method
Weigh polyurethane acrylic resin, 2,4,6- trimethylbenzoyl phenyls phosphinic acid ethyl ester, 4- dimethyl respectively according to the ratio
Benzocaine.Above-mentioned material is mixed evenly to be prepared into intermediate product A for use.
Weigh palmitic acid hexyl acetate, lithium magnesium silicate, cocounut oil acid methyl single ethanol amide, light spread powder respectively according to the ratio.
Above-mentioned material is mixed evenly to be prepared into intermediate product B for use.
It is for use that A and B is uniformly mixed to product C among preparing.
Into intermediate product C, it is added in weighted according to the ratio essence and pearl powder or glitter powder or fluorescent powder or temperature change powder
Any one, be heated up to 30 DEG C, at the uniform velocity stir 30min, until uniformly.Finished product D is obtained, is sealed.
Finished product D is added in 3D and is used as 3D pigment, paying attention to must not be light-exposed in adition process.
By sample made from above-described embodiment 1-3, traditional product carries out measure of merit together on the market, and test result is such as
Under：
| Sample | Embodiment 1 | Embodiment 2 | Embodiment 3 | Market product opens object person | Market product moral prestige |
| Surface effect | Pearl powder or glitter powder or fluorescent powder or temperature change powder effect | Fragrance effects | Fragrance and pearl powder or glitter powder or fluorescent powder or temperature change powder effect | Without color British plain spirits | Solid color |
According to 3 embodiments it is known that when using the special-effect agent in the present invention in use, product effect is more various
Change.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of 3D printing pen consumptive material with special-effect, which is characterized in that its material includes according to weight percent：Together
Polymers 63%~90%, photoinitiator 1%~12%, aided initiating 0.8%~6%, surfactant 1%~7%, antiplastering aid 1%~5%,
Suspending agent 0.1%~2%, light spread powder 0.5%~2%, special-effect agent 1%~16%.
2. a kind of 3D printing pen consumptive material with special-effect as described in claim 1, which is characterized in that oligomer is poly-
Urethane acrylate resin；Photoinitiator is 2,4,6- trimethylbenzoyl phenyl phosphinic acid ethyl esters；Aided initiating is 4- dimethyl
Benzocaine；Surfactant is cocounut oil acid methyl single ethanol amide；Antiplastering aid is palm acid ethyl ester；Suspending agent
For lithium magnesium silicate；Special-effect agent can be any one in pearl powder, glitter powder, fluorescent powder, temperature change powder.
3. such as a kind of 3D printing pen consumptive material with special-effect of claim 1-2 any one of them, which is characterized in that also
Essence can be added.
4. a kind of 3D printing pen consumptive material with special-effect as described in claim 1-2, which is characterized in that wherein special
The additive amount of effect agent is respectively by weight percentage：Pearl powder 1%~3% or glitter powder 2%~16% or fluorescent powder 1%~5% or
Temperature change powder 0.1%~2%.
5. a kind of 3D printing pen consumptive material with special-effect as claimed in claim 3, which is characterized in that when essence and pearl
When any one of light powder, glitter powder, fluorescent powder, temperature change powder are used cooperatively, according to weight percent, the additive amount of essence is:
1%~4%.
6. a kind of 3D printing pen consumptive material with special-effect as claimed in claim 5, which is characterized in that percentage by weight
Than the additive amount of special-effect agent is pearl powder 1.1% or glitter powder 8.3% or fluorescent powder 2.3% or temperature change powder 0.9%；Work as essence
When being used cooperatively with pearl powder or glitter powder or any one of fluorescent powder or temperature change powder, according to weight percent, essence adds
Dosage is:2.5%.
7. a kind of 3D printing pen consumptive material with special-effect as described in claim 1-6, which is characterized in that glitter powder is adopted
With aluminum material matter；Fluorescent powder uses novel light-storing fluorescence powder, model MHG-4D；Alternating temperature powder uses microencapsulation reversible temperature-sensitive alternating temperature
Powder, alternating temperature temperature select 43 DEG C, 45 DEG C, 50 DEG C 3 value in any one.
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