CN108585811A - A kind of high rigidity energy-saving brick and preparation method thereof - Google Patents
A kind of high rigidity energy-saving brick and preparation method thereof Download PDFInfo
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- CN108585811A CN108585811A CN201810470703.9A CN201810470703A CN108585811A CN 108585811 A CN108585811 A CN 108585811A CN 201810470703 A CN201810470703 A CN 201810470703A CN 108585811 A CN108585811 A CN 108585811A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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Abstract
A kind of high rigidity energy-saving brick of present invention offer and preparation method thereof, is prepared by following component：Diatomite, modified alta-mud powder, Pond Silt, clinker, charcoal, scrap glass, quartz sand, gangue, flyash, talcum powder, titanium dioxide, expanded perlite and water.Energy-saving brick hardness prepared by the present invention is high, wearability is good, mechanical performance is excellent, service life is long, and raw material sources are extensive, there is the waste in environment in raw material, with certain energy conservation and environmental protection meaning, cost of manufacture can be also reduced, and preparation method is simple, be convenient for practical operation.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of high rigidity energy-saving brick and preparation method thereof.
Background technology
Industrialized process brings social progress to us, productivity greatly improves, but has also caused one simultaneously
The energy crisis of series.With the aggravation year by year to energy extraction, in recent years, it is more and more that energy problem causes people
Concern, all kinds of buildings and engineering all need largely to use brick, people higher and higher to the quality requirement of building, therefore to using brick
The requirements such as block hardness, wear-resisting property are also higher and higher.
The traditional brick-making technology in China is to utilize vitrified bond brickmaking, need to largely exploit arable land, farmland is caused to destroy, because
This many research staff starts with other materials etc. to replace or part replaces clay, such as building waste residue, but due to present
The more cement ingredients of building waste residue easily lead to brick decortication, and the plasticity of building waste residue is poor；And it is made of domestic sludge
Brick intensity it is poor, and fired brick needed in sintering process consume amount of heat, the waste of the energy can be caused.
In summary, it is therefore desirable to a kind of better brick, to improve the deficiencies in the prior art.
Invention content
The object of the present invention is to provide a kind of high rigidity energy-saving brick and preparation method thereof, energy-saving brick hardness prepared by the present invention
Height, wearability is good, mechanical performance is excellent, service life is long, and raw material sources are extensive, has in raw material discarded in environment
Object has certain energy conservation and environmental protection meaning, can also reduce cost of manufacture, and preparation method is simple, is convenient for practical operation.
The present invention provides the following technical solutions：
A kind of high rigidity energy-saving brick, includes the raw material of following parts by weight：38-46 parts of diatomite, modified alta-mud powder 25-32
Part, 28-41 parts of Pond Silt, 22-34 parts of clinker, 20-33 parts of charcoal, 28-43 parts of scrap glass, 22-28 parts of quartz sand, bastard coal
18-28 parts of stone, 30-39 parts of flyash, 27-35 parts of talcum powder, 19-27 parts of titanium dioxide, 22-31 parts of expanded perlite and water 14-
22 parts.
Preferably, the energy-saving brick includes the raw material of following parts by weight：38-43 parts of diatomite, modified alta-mud powder 28-
32 parts, 28-37 parts of Pond Silt, 22-31 parts of clinker, 24-33 parts of charcoal, 28-36 parts of scrap glass, 25-28 parts of quartz sand, coal
18-27 parts of spoil, 32-39 parts of flyash, 27-30 parts of talcum powder, 22-27 parts of titanium dioxide, 22-29 parts of expanded perlite and water
17-22 parts.
Preferably, the energy-saving brick includes the raw material of following parts by weight：42 parts of diatomite, 32 parts of modified alta-mud powder,
35 parts of Pond Silt, 30 parts of clinker, 28 parts of charcoal, 32 parts of scrap glass, 25 parts of quartz sand, 21 parts of gangue, 33 parts of flyash,
17 parts of 30 parts of talcum powder, 22 parts of titanium dioxide, 28 parts of expanded perlite and water.
A kind of preparation method of high rigidity energy-saving brick, including following preparation process：
A, diatomite is pre-processed, then is modified processing, later with clinker, charcoal, scrap glass, quartz sand and bastard coal
Stone mixes, and imports in planetary ball mill, with the rotating speed ball milling 2-3h of 600-800rpm, obtains powder；
B, modified alta-mud powder, flyash, talcum powder, titanium dioxide, expanded perlite and water is added into powder again, imports ball
In grinding jar, wet-milling 3-5h is carried out, Pond Silt is added, stirs evenly, obtain mixture one；
C, mixture one is placed in drying box, at 60-80 DEG C, is dried to water content in 20-30wt%, then import in mold
It is suppressed, obtains adobe；
D, adobe is placed in drying box, 30-50min is preheated at 80-100 DEG C, then imported and fire in kiln, with 3-5 DEG C/min
Heating rate be warming up to 500-600 DEG C, fire 1-2h, then 900-1000 DEG C is warming up to the heating rate of 6-10 DEG C/min,
2-3h is fired, after being down to room temperature, you can obtain finished product.
Preferably, the preprocess method of the step a is：Diatomite and absolute ethyl alcohol are mixed, ultrasonic disperse 20-
30min adds polyethylene glycol and water, and 15-20min is stirred to react at 70-80 DEG C, through filtering, dry, obtains solids,
By solids, toluene, gamma-aminopropyl-triethoxy-silane mix, be stirred to react 25-35min at 40-50 DEG C, using filter,
It is dry, you can.
Preferably, the modification processing method of the step a is：By pretreated diatomite and N- (4- carboxyl phenyls) horse
Come dant monomer, n,N-Dimethylformamide mixing, 1-2h is stirred to react at 55-60 DEG C, adds thionyl chloride continuation
It is stirred to react 30-40min, through filtering, drying, you can.
Preferably, N- (4- carboxyl phenyls) maleimide monomers and n,N-Dimethylformamide in mass ratio 2:1
Mixing.
Preferably, the preparation method of the modified alta-mud powder of the step b is：Bentonite powder and sodium hydroxide is molten
Liquid mixes, and stirs and after spray-dried, it is molten to add ethyl alcohol to 5-6 for ultrasonic disperse 30-40min, then regulation system pH value
Liquid, γ-mercaptopropyl trimethoxysilane mixing, are stirred to react 1-2h at 70-80 DEG C, add silk gum solution, ethylene glycol two
Glycidyl ether the reaction was continued 40-50min, after being filtered, washed, drying, grind, you can obtain modified alta-mud powder.
The beneficial effects of the invention are as follows：
Energy-saving brick hardness prepared by the present invention is high, wearability is good, mechanical performance is excellent, service life is long, and raw material sources are extensive,
There is the waste in environment in raw material, there is certain energy conservation and environmental protection meaning, can also reduce cost of manufacture, and it is made
Preparation Method is simple, is convenient for practical operation.
The modified alta-mud powder added in the present invention, wherein bentonite powder coordinate γ-mercaptopropyl trimethoxysilane
After graft reaction, its compatibility can be significantly improved, bentonite bed spacing can be enhanced, keep its dispersion performance excellent, further with second
After glycol diglycidyl ether complex reaction, polarity and nonpolar compatible good high score subnet can be formed in bentonite powder
Shape space structure makes its compatibility further enhance, being so that the hardness and wear resistance of finished product is all notable after sintering
It improves.
Specific implementation mode
Embodiment 1
A kind of high rigidity energy-saving brick, includes the raw material of following parts by weight：46 parts of diatomite, 32 parts of modified alta-mud powder, pond
28 parts of mud, 22 parts of clinker, 33 parts of charcoal, 28 parts of scrap glass, 28 parts of quartz sand, 28 parts of gangue, 39 parts of flyash, talcum
14 parts of 27 parts of powder, 19 parts of titanium dioxide, 31 parts of expanded perlite and water.
A kind of preparation method of high rigidity energy-saving brick, including following preparation process：
A, diatomite is pre-processed, then is modified processing, later with clinker, charcoal, scrap glass, quartz sand and bastard coal
Stone mixes, and imports in planetary ball mill, with the rotating speed ball milling 3h of 600rpm, obtains powder；
B, modified alta-mud powder, flyash, talcum powder, titanium dioxide, expanded perlite and water is added into powder again, imports ball
In grinding jar, wet-milling 3h is carried out, Pond Silt is added, stirs evenly, obtain mixture one；
C, mixture one is placed in drying box, at 60 DEG C, is dried to water content in 20wt%, then import in mold and pressed
System, obtains adobe；
D, adobe is placed in drying box, 30min is preheated at 80 DEG C, then imported and fire in kiln, with the heating rate of 5 DEG C/min
500 DEG C are warming up to, 2h is fired, then 900 DEG C are warming up to the heating rate of 10 DEG C/min, 3h is fired, after being down to room temperature, you can
To finished product.
The preprocess method of step a is：Diatomite and absolute ethyl alcohol are mixed, ultrasonic disperse 30min is added poly-
Ethylene glycol and water are stirred to react 15min at 70 DEG C, through filtering, drying, solids are obtained, by solids, toluene, γ-ammonia third
Ethyl triethoxy silicane alkane mixes, and 35min is stirred to react at 50 DEG C, using filter, drying, you can.
The modification processing method of step a is：By pretreated diatomite and N- (4- carboxyl phenyls) maleimide list
Body, n,N-Dimethylformamide mixing, are stirred to react 1h at 60 DEG C, add thionyl chloride and continue to be stirred to react 30min, pass through
Filtering, drying, you can.
N- (4- carboxyl phenyls) maleimide monomers and N,N-dimethylformamide in mass ratio 2:1 mixing.
The preparation method of the modified alta-mud powder of step b is：Bentonite powder is mixed with sodium hydroxide solution, is stirred
And ultrasonic disperse 30min, then regulation system pH value after spray-dried, add ethanol solution, γ-mercapto propyl trimethoxy to 5
Base silane mixes, and 2h is stirred to react at 70 DEG C, adds that silk gum solution, the reaction was continued for ethylene glycol diglycidyl base ether
50min, after being filtered, washed, drying, grind, you can obtain modified alta-mud powder.
Embodiment 2
A kind of high rigidity energy-saving brick, includes the raw material of following parts by weight：38 parts of diatomite, 28 parts of modified alta-mud powder, pond
28 parts of mud, 22 parts of clinker, 24 parts of charcoal, 28 parts of scrap glass, 25 parts of quartz sand, 18 parts of gangue, 32 parts of flyash, talcum
17 parts of 27 parts of powder, 27 parts of titanium dioxide, 22 parts of expanded perlite and water.
A kind of preparation method of high rigidity energy-saving brick, including following preparation process：
A, diatomite is pre-processed, then is modified processing, later with clinker, charcoal, scrap glass, quartz sand and bastard coal
Stone mixes, and imports in planetary ball mill, with the rotating speed ball milling 2h of 600rpm, obtains powder；
B, modified alta-mud powder, flyash, talcum powder, titanium dioxide, expanded perlite and water is added into powder again, imports ball
In grinding jar, wet-milling 3h is carried out, Pond Silt is added, stirs evenly, obtain mixture one；
C, mixture one is placed in drying box, at 60 DEG C, is dried to water content in 20wt%, then import in mold and pressed
System, obtains adobe；
D, adobe is placed in drying box, 30min is preheated at 80 DEG C, then imported and fire in kiln, with the heating rate of 5 DEG C/min
500 DEG C are warming up to, 1h is fired, then 900 DEG C are warming up to the heating rate of 6 DEG C/min, 2h is fired, after being down to room temperature, you can
To finished product.
The preprocess method of step a is：Diatomite and absolute ethyl alcohol are mixed, ultrasonic disperse 20min is added poly-
Ethylene glycol and water are stirred to react 15min at 70 DEG C, through filtering, drying, solids are obtained, by solids, toluene, γ-ammonia third
Ethyl triethoxy silicane alkane mixes, and 25min is stirred to react at 40 DEG C, using filter, drying, you can.
The modification processing method of step a is：By pretreated diatomite and N- (4- carboxyl phenyls) maleimide list
Body, n,N-Dimethylformamide mixing, are stirred to react 1h at 55 DEG C, add thionyl chloride and continue to be stirred to react 30min, pass through
Filtering, drying, you can.
N- (4- carboxyl phenyls) maleimide monomers and N,N-dimethylformamide in mass ratio 2:1 mixing.
The preparation method of the modified alta-mud powder of step b is：Bentonite powder is mixed with sodium hydroxide solution, is stirred
And ultrasonic disperse 30min, then regulation system pH value after spray-dried, add ethanol solution, γ-mercapto propyl trimethoxy to 5
Base silane mixes, and 1h is stirred to react at 70 DEG C, adds that silk gum solution, the reaction was continued for ethylene glycol diglycidyl base ether
40min, after being filtered, washed, drying, grind, you can obtain modified alta-mud powder.
Embodiment 3
A kind of high rigidity energy-saving brick, includes the raw material of following parts by weight：42 parts of diatomite, 32 parts of modified alta-mud powder, pond
35 parts of mud, 30 parts of clinker, 28 parts of charcoal, 32 parts of scrap glass, 25 parts of quartz sand, 21 parts of gangue, 33 parts of flyash, talcum
17 parts of 30 parts of powder, 22 parts of titanium dioxide, 28 parts of expanded perlite and water.
A kind of preparation method of high rigidity energy-saving brick, including following preparation process：
A, diatomite is pre-processed, then is modified processing, later with clinker, charcoal, scrap glass, quartz sand and bastard coal
Stone mixes, and imports in planetary ball mill, with the rotating speed ball milling 3h of 800rpm, obtains powder；
B, modified alta-mud powder, flyash, talcum powder, titanium dioxide, expanded perlite and water is added into powder again, imports ball
In grinding jar, wet-milling 5h is carried out, Pond Silt is added, stirs evenly, obtain mixture one；
C, mixture one is placed in drying box, at 80 DEG C, is dried to water content in 30wt%, then import in mold and pressed
System, obtains adobe；
D, adobe is placed in drying box, 50min is preheated at 100 DEG C, then imported and fire in kiln, with the heating speed of 5 DEG C/min
Degree is warming up to 600 DEG C, fires 2h, then be warming up to 1000 DEG C with the heating rate of 10 DEG C/min, fires 3h, after being down to room temperature, i.e.,
Finished product can be obtained.
The preprocess method of step a is：Diatomite and absolute ethyl alcohol are mixed, ultrasonic disperse 20-30min, then added
Enter polyethylene glycol and water, 20min is stirred to react at 80 DEG C, through filtering, drying, solids is obtained, by solids, toluene, γ-
Aminopropyl triethoxysilane mixes, and 35min is stirred to react at 50 DEG C, using filter, drying, you can.
The modification processing method of step a is：By pretreated diatomite and N- (4- carboxyl phenyls) maleimide list
Body, n,N-Dimethylformamide mixing, are stirred to react 2h at 60 DEG C, add thionyl chloride and continue to be stirred to react 40min, pass through
Filtering, drying, you can.
N- (4- carboxyl phenyls) maleimide monomers and N,N-dimethylformamide in mass ratio 2:1 mixing.
The preparation method of the modified alta-mud powder of step b is：Bentonite powder is mixed with sodium hydroxide solution, is stirred
And ultrasonic disperse 40min, then regulation system pH value after spray-dried, add ethanol solution, γ-mercapto propyl trimethoxy to 6
Base silane mixes, and 2h is stirred to react at 80 DEG C, adds that silk gum solution, the reaction was continued for ethylene glycol diglycidyl base ether
50min, after being filtered, washed, drying, grind, you can obtain modified alta-mud powder.
Finished product prepared by above example is detected, following detection data is obtained：
Table one：
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Hardness（Mohs' hardness/grade） | 7 | 8 | 8 |
| Water absorption rate（%） | 2 | 1 | 1 |
| Corrosion resistance | It is excellent | It is excellent | It is excellent |
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to the foregoing embodiments
Invention is explained in detail, for those skilled in the art, still can be to foregoing embodiments institute
The technical solution of record is modified or equivalent replacement of some of the technical features.It is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of high rigidity energy-saving brick, which is characterized in that include the raw material of following parts by weight：38-46 parts of diatomite, bentone
Native powder 25-32 parts, 28-41 parts of Pond Silt, 22-34 parts of clinker, 20-33 parts of charcoal, 28-43 parts of scrap glass, quartz sand
22-28 parts, 18-28 parts of gangue, 30-39 parts of flyash, 27-35 parts of talcum powder, 19-27 parts of titanium dioxide, expanded perlite 22-
31 parts and 14-22 parts of water.
2. a kind of high rigidity energy-saving brick according to claim 1, which is characterized in that the energy-saving brick includes following parts by weight
Raw material：38-43 parts of diatomite, 28-32 parts of modified alta-mud powder, 28-37 parts of Pond Silt, 22-31 parts of clinker, charcoal
24-33 parts, 28-36 parts of scrap glass, 25-28 parts of quartz sand, 18-27 parts of gangue, 32-39 parts of flyash, talcum powder 27-30
Part, 22-27 parts of titanium dioxide, 22-29 parts of expanded perlite and 17-22 parts of water.
3. a kind of high rigidity energy-saving brick according to claim 1, which is characterized in that the energy-saving brick includes following parts by weight
Raw material：42 parts of diatomite, 32 parts of modified alta-mud powder, 35 parts of Pond Silt, 30 parts of clinker, 28 parts of charcoal, scrap glass
32 parts, 25 parts of quartz sand, 21 parts of gangue, 33 parts of flyash, 30 parts of talcum powder, 22 parts of titanium dioxide, 28 parts of expanded perlite and
17 parts of water.
4. a kind of preparation method of high rigidity energy-saving brick of claim 1-3 any one of them, which is characterized in that including following system
Standby step：
A, diatomite is pre-processed, then is modified processing, later with clinker, charcoal, scrap glass, quartz sand and bastard coal
Stone mixes, and imports in planetary ball mill, with the rotating speed ball milling 2-3h of 600-800rpm, obtains powder；
B, modified alta-mud powder, flyash, talcum powder, titanium dioxide, expanded perlite and water is added into powder again, imports ball
In grinding jar, wet-milling 3-5h is carried out, Pond Silt is added, stirs evenly, obtain mixture one；
C, mixture one is placed in drying box, at 60-80 DEG C, is dried to water content in 20-30wt%, then import in mold
It is suppressed, obtains adobe；
D, adobe is placed in drying box, 30-50min is preheated at 80-100 DEG C, then imported and fire in kiln, with 3-5 DEG C/min
Heating rate be warming up to 500-600 DEG C, fire 1-2h, then 900-1000 DEG C is warming up to the heating rate of 6-10 DEG C/min,
2-3h is fired, after being down to room temperature, you can obtain finished product.
5. a kind of preparation method of high rigidity energy-saving brick according to claim 4, which is characterized in that the step a's is pre-
Processing method is：Diatomite and absolute ethyl alcohol are mixed, ultrasonic disperse 20-30min adds polyethylene glycol and water,
It is stirred to react 15-20min at 70-80 DEG C, through filtering, drying, solids is obtained, by solids, toluene, three second of γ-aminopropyl
Oxysilane mixes, and 25-35min is stirred to react at 40-50 DEG C, using filter, drying, you can.
6. a kind of preparation method of high rigidity energy-saving brick according to claim 4, which is characterized in that the step a's changes
Property processing method is：By pretreated diatomite and N- (4- carboxyl phenyls) maleimide monomer, N, N- dimethyl formyls
Amine mixes, and is stirred to react 1-2h at 55-60 DEG C, adds thionyl chloride and continue to be stirred to react 30-40min, through filtering, doing
It is dry, you can.
7. a kind of preparation method of high rigidity energy-saving brick according to claim 6, which is characterized in that N- (the 4- carboxyls
Phenyl) maleimide monomer and N,N-dimethylformamide in mass ratio 2:1 mixing.
8. a kind of preparation method of high rigidity energy-saving brick according to claim 4, which is characterized in that the step b's changes
The preparation method of property bentonite powder is：Bentonite powder is mixed with sodium hydroxide solution, stirs simultaneously ultrasonic disperse 30-
After spray-dried, it is mixed to add ethanol solution, γ-mercaptopropyl trimethoxysilane to 5-6 for 40min, then regulation system pH value
It closes, 1-2h is stirred to react at 70-80 DEG C, add silk gum solution, ethylene glycol diglycidyl base ether the reaction was continued 40-
50min, after being filtered, washed, drying, grind, you can obtain modified alta-mud powder.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109824350A (en) * | 2019-02-25 | 2019-05-31 | 高阳 | A kind of preparation method of ceramics resistant brick |
| CN114057468A (en) * | 2021-12-01 | 2022-02-18 | 贵州欧玛陶瓷有限责任公司 | Building ceramic using fly ash of garbage power plant as raw material and preparation process thereof |
| CN115141009A (en) * | 2022-07-13 | 2022-10-04 | 国发环保新材料(江门)有限公司 | Artificial stone prepared from coal gangue and fly ash and method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106630942A (en) * | 2016-12-27 | 2017-05-10 | 定远县明友墙体材料有限责任公司 | Preparation method of high-hardness and high-wear-resistance sintered brick |
| CN106747605A (en) * | 2016-12-27 | 2017-05-31 | 定远县明友墙体材料有限责任公司 | Preparation method of insulating brick with good thermal stability and heat insulation effect |
| CN107011918A (en) * | 2017-03-27 | 2017-08-04 | 成都理工大学 | A kind of sulfhydrylation bentonite of restoration of soil polluted by heavy metal and preparation method thereof |
-
2018
- 2018-05-17 CN CN201810470703.9A patent/CN108585811A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106630942A (en) * | 2016-12-27 | 2017-05-10 | 定远县明友墙体材料有限责任公司 | Preparation method of high-hardness and high-wear-resistance sintered brick |
| CN106747605A (en) * | 2016-12-27 | 2017-05-31 | 定远县明友墙体材料有限责任公司 | Preparation method of insulating brick with good thermal stability and heat insulation effect |
| CN107011918A (en) * | 2017-03-27 | 2017-08-04 | 成都理工大学 | A kind of sulfhydrylation bentonite of restoration of soil polluted by heavy metal and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109824350A (en) * | 2019-02-25 | 2019-05-31 | 高阳 | A kind of preparation method of ceramics resistant brick |
| CN114057468A (en) * | 2021-12-01 | 2022-02-18 | 贵州欧玛陶瓷有限责任公司 | Building ceramic using fly ash of garbage power plant as raw material and preparation process thereof |
| CN115141009A (en) * | 2022-07-13 | 2022-10-04 | 国发环保新材料(江门)有限公司 | Artificial stone prepared from coal gangue and fly ash and method |
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Application publication date: 20180928 |