CN108585528A - A kind of novel nucleated glass and preparation method thereof - Google Patents
A kind of novel nucleated glass and preparation method thereof Download PDFInfo
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- CN108585528A CN108585528A CN201810471500.1A CN201810471500A CN108585528A CN 108585528 A CN108585528 A CN 108585528A CN 201810471500 A CN201810471500 A CN 201810471500A CN 108585528 A CN108585528 A CN 108585528A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
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- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
A kind of novel nucleated glass of present invention offer and preparation method thereof, is related to glass making techniques field.The present invention is made of following raw material:Silica, calcium oxide, zircon, silica sand, aluminium powder, magnesia, whisker, nucleating agent, potassium oxide, fluorine.Whisker is uniformly dispersed in the glass matrix of novel nucleated glass of the present invention, whisker is well combined with glass matrix, improves the mechanical property of devitrified glass, and novel nucleated glass fluorine content of the present invention is low, translucent beautiful matter shape is presented in the devitrified glass perception, moisture with natural jade and wax sense, exquisite in texture are glittering and translucent, it is radiationless, and good toughness, intensity are high, are easy further processing molding, can be widely used in the fields such as the substitute of high-grade stone.
Description
Technical field
The present invention relates to glass making techniques fields, and in particular to a kind of novel nucleated glass and preparation method thereof.
Background technology
As Chinese national economy stablizes sustainable development, people's living standard improves therewith, the demand day to high-grade material
Benefit expands, especially more urgent to the substitute products demand of radiationless high-grade stone, but the replacement production of domestic high-grade stone
Product brittleness is big, it is not easy to which machine-shaping causes many high-grade stones to need from external import, and cost significantly increases.
Devitrified glass is also known as glass-ceramic, and the double grading with glass and ceramics, devitrified glass is made of crystal,
Atomic arrangement is regular, and therefore, devitrified glass is higher and stronger than glass toughness than the brightness of ceramics.Devitrified glass has concentrated glass
Triple advantages of glass, ceramics and lithotome are better than lithotome and ceramics, can be used for building curtain wall and indoor high-grade decoration,
Structural material mechanically, the insulating materials on electronics, electrician, baseboard material, the micro-wave oven of large scale integrated circuit can also be done
The vessel of resistance to hot tearing, chemical industry and anti-corrosion material and mine wear-resistant material etc. become the substitute products of ideal high-grade stone.
Existing devitrified glass is mostly high fluorine glass product, since fluorine volatilizees seriously in production, makes the stability of production
Bad control causes devitrified glass production success rate relatively low, even if successfully produce devitrified glass there is also tones it is single, do not have
It is textured, apparent porosity is high, production stability is low and brittleness is big, it is not easy to the shortcomings of machine-shaping, and high fluorine glass produces
Product to kiln seriously corroded, cause kiln reduced service life, production cost to increase in process of production.
Therefore, it is particularly important to develop a kind of novel nucleated glass.
Invention content
In view of the shortcomings of the prior art, a kind of novel nucleated glass of present invention offer and preparation method thereof.
In order to achieve the above object, technical scheme of the present invention is achieved by the following technical programs:
A kind of novel nucleated glass, the novel nucleated glass are made of the raw material of following parts by weight:Silica 50-70
Part, 3-8 parts of calcium oxide, 2-6 parts of zircon, 2-5 parts of silica sand, 2-6 parts of aluminium powder, 3-8 parts of magnesia, 1-3 parts of whisker, nucleating agent
0.6-2.6 parts, 1-3.7 parts of potassium oxide, 0.1-0.4 parts of fluorine.
Further, the novel nucleated glass is made of the raw material of following parts by weight:55-65 parts of silica, oxidation
4-7 parts of calcium, 3-5 parts of zircon, 3-4 parts of silica sand, 3-5 parts of aluminium powder, 4-7 parts of magnesia, 1.5-2.6 parts of whisker, nucleating agent 1-2
Part, 1.8-3 parts of potassium oxide, 0.2-0.3 parts of fluorine.
Further, the novel nucleated glass is made of the raw material of following parts by weight:60 parts of silica, calcium oxide
5.5 parts, 4 parts of zircon, 3.5 parts of silica sand, 4 parts of aluminium powder, 5.5 parts of magnesia, 2 parts of whisker, 1.6 parts of nucleating agent, potassium oxide 2.3
Part, 0.25 part of fluorine.
Further, the nucleating agent is MnO2, ZrO2, TiO2 according to mass ratio 0.5:1:1 mixes.
Further, the whisker is one kind in silicon whisker, potassium titanate crystal whisker, calcium sulfate crystal whiskers, zinc sulfate whisker.
A kind of preparation method of novel nucleated glass, includes the following steps:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1450-1500 DEG C after mixing, obtained glass metal will be melted and cool down
To 550-600 DEG C, after putting into the mold compression moulding of glass press, parent glass is obtained;
S3, the parent glass for obtaining step S2 are through coring processing, Crystallizing treatment, cooling, you can.
Further, the step S3 is to be sent into obtained parent glass in 600-650 DEG C of kiln, keeps the temperature 3-6h, makes
Soaking and eliminate stress, then heated up with 2-3 DEG C/min of heating rate, be warming up to 750-800 DEG C, keep the temperature 1-3h, into
Row coring is handled;Then continue to heat up with 2-3 DEG C/min of heating rate, be warming up to 860-900 DEG C, keep the temperature 1-3h, carry out crystallization
Processing, Crystallizing treatment postcooling are come out of the stove to 100 DEG C or less, you can.
A kind of novel nucleated glass of present invention offer and preparation method thereof, advantage is compared with prior art:
Whisker is uniformly dispersed in the glass matrix of novel nucleated glass of the present invention, and whisker is well combined with glass matrix, carries
The high mechanical property of devitrified glass, novel nucleated glass fluorine content of the present invention is low, which is presented translucent jade
Matter shape, the moisture with natural jade and wax sense, exquisite in texture is glittering and translucent, radiationless, and good toughness, intensity are high,
It is easy further processing molding, can be widely used in the fields such as the substitute of high-grade stone;
Novel nucleated glass preparation process of the present invention is simple, and nucleating agent can be effectively facilitated silica, oxidation in raw material
Calcium, aluminium powder, magnesia start crystallization at a lower temperature, and are formed using diopside as the devitrified glass of principal crystalline phase;Control is former
Expect composition proportion, it is therefore an objective to control crystallization amount, keep glass glossy, improve the brightness value of glass, silica, zircon,
The effect of whisker, silica sand, aluminium powder forms glass network, simultaneously participates in the formation of principal crystalline phase as Network former.It improves micro-
The chemical stability of crystal glass.Calcium oxide, magnesia, potassium oxide are as network modifying oxide, except reduction glass system
Outside glass melting temperature, breakpoint effect is also acted as, is conducive to the precipitation of crystal.Nucleating agent promotion system is nucleated crystallization, and zirconium dioxide is made
Contribute to crystal grain thinning for Nucleating Agent, keeps crystal grain more uniform, it is beneficial for the raising of mechanical strength, but excessively can also increase
Fusion temperature, and then improve the performance of glass.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, with reference to the embodiment of the present invention pair
Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making wound
The every other embodiment obtained under the premise of the property made labour, shall fall within the protection scope of the present invention.
Embodiment 1:
The present embodiment novel nucleated glass is made of the raw material of following parts by weight:50 parts of silica, 3 parts of calcium oxide, zirconium
2 parts of diamond stone, 2 parts of silica sand, 2 parts of aluminium powder, 3 parts of magnesia, 1 part of whisker, 0.6 part of nucleating agent, 1 part of potassium oxide, 0.1 part of fluorine;
Wherein, nucleating agent MnO2, ZrO2, TiO2 is according to mass ratio 0.5:1:1 mixes;Whisker is silicon whisker;
The preparation method of the present embodiment novel nucleated glass, includes the following steps:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1450 DEG C after mixing, obtained glass metal will be melted and be cooled to 550
DEG C, after putting into the mold compression moulding of glass press, obtain parent glass;
Through being sent into 600 DEG C of kiln, heat preservation 3h is allowed to soaking and eliminates stress for S3, the parent glass for obtaining step S2,
Then it is heated up with 2 DEG C/min of heating rate, is warming up to 750 DEG C, keep the temperature 1h, carry out coring processing;Then with heating rate 2
DEG C/min continues to heat up, and is warming up to 860 DEG C, keeps the temperature 1h, carries out Crystallizing treatment, Crystallizing treatment postcooling is come out of the stove to 100 DEG C, i.e.,
It can.
Embodiment 2:
The present embodiment novel nucleated glass is made of the raw material of following parts by weight:70 parts of silica, 8 parts of calcium oxide, zirconium
6 parts of diamond stone, 5 parts of silica sand, 6 parts of aluminium powder, 8 parts of magnesia, 3 parts of whisker, 2.6 parts of nucleating agent, 3.7 parts of potassium oxide, 0.4 part of fluorine;
Wherein, nucleating agent MnO2, ZrO2, TiO2 is according to mass ratio 0.5:1:1 mixes;Whisker is that potassium titanate is brilliant
Palpus;
The preparation method of the present embodiment novel nucleated glass, includes the following steps:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1500 DEG C after mixing, obtained glass metal will be melted and be cooled to 600
DEG C, after putting into the mold compression moulding of glass press, obtain parent glass;
Through being sent into 650 DEG C of kiln, heat preservation 6h is allowed to soaking and eliminates stress for S3, the parent glass for obtaining step S2,
Then it is heated up with 3 DEG C/min of heating rate, is warming up to 800 DEG C, keep the temperature 3h, carry out coring processing;Then with heating rate 3
DEG C/min continues to heat up, and is warming up to 900 DEG C, keeps the temperature 3h, carries out Crystallizing treatment, Crystallizing treatment postcooling is come out of the stove to 80 DEG C, you can.
Embodiment 3:
The present embodiment novel nucleated glass is made of the raw material of following parts by weight:60 parts of silica, 5.5 parts of calcium oxide,
4 parts of zircon, 3.5 parts of silica sand, 4 parts of aluminium powder, 5.5 parts of magnesia, 2 parts of whisker, 1.6 parts of nucleating agent, 2.3 parts of potassium oxide, fluorine
0.25 part;
Wherein, nucleating agent MnO2, ZrO2, TiO2 is according to mass ratio 0.5:1:1 mixes;Whisker is that zinc sulfate is brilliant
Palpus;
The preparation method of the present embodiment novel nucleated glass, includes the following steps:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1480 DEG C after mixing, obtained glass metal will be melted and be cooled to 580
DEG C, after putting into the mold compression moulding of glass press, obtain parent glass;
S3, the parent glass for obtaining step S2 keep the temperature 4.5h, are allowed to soaking and eliminate answer through being sent into 630 DEG C of kiln
Then power is heated up with 3 DEG C/min of heating rate, be warming up to 780 DEG C, keeps the temperature 2h, carries out coring processing;Then with the speed that heats up
2 DEG C/min of rate continues to heat up, and is warming up to 880 DEG C, keeps the temperature 2h, carries out Crystallizing treatment, and Crystallizing treatment postcooling is come out of the stove to 70 DEG C, i.e.,
It can.
Embodiment 4:
The present embodiment novel nucleated glass is made of the raw material of following parts by weight:55 parts of silica, 4 parts of calcium oxide, zirconium
3 parts of diamond stone, 3 parts of silica sand, 3 parts of aluminium powder, 4 parts of magnesia, 1.5 parts of whisker, 1 part of nucleating agent, 1.8 parts of potassium oxide, 0.2 part of fluorine;
Wherein, nucleating agent MnO2, ZrO2, TiO2 is according to mass ratio 0.5:1:1 mixes;Whisker is that calcium sulfate is brilliant
Palpus;
The preparation method of the present embodiment novel nucleated glass, includes the following steps:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1460 DEG C after mixing, obtained glass metal will be melted and be cooled to 560
DEG C, after putting into the mold compression moulding of glass press, obtain parent glass;
Through being sent into 620 DEG C of kiln, heat preservation 5h is allowed to soaking and eliminates stress for S3, the parent glass for obtaining step S2,
Then it is heated up with 3 DEG C/min of heating rate, is warming up to 760 DEG C, keep the temperature 2.5h, carry out coring processing;Then with the speed that heats up
3 DEG C/min of rate continues to heat up, and is warming up to 870 DEG C, keeps the temperature 2.5h, carries out Crystallizing treatment, and Crystallizing treatment postcooling is come out of the stove to 60 DEG C,
.
Embodiment 5:
The present embodiment novel nucleated glass is made of the raw material of following parts by weight:65 parts of silica, 7 parts of calcium oxide, zirconium
5 parts of diamond stone, 4 parts of silica sand, 5 parts of aluminium powder, 7 parts of magnesia, 2.6 parts of whisker, 2 parts of nucleating agent, 3 parts of potassium oxide, 0.3 part of fluorine;
Wherein, nucleating agent MnO2, ZrO2, TiO2 is according to mass ratio 0.5:1:1 mixes;Whisker is that zinc sulfate is brilliant
Palpus;
The preparation method of the present embodiment novel nucleated glass, includes the following steps:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1490 DEG C after mixing, obtained glass metal will be melted and be cooled to 580
DEG C, after putting into the mold compression moulding of glass press, obtain parent glass;
Through being sent into 640 DEG C of kiln, heat preservation 4h is allowed to soaking and eliminates stress for S3, the parent glass for obtaining step S2,
Then it is heated up with 2 DEG C/min of heating rate, is warming up to 790 DEG C, keep the temperature 1.5h, carry out coring processing;Then with the speed that heats up
2 DEG C/min of rate continues to heat up, and is warming up to 890 DEG C, keeps the temperature 1.5h, carries out Crystallizing treatment, Crystallizing treatment postcooling is to 100 DEG C or less
It comes out of the stove, you can.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although ginseng
According to previous embodiment, invention is explained in detail, it will be understood by those of ordinary skill in the art that:It still can be with
Technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features;And
These modifications or replacements, the spirit and model of various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution
It encloses.
Claims (7)
1. a kind of novel nucleated glass, which is characterized in that the novel nucleated glass is made of the raw material of following parts by weight:Dioxy
50-70 parts of SiClx, 3-8 parts of calcium oxide, 2-6 parts of zircon, 2-5 parts of silica sand, 2-6 parts of aluminium powder, 3-8 parts of magnesia, whisker 1-3
Part, 0.6-2.6 parts of nucleating agent, 1-3.7 parts of potassium oxide, 0.1-0.4 parts of fluorine.
2. novel nucleated glass according to claim 1, which is characterized in that the novel nucleated glass is by following parts by weight
Raw material is made:55-65 parts of silica, 4-7 parts of calcium oxide, 3-5 parts of zircon, 3-4 parts of silica sand, 3-5 parts of aluminium powder, magnesia 4-
7 parts, 1.5-2.6 parts of whisker, 1-2 parts of nucleating agent, 1.8-3 parts of potassium oxide, 0.2-0.3 parts of fluorine.
3. novel nucleated glass according to claim 1, which is characterized in that the novel nucleated glass is by following parts by weight
Raw material is made:60 parts of silica, 5.5 parts of calcium oxide, 4 parts of zircon, 3.5 parts of silica sand, 4 parts of aluminium powder, 5.5 parts of magnesia, crystalline substance
2 parts of palpus, 1.6 parts of nucleating agent, 2.3 parts of potassium oxide, 0.25 part of fluorine.
4. according to claims 1 or 2 or 3 novel nucleated glass, it is characterised in that:The nucleating agent be MnO2, ZrO2,
TiO2 is according to mass ratio 0.5:1:1 mixes.
5. according to claims 1 or 2 or 3 novel nucleated glass, it is characterised in that:The whisker is silicon whisker, potassium titanate
One kind in whisker, calcium sulfate crystal whiskers, zinc sulfate whisker.
6. a kind of preparation method of the novel nucleated glass as described in claim 1-5 is any, which is characterized in that including following step
Suddenly:
S1, each raw material is weighed according to parts by weight;
S2, each raw material is melted under the conditions of 1450-1500 DEG C after mixing, obtained glass metal will be melted and be cooled to
550-600 DEG C, after putting into the mold compression moulding of glass press, obtain parent glass;
S3, the parent glass for obtaining step S2 are through coring processing, Crystallizing treatment, cooling, you can.
7. preparation method according to claim 6, which is characterized in that the step S3 is to be sent into obtained parent glass
In 600-650 DEG C of kiln, 3-6h is kept the temperature, soaking is allowed to and eliminates stress, then heated up with 2-3 DEG C/min of heating rate,
It is warming up to 750-800 DEG C, keeps the temperature 1-3h, carries out coring processing;Then continue to heat up with 2-3 DEG C/min of heating rate, be warming up to
860-900 DEG C, 1-3h is kept the temperature, carries out Crystallizing treatment, Crystallizing treatment postcooling is come out of the stove to 100 DEG C or less, you can.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112479593A (en) * | 2020-11-18 | 2021-03-12 | 晶研一材料科技(宜兴)有限公司 | Heat-resistant adjustable-hardness special microcrystalline ceramic glass |
CN112479594A (en) * | 2020-11-18 | 2021-03-12 | 晶研一材料科技(宜兴)有限公司 | Method for processing microcrystalline ceramic glass |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62108742A (en) * | 1985-11-07 | 1987-05-20 | Asahi Glass Co Ltd | Preparation of augite series crystallized glass |
JPH03199136A (en) * | 1989-12-28 | 1991-08-30 | Asahi Glass Co Ltd | Production of pyroxene-line crystallized glass |
DE4125698C1 (en) * | 1991-08-02 | 1992-11-26 | Schott Glaswerke, 6500 Mainz, De | Glass ceramic material for replacing granite or marble in decorative applications - contains silica, alumina, calcia, magnesia, zirconia, barium oxide, potassium oxide, sodium oxide and fluorine |
JPH0710596A (en) * | 1993-06-24 | 1995-01-13 | Towa Denka Kogyo Kk | Crystallized glass and production thereof |
CN101805128A (en) * | 2010-04-20 | 2010-08-18 | 香港福山实业有限公司 | Jade-type glass-ceramic and preparation method thereof |
CN103663980A (en) * | 2013-12-06 | 2014-03-26 | 辽宁红山玉科技有限公司 | Low-fluorine microcrystalline glass |
CN106517800A (en) * | 2016-11-18 | 2017-03-22 | 中建材(江苏)应用技术研究院有限公司 | Glass ceramics and preparation method thereof |
CN106608712A (en) * | 2015-10-21 | 2017-05-03 | 北京化工大学 | In-situ reaction whisker glass ceramic and preparation method thereof |
CN107382074A (en) * | 2017-06-28 | 2017-11-24 | 常州美帛纺织品有限公司 | A kind of microcrystal glass plate and preparation method thereof |
-
2018
- 2018-05-17 CN CN201810471500.1A patent/CN108585528A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62108742A (en) * | 1985-11-07 | 1987-05-20 | Asahi Glass Co Ltd | Preparation of augite series crystallized glass |
JPH03199136A (en) * | 1989-12-28 | 1991-08-30 | Asahi Glass Co Ltd | Production of pyroxene-line crystallized glass |
DE4125698C1 (en) * | 1991-08-02 | 1992-11-26 | Schott Glaswerke, 6500 Mainz, De | Glass ceramic material for replacing granite or marble in decorative applications - contains silica, alumina, calcia, magnesia, zirconia, barium oxide, potassium oxide, sodium oxide and fluorine |
JPH0710596A (en) * | 1993-06-24 | 1995-01-13 | Towa Denka Kogyo Kk | Crystallized glass and production thereof |
CN101805128A (en) * | 2010-04-20 | 2010-08-18 | 香港福山实业有限公司 | Jade-type glass-ceramic and preparation method thereof |
CN103663980A (en) * | 2013-12-06 | 2014-03-26 | 辽宁红山玉科技有限公司 | Low-fluorine microcrystalline glass |
CN106608712A (en) * | 2015-10-21 | 2017-05-03 | 北京化工大学 | In-situ reaction whisker glass ceramic and preparation method thereof |
CN106517800A (en) * | 2016-11-18 | 2017-03-22 | 中建材(江苏)应用技术研究院有限公司 | Glass ceramics and preparation method thereof |
CN107382074A (en) * | 2017-06-28 | 2017-11-24 | 常州美帛纺织品有限公司 | A kind of microcrystal glass plate and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
国家建委材料科学研究院技术情报所编: "《建材情报资料 7302 国外矿渣微晶玻璃资料汇编 第2集》", 30 April 1973, 国家建委材料科学研究院技术情报所 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112479593A (en) * | 2020-11-18 | 2021-03-12 | 晶研一材料科技(宜兴)有限公司 | Heat-resistant adjustable-hardness special microcrystalline ceramic glass |
CN112479594A (en) * | 2020-11-18 | 2021-03-12 | 晶研一材料科技(宜兴)有限公司 | Method for processing microcrystalline ceramic glass |
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Application publication date: 20180928 |