CN108585520A - A kind of abrasion-resistance glass and preparation method thereof - Google Patents
A kind of abrasion-resistance glass and preparation method thereof Download PDFInfo
- Publication number
- CN108585520A CN108585520A CN201810471141.XA CN201810471141A CN108585520A CN 108585520 A CN108585520 A CN 108585520A CN 201810471141 A CN201810471141 A CN 201810471141A CN 108585520 A CN108585520 A CN 108585520A
- Authority
- CN
- China
- Prior art keywords
- parts
- resistance
- abrasion
- resistance glass
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of abrasion-resistance glass, include the raw material of following parts by weight:34 40 parts of improved silica, 32 36 parts of Reactive alumina, modified 22 28 parts of clinker, 12 18 parts of flyash, 6 10 parts of silicon powder, 8 14 parts of compound rare-earth mine, 4 10 parts of wear resistant filler, 37 parts of resistance to grinding reinforcing agent.The object of the present invention is to provide a kind of abrasion-resistance glass and preparation method thereof, for the glass on keeping original base performance, wearability has obtained very big improvement, has higher use value and good application prospect.
Description
Technical field
The present invention relates to glass technology fields, and in particular to a kind of abrasion-resistance glass and preparation method thereof.
Background technology
Glass is amorphous inorganic non-metallic material, and usually with a variety of inorganic minerals, (such as quartz sand, borax, boric acid, weight are brilliant
Stone, barium carbonate, lime stone, feldspar, soda ash etc.) be primary raw material, additionally incorporate made of a small amount of auxiliary material, it is main at
It is divided into silica and other oxides, the chemical composition of simple glass is Na2SiO3, CaSiO3, SiO2 or Na2OCaO
6SiO2 etc., main component are silicate double salt, are a kind of non-crystalline solids of random structure, are widely used in building, are used
, every wind light transmission, to belong to mixture, separately there is the oxide for being mixed into certain metals or salt and shows the coloured glass of color
Glass, and by tempered glass etc. made from the method for physics or chemistry, some transparent plastics are also referred to as organic glass sometimes
Glass.
Existing glass wearability is not also fine, still needs to further improve.
Invention content
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of abrasion-resistance glass and preparation method thereof, the glass
On keeping original base performance, wearability has obtained very big improvement, has higher use value and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that:
The present invention provides a kind of abrasion-resistance glass, include the raw material of following parts by weight:
34-40 parts of improved silica, 32-36 parts of Reactive alumina, modified 22-28 parts of clinker, flyash 12-18
Part, 6-10 parts of silicon powder, 8-14 parts of compound rare-earth mine, 4-10 parts, the 3-7 of resistance to grinding reinforcing agent parts of wear resistant filler.
Preferably, the abrasion-resistance glass includes the raw material of following parts by weight:
37 parts of improved silica, 34 parts of Reactive alumina, modified 25 parts of clinker, 15 parts of flyash, silicon powder 8
Part, 11 parts of compound rare-earth mine, 7 parts of wear resistant filler, 5 parts of resistance to grinding reinforcing agent.
Preferably, the improved silica preparation method is that silica is added in ethanol solution to carry out ultrasound point
It dissipates, is then modified with silane coupling agent, centrifuge, be drying to obtain improved silica.
Preferably, the preparation method of the modified clinker be by clinker feeding temperature be 755-855 DEG C in calcining furnace into
Row calcining, is then cooled to room temperature, and it is 10-20% ferric chloride solutions that mass fraction, which is then added, reacts 15-25min to get changing
Property clinker.
Preferably, the compound rare-earth mine is monazite, granite, spodumene according to weight ratio 7:3:1 progress is compound.
Preferably, the monazite, granite, spodumene grain size are 40 mesh.
Preferably, the wear resistant filler is one or more compositions in silicon carbide, barium sulfate, white fused alumina.
Preferably, the resistance to grinding reinforcing agent is polysiloxanes, polyaniline according to weight ratio 5:The mixture of 2 compositions.
The present invention also provides a kind of preparation methods of abrasion-resistance glass, include the following steps:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth
Mine, wear resistant filler, resistance to grinding reinforcing agent are added in high-speed mixer, rotating speed 1150-1250r/min, mixing time 25-
35min is then calcined, and calcination temperature is 1155-1250 DEG C, calcines 35-45min, by the glass metal of melting feeding go from
Sub- cold water is quenched, cooling, obtains substance A;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 10-100 to be milled to grain size
Mesh is then annealed, and annealing temperature is 550-750 DEG C to get abrasion-resistance glass.
Preferably, the preparation process is:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth
Mine, wear resistant filler, resistance to grinding reinforcing agent are added in high-speed mixer, rotating speed 1200r/min, mixing time 30min, then
It is calcined, calcination temperature is 1200 DEG C, calcines 40min, and the glass metal of melting, which is sent into deionization cold water, to quench, cold
But, substance A is obtained;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 55 mesh to be milled to grain size, with
After anneal, annealing temperature be 600 DEG C to get abrasion-resistance glass.
Compared with prior art, the present invention has following advantageous effect:
(1) a kind of abrasion-resistance glass and preparation method thereof of the invention, silica, clinker are by being modified, increased activity, then
It is aided with Reactive alumina, improves the activity of component, the present invention is mostly matched with active constituent, compared with the prior art
In, raw material preferably mutually melts, and wearability is greatly improved.
(2) a kind of abrasion-resistance glass and preparation method thereof of the invention, resistance to grinding reinforcing agent are polysiloxanes, polyaniline composition original
Material, this is combined as solution combination, and polysiloxanes good combination property blends polyaniline and applies on glass, makes glass in crystallization mistake
The stable structure formed in journey, then improves wearability.
(3) a kind of abrasion-resistance glass and preparation method thereof of the invention, the glass is on keeping original base performance, wearability
Very big improvement has been obtained, there is higher use value and good application prospect.
Specific implementation mode
With reference to specific embodiment, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of abrasion-resistance glass of the present embodiment, includes the raw material of following parts by weight:
34 parts of improved silica, 32 parts of Reactive alumina, modified 22 parts of clinker, 12 parts of flyash, silicon powder 6
Part, 8 parts of compound rare-earth mine, 4 parts of wear resistant filler, 3 parts of resistance to grinding reinforcing agent.
The improved silica preparation method of the present embodiment is that silica is added in ethanol solution to carry out ultrasound point
It dissipates, is then modified with silane coupling agent, centrifuge, be drying to obtain improved silica.
It is to be forged in calcining furnace at 755 DEG C that the preparation method of the modification clinker of the present embodiment, which is by clinker feeding temperature,
It burns, is then cooled to room temperature, it is 10% ferric chloride solution that mass fraction, which is then added, and reaction 15min is to get modified clinker.
The compound rare-earth mine of the present embodiment is monazite, granite, spodumene according to weight ratio 7:3:1 progress is compound.
The monazite, granite, spodumene grain size of the present embodiment are 40 mesh.
Preferably, the resistance to grinding reinforcing agent is polysiloxanes, polyaniline according to weight ratio to the present embodiment of the present embodiment
5:The mixture of 2 compositions.
A kind of preparation method of abrasion-resistance glass of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth
Mine, wear resistant filler, resistance to grinding reinforcing agent are added in high-speed mixer, rotating speed 1150r/min, mixing time 25min, then
It is calcined, calcination temperature is 1155 DEG C, calcines 35min, and the glass metal of melting, which is sent into deionization cold water, to quench, cold
But, substance A is obtained;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 10 mesh to be milled to grain size, with
After anneal, annealing temperature be 550 DEG C to get abrasion-resistance glass.
Embodiment 2.
A kind of abrasion-resistance glass of the present embodiment, includes the raw material of following parts by weight:
40 parts of improved silica, 36 parts of Reactive alumina, modified 28 parts of clinker, 18 parts of flyash, silicon powder 10
Part, 14 parts of compound rare-earth mine, 10 parts of wear resistant filler, 7 parts of resistance to grinding reinforcing agent.
The abrasion-resistance glass of the present embodiment includes the raw material of following parts by weight:
The improved silica preparation method of the present embodiment is that silica is added in ethanol solution to carry out ultrasound point
It dissipates, is then modified with silane coupling agent, centrifuge, be drying to obtain improved silica.
It is to be forged in calcining furnace at 855 DEG C that the preparation method of the modification clinker of the present embodiment, which is by clinker feeding temperature,
It burns, is then cooled to room temperature, it is 20% ferric chloride solution that mass fraction, which is then added, and reaction 25min is to get modified clinker.
The compound rare-earth mine of the present embodiment is monazite, granite, spodumene according to weight ratio 7:3:1 progress is compound.
The monazite, granite, spodumene grain size of the present embodiment are 40 mesh.
Preferably, the resistance to grinding reinforcing agent is polysiloxanes, polyaniline according to weight ratio to the present embodiment of the present embodiment
5:The mixture of 2 compositions.
A kind of preparation method of abrasion-resistance glass of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth
Mine, wear resistant filler, resistance to grinding reinforcing agent are added in high-speed mixer, rotating speed 1250r/min, mixing time 35min, then
It is calcined, calcination temperature is 1250 DEG C, calcines 45min, and the glass metal of melting, which is sent into deionization cold water, to quench, cold
But, substance A is obtained;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 100 mesh to be milled to grain size, with
After anneal, annealing temperature be 750 DEG C to get abrasion-resistance glass.
Embodiment 3.
A kind of abrasion-resistance glass of the present embodiment, includes the raw material of following parts by weight:
37 parts of improved silica, 34 parts of Reactive alumina, modified 25 parts of clinker, 15 parts of flyash, silicon powder 8
Part, 11 parts of compound rare-earth mine, 7 parts of wear resistant filler, 5 parts of resistance to grinding reinforcing agent.
The improved silica preparation method of the present embodiment is that silica is added in ethanol solution to carry out ultrasound point
It dissipates, is then modified with silane coupling agent, centrifuge, be drying to obtain improved silica.
It is to be forged in calcining furnace at 800 DEG C that the preparation method of the modification clinker of the present embodiment, which is by clinker feeding temperature,
It burns, is then cooled to room temperature, it is 15% ferric chloride solution that mass fraction, which is then added, and reaction 20min is to get modified clinker.
The compound rare-earth mine of the present embodiment is monazite, granite, spodumene according to weight ratio 7:3:1 progress is compound.
The monazite, granite, spodumene grain size of the present embodiment are 40 mesh.
Preferably, the resistance to grinding reinforcing agent is polysiloxanes, polyaniline according to weight ratio to the present embodiment of the present embodiment
5:The mixture of 2 compositions.
A kind of preparation method of abrasion-resistance glass of the present embodiment, includes the following steps:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth
Mine, wear resistant filler, resistance to grinding reinforcing agent are added in high-speed mixer, rotating speed 1200r/min, mixing time 30min, then
It is calcined, calcination temperature is 1200 DEG C, calcines 40min, and the glass metal of melting, which is sent into deionization cold water, to quench, cold
But, substance A is obtained;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 55 mesh to be milled to grain size, with
After anneal, annealing temperature be 600 DEG C to get abrasion-resistance glass.
Comparative example 1.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not adding wear resistant filler.
Comparative example 2.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not adding resistance to grinding reinforcing agent.
Comparative example 3.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that resistance to grinding reinforcing agent is not added with poly- silica
Alkane.
Comparative example 4.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that resistance to grinding reinforcing agent is not added with polyaniline.
Glass prepared by embodiment 3 and comparative example 1-4 is tested to obtain the performance test results as follows
Wearability | |
Embodiment 3 | It is excellent |
Comparative example 1 | Well |
Comparative example 2 | Well |
Comparative example 3 | It is excellent |
Comparative example 4 | It is excellent |
A kind of abrasion-resistance glass and preparation method thereof of the present invention, on keeping original base performance, wearability obtains the glass
Very big improvement has been arrived, there is higher use value and good application prospect.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (10)
1. a kind of abrasion-resistance glass, which is characterized in that include the raw material of following parts by weight:
34-40 parts of improved silica, 32-36 parts of Reactive alumina, modified 22-28 parts of clinker, 12-18 parts of flyash,
6-10 parts of silicon powder, 8-14 parts of compound rare-earth mine, 4-10 parts, the 3-7 of resistance to grinding reinforcing agent parts of wear resistant filler.
2. a kind of abrasion-resistance glass according to claim 1, which is characterized in that the abrasion-resistance glass includes following parts by weight
Raw material:
37 parts of improved silica, 25 parts of clinker of modification, 15 parts of flyash, 8 parts of silicon powder, is answered at 34 parts of Reactive alumina
Close 11 parts of Rare Earth Mine, 7 parts of wear resistant filler, 5 parts of resistance to grinding reinforcing agent.
3. a kind of abrasion-resistance glass according to claim 1 or 2, which is characterized in that the improved silica preparation method
Ultrasonic disperse is carried out for silica to be added in ethanol solution, is then modified with silane coupling agent, is centrifuged, drying is
Obtain improved silica.
4. a kind of abrasion-resistance glass according to claim 1, which is characterized in that the preparation method of the modified clinker is by stove
It is to be calcined in calcining furnace at 755-855 DEG C that slag, which is sent into temperature, is then cooled to room temperature, and it is 10- that mass fraction, which is then added,
20% ferric chloride solution, reaction 15-25min is to get modified clinker.
5. a kind of abrasion-resistance glass according to claim 1, which is characterized in that the compound rare-earth mine is monazite, Hua Gang
Rock, spodumene are according to weight ratio 7:3:1 progress is compound.
6. a kind of abrasion-resistance glass according to claim 5, which is characterized in that the monazite, granite, spodumene grain size
For 40 mesh.
7. a kind of abrasion-resistance glass according to claim 1, which is characterized in that the wear resistant filler be silicon carbide, barium sulfate,
One or more compositions in white fused alumina.
8. a kind of abrasion-resistance glass according to claim 1, which is characterized in that the resistance to grinding reinforcing agent is polysiloxanes, gathers
Aniline is according to weight ratio 5:The mixture of 2 compositions.
9. a kind of preparing the method such as claim 1-8 any one of them abrasion-resistance glass, which is characterized in that including following step
Suddenly:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth mine, resistance to
Filler, resistance to grinding reinforcing agent are ground, is added in high-speed mixer, rotating speed 1150-1250r/min, mixing time 25-35min, with
After calcined, calcination temperature is 1155-1250 DEG C, calcines 35-45min, by the glass metal of melting be sent into deionization cold water into
Row quenching, it is cooling, obtain substance A;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 10-100 mesh to be milled to grain size, with
After anneal, annealing temperature be 550-750 DEG C to get abrasion-resistance glass.
10. a kind of preparation method of abrasion-resistance glass according to claim 9, which is characterized in that the preparation process is:
Step 1 weighs each component raw material as required;
Step 2, by improved silica, Reactive alumina, modified clinker, flyash, silicon powder, compound rare-earth mine, resistance to
Filler, resistance to grinding reinforcing agent are ground, is added in high-speed mixer, rotating speed 1200r/min, mixing time 30min are then forged
It burns, calcination temperature is 1200 DEG C, calcines 40min, and the glass metal of melting, which is sent into deionization cold water, to quench, cooling, obtains
Substance A;
Step 3 sends to ball milling of entering in ball mill by substance A is mixed made from step 2, and it is 55 mesh to be milled to grain size, with laggard
Row annealing, annealing temperature are 600 DEG C to get abrasion-resistance glass.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810471141.XA CN108585520A (en) | 2018-05-17 | 2018-05-17 | A kind of abrasion-resistance glass and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810471141.XA CN108585520A (en) | 2018-05-17 | 2018-05-17 | A kind of abrasion-resistance glass and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108585520A true CN108585520A (en) | 2018-09-28 |
Family
ID=63631759
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810471141.XA Withdrawn CN108585520A (en) | 2018-05-17 | 2018-05-17 | A kind of abrasion-resistance glass and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108585520A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111533451A (en) * | 2020-05-12 | 2020-08-14 | 广州鑫泓设备设计有限公司 | Novel glass handicraft processing technology |
CN114057396A (en) * | 2021-12-14 | 2022-02-18 | 赵嘉成 | Acid and alkali resistant colorful glass and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1099359A (en) * | 1993-08-21 | 1995-03-01 | 陈树军 | Formula and process of preparing devitroceram using flyash |
CN104310979A (en) * | 2014-10-22 | 2015-01-28 | 华文蔚 | Functional ceramic powder material as well as preparation method and application thereof |
CN105417956A (en) * | 2016-01-17 | 2016-03-23 | 北京清迈华清控股(集团)有限公司 | Method for producing microlite by using high silicon-iron tailings |
CN106587613A (en) * | 2016-11-29 | 2017-04-26 | 枞阳县铭瑞电子科技有限公司 | Wearable mobile phone rear glass cover plate |
CN107010839A (en) * | 2017-04-18 | 2017-08-04 | 宋小明 | A kind of micro crystal material of cerium mischmetal containing lanthanum and preparation method thereof |
CN108455868A (en) * | 2018-02-09 | 2018-08-28 | 和县华安玻璃制品有限公司 | A kind of freeze proof glassware of high abrasion and its preparation process |
-
2018
- 2018-05-17 CN CN201810471141.XA patent/CN108585520A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1099359A (en) * | 1993-08-21 | 1995-03-01 | 陈树军 | Formula and process of preparing devitroceram using flyash |
CN104310979A (en) * | 2014-10-22 | 2015-01-28 | 华文蔚 | Functional ceramic powder material as well as preparation method and application thereof |
CN105417956A (en) * | 2016-01-17 | 2016-03-23 | 北京清迈华清控股(集团)有限公司 | Method for producing microlite by using high silicon-iron tailings |
CN106587613A (en) * | 2016-11-29 | 2017-04-26 | 枞阳县铭瑞电子科技有限公司 | Wearable mobile phone rear glass cover plate |
CN107010839A (en) * | 2017-04-18 | 2017-08-04 | 宋小明 | A kind of micro crystal material of cerium mischmetal containing lanthanum and preparation method thereof |
CN108455868A (en) * | 2018-02-09 | 2018-08-28 | 和县华安玻璃制品有限公司 | A kind of freeze proof glassware of high abrasion and its preparation process |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111533451A (en) * | 2020-05-12 | 2020-08-14 | 广州鑫泓设备设计有限公司 | Novel glass handicraft processing technology |
CN114057396A (en) * | 2021-12-14 | 2022-02-18 | 赵嘉成 | Acid and alkali resistant colorful glass and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101215091A (en) | Preparation method of leadless glass powder for electronic slurry | |
CN113087420B (en) | Stokehole modified steel slag and preparation method thereof | |
CN100383071C (en) | Sludge microcrystalline glass and its preparation method | |
WO2011057537A1 (en) | Composition used to produce igneous rock crystal glass material, igneous rock crystal glass material and production method thereof | |
CN106396410A (en) | Production method of microcrystalline glass | |
CN108585520A (en) | A kind of abrasion-resistance glass and preparation method thereof | |
CN113816640A (en) | Tuff-based composite mineral admixture and preparation method thereof | |
CN110590170B (en) | Fly ash-based inorganic fiber and preparation method thereof | |
CN106517800A (en) | Glass ceramics and preparation method thereof | |
CN105236747A (en) | Mechanical force arm | |
CN105271764B (en) | A kind of low energy consumption iron tailings building microcrystalline glass and preparation method thereof | |
CN108298814A (en) | A kind of novel building glass and preparation method thereof | |
CN108358455B (en) | Method for preparing microcrystalline glass by using lead-zinc tailings and quartz tailings | |
CN106336134A (en) | Preparation method of low-clinker cement | |
Lu et al. | PREPARATION AND PERFORMANCE STUDY OF GLASS-CERAMIC GLAZES DERIVED FROM BLAST FURNACE SLAG AND FLY ASH | |
CN108395103A (en) | A kind of body crystallization α cordierite glass-ceramic standby using Bayan Obo tailing and coal ash for manufacturing and preparation method thereof | |
KR101579512B1 (en) | Composition for soda lime glass | |
CN108751719A (en) | A kind of preparation method based on modified grammite devitrified glass | |
CN101186444B (en) | Low-cost microcrystalline glass material and preparing technique thereof | |
KR101924840B1 (en) | Component for manufacturing bio-far ir glass tile and manufacturing method of bio-far ir glass tile | |
KR100579189B1 (en) | Method for preparing the crystallized glass tile using cullet | |
CN105462300A (en) | Paint and preparation method thereof | |
CN110698103A (en) | Chemical excitant for preparing coal ash/slag geopolymer | |
CN115353289B (en) | Glass powder and preparation method and application thereof | |
CN104030565A (en) | Thermos bottle blank material with high thermal stability |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180928 |
|
WW01 | Invention patent application withdrawn after publication |