CN108455868A - A kind of freeze proof glassware of high abrasion and its preparation process - Google Patents
A kind of freeze proof glassware of high abrasion and its preparation process Download PDFInfo
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- CN108455868A CN108455868A CN201810134530.3A CN201810134530A CN108455868A CN 108455868 A CN108455868 A CN 108455868A CN 201810134530 A CN201810134530 A CN 201810134530A CN 108455868 A CN108455868 A CN 108455868A
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- glassware
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- high abrasion
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
The present invention relates to glassware manufacturing fields, and in particular to a kind of freeze proof glassware of high abrasion and its preparation process, the glassware are made of following parts by weight raw material：60 75 parts of SiO 2 powders, 10 20 parts of sodium carbonate, 3 10 parts of potassium carbonate, 26 parts of lime powders, 15 25 parts of flyash, 48 parts of titania powders, 37 parts of boron oxide powder, 49 parts of phosphoric acid, 16 parts of aluminium powders, it is melted by heating, extrusion forming, annealing, tempering obtains the freeze proof glassware of high abrasion；Technical solution provided by the present invention can effectively overcome frost resistance existing for the made glassware of the prior art poor, and the defect to wear no resistance is worthy to be popularized.
Description
Technical field
The present invention relates to glassware manufacturing fields, and in particular to a kind of freeze proof glassware of high abrasion and its prepares work
Skill.
Background technology
Glass is that one kind is transparent, airtight, and has the material of certain degree of hardness.Glass is in chemical inertness in surroundings,
Also it will not work with biology.Glass does not dissolve in acid (exception generally：Hydrofluoric acid is reacted with glass generates SiF4, so as to cause glass
The corrosion of glass).Glassware, which has, cleans transparent, easy to clean advantage, has brought in daily life greatly
Convenient, people’s lives gradually be unable to do without the presence of glassware.
In patent application CN102898025A disclosed in China for obtain a kind of amber glassware formula and its
The parts by weight of preparation method, constitutive material are：Quartz sand 360-370, aluminium hydroxide 15-16, calcite 38-42, dolomite
30-35, soda ash 120-125, potassium carbonate 2.5-3.0, barium sulfate 3.5-4.0, iron oxide 1.0-2.0 and sulfur oxide 1.0-2.0.This
The technology sky that amber glassware product is generated in cell furnace has been filled up by the amber glassware dispensing material side of invention
In vain, which is specially newly-designed for production amber glassware, and color is unique, multigroup part, is easily melted, simple for process,
Yield is big, high financial profit.
For a kind of system of high intensity antibiotic glass vessel of acquisition in patent application CN107265849A disclosed in China
Standby technique, includes the following steps：(1) raw material is weighed, is mixed：Weigh each raw material of following parts by weight：70-80 parts of quartz sand, side
Solve 10-15 parts of stone, 3-5 parts of aluminium hydroxide, 14-16 parts of boron oxide, 1-3 parts of potassium carbonate, 0.4-0.8 parts of silver orthophosphate, nano oxidized
0.01-0.05 parts of cerium；Sieving, mixing；(2) high temperature melting：Mixed powder is sent into smelting furnace high temperature melting, 0.5- is added after fusing
1.5 parts of four acicular type zinc oxide crystal whiskers obtain glass melt after being melted；(3) processing and forming；(4) it anneals；(5) tempering is handled；This hair
The temperature and cooling rate of annealing is rationally arranged in each reasonable raw material proportioning in bright after passing through high temperature melting, processing and forming,
Tempering processing when temperature and the parameters such as heating rate, make glassware produced by the present invention that there is heat-resist, color and luster
The advantages that beautiful, while anti-microbial property is strong.
Although the made glassware of the prior art has certain heat resistance, in beautiful color, it is poor that there is also frost resistances, resistance to
The defect of mill property difference.
Invention content
In view of the above problems, the present invention proposes a kind of freeze proof glassware of high abrasion.The made glass of the present invention
Vessel compensate for the defect that frost resistance existing for existing glassware is poor, wears no resistance.
In order to achieve the above purpose, the present invention uses technical solution below：
A kind of freeze proof glassware of high abrasion and its preparation process, the glassware are made of following parts by weight raw material：
60-75 parts of SiO 2 powders, 10-20 parts of sodium carbonate, 3-10 parts of potassium carbonate, 2-6 parts of lime powders, 15-25 parts of flyash,
4-8 parts of titania powders, 3-7 parts of boron oxide powder, 4-9 parts of phosphoric acid, 1-6 parts of aluminium powders.
Preferably, which is made of following parts by weight raw material：65-70 parts of SiO 2 powders, 15-18 parts of carbon
Sour sodium, 5-8 part potassium carbonate, 3-5 parts of lime powders, 16-20 parts of flyash, 5-7 parts of titania powders, 4-6 parts of boron oxides
Powder, 5-8 part phosphoric acid, 2-5 parts of aluminium powders.
The preparation process of the glassware includes the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, in certain temperature
Tube furnace in be heat-treated 2h, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, is added water to wherein with suitable material-water ratio,
It is to slowly warm up to 400-500 DEG C under heating conditions, is ultrasonically treated a period of time, is cooled to room temperature, subsequent vacuum dehydration is standby
With；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, suitable adhesive are added, after sealing
It is heated to molten condition, obtains glass melt, using die pressing compression moulding, the different glassware of specification is made, then certainly
It is sent into annealing furnace annealing after being so cooled to hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof vierics of high abrasion is obtained after the completion of tempering
Ware.
Preferably, tubular type in-furnace temperature is 1000-1100 DEG C in step (1).
Preferably, material-water ratio is 2 in step (2):1.
Preferably, sonication treatment time is 5-10min in step (2).
Using above-mentioned technical solution, the beneficial effects of the invention are as follows：Aluminium, titanium dioxide, boron oxide can promote thermalization
It learns reaction and generates Al6O13Si2、TiB2Etc. hard, wear-resistant phases, they undertake main wear-resistant effect in friction process, melting system
Aluminium powder is preferentially melted as low melting point in standby glass process, can effectively be filled coating and be cracked in curing process
And hole, play toughened and reinforced effect；The pyrogenous origin product P of phosphoric acid4O10It is phosphorus oxygen glass structure, introduces in the melt
B2O3, [BPO can be formed4] structural unit so that glass structure is changed into cotton-shaped by chain, is strengthened reticular structure, is enhanced
Good combination interface effectively raises the intensity and antioxygenic property of glassware；Flyash and SiO 2 powder
Blending prepares glassware, compression strength, flexural strength and the toughness of glassware can be significantly improved, in addition, flyash
Coordinate with silica, additionally it is possible to which the freezing tolerance for improving glassware to a certain extent extends the use of glassware
Service life.
Specific implementation mode is handed over flat
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described.Based on the embodiment of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Embodiment 1：
A kind of freeze proof glassware of high abrasion, the glassware are made of following parts by weight raw material：60 parts of silica
Powder, 20 parts of sodium carbonate, 3 parts of potassium carbonate, 6 parts of lime powders, 15 parts of flyash, 8 parts of titania powders, 3 parts of boron oxides
Powder, 9 parts of phosphoric acid, 1 part of aluminium powder.
The preparation process of the glassware includes the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, at 1000 DEG C
2h is heat-treated in tube furnace, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, with 2:1 material-water ratio adds water to wherein,
It is to slowly warm up to 450 DEG C under heating conditions, is ultrasonically treated 10min, is cooled to room temperature, subsequent vacuum dehydration is spare；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, suitable adhesive are added, after sealing
It is heated to molten condition, obtains glass melt, using die pressing compression moulding, the different glassware of specification is made, then certainly
It is sent into annealing furnace annealing after being so cooled to hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof vierics of high abrasion is obtained after the completion of tempering
Ware.
Embodiment 2：
A kind of freeze proof glassware of high abrasion, the glassware are made of following parts by weight raw material：75 parts of silica
Powder, 10 parts of sodium carbonate, 10 parts of potassium carbonate, 2 parts of lime powders, 25 parts of flyash, 4 parts of titania powders, 7 parts of boron oxides
Powder, 4 parts of phosphoric acid, 6 parts of aluminium powders.
The preparation process of the glassware includes the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, at 1100 DEG C
2h is heat-treated in tube furnace, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, with 2:1 material-water ratio adds water to wherein,
It is to slowly warm up to 450 DEG C under heating conditions, is ultrasonically treated 10min, is cooled to room temperature, subsequent vacuum dehydration is spare；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, suitable adhesive are added, after sealing
It is heated to molten condition, obtains glass melt, using die pressing compression moulding, the different glassware of specification is made, then certainly
It is sent into annealing furnace annealing after being so cooled to hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof vierics of high abrasion is obtained after the completion of tempering
Ware.
Embodiment 3：
A kind of freeze proof glassware of high abrasion, the glassware are made of following parts by weight raw material：65 parts of silica
Powder, 18 parts of sodium carbonate, 5 parts of potassium carbonate, 5 parts of lime powders, 16 parts of flyash, 7 parts of titania powders, 4 parts of boron oxides
Powder, 8 parts of phosphoric acid, 2 parts of aluminium powders.
The preparation process of the glassware includes the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, at 1100 DEG C
2h is heat-treated in tube furnace, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, with 2:1 material-water ratio adds water to wherein,
It is to slowly warm up to 400 DEG C under heating conditions, is ultrasonically treated 10min, is cooled to room temperature, subsequent vacuum dehydration is spare；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, suitable adhesive are added, after sealing
It is heated to molten condition, obtains glass melt, using die pressing compression moulding, the different glassware of specification is made, then certainly
It is sent into annealing furnace annealing after being so cooled to hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof vierics of high abrasion is obtained after the completion of tempering
Ware.
Embodiment 4：
A kind of freeze proof glassware of high abrasion, the glassware are made of following parts by weight raw material：70 parts of silica
Powder, 15 parts of sodium carbonate, 8 parts of potassium carbonate, 3 parts of lime powders, 20 parts of flyash, 5 parts of titania powders, 6 parts of boron oxides
Powder, 5 parts of phosphoric acid, 5 parts of aluminium powders.
The preparation process of the glassware includes the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, at 1000 DEG C
2h is heat-treated in tube furnace, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, with 2:1 material-water ratio adds water to wherein,
It is to slowly warm up to 500 DEG C under heating conditions, is ultrasonically treated 5min, is cooled to room temperature, subsequent vacuum dehydration is spare；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, suitable adhesive are added, after sealing
It is heated to molten condition, obtains glass melt, using die pressing compression moulding, the different glassware of specification is made, then certainly
It is sent into annealing furnace annealing after being so cooled to hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof vierics of high abrasion is obtained after the completion of tempering
Ware.
Embodiment 5：
A kind of freeze proof glassware of high abrasion, the glassware are made of following parts by weight raw material：68 parts of silica
Powder, 16 parts of sodium carbonate, 7 parts of potassium carbonate, 4 parts of lime powders, 18 parts of flyash, 6 parts of titania powders, 5 parts of boron oxides
Powder, 7 parts of phosphoric acid, 4 parts of aluminium powders.
The preparation process of the glassware includes the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, at 1050 DEG C
2h is heat-treated in tube furnace, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, with 2:1 material-water ratio adds water to wherein,
It is to slowly warm up to 400 DEG C under heating conditions, is ultrasonically treated 5min, is cooled to room temperature, subsequent vacuum dehydration is spare；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, suitable adhesive are added, after sealing
It is heated to molten condition, obtains glass melt, using die pressing compression moulding, the different glassware of specification is made, then certainly
It is sent into annealing furnace annealing after being so cooled to hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof vierics of high abrasion is obtained after the completion of tempering
Ware.
Glassware in glassware and market in the embodiment of the present invention is done into contrast properties test, test result
It is as follows：
The glassware is compared with glassware common in market as can be seen from the above table, and this product has excellent resistance to
Mill property and frost resistance.
Above example is only to illustrate the technical solution of type of the present invention, rather than its limitations；Although with reference to aforementioned implementation
Type of the present invention is described in detail in example, it will be understood by those of ordinary skill in the art that：It still can be to aforementioned each
Technical solution recorded in embodiment is modified or equivalent replacement of some of the technical features；And these are changed
Or it replaces, the spirit and scope for each embodiment technical solution of type of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (6)
1. a kind of freeze proof glassware of high abrasion, which is characterized in that the glassware is made of following parts by weight raw material：60-
75 parts of SiO 2 powders, 10-20 parts of sodium carbonate, 3-10 parts of potassium carbonate, 2-6 parts of lime powders, 15-25 parts of flyash, 4-8
Part titania powder, 3-7 parts of boron oxide powder, 4-9 parts of phosphoric acid, 1-6 parts of aluminium powders.
2. the freeze proof glassware of high abrasion according to claim 1, which is characterized in that the glassware is by following parts by weight
Number raw material is made：65-70 parts of SiO 2 powders, 15-18 parts of sodium carbonate, 5-8 parts of potassium carbonate, 3-5 parts of lime powders, 16-
20 parts of flyash, 5-7 parts of titania powders, 4-6 parts of boron oxide powder, 5-8 parts of phosphoric acid, 2-5 parts of aluminium powders.
3. the freeze proof glassware of high abrasion according to claim 1, which is characterized in that the preparation process packet of the glassware
Include the following steps：
(1) SiO 2 powder, boron oxide powder and aluminium powder is taken to stir evenly, as in nitrogen atmosphere, in the pipe of certain temperature
2h is heat-treated in formula stove, it is spare；
(2) sodium carbonate, potassium carbonate, lime powder are added in a kettle, is added water to wherein, is being added with suitable material-water ratio
It is to slowly warm up to 400-500 DEG C under conditions of heat, is ultrasonically treated a period of time, is cooled to room temperature, subsequent vacuum dehydration is spare；
(3) above-mentioned steps resulting material and surplus material are added in smelting furnace together, add suitable adhesive, is heated after sealing
To molten condition, glass melt is obtained, using die pressing compression moulding, the different glassware of specification is made, is then dropped naturally
Temperature is sent into annealing furnace annealing to after hardening；
(4) glassware after annealing is sent into tempering in tempering case, the freeze proof glassware of high abrasion is obtained after the completion of tempering.
4. the preparation process of the freeze proof glassware of high abrasion according to claim 3, which is characterized in that the step (1)
Middle tubular type in-furnace temperature is 1000-1100 DEG C.
5. the preparation process of the freeze proof glassware of high abrasion according to claim 3, which is characterized in that the step (2)
Middle material-water ratio is 2:1.
6. the preparation process of the freeze proof glassware of high abrasion according to claim 3, which is characterized in that the step (2)
Middle sonication treatment time is 5-10min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810134530.3A CN108455868A (en) | 2018-02-09 | 2018-02-09 | A kind of freeze proof glassware of high abrasion and its preparation process |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810134530.3A CN108455868A (en) | 2018-02-09 | 2018-02-09 | A kind of freeze proof glassware of high abrasion and its preparation process |
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| CN108455868A true CN108455868A (en) | 2018-08-28 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108585520A (en) * | 2018-05-17 | 2018-09-28 | 合肥协耀玻璃制品有限公司 | A kind of abrasion-resistance glass and preparation method thereof |
| CN117401905A (en) * | 2023-10-12 | 2024-01-16 | 洪泽县港宏玻璃瓶制造有限公司 | High-temperature-resistant and pressure-resistant perfume bottle and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107117821A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of high strength micro-crystalline glass and preparation method thereof |
| CN107265849A (en) * | 2017-06-12 | 2017-10-20 | 和县晶晶玻璃制品有限公司 | A kind of production technology of high intensity antibiotic glass vessel |
-
2018
- 2018-02-09 CN CN201810134530.3A patent/CN108455868A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107265849A (en) * | 2017-06-12 | 2017-10-20 | 和县晶晶玻璃制品有限公司 | A kind of production technology of high intensity antibiotic glass vessel |
| CN107117821A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of high strength micro-crystalline glass and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108585520A (en) * | 2018-05-17 | 2018-09-28 | 合肥协耀玻璃制品有限公司 | A kind of abrasion-resistance glass and preparation method thereof |
| CN117401905A (en) * | 2023-10-12 | 2024-01-16 | 洪泽县港宏玻璃瓶制造有限公司 | High-temperature-resistant and pressure-resistant perfume bottle and preparation method thereof |
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