CN108582926A - A kind of preparation method of two-way bulletproof glass - Google Patents

A kind of preparation method of two-way bulletproof glass Download PDF

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Publication number
CN108582926A
CN108582926A CN201810397208.XA CN201810397208A CN108582926A CN 108582926 A CN108582926 A CN 108582926A CN 201810397208 A CN201810397208 A CN 201810397208A CN 108582926 A CN108582926 A CN 108582926A
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China
Prior art keywords
thickness
thermoplastic resin
glass
sheet glass
original sheet
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CN201810397208.XA
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Chinese (zh)
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CN108582926B (en
Inventor
骆罗辉
任明生
许鑫
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Jiangsu Hua Shang Automotive Glass Industries Co Ltd
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Jiangsu Hua Shang Automotive Glass Industries Co Ltd
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    • B32B17/064
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/42Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/10Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00Protective equipment
    • B32B2571/02Protective equipment defensive, e.g. armour plates, anti-ballistic clothing

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  • Joining Of Glass To Other Materials (AREA)

Abstract

The present invention provides a kind of preparation methods of two-way bulletproof glass, include the following steps:Raw material preparation:Original sheet glass is cut, edging, cleaning and printing, drying carries out hot bending again that original sheet glass is made to reach required camber, thermoplastic resin board timber-used water knife is cut by required figure, surface is subjected to cleaning treatment after the completion of cutting, thermoplastic resin plank is put into after cleaning treatment and closes piece interior carry out dehumidification treatments, the thermoplastic resin plank after dehumidifying is put into promote between original sheet glass described in the two panels after hot bending carries out crooked reason in vacuum tank;Close piece:The original sheet glass that PVB films that TPU membrane that thermoplastic resin plank that TPU membrane that thermoplastic resin plank that TPU membrane that PVB films that original sheet glass that thickness is 4mm, thickness are 0.76mm, thickness are 0.65mm, thickness are 1.5mm, thickness are 0.65mm, thickness are 1.5mm, thickness are 0.65mm, thickness are 0.76mm, thickness are 4mm is subjected to laminating process successively.

Description

A kind of preparation method of two-way bulletproof glass
Technical field
The invention belongs to the production technology fields of bulletproof glass, are more particularly to a kind of preparation side of two-way bulletproof glass Method.
Background technology
Bulletproof glass is by glass either organic glass and single one kind after the special processing of good engineering plastics Compound material, so the bulletproof glass that no manufacturer produces is also just different.But most of is all common Glassy layer between press from both sides a kind of upper special makrolon material layer.In this process, a kind of similar simple glass is formd But a kind of substance thicker than simple glass.Makrolon is a kind of rigid transparent plastic.The thickness of bulletproof glass is about in 7mm To between 75mm, penetrate on bulletproof glass, the bulletproof glass of outer layer also can quilt attack wear, but this special makrolon Material layer can absorb the energy of bullet, to hinder it to penetrate the internal layer of glass.The bulletproof glass of these similar bulks is Public purposes is played during World War II, its usual thickness is and unusual in 10.0cm to 12.0cm Weight, this kind of glass often may be only available for the gate of financial system, and applicable range is narrower, and bulletproof glass structure is general at present It is combined into a strata carbonic ester plate all over for compound glass, quality is overweight, of high cost, can increase the weight of automobile, increases consumption Oil, so not being suitable for automobile application.So to overcome existing technical deficiency, exploitation is a kind of to process simple, bulletproof effect Good, novel frivolous, safety is without the two-way bulletproof glass of fragment splashing.
Invention content
The object of the present invention is to provide a kind of preparation methods for the two-way bulletproof glass that frivolous, safety is splashed without fragment.
According to an aspect of the invention, there is provided a kind of preparation method of bulletproof glass, includes the following steps:
Raw material preparation:Original sheet glass is cut, edging, cleaning and printing, drying carries out hot bending again makes original sheet glass Reach required camber,
Thermoplastic resin board timber-used water knife is cut by required figure, carries out on surface at cleaning after the completion of cutting It manages, thermoplastic resin plank is put into after cleaning treatment and closes piece interior carry out dehumidification treatments,
Thermoplastic resin plank after dehumidifying is put between original sheet glass described in the two panels after hot bending and is promoted in vacuum tank Carry out crooked reason;
Close piece:It is successively 0.65mm's by PVB films that original sheet glass that thickness is 4mm, thickness are 0.76mm, thickness The thermoplastic resin that TPU membrane that thermoplastic resin plank that TPU membrane, thickness are 1.5mm, thickness are 0.65mm, thickness are 1.5mm The original sheet glass that PVB films that TPU membrane that plank, thickness are 0.65mm, thickness are 0.76mm, thickness are 4mm carries out joint place Reason;
Cold pumping:Original sheet glass after hot bending is put into vacuum bag, puts into and opens the cold pumping of vacuum pump progress in autoclave;
High-pressure molding:Vacuum pump is not closed, the high pressure when taking out, 125 DEG C, pressure 1100Kpa of high pressure temperature, equilibration time 120min carries out decompression processing when temperature in the kettle drops to 36 DEG C, and bulletproof glass is made.
In some embodiments, 15-25 DEG C of the temperature for closing piece room, the humidity 30-40% for closing piece room.
In some embodiments, the temperature setting of the vacuum tank is 100 DEG C, when heat preservation a length of 20min.
In some embodiments, the thermoplastic resin is PC plate.
In some embodiments, the vacuum bag at least ensures that there are four gas outlets.
In some embodiments, when carrying out cold pumping, the vacuum degree in the autoclave is in -0.096-0.01MPa, cold pumping Shi Changwei 3 hours or so.
A kind of bulletproof glass, including:
First original sheet glass,
The first PVB films on first sheet glass are fitted in,
The first TPU membrane on the PVB films is fitted in,
The first thermoplastic resin plank in the TPU membrane is fitted in,
The first TPU membrane on the thermoplastic resin plank is fitted in,
The second thermoplastic resin plank in first TPU membrane is fitted in,
The second TPU membrane on the second thermoplastic resin plank is fitted in,
The 2nd PVB films in second TPU membrane are fitted in,
And fit in the second original sheet glass on the 2nd PVB films.
Advantage is:The different types of film used between different materials in bulletproof glass of the present invention, so not Merely reduce production development cost and also improve ballistic performance, can effectively prevent because by fierce shooting and The splashing glass of the inner face sent out.
The thickness of the bulletproof glass of the present invention is 13.6mm, and light transmittance can reach 84% or so, good flame resistance, sound-insulating and heat-insulating Performance is good, can prevent 79 formula 7.62mm light submachine guns, 10 meters of distance contact three rounds of ammunition, explosion-proof is high, can effectively prevent son Bullet passes through glass fragment secondary injury caused by human body.
Bulletproof glass prepared by the present invention can be applied to anti-needed for the aviation field of different performance requirement, ground forces Play glass, the car etc. that automobile industry such as armoured van, family use;Building trade such as bank, prison etc. other can be by gunslinging Place.
Specific implementation mode
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Fig. 1 schematically shows a kind of two-way bulletproof glass of the present invention.As shown in Figure 1, two-way bulletproof glass includes:The One sheet glass fits in the first PVB films on first sheet glass, fits in the first TPU membrane on the PVB films, The first thermoplastic resin plank in the TPU membrane is fitted in, the first TPU membrane on the thermoplastic resin plank is fitted in, The second thermoplastic resin plank in first TPU membrane is fitted in, on the second thermoplastic resin plank is fitted in Two TPU membranes fit in the 2nd PVB films in second TPU membrane, and fit on the 2nd PVB films second Sheet glass.
A kind of preparation method of bulletproof glass, includes the following steps:
Raw material prepare
a:Original sheet glass cut, edging, cleaning and printing, drying are carried out again needed for hot bending so that glass raw material reaches Camber.
b:Thermoplastic resin plank (PC plate) is cut with water knife by required figure, carries out surface after the completion of cutting Thermoplastic resin plank (PC plate) is put into after cleaning treatment and closes piece interior carry out dehumidification treatments, closes the temperature of piece room by cleaning treatment 15-25 DEG C of degree, humidity 30-40%;Thermoplastic resin plank (PC plate) after dehumidifying is put into the original of two sheet glass after hot bending again It is promoted between piece and carries out crooked reason in vacuum tank, without folded poor between two panels original sheet glass.Temperature setting is 100 DEG C, when heat preservation A length of 20min, it is ensured that reach required radian, consequently facilitating closing piece operation.
Close piece:Successively by the original sheet glass of 4mm, the PVB films of 0.76mm, the TPU membrane of 0.65mm, the thermoplasticity of 1.5mm Thermoplastic resin plank (PC plate), the TPU membrane of 0.65mm, the 0.76mm of resin plate (PC plate), the TPU membrane of 0.65mm, 1.5mm PVB films, 4mm original sheet glass be combined to obtain sheet glass.Before closing piece, the two-side transparent of thermoplastic resin plank need to be protected Cuticula is torn.The temperature for closing piece is 15-25 DEG C, humidity 30-40%.Wherein, PVB films have been exactly connection effect.
Cold pumping:Sheet glass after conjunction piece is put into vacuum bag, vacuum bag at least ensures that there are four gas outlets.Ensure taking out When vacuum, quickly the air pressure in vacuum bag can be discharged.It is pushed into autoclave, connects vacuum pump and carry out cold pumping, connect vacuum pump Carry out cold pumping.Ensure vacuum degree in -0.096~0.10Mpa, cold pumping a length of 3 hours.
High-pressure molding:Autoclave door is shut, high temperature is carried out successively, high pressure, heat preservation, cooling, decompression, cooling, goes out kettle, obtain Novel frivolous, safety is without the two-way bulletproof glass of fragment splashing.High-pressure is 1100Kpa, and maximum temperature is 125 DEG C, when balance Between be 120 minutes, temperature-fall period is depressured when temperature drops to 36 DEG C.
By traditional bulletproof glass, example carries out contrast experiment with the embodiment of the present invention as a contrast, and the results are shown in Table 1.
Thickness mm Light transmittance Fragment splashes Weight kg Shellproof grade
Embodiment 13.6 84.5% Without splashing 7.94 F79-H
Reference examples 24.52 82% There is splashing 17.64 F64
As shown in Table 1, bulletproof glass property indices of the present invention are superior to reference examples, illustrate this experiment bulletproof glass, Thickness is thin, and light transmittance is high, and heat-proof quality is good, and shellproof grade and explosion-proof are high, can effectively prevent bullet pass through glass and Glass breaking secondary injury caused by human body.
Although above having used general explanation and specific implementation case, the present invention is described in detail, On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art, because This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (7)

1. a kind of preparation method of two-way bulletproof glass, which is characterized in that include the following steps:
Raw material preparation:Original sheet glass is cut, edging, cleaning and printing, drying carries out hot bending again makes the original sheet glass Reach required camber,
Thermoplastic resin board timber-used water knife is cut by required figure, surface is subjected to cleaning treatment after the completion of cutting, clearly Thermoplastic resin plank is put into after clean processing and closes piece interior carry out dehumidification treatments,
Thermoplastic resin plank after dehumidifying is put into promote between original sheet glass described in the two panels after hot bending and is carried out in vacuum tank Crooked is managed;
Close piece:Successively by PVB films that original sheet glass that thickness is 4mm, thickness are 0.76mm, thickness be 0.65mm TPU membrane, Thermoplastic resin plank that TPU membrane that thermoplastic resin plank that thickness is 1.5mm, thickness are 0.65mm, thickness are 1.5mm, The original sheet glass that PVB films that TPU membrane that thickness is 0.65mm, thickness are 0.76mm, thickness are 4mm carries out laminating process and obtains glass Glass piece;
Cold pumping:The sheet glass is put into vacuum bag, puts into and opens the cold pumping of vacuum pump progress in autoclave;
High-pressure molding:Vacuum pump is not closed, the high pressure when taking out, 125 DEG C, pressure 1100Kpa of high pressure temperature, equilibration time 120min carries out decompression processing when temperature in the kettle drops to 36 DEG C, and bulletproof glass is made.
2. the preparation method of two-way bulletproof glass according to claim 1, which is characterized in that the temperature for closing piece room 15-25 DEG C, the humidity 30-40% for closing piece room.
3. the preparation method of two-way bulletproof glass according to claim 1, which is characterized in that the temperature of the vacuum tank is set Be set to 100 DEG C, when heat preservation a length of 20min.
4. the preparation method of two-way bulletproof glass according to claim 1, which is characterized in that the thermoplastic resin is PC Plate.
5. the preparation method of two-way bulletproof glass according to claim 1, which is characterized in that the vacuum bag at least ensures that There are four gas outlets.
6. the preparation method of two-way bulletproof glass according to claim 1, which is characterized in that when carrying out cold pumping, the height Press the vacuum degree in kettle in -0.096-0.01MPa, cold pumping a length of 3 hours or so.
7. according to the two-way bulletproof glass prepared by the preparation method of the two-way bulletproof glass of claim 1-6 any one of them, It is characterised in that it includes:
First original sheet glass,
The first PVB films on first sheet glass are fitted in,
The first TPU membrane on the PVB films is fitted in,
The first thermoplastic resin plank in the TPU membrane is fitted in,
The first TPU membrane on the thermoplastic resin plank is fitted in,
The second thermoplastic resin plank in first TPU membrane is fitted in,
The second TPU membrane on the second thermoplastic resin plank is fitted in,
The 2nd PVB films in second TPU membrane are fitted in,
And fit in the second original sheet glass on the 2nd PVB films.
CN201810397208.XA 2018-04-28 2018-04-28 Preparation method of bidirectional bulletproof glass Active CN108582926B (en)

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Application Number Priority Date Filing Date Title
CN201810397208.XA CN108582926B (en) 2018-04-28 2018-04-28 Preparation method of bidirectional bulletproof glass

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CN108582926B CN108582926B (en) 2021-02-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112833712A (en) * 2019-11-25 2021-05-25 明盾技术河北有限公司 Preparation method of bulletproof window glass with electromagnetic shielding effect

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010032540A1 (en) * 1997-06-18 2001-10-25 Noel Gourio Armoured glazing, in particular for vehicle fixed or mobile side glazing
CN103486908A (en) * 2013-09-06 2014-01-01 天津广源新材料科技有限公司 Bullet-proof glass
CN204718498U (en) * 2015-06-18 2015-10-21 广州兴华玻璃工业有限公司 Hollow bulletproof glass
CN106746760A (en) * 2016-12-02 2017-05-31 重庆市三星精艺玻璃股份有限公司 A kind of preparation method of laminated glass

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010032540A1 (en) * 1997-06-18 2001-10-25 Noel Gourio Armoured glazing, in particular for vehicle fixed or mobile side glazing
CN103486908A (en) * 2013-09-06 2014-01-01 天津广源新材料科技有限公司 Bullet-proof glass
CN204718498U (en) * 2015-06-18 2015-10-21 广州兴华玻璃工业有限公司 Hollow bulletproof glass
CN106746760A (en) * 2016-12-02 2017-05-31 重庆市三星精艺玻璃股份有限公司 A kind of preparation method of laminated glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112833712A (en) * 2019-11-25 2021-05-25 明盾技术河北有限公司 Preparation method of bulletproof window glass with electromagnetic shielding effect

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