CN108578350A - A kind of care composition and preparation method thereof containing spirulina extract - Google Patents
A kind of care composition and preparation method thereof containing spirulina extract Download PDFInfo
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- CN108578350A CN108578350A CN201810421138.7A CN201810421138A CN108578350A CN 108578350 A CN108578350 A CN 108578350A CN 201810421138 A CN201810421138 A CN 201810421138A CN 108578350 A CN108578350 A CN 108578350A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/99—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from microorganisms other than algae or fungi, e.g. protozoa or bacteria
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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Abstract
The invention discloses a kind of care composition and preparation method thereof containing spirulina extract.The care composition includes grease, pH adjusting agent, surfactant, thickener, preservative, vitamin, sodium chloride, essence, deionized water and spirulina extract.The spirulina extract and grease that are added in this product can generate the moisture-keeping function of collaboration, form layer protecting film in skin surface, reduce the transepidermal water loss rate of skin, reduce the stimulation to skin.
Description
Technical field
The present invention relates to daily cosmetics technical field, more particularly to a kind of care composition and preparation method thereof.
Background technology
With being gradually increased for people's living standard, care product also experienced diversified update.For skin
The care product of skin is primarily as a kind of skin cleaner, but it can also take away a part while cleaning skin dirt
Protection skin is played on skin, moistens the grease of moisture-keeping function, so that having dry skin, being coarse, sensitive, if it is in dry season
Section just becomes apparent.Therefore, how to enable care product to have and preferably moisten moistening effect also just at current makeup
The project of one worth exploratory development in product field.
Invention content
The object of the present invention is to provide a kind of care composition and preparation method thereof with moisture-keeping function.
To achieve the above object, the technical solution adopted by the present invention is:
A kind of care composition containing spirulina extract, including it is grease, pH adjusting agent, surfactant, thickener, anti-
Rotten agent, vitamin, sodium chloride, essence, deionized water, spirulina extract.
Preferably, spirulina extract is blunt top spirulina extract.
Preferably, spirulina extract is made according to the preparation method included the following steps:
Spirulina is cleaned, spirulina powder is obtained after spray drying;
By spirulina powder in the H that mass fraction is 10-30wt%2SO4It is dissolved in solution, spirulina powder and H2SO4Solution is pressed
According to parts by weight 1:(2-10) mixed dissolution, 4-8h is kept the temperature under the conditions of 50-90 DEG C;
Dissolved product is neutralized to neutrality with sodium hydroxide solution, is filtered, filtrate freezes 4- under the conditions of -4-0 DEG C
8h obtains spirulina extract solution after suction filtration.
Preferably, pH adjusting agent is selected from least one of sodium hydroxide, potassium hydroxide, triethanolamine.
In a more preferred embodiment, pH adjusting agent is sodium hydroxide.Compared to potassium hydroxide and triethanolamine, hydrogen is used
The product that sodium oxide molybdena obtains has higher viscosity, while thermal stability performance is excellent.
Preferably, grease includes at least one of vaseline, paraffin.
In a more preferred embodiment, grease is vaseline, and compared to paraffin, the product obtained using vaseline can generate greatly
Small moderate suspended particulate has more novel appearance compared with existing product, while also having higher thermal stability.
Preferably, surfactant is selected from laureth sodium sulfovinate, Cocoamidopropyl betaine, lauryl grape
At least one of glycosides, coconut oleoyl amine monoethanolamine, polyquaternium.
Preferably, preservative is selected from least one of Phenoxyethanol, EDETATE SODIUM, pungent glycol.
Preferably, thickener is acrylic acid (ester) analog copolymer.
Preferably, include following components according to parts by weight:0.5-3 parts of grease, 2-20 parts of spirulina extract, pH adjusting agent
0.1-0.3 parts, 12-20 parts of laureth sodium sulfovinate, 4-10 parts of Cocoamidopropyl betaine, lauryl glucoside 2-10
Part, 0.5-3 parts of coconut oleoyl amine monoethanolamine, 0.5-5 parts of polyquaternium, 5-10 parts of acrylic acid (ester) analog copolymer, Phenoxyethanol
0.4-1 parts, glycol 0.2-1 parts pungent, 0.05-0.3 parts of EDETATE SODIUM, 0.1-2 parts of panthenol, 0.2-2 parts of sodium chloride, essence 0.2-
0.8 part, 35-65 parts of deionized water.
The preparation method of above-mentioned care composition, includes the following steps:
A. deionized water, preservative, surfactant, spirulina extract are mixed, stirring forms solution one;
B. the thickener disperseed through deionized water is added in solution one, after stirring evenly, pH adjusting agent is added and adjusts pH
It to 6.5-6.8, stirs evenly, is cooled to room temperature, form solution two;
C. solution two is added in the dissolved grease of heating stirring, sodium chloride is then added, form care composition.
The beneficial effects of the invention are as follows:
The present invention provides a kind of care products for having and moistening moistening effect, to skin tape when can reduce cleaning
Stimulation.The spirulina extract and grease of addition can generate the moisture-keeping function of collaboration, and layer protecting film is formed in skin surface,
The transepidermal water loss rate of skin is reduced, the stimulation to skin is reduced.
Description of the drawings
Fig. 1 is the moisture of skin time comparison diagram of one embodiment of the present of invention.
Fig. 2 be the present invention embodiment illustrated in fig. 1 use before and after transepidermal water loss rate comparison diagram.
Specific implementation mode
The technique effect of design and the generation of the present invention is clearly and completely described below with reference to embodiment, with
It is completely understood by the purpose of the present invention, feature and effect.
Embodiment 1
Different pH adjusting agents compare
Formula one:Vaseline 1.5kg, sodium hydroxide 0.2kg, laureth sodium sulfovinate 18kg, cocamidopropyl propyl amide sweet tea
Dish alkali 6kg, lauryl glucoside 5kg, coconut oleoyl amine monoethanolamine 2kg, -7 2kg of polyquaternium, acrylic acid (ester) analog copolymer
6kg, Phenoxyethanol 0.6kg, pungent glycol 0.4kg, EDETATE SODIUM 0.2kg, panthenol 0.5kg, sodium chloride 0.6kg, essence 0.5kg,
Deionized water 56.5kg.
Formula two:Vaseline 1.5kg, potassium hydroxide 0.2kg, laureth sodium sulfovinate 18kg, cocamidopropyl propyl amide sweet tea
Dish alkali 6kg, lauryl glucoside 5kg, coconut oleoyl amine monoethanolamine 2kg, -7 2kg of polyquaternium, acrylic acid (ester) analog copolymer
6kg, Phenoxyethanol 0.6kg, pungent glycol 0.4kg, EDETATE SODIUM 0.2kg, panthenol 0.5kg, sodium chloride 0.6kg, essence 0.5kg,
Deionized water 56.5kg.
Formula three:Vaseline 1.5kg, triethanolamine 0.2kg, laureth sodium sulfovinate 18kg, cocamidopropyl propyl amide sweet tea
Dish alkali 6kg, lauryl glucoside 5kg, coconut oleoyl amine monoethanolamine 2kg, -7 2kg of polyquaternium, acrylic acid (ester) analog copolymer
6kg, Phenoxyethanol 0.6kg, pungent glycol 0.4kg, EDETATE SODIUM 0.2kg, panthenol 0.5kg, sodium chloride 0.6kg, essence 0.5kg,
Deionized water 56.5kg.
It is prepared respectively according to following preparation method according to above-mentioned formula one to three.
(1) a part of deionized water is reserved, remaining deionized water is added in emulsification pot, EDTA is added in heating stirring
Disodium, laureth sodium sulfovinate are heated to dissolving completely, and after being warming up to 75-85 DEG C, coconut oleoyl amine monoethanolamine is added,
Stirring and dissolving is complete, keeps the temperature 30 minutes.
(2) temperature for emulsifying pot is down to 60 DEG C, lauryl glucoside, Cocoamidopropyl betaine is added, stirring is extremely
It is completely dissolved.
(3) temperature for emulsifying pot is down to 45 DEG C, panthenol, polyquaternium -7, Phenoxyethanol, pungent glycol is added.
(4) it is added and uses deionized water 1:Acrylic acid (ester) analog copolymer of 1 dispersion, after stirring evenly, addition water dissolution
PH adjusting agent in and adjust pH, control in 6.5-6.8, be slowly stirred uniformly, be cooled to room temperature.
(5) by vaseline heating stirring, make it completely dissolved, control mixing speed, then be slowly added to emulsification pot in, shape
Then suitable at size, evengranular suspended oil fat granule is added sodium chloride and adjusts viscosity.
In this experiment, after in order to ensure that pH adjusting agent is added in step 4 to be adjusted, pH is controlled 6.7, can be to formula
The amount of pH adjusting agent (potassium hydroxide, triethanolamine) in two and three can be finely adjusted and change the amount of deionized water to expire
Foot.30 days heat resistances experiment under different temperatures is carried out to three formulas product obtained.Experimental result such as following table:
The different pH adjusting agent heat resistances of table 1. compare
Under other component content unanimous circumstances, when being adjusted to 6.7 by three sections of different pH adjusting agents, hydrogen-oxygen is used
Change the viscosity highest for the product that sodium obtains, meanwhile, the heat resistance of suspension grease is also best, as can be seen from the above table, selects hydrogen
Sodium oxide molybdena is showed as 30 days heat resistances experiment of the product made from pH adjusting agent at a temperature of 40 DEG C, 45 DEG C, 50 DEG C three kinds
Well, when selecting potassium hydroxide as pH adjusting agent, after carrying out 30 days heat-resistant experiments under the conditions of 50 DEG C, product will appear grease
Clustering phenomena influences the perception and using effect of product.And select triethanolamine as pH adjusting agent, 45 DEG C of heat resistance experiment
There is grease clustering phenomena, is even more to be gathered into bulky grain in 50 DEG C of heat resistance experiment, is easy to produce perception and using effect
Raw tremendous influence.
Embodiment 2
The selection of different oil components
Respectively according in embodiment 1 formula one and formula as below prepared according to the method in embodiment 1:
Formula four:A kind of care composition containing spirulina extract changes vaseline into differing only in for formula one
Shea butter.
Formula five:A kind of care composition containing spirulina extract changes vaseline into differing only in for formula one
White oil.
Formula six:A kind of care composition containing spirulina extract changes vaseline into differing only in for formula one
Paraffin.
It is found in preparation process, the product for being formulated five will appear water-oil separating, oil phase floats on the wild effect of liquid level.
In formula four after addition shea butter, the grease of suspension is harder, and it is apparent to use granular sensation, cannot form thin grease well
Film is also difficult to play the role of skin care in skin surface.In terms of lotion appearance and the skin sense used, selected in formula six
The paraffin selected is in preparation process and formula is one more similar, but is formulated six and is showed in terms of high-temperature stability not good enough, occurs
Phenomena such as peculiar smell, flavescence, transparency decline, it may be possible to because caused by grease is emulsified by surfactant moieties.Therefore, of the invention
In the preferred grease of vaseline and paraffin as addition, more preferable vaseline is as the grease added, using vaseline as the oil added
When fat, the appearance of product will not be destroyed because there is the phenomenon that water-oil separating, the vaseline particle of suspension is softer, without apparent
Granular sensation can form oil membrane in skin surface and play the effectiveness of skin care, while is maintained under the condition of high temperature
Good stability.
Embodiment 3
Grease additive amount compares
The formula table of the different vaseline additive amounts of table 2.
Formula seven | Formula one | Formula eight | |
Laureth sodium sulfovinate | 18 | 18 | 18 |
Cocoamidopropyl betaine | 6 | 6 | 6 |
Lauryl glucoside | 5 | 5 | 5 |
Coconut oleoyl amine monoethanolamine | 2 | 2 | 2 |
Acrylic acid (ester) analog copolymer | 6 | 6 | 6 |
Vaseline | 0.5 | 1.5 | 3.0 |
Panthenol | 0.5 | 0.5 | 0.5 |
Sodium hydroxide | 0.2 | 0.2 | 0.2 |
Sodium chloride | 0.6 | 0.6 | 0.6 |
Phenoxyethanol | 0.6 | 0.6 | 0.6 |
Pungent glycol | 0.4 | 0.4 | 0.4 |
Polyquaternium -7 | 2 | 2 | 2 |
EDETATE SODIUM | 0.2 | 0.2 | 0.2 |
Essence | 0.5 | 0.5 | 0.5 |
Deionized water | 57.5 | 56.5 | 55 |
Respectively formula seven and formula eight are prepared according to the method in embodiment 1 according to the formula of above-mentioned parts by weight.Formula seven
The vaseline amount that product obtained suspends is seldom, and the moisture feeling after appearance and use all compares shortcoming;And it is outstanding to be formulated the scheme in eight
Floating vaseline amount is excessive, when 45 DEG C of baking oven heat-resistant stabilities are tested, observes in or so week and is gathered into big grease
Grain.And it is all good in terms of appearance and stability and also more satisfactory for the use of rear skin sense to be formulated one.So the present invention is preferred
Vaseline additive amount is 1.5 parts.
Embodiment 4
Spirulina additive amount compares
Preferred spirulina is blunt top spirulina also known as Bo Nate spirulinas in the present invention, originates in African Chad, domestic
It is mainly distributed on the ground such as Hainan, Guangdong, Yunnan.Spirulina type mainly has spirulina maxim, blunt top spirulina, Spirulina subaalsa
Three classes.The protein content highest of blunt top spirulina (Bo Nate spirulinas), phycocyanin is most containing also amount, and SOD activity is high, can
Dissolubility protein content is high.
The extracting method of spirulina is specially in this programme:Freshly harvested natural Bo Nate spirulinas algal gel clear water is anti-
After backwashing is washed, and after removing mixes salts and fertilizers therein, Direct spraying drying obtains natural Bo Nate spirulina powders, by institute
The H of the spirulina powder 10-30wt% obtained2SO4Solution dissolves, and the mass ratio of algae powder and acid solution is 1:(2-10), control temperature exist
50-90 DEG C, after keeping the temperature 4-8 hours, it is neutralized to neutrality with saturation sodium hydroxide solution, is filtered, by filtrate as -4 DEG C -0 DEG C
At a temperature of freeze 4-8 hours, rapid filtration under suction, remove solution in NaSO4, the faint yellow clear spirulina for obtaining slightly smell carries
Take liquid.
The different spirulina additive amount formulas of table 3.
By above-mentioned formula 1. -6. prepared according to the method in embodiment 1, wherein spirulina extract is in step (3)
Middle addition.To each recipe ingredient and from selecting on the market in common shower cream, selected a Pearly-lustre type shower cream and
A transparent type shower cream is done using comparison.
Between test object is 18-40 Sui of 80 skin healths, male to female ratio respectively accounts for 1 half, is randomly divided into 8 groups, every group
10 people, respectively using formula 1., formula 2., formula 3., formula 4., formula 5., formula 6., commercially available Pearly-lustre type, commercial clear type,
Before use, and measuring using rear 30min, 60min, 90min, 120min the skin moisture content of every subject respectively
Comparison (with moisture before using for 100%) and transepidermal water loss rate (TEWL) before using and 1 hour percutaneous after using
The comparison (preceding for 100% to use) of percentage of water loss.Each DATA REASONING 3 times, is averaged.
The instrument that this experiment test skin moisture content uses is Germany Courage+Khazaka electronic GmbH
Derma Unit SSC, the instrument that test transepidermal water loss rate (TEWL) uses are the Tewameter TM300 of CK companies of Germany.It surveys
Try external environment:Temperature:25 DEG C of room temperature, humidity 60%.
Experimental result is as shown in Figure 1 and Figure 2.In Fig. 1, in the 1-2h periods, the broken line of the top is to be formulated 4., 5., 6.,
Downwards be respectively be formulated 3., 2., commercially available Pearly-lustre type, formula 1. with commercial clear type.It will be seen from figure 1 that rigid in use, skin
Skin absorbs moisture because of taking a shower, and moisture content of skin has the promotion of short time, but later with the stream of this part water
It loses, moisture content of skin is begun to decline to tending to be steady, and is found by this comparison, and the grease of suspension is for keeping moisture to have certain effect
Fruit, and the addition of spirulina further enhances the effect of the water tariff collection of product.Depending on the comparison, the preferred addition spiral of this experiment
The amount of algae extract is 10 parts.
It can be seen that from test result Fig. 2 after having used cleaning, the transepidermal water loss rate of skin increases, that is, loses water
The speed divided is accelerated, but the product added with suspension vaseline can slow down the speed of water loss quickening after cleaning, and adds
Just slower added with the reducing speed of the product of spirulina extract, this illustrates spirulina and vaseline between the two for slowing down water
Shunting, which is lost, has certain synergistic effect, i.e. blunt top spirulina that can promote the moisturizing of suspension vaseline.
In conjunction with figure one as a result, the preferred spirulina extract dosage of the present invention is 10 parts.
Embodiment 5
Different preparation methods compare
4. formula in selection example 4 is prepared according to the preparation method in embodiment 1, wherein spirulina extracts
Object addition in step (3).In step (5), it is cooled to room temperature, the vaseline (55-65 DEG C) of heating and thermal insulation is respectively adopted quickly
Stirring (formed larger or prodigious whirlpool), moderate-speed mixer (forming a smaller whirlpool) mix slowly (no whirlpool or very
Small whirlpool) mode be slowly added into emulsification pot in.
It is 500g that cross agitating paddle, the amount of drawing a design are used when laboratory is drawn a design.Quickly stirring corresponds to 1200- at this time
2000rpm, moderate-speed mixer correspond to 600-1200rpm, mix slowly corresponding 100-600rpm.
And in workshop pilot scale, using screw type agitating paddle, pilot scale amount is 100kg.Quickly stirring corresponds to 45- at this time
60rpm, moderate-speed mixer correspond to 25-45rpm, mix slowly corresponding to 5-25rpm.
Quickly stirring and moderate-speed mixer include only maximum in above-mentioned each range, do not include minimum, mix slowly packet
Containing maximum and minimum.The result such as following table of gained suspension vaseline:
The different mixing speed results contrasts of table 4.
Quickly stirring | Vaseline is stirred very tiny, beautiful insufficient |
Moderate-speed mixer | Vaseline is of moderate size, and novel appearance is beautiful |
It mixes slowly | Vaseline particle is larger, and size is uneven, and appearance is plain |
The above results surface, the present invention preferred medium mixing speed in the selection of production technology.
Embodiment 6
A kind of care composition, gross mass 100kg, including:Vaseline 3kg, sodium hydroxide 0.3kg, laruyl alcohol are poly-
Ether sodium sulfovinate 20kg, Cocoamidopropyl betaine 10kg, lauryl glucoside 2kg, coconut oleoyl amine monoethanolamine 3kg, gather
- 7 0.5kg of quaternary ammonium salt, acrylic acid (ester) analog copolymer 5kg, Phenoxyethanol 0.4kg, pungent glycol 0.2kg, EDETATE SODIUM 0.1kg,
Panthenol 0.1kg, sodium chloride 0.2kg, essence 0.2kg, blunt top spirulina extract 20kg, deionized water 35kg.
Embodiment 7
A kind of care composition, gross mass 100kg, including:Vaseline 0.5kg, sodium hydroxide 0.1kg, laruyl alcohol
Polyethers sodium sulfovinate 12kg, Cocoamidopropyl betaine 4kg, lauryl glucoside 10kg, coconut oleoyl amine monoethanolamine
0.5kg, -7 5kg of polyquaternium, acrylic acid (ester) analog copolymer 10kg, Phenoxyethanol 1kg, pungent glycol 1kg, EDETATE SODIUM
0.3kg, panthenol 2kg, sodium chloride 2kg, essence 0.8kg, blunt top spirulina extract 2kg, deionized water 48.8kg.
Embodiment 8
A kind of care composition, gross mass 100kg, including:Vaseline 0.5kg, sodium hydroxide 0.1kg, laruyl alcohol
Polyethers sodium sulfovinate 12kg, Cocoamidopropyl betaine 4kg, lauryl glucoside 2kg, coconut oleoyl amine monoethanolamine 3kg, gather
- 7 5kg of quaternary ammonium salt, acrylic acid (ester) analog copolymer 5kg, Phenoxyethanol 0.4kg, pungent glycol 0.2kg, EDETATE SODIUM 0.05kg,
Panthenol 0.1kg, sodium chloride 0.2kg, essence 0.2kg, blunt top spirulina extract 2.25kg, deionized water 65kg.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Belong to those skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in all are answered
It is included within the scope of the present invention.Therefore, protection scope of the present invention should be subject to the protection scope in claims.
Claims (7)
1. a kind of care composition containing spirulina extract, which is characterized in that including grease, pH adjusting agent, surfactant,
Thickener, preservative, vitamin, sodium chloride, essence, deionized water, spirulina extract.
2. care composition according to claim 1, which is characterized in that the spirulina extract carries for blunt top spirulina
Take object.
3. care composition according to claim 1, which is characterized in that the spirulina extract is by including the following steps
Method be prepared:
Spirulina powder is obtained after taking spirulina to be spray-dried, addition mass percentage concentration is the acid solution of 10-30wt% at 50-90 DEG C
Lower reaction, the spirulina powder:The mass ratio of acid solution is 1:(2-10);
Lye is added to neutralize;
Filtering, after taking filtrate to be freezed under the conditions of -4-0 DEG C, suction filtration obtains the solution of spirulina extract.
4. care composition according to claim 1, which is characterized in that the pH adjusting agent is selected from sodium hydroxide, hydrogen-oxygen
Change at least one of potassium, triethanolamine.
5. care composition according to claim 1, which is characterized in that the grease in vaseline, paraffin at least
It is a kind of.
6. care composition according to claim 1, which is characterized in that according to parts by weight include following components:Grease
0.5-3 parts, 2-20 parts of spirulina extract, 0.1-0.3 parts of pH adjusting agent, 12-20 parts of laureth sodium sulfovinate, cocounut oil acyl
4-10 parts of amine propyl betaine, 2-10 parts of lauryl glucoside, 0.5-3 parts of coconut oleoyl amine monoethanolamine, polyquaternium 0.5-5
Part, 5-10 parts of acrylic acid (ester) analog copolymer, 0.4-1 parts of Phenoxyethanol, glycol 0.2-1 parts pungent, 0.05-0.3 parts of EDETATE SODIUM,
0.1-2 parts of panthenol, 0.2-2 parts of sodium chloride, 0.2-0.8 parts of essence, 35-65 parts of deionized water.
7. the preparation method of claim 1-6 any one of them care compositions, which is characterized in that include the following steps:
A. deionized water, preservative, surfactant, spirulina extract are mixed, stirring forms solution one;
B. the thickener disperseed through deionized water is added in solution one, after stirring evenly, pH adjusting agent adjusting pH is added and arrives
6.5-6.8 is stirred evenly, and is cooled to room temperature, forms solution two;
C. solution two is added in the dissolved grease of heating stirring, sodium chloride is then added, form care composition.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110538104A (en) * | 2018-05-29 | 2019-12-06 | 张文利 | Shampoo containing Mallotus oblongifolius muell-Arg extract and preparation method thereof |
CN112121002A (en) * | 2020-11-06 | 2020-12-25 | 广州上悦生物科技有限公司 | Moisturizing and repairing composition and cosmetic |
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CN1206587A (en) * | 1997-07-29 | 1999-02-03 | 张许昌 | Natural spiroalgae cosmetic for skin and hair cleaning and protection |
CN103800275A (en) * | 2014-02-08 | 2014-05-21 | 李美凤 | Whitening anti-aging cosmetic and preparation method thereof |
CN104224611A (en) * | 2013-06-24 | 2014-12-24 | 张丽娜 | Traditional Chinese medicine spirulina hair blacking cream |
CN104224674A (en) * | 2013-06-20 | 2014-12-24 | 张丽娜 | Spirulina moisture-retention cleansing milk |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1206587A (en) * | 1997-07-29 | 1999-02-03 | 张许昌 | Natural spiroalgae cosmetic for skin and hair cleaning and protection |
CN104224674A (en) * | 2013-06-20 | 2014-12-24 | 张丽娜 | Spirulina moisture-retention cleansing milk |
CN104224611A (en) * | 2013-06-24 | 2014-12-24 | 张丽娜 | Traditional Chinese medicine spirulina hair blacking cream |
CN103800275A (en) * | 2014-02-08 | 2014-05-21 | 李美凤 | Whitening anti-aging cosmetic and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110538104A (en) * | 2018-05-29 | 2019-12-06 | 张文利 | Shampoo containing Mallotus oblongifolius muell-Arg extract and preparation method thereof |
CN112121002A (en) * | 2020-11-06 | 2020-12-25 | 广州上悦生物科技有限公司 | Moisturizing and repairing composition and cosmetic |
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Application publication date: 20180928 |