Battery case aluminum alloy strip and preparation method thereof
Technical field
The present invention relates to a kind of battery case aluminum alloy strips and preparation method thereof.
Background technology
Currently, the shell of the lithium rechargeable battery of square, using aluminium sheet or aluminium alloy plate as raw material, by being pressed into
Type (the thinning molding of deep drawing) and manufacture, battery has the knot that electrode, partition board, electrolyte etc. are enclosed using the shell and lid
The engagement of structure, the shell and aluminum or lid made of aluminum alloy uses laser welding.
Therefore, to the aluminium sheet of battery case or aluminium alloy plate, it is desirable that the compression moulding as characteristic necessary to manufacture
Property, laser welding it is good, also require the strength durable after shell is made simultaneously good.The intensity of so-called shell is resistance to
Long property is not easy to be deformed because of external force specifically, referring to not expanding long-time uses, even if deformation is not easy to out
The characteristic in hole etc..
In recent years, it in order to make various running softwares, needs to improve battery capacity, demand shell is thinner and suitable for utensil
The shell of the wide shape of more slim width compared with prior art.
In the shell for enclosing battery, internal temperature rises to 85 DEG C or so.Internal pressure is generated in shell sometimes as a result, to lead
Cause case swells.Therefore, demand reduces such material expanded.In addition, can also enclose the electronic equipment of battery by
To external force.Under such circumstances, it is desirable to battery case not damaged, material for needing resistance to embedability high deformation.In addition,
Even if it is required that under shell state after molding by formed big intrusion external force when, be not easy to the characteristic of trepanning, certainly
Also require deformation drag big.From the aspect of the durability of battery case, high intensity is desired characteristic.
But for the material of high intensity, it is difficult to be shaped to have thin-walled and cover thickness is small, width and height are big
The shell of shape.The ratio of wide, i.e. cover the width/thickness of the thin width of shell is bigger, and the difficulty of mouldability more increases.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of battery case aluminium alloy plate is provided
Band, it can make its crystal grain uniformity, the diameter of crystal grain that can be less than 50 μm, ensure its tensile strength, yield strength and prolong
Stretch the physical properties requirement such as rate.
In order to solve the above-mentioned technical problem, the technical scheme is that:A kind of battery case aluminum alloy strip, it contains
Chemical composition and each chemical composition mass percent it is as follows:
Si:≤ 0.2%;
Fe:0.5%~0.6%;
Cu:0.05%~0.10%;
Mn:0.06%~1.15%;
Mg:≤ 0.03%;
Zn:≤ 0.03%;
Ti:0.02%~0.04%;
Inevitable impurity element:≤ 0.15%;
Surplus is Al, amounts to 100%.
The present invention also provides a kind of preparation method of battery case aluminum alloy strip, method includes to have the following steps:
S1:Obtain blank;
S2:Blank is handled by thick cold rolling and pinch pass, obtains the first semi-finished product;Wherein, thick cold rolling uses roughing roller
Group;Pinch pass uses finish rolling roller group;
S3:First semi-finished product obtain the second semi-finished product by annealing;Wherein, it in annealing process, first uses
Circulated air pair first semi-finished product at a temperature of 255 DEG C~265 DEG C carry out purging oil removing 5~7 hours, then at 345 DEG C~355 DEG C
At a temperature of annealing is carried out 4~6 hours to the first semi-finished product;
S4:Pinch pass again is carried out to the second semi-finished product to handle, and obtains third semi-finished product;
S5:Then finished product is obtained after third semi-finished product being cleaned, cut and packed successively.
Further, the thickness of blank is 7.5 ± 0.3mm, in step s 2, passes through thick cold rolling three times and primary essence successively
Cold-rolling treatment obtains the first semi-finished product;Wherein, the inlet thickness of thick cold rolling is 7.5 ± 0.3mm for the first time, for the first time thick cold rolling
Exit thickness be 5.1 ± 0.10mm;The inlet thickness of second of thick cold rolling is 5.1 ± 0.10mm, and second of thick cold rolling goes out
Mouth thickness is 3.5 ± 0.10mm;The inlet thickness of the thick cold rolling of third time is 3.5 ± 0.10mm, and the outlet of the thick cold rolling of third time is thick
Degree is 2.4 ± 0.05mm;The inlet thickness of first time pinch pass is 2.4 ± 0.05mm, and the exit thickness of first time pinch pass is
1.93±0.03mm;In step s 4, the inlet thickness of pinch pass is 1.93 ± 0.03mm, the again outlet of pinch pass again
Thickness is 1.2 ± 0.02mm.
Further, the roughness of the roughing roller of the roughing roller group is 0.4 ± 0.03um, the planishing roll of the finish rolling roller group
Roughness be 0.3 ± 0.03um.
The present invention also provides a kind of preparation method of battery case aluminum alloy strip, method includes to have the following steps:
B1:Obtain blank;
B2:Blank is handled by thick cold rolling and pinch pass, obtains First Transition product;Wherein, thick cold rolling uses roughing roller
Group;Pinch pass uses finish rolling roller group;
B3:First Transition product obtain the second transition product by annealing;Wherein, it in annealing process, first uses
Circulated air carries out purging oil removing 5~7 hours at a temperature of 255 DEG C~265 DEG C to First Transition product, then at 345 DEG C~355 DEG C
At a temperature of annealing is carried out 4~6 hours to First Transition product;
B4:Then finished product is obtained after the second transition product being cut and packed successively.
Further, the thickness of blank is 7.5 ± 0.3mm, in step B2, passes through thick cold rolling three times and twice essence successively
Cold-rolling treatment obtains First Transition product;Wherein, the inlet thickness of thick cold rolling is 7.5 ± 0.3mm for the first time, for the first time thick cold rolling
Exit thickness be 5.1 ± 0.10mm;The inlet thickness of second of thick cold rolling is 5.1 ± 0.10mm, and second of thick cold rolling goes out
Mouth thickness is 3.5 ± 0.10mm;The inlet thickness of the thick cold rolling of third time is 3.5 ± 0.10mm, and the outlet of the thick cold rolling of third time is thick
Degree is 2.4 ± 0.05mm;The inlet thickness of first time pinch pass is 2.4 ± 0.05mm, and the exit thickness of first time pinch pass is
1.7±0.03mm;The inlet thickness of second of pinch pass is 1.7 ± 0.03mm, and the exit thickness of second of pinch pass is 1.2
±0.02mm。
Further, the thickness of blank is 7.5 ± 0.3mm, in step B2, passes through thick cold rolling three times and twice essence successively
Cold-rolling treatment obtains First Transition product;Wherein, the inlet thickness of thick cold rolling is 7.5 ± 0.3mm for the first time, for the first time thick cold rolling
Exit thickness be 4.9 ± 0.10mm;The inlet thickness of second of thick cold rolling is 4.9 ± 0.10mm, and second of thick cold rolling goes out
Mouth thickness is 3.8 ± 0.10mm;The inlet thickness of the thick cold rolling of third time is 3.8 ± 0.10mm, and the outlet of the thick cold rolling of third time is thick
Degree is 2.4 ± 0.05mm;The inlet thickness of first time pinch pass is 2.4 ± 0.05mm, and the exit thickness of first time pinch pass is
1.55±0.03mm;The inlet thickness of second of pinch pass is 1.55 ± 0.03mm, and the exit thickness of second of pinch pass is
1.0±0.02mm。
Further, the roughness of the roughing roller of the roughing roller group is 0.4 ± 0.03um, the planishing roll of the finish rolling roller group
Roughness be 0.3 ± 0.03um.
After using above-mentioned technical proposal, this battery case that chemical composition and preparation method using the present invention are prepared
Meet GB/T3190 regulations with aluminium alloy plate, and the physical properties such as tensile strength, yield strength, elongation percentage conform to
It asks, crystal grain uniformity, crystal grain diameter is less than 50 μm, can be suitable for the preparation of battery case, good moldability.
Specific implementation mode
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into
One step is described in detail.
Embodiment one
The mass percent of a kind of battery case aluminum alloy strip, chemical composition and each chemical composition that it contains is as follows:
Si:0.1%;
Fe:0.5%;
Cu:0.05%;
Mn:0.06%;
Mg:0.01%;
Zn:0.01%;
Ti:0.02%;
Inevitable impurity element:0.05%;
Surplus is Al, amounts to 100%.
The preparation method of the battery case aluminum alloy strip, method include to have the following steps:
S1:Obtain blank;
S2:Blank is handled by thick cold rolling and pinch pass, obtains the first semi-finished product;Wherein, thick cold rolling uses roughing roller
Group;Pinch pass uses finish rolling roller group;
S3:First semi-finished product obtain the second semi-finished product by annealing;Wherein, it in annealing process, first uses
Circulated air pair first semi-finished product at a temperature of 260 DEG C carry out purging oil removing 6 hours, then the first half at a temperature of 350 DEG C pair
Finished product carries out annealing 5 hours;
S4:Pinch pass again is carried out to the second semi-finished product to handle, and obtains third semi-finished product;
S5:Then finished product is obtained after third semi-finished product being cleaned, cut and packed successively.
The thickness of blank is 7.5 ± 0.3mm, in step s 2, is handled successively by thick cold rolling three times and a pinch pass,
Obtain the first semi-finished product;Wherein, the inlet thickness of thick cold rolling is 7.5 ± 0.3mm for the first time, and the outlet of thick cold rolling is thick for the first time
Degree is 5.1 ± 0.10mm, and entrance tension is 50 ± 3KN, and outlet tension is 55 ± 3KN;The inlet thickness of thick cold rolling is for the second time
The exit thickness of 5.1 ± 0.10mm, second of thick cold rolling are 3.5 ± 0.10mm, and entrance tension is 50 ± 3KN, and outlet tension is
46±3KN;The inlet thickness of the thick cold rolling of third time is 3.5 ± 0.10mm, the exit thickness of the thick cold rolling of third time is 2.4 ±
0.05mm, entrance tension are 40 ± 3KN, and outlet tension is 35 ± 3KN;The inlet thickness of first time pinch pass be 2.4 ±
0.05mm, the exit thickness of first time pinch pass are 1.93 ± 0.03mm, and entrance tension is 31 ± 3KN, outlet tension is 28 ±
3KN;In step s 4, the inlet thickness of pinch pass is 1.93 ± 0.03mm again, and the exit thickness of pinch pass is 1.2 again
± 0.02mm, entrance tension are 25 ± 2KN, and outlet tension is 21 ± 2KN.
The roughness of the roughing roller of the roughing roller group be 0.4 ± 0.03um, the planishing roll of the finish rolling roller group it is coarse
Degree is 0.3 ± 0.03um.
By detection, tensile strength Rm can reach 120~150mpa, yield strength Rp0.2 >=100mpa, extend
Rate A50 >=6%, Vickers hardness >=54HV, crystal grain diameter are less than 50 μm, surface roughness:≤ 0.3 μm, physical property is equal
It meets the requirements.
Embodiment two
The mass percent of a kind of battery case aluminum alloy strip, chemical composition and each chemical composition that it contains is as follows:
Si:0.2%;
Fe:0.6%;
Cu:0.10%;
Mn:1.15%;
Mg:0.03%;
Zn:0.03%;
Ti:0.04%;
Inevitable impurity element:0.15%;
Surplus is Al, amounts to 100%.
The preparation method of the battery case aluminum alloy strip, method include to have the following steps:
B1:Obtain blank;
B2:Blank is handled by thick cold rolling and pinch pass, obtains First Transition product;Wherein, thick cold rolling uses roughing roller
Group;Pinch pass uses finish rolling roller group;
B3:First Transition product obtain the second transition product by annealing;Wherein, it in annealing process, first uses
Circulated air carries out purging oil removing 6 hours, then pair the first mistake at a temperature of 350 DEG C at a temperature of 260 DEG C to First Transition product
The product of crossing carry out annealing 5 hours;
B4:Then finished product is obtained after the second transition product being cut and packed successively.
The thickness of blank is 7.5 ± 0.3mm, in step B2, is handled successively by thick cold rolling three times and pinch pass twice,
Obtain First Transition product;Wherein, the inlet thickness of thick cold rolling is 7.5 ± 0.3mm for the first time, and the outlet of thick cold rolling is thick for the first time
Degree is 5.1 ± 0.10mm, and entrance tension is 50 ± 3KN, and outlet tension is 55 ± 3KN;The inlet thickness of thick cold rolling is for the second time
The exit thickness of 5.1 ± 0.10mm, second of thick cold rolling are 3.5 ± 0.10mm, and entrance tension is 50 ± 3KN, and outlet tension is
46±3KN;The inlet thickness of the thick cold rolling of third time is 3.5 ± 0.10mm, the exit thickness of the thick cold rolling of third time is 2.4 ±
0.05mm, entrance tension are 40 ± 3KN, and outlet tension is 35 ± 3KN;The inlet thickness of first time pinch pass be 2.4 ±
0.05mm, the exit thickness of first time pinch pass are 1.7 ± 0.03mm, and entrance tension is 31 ± 3KN, outlet tension is 28 ±
3KN;The inlet thickness of second of pinch pass is 1.7 ± 0.03mm, and the exit thickness of second of pinch pass is 1.2 ± 0.02mm,
Entrance tension is 25 ± 2KN, and outlet tension is 21 ± 2KN.
The roughness of the roughing roller of the roughing roller group be 0.4 ± 0.03um, the planishing roll of the finish rolling roller group it is coarse
Degree is 0.3 ± 0.03um.
By detection, tensile strength Rm can reach 105~120mpa, and yield strength Rp0.2 prolongs in 45~55mpa
Rate A50 >=38% is stretched, physical property meets the requirements, and crystal grain diameter is less than 50 μm, surface roughness:≤ 0.35μm.
Embodiment three
The mass percent of a kind of battery case aluminum alloy strip, chemical composition and each chemical composition that it contains is as follows:
Si:0.2%;
Fe:0.55%;
Cu:0.07%;
Mn:1.1%;
Mg:0.02%;
Zn:0.02%;
Ti:0.03%;
Inevitable impurity element:0.1%;
Surplus is Al, amounts to 100%.
The preparation method of the battery case aluminum alloy strip, method include to have the following steps:
B1:Obtain blank;
B2:Blank is handled by thick cold rolling and pinch pass, obtains First Transition product;Wherein, thick cold rolling uses roughing roller
Group;Pinch pass uses finish rolling roller group;
B3:First Transition product obtain the second transition product by annealing;Wherein, it in annealing process, first uses
Circulated air carries out purging oil removing 5 hours, then pair the first mistake at a temperature of 355 DEG C at a temperature of 260 DEG C to First Transition product
The product of crossing carry out annealing 6 hours;
B4:Then finished product is obtained after the second transition product being cut and packed successively.
The thickness of blank is 7.5 ± 0.3mm, in step B2, is handled successively by thick cold rolling three times and pinch pass twice,
Obtain First Transition product;Wherein, the inlet thickness of thick cold rolling is 7.5 ± 0.3mm for the first time, and the outlet of thick cold rolling is thick for the first time
Degree is 4.9 ± 0.10mm, and entrance tension is 50 ± 3KN, and outlet tension is 55 ± 3KN;The inlet thickness of thick cold rolling is for the second time
The exit thickness of 4.9 ± 0.10mm, second of thick cold rolling are 3.8 ± 0.10mm, and entrance tension is 50 ± 3KN, and outlet tension is
46±3KN;The inlet thickness of the thick cold rolling of third time is 3.8 ± 0.10mm, the exit thickness of the thick cold rolling of third time is 2.4 ±
0.05mm, entrance tension are 40 ± 3KN, and outlet tension is 35 ± 3KN;The inlet thickness of first time pinch pass be 2.4 ±
0.05mm, the exit thickness of first time pinch pass are 1.55 ± 0.03mm, and entrance tension is 31 ± 3KN, outlet tension is 28 ±
3KN;The inlet thickness of second of pinch pass is 1.55 ± 0.03mm, the exit thickness of second of pinch pass is 1.0 ±
0.02mm, entrance tension are 25 ± 3KN, and outlet tension is 21 ± 3KN.
The roughness of the roughing roller of the roughing roller group be 0.4 ± 0.03um, the planishing roll of the finish rolling roller group it is coarse
Degree is 0.3 ± 0.03um.
By detection, tensile strength Rm can reach 105~120mpa, and yield strength Rp0.2 prolongs in 45~55mpa
Rate A50 >=38% is stretched, physical property meets the requirements, and crystal grain diameter is less than 50 μm, surface roughness:≤ 0.35μm.
Particular embodiments described above, pair present invention solves the technical problem that, technical solution and advantageous effect carry out
It is further described, it should be understood that the above is only a specific embodiment of the present invention, is not limited to
The present invention, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in
Within protection scope of the present invention.