CN108559376A - A kind of low contact angle emulsion coating of high rigidity and its application - Google Patents
A kind of low contact angle emulsion coating of high rigidity and its application Download PDFInfo
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- CN108559376A CN108559376A CN201810114434.2A CN201810114434A CN108559376A CN 108559376 A CN108559376 A CN 108559376A CN 201810114434 A CN201810114434 A CN 201810114434A CN 108559376 A CN108559376 A CN 108559376A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of low contact angle emulsion coating of high rigidity and its applications, including:25 30 parts of isophorone diisocyanate,60 90 parts of composite water soluble emulsion acrylic resin,24 70 parts of water-base resin,10 20 parts of deionized water,5 10 parts of cosolvent,48 parts of ammonium polyphosphate,56 parts of a concentration of 25 40% polyethylenimine solution,Double 0.1 0.2 parts of the stearic amides of vinyl,12 parts of silane coupling agent,12 parts of UV resistant agent,Pass through the polyethylenimine solution in coating paste first,The characteristic of the double stearic amides of vinyl and silane coupling agent,Not only greatly improve the intensity and bond properties of coating paste,Also ensure performance stabilization,And without chronic volatility toxic compounds such as formaldehyde,The coating of formation is smooth flexible,Has water resistant,Anti-pollution,The functions such as antibacterial,Secondly by the protection of UV resistant agent,It can reach effective fire-retardant,Even heat is set to be dispersed in lotion,Improve coating's permeability,It is fire-retardant and other effects,With the very strong market competitiveness.
Description
Technical field
The present invention relates to coating technology field more particularly to a kind of low contact angle emulsion coating of high rigidity and its applications.
Background technology
Most common coating paste is mainly made of polyvinyl chloride resin and filler currently on the market, although this coating material
Has many advantages, such as attractive and durable waterproof, however its poor air permeability, intensity is low and contains organic solvent, for a long time using can be dirty
Room air is contaminated, this is undoubtedly needed using new coating material substitution polyvinyl chloride resin.Emerge a collection of environmental protection in the market in recent years
Water-base resin coating material, although this kind of material is free of volatile organic solvent, in gas permeability, plasticization temperature, compound
The intensity of material, bond properties, additional functional and there are still deficiencies with the stickiness of base material etc., lack in view of above
It falls into, it is really necessary to design a kind of low contact angle emulsion coating of high rigidity and its application.
Invention content
Technical problem to be solved by the present invention lies in:A kind of low contact angle emulsion coating of high rigidity and its application are provided,
To solve the problems, such as that background technology proposes.
In order to solve the above technical problems, the technical scheme is that:A kind of low contact angle emulsion coating of high rigidity, packet
It includes:25-30 parts of isophorone diisocyanate, 24-70 parts of water-base resin, is gone 60-90 parts of composite water soluble emulsion acrylic resin
10-20 parts of ionized water, 5-10 parts of cosolvent, 4-8 parts of ammonium polyphosphate, 5-6 parts of the polyethylenimine solution of a concentration of 25-40%, second
Alkenyl double 0.1-0.2 parts of stearic amide, 1-2 parts of silane coupling agent, 1-2 parts of UV resistant agents.
Further, the water-base resin is aqueous polyethers epoxy alkyd resin.
Further, the cosolvent is propylene glycol monomethyl ether.
Further, the silane coupling agent is vinyltriethoxysilane.
Further, the coating application, which is characterized in that be used for surface of wall.
Further, the application is it is characterized in that, the application process is as follows:
1), before construction, first by the polyethylenimine solution of a concentration of 25-40%, the double stearic amide of vinyl and silane coupled
Agent is dissolved in 10-20 parts of deionized water, is configured to mixed solution;
2), again by mixed solution and isophorone diisocyanate, composite water soluble emulsion acrylic resin, water-base resin, hydrotropy
Agent and ammonium polyphosphate are mixed by regulation proportioning;
3), using closed ultrasonic be dispersed with stirring 3-4h so that coating is uniformly mixed, and the slaking reaction of 2-5h is kept after stirring;
4)And then construction, the construction method are round brush, the round brush mode is from top to bottom;
5), round brush when, be maintained at 2-3 times in surface of wall reciprocal time;
6), then air-dry cooling, cooling temperature is maintained at 25-30 DEG C, maintains 15-30h;
7), round brush UV resistant agent again, the round brush mode is from top to bottom that reciprocal time is maintained at 1-2 times.
Compared with prior art, a kind of low contact angle emulsion coating of the high rigidity and its application, pass through coating paste first
In polyethylenimine solution, the double stearic amide of vinyl and silane coupling agent characteristic, not only greatly improve coating slurry
The intensity and bond properties of material also ensure performance stabilization, and without the chronic volatility toxic compounds such as formaldehyde, the painting of formation
Layer is smooth flexible, has the functions such as water resistant, anti-pollution, antibacterial, secondly by the protection of UV resistant agent, can reach effective
It is fire-retardant, so that even heat is dispersed in lotion, improve coating's permeability, fire-retardant and other effects, there is the very strong market competitiveness.
Specific implementation mode
Hereinafter, a variety of specific details are elaborated, in order to provide the saturating of the concept to constituting described embodiment basis
Thorough understanding.However, it will be apparent to those skilled in the art that described embodiment can be in these no specific details
In some or all situations get off practice.In other cases, well-known processing step is not specifically described.
Embodiment 1
Scratch resistance nanometer water ceramic inorganic-organic polymer coating that the present embodiment is enumerated, including:Isophorone diisocyanate
25 parts of ester, 60 parts of composite water soluble emulsion acrylic resin, 24 parts of water-base resin, 10 parts of deionized water, 5 parts of cosolvent, polyphosphoric acid
Double 0.1 part of the stearic amide of 4 parts of ammonium, 5 parts of the polyethylenimine solution of a concentration of 25-40%, vinyl, 1 part of silane coupling agent,
1 part of UV resistant agent, the water-base resin are aqueous polyethers epoxy alkyd resin, and the cosolvent is propylene glycol first
Ether, the silane coupling agent are vinyltriethoxysilane, the coating application, which is characterized in that are used for wall table
Face, the application is it is characterized in that, the application process is as follows, before construction, first by the polyethylene of a concentration of 25-40%
The double stearic amides of imide liquor, vinyl and silane coupling agent are dissolved in 10-20 parts of deionized water, are configured to mix molten
Liquid, then by mixed solution and isophorone diisocyanate, composite water soluble emulsion acrylic resin, water-base resin, cosolvent and
Ammonium polyphosphate is mixed by regulation proportioning, 3-4h is dispersed with stirring using closed ultrasonic so that coating is uniformly mixed, stirring
Afterwards keep 2-5h slaking reaction, then construct, the construction method be round brush, the round brush mode be from top to bottom,
It when round brush, is maintained at 2-3 times in surface of wall reciprocal time, then air-dries cooling, cooling temperature is maintained at 25-30 DEG C, maintains
15-30h, round brush UV resistant agent, the round brush mode are from top to bottom that reciprocal time is maintained at 1-2 times again.
A kind of low contact angle emulsion coating of the high rigidity and its application, it is molten by the polyethyleneimine in coating paste first
The characteristic of the double stearic amides of liquid, vinyl and silane coupling agent, not only greatly improves the intensity and adhesiveness of coating paste
Can, performance stabilization is also ensured, and without chronic volatility toxic compounds such as formaldehyde, the coating of formation is smooth flexible, tool
The functions such as standby water resistant, anti-pollution, antibacterial can reach effective fire-retardant, make even heat secondly by the protection of UV resistant agent
It is dispersed in lotion, improves coating's permeability, fire-retardant and other effects, there is the very strong market competitiveness.
Embodiment 2
Scratch resistance nanometer water ceramic inorganic-organic polymer coating that the present embodiment is enumerated, including:Isophorone diisocyanate
27 parts of ester, 75 parts of composite water soluble emulsion acrylic resin, 55 parts of water-base resin, 15 parts of deionized water, 7 parts of cosolvent, polyphosphoric acid
7 parts of ammonium, 5.5 parts of the polyethylenimine solution of a concentration of 25-40%, vinyl double 0.15 part of stearic amide, silane coupling agents
1.5 parts, 1.5 parts of UV resistant agent, the water-base resin are aqueous polyethers epoxy alkyd resin, and the cosolvent is
Propylene glycol monomethyl ether, the silane coupling agent are vinyltriethoxysilane, the coating application, which is characterized in that are used
In surface of wall, the application is it is characterized in that, the application process is as follows, before construction, first by a concentration of 25-40%
Polyethylenimine solution, the double stearic amide of vinyl and silane coupling agent be dissolved in 10-20 part of deionized water, preparation
At mixed solution, then by mixed solution and isophorone diisocyanate, composite water soluble emulsion acrylic resin, water-base resin,
Cosolvent and ammonium polyphosphate are mixed by regulation proportioning, 3-4h are dispersed with stirring using closed ultrasonic so that coating mixing is equal
It is even, after stirring keep 2-5h slaking reaction, then construct, the construction method be round brush, the round brush mode be from
It under, when round brush, is maintained at 2-3 times in surface of wall reciprocal time, then air-dries cooling, cooling temperature is maintained at 25-30
DEG C, 15-30h is maintained, again round brush UV resistant agent, the round brush mode is from top to bottom that reciprocal time is maintained at 1-2
It is secondary.
A kind of low contact angle emulsion coating of the high rigidity and its application, it is molten by the polyethyleneimine in coating paste first
The characteristic of the double stearic amides of liquid, vinyl and silane coupling agent, not only greatly improves the intensity and adhesiveness of coating paste
Can, performance stabilization is also ensured, and without chronic volatility toxic compounds such as formaldehyde, the coating of formation is smooth flexible, tool
The functions such as standby water resistant, anti-pollution, antibacterial can reach effective fire-retardant, make even heat secondly by the protection of UV resistant agent
It is dispersed in lotion, improves coating's permeability, fire-retardant and other effects, there is the very strong market competitiveness.
Embodiment 3
Scratch resistance nanometer water ceramic inorganic-organic polymer coating that the present embodiment is enumerated, including:Isophorone diisocyanate
30 parts of ester, 90 parts of composite water soluble emulsion acrylic resin, 70 parts of water-base resin, 20 parts of deionized water, 10 parts of cosolvent, polyphosphoric acid
Double 0.2 part of the stearic amide of 8 parts of ammonium, 6 parts of the polyethylenimine solution of a concentration of 25-40%, vinyl, 2 parts of silane coupling agent,
2 parts of UV resistant agent, the water-base resin are aqueous polyethers epoxy alkyd resin, and the cosolvent is propylene glycol first
Ether, the silane coupling agent are vinyltriethoxysilane, the coating application, which is characterized in that are used for wall table
Face, the application is it is characterized in that, the application process is as follows, before construction, first by the polyethylene of a concentration of 25-40%
The double stearic amides of imide liquor, vinyl and silane coupling agent are dissolved in 10-20 parts of deionized water, are configured to mix molten
Liquid, then by mixed solution and isophorone diisocyanate, composite water soluble emulsion acrylic resin, water-base resin, cosolvent and
Ammonium polyphosphate is mixed by regulation proportioning, 3-4h is dispersed with stirring using closed ultrasonic so that coating is uniformly mixed, stirring
Afterwards keep 2-5h slaking reaction, then construct, the construction method be round brush, the round brush mode be from top to bottom,
It when round brush, is maintained at 2-3 times in surface of wall reciprocal time, then air-dries cooling, cooling temperature is maintained at 25-30 DEG C, maintains
15-30h, round brush UV resistant agent, the round brush mode are from top to bottom that reciprocal time is maintained at 1-2 times again.
A kind of low contact angle emulsion coating of the high rigidity and its application, it is molten by the polyethyleneimine in coating paste first
The characteristic of the double stearic amides of liquid, vinyl and silane coupling agent, not only greatly improves the intensity and adhesiveness of coating paste
Can, performance stabilization is also ensured, and without chronic volatility toxic compounds such as formaldehyde, the coating of formation is smooth flexible, tool
The functions such as standby water resistant, anti-pollution, antibacterial can reach effective fire-retardant, make even heat secondly by the protection of UV resistant agent
It is dispersed in lotion, improves coating's permeability, fire-retardant and other effects, there is the very strong market competitiveness.
The present invention is not limited to above-mentioned specific embodiment, those skilled in the art from above-mentioned design,
Without performing creative labour, the various transformation made are within the scope of the present invention.
Claims (6)
1. a kind of low contact angle emulsion coating of high rigidity, including:25-30 parts of isophorone diisocyanate, composite water soluble propylene
60-90 parts of acid resin lotion, 24-70 parts of water-base resin, 10-20 parts of deionized water, 5-10 parts of cosolvent, 4-8 parts of ammonium polyphosphate,
5-6 parts of polyethylenimine solution, vinyl double 0.1-0.2 parts of stearic amide, the silane coupling agent 1-2 of a concentration of 25-40%
Part, 1-2 parts of UV resistant agent.
2. the coating as described in claim 1, it is characterised in that:The water-base resin is aqueous polyethers epoxy-modified alkyd
Resin.
3. the coating as described in claim 1, it is characterised in that:The cosolvent is propylene glycol monomethyl ether.
4. the coating as described in claim 1, it is characterised in that:The silane coupling agent is vinyl triethoxyl silicon
Alkane.
5. the coating application as described in claim 1-4 is any, which is characterized in that be used for surface of wall.
6. application as claimed in claim 5 is it is characterized in that, the application process is as follows:
1), before construction, first by the polyethylenimine solution of a concentration of 25-40%, the double stearic amide of vinyl and silane coupled
Agent is dissolved in 10-20 parts of deionized water, is configured to mixed solution;
2), again by mixed solution and isophorone diisocyanate, composite water soluble emulsion acrylic resin, water-base resin, hydrotropy
Agent and ammonium polyphosphate are mixed by regulation proportioning;
3), using closed ultrasonic be dispersed with stirring 3-4h so that coating is uniformly mixed, and the slaking reaction of 2-5h is kept after stirring;
4)And then construction, the construction method are round brush, the round brush mode is from top to bottom;
5), round brush when, be maintained at 2-3 times in surface of wall reciprocal time;
6), then air-dry cooling, cooling temperature is maintained at 25-30 DEG C, maintains 15-30h;
7), round brush UV resistant agent again, the round brush mode is from top to bottom that reciprocal time is maintained at 1-2 times.
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CN201810114434.2A CN108559376B (en) | 2018-02-05 | 2018-02-05 | High-hardness low-contact-angle emulsion coating and application thereof |
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CN201810114434.2A CN108559376B (en) | 2018-02-05 | 2018-02-05 | High-hardness low-contact-angle emulsion coating and application thereof |
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CN108559376B CN108559376B (en) | 2020-05-05 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3999224A4 (en) * | 2019-07-18 | 2023-04-05 | Evonik Operations GmbH | Combined use of polyol ethers and cationic polyelectrolytes in aqueous polyurethane dispersions |
CN116239948A (en) * | 2022-12-27 | 2023-06-09 | 江苏汇鼎光学眼镜有限公司 | Super-water-resistant lens and preparation method thereof |
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JP2013241584A (en) * | 2012-04-27 | 2013-12-05 | Dainippon Toryo Co Ltd | Flame-retardant aqueous coating composition, and flame-retardant coating film and building board using the same |
CN105295626A (en) * | 2015-11-25 | 2016-02-03 | 安徽索亚装饰材料有限公司 | Composite modified aqueous acrylic resin emulsion coating-containing pearlescent flame retardation wallpaper |
CN105442335A (en) * | 2015-11-25 | 2016-03-30 | 安徽索亚装饰材料有限公司 | High-toughness wallpaper containing modified acrylic resin emulsion coating |
CN105567044A (en) * | 2016-03-01 | 2016-05-11 | 安徽爱迪尔新材料科技有限公司 | Pure acrylic emulsion outer wall coating |
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JP2007262220A (en) * | 2006-03-28 | 2007-10-11 | Cci Corp | Method for producing damping coating |
JP2013241584A (en) * | 2012-04-27 | 2013-12-05 | Dainippon Toryo Co Ltd | Flame-retardant aqueous coating composition, and flame-retardant coating film and building board using the same |
CN105295626A (en) * | 2015-11-25 | 2016-02-03 | 安徽索亚装饰材料有限公司 | Composite modified aqueous acrylic resin emulsion coating-containing pearlescent flame retardation wallpaper |
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Publication number | Priority date | Publication date | Assignee | Title |
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EP3999224A4 (en) * | 2019-07-18 | 2023-04-05 | Evonik Operations GmbH | Combined use of polyol ethers and cationic polyelectrolytes in aqueous polyurethane dispersions |
CN116239948A (en) * | 2022-12-27 | 2023-06-09 | 江苏汇鼎光学眼镜有限公司 | Super-water-resistant lens and preparation method thereof |
CN116239948B (en) * | 2022-12-27 | 2024-01-02 | 江苏汇鼎光学眼镜有限公司 | Super-water-resistant lens and preparation method thereof |
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Effective date of registration: 20230407 Address after: Room 330, Building 3, Chuangyue Era Cultural and Creative Park, No. 61 Xianan Road, Guicheng Street, Nanhai District, Foshan City, Guangdong Province, 528253 Patentee after: Foshan Nanhai Dual-Dimensional Water-based Materials Co.,Ltd. Address before: 510001 Spring Rose 2A, Shuixie, Renmin Road, Longhua District, Shenzhen City, Guangdong Province Patentee before: SITU (SHENZHEN) TECHNOLOGY Co.,Ltd. |