CN108559156A - The preparation method of oil resistant flexible cable material - Google Patents
The preparation method of oil resistant flexible cable material Download PDFInfo
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- CN108559156A CN108559156A CN201810313919.4A CN201810313919A CN108559156A CN 108559156 A CN108559156 A CN 108559156A CN 201810313919 A CN201810313919 A CN 201810313919A CN 108559156 A CN108559156 A CN 108559156A
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- flexible cable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
Abstract
The invention discloses the preparation methods of oil resistant flexible cable material, the technique is by vinyltriethoxysilane, polymethylphenyl siloxane fluid, sodium pyrosulfite, cyclosiloxane fatty ester, repefral, manganese acetate, sodium chromate, the raw materials such as hexa be prepared into activation adhesive after with high density polyethylene (HDPE), acrylonitrile, silicon rubber, polyalkylene glycol, melamine phosphate, 2 amino-phenol, 4 sulphonyl methylamine, metaboric acid, N methyl tetrahydrochysene pyrroles Lip river, carbon tetrachloride, 1 phenyl, 1 cyano pentamethylene, methyl methacrylate, the raw materials such as dimercaprol dimercaptopropanol pass through high temperature mixing respectively, magnetic agitation, casting die, stand cooling, water cooling drawing, solid solution aging and etc. oil resistant flexible cable material is prepared.The oil resistant flexible cable material being prepared, chemical property is good, it is elastic it is big, there is oil resistant corrosive nature, can be adapted for a variety of user demands.
Description
Technical field
The present invention relates to cable material technical fields, and in particular to arrives the preparation method of oil resistant flexible cable material.
Background technology
Cable is typically by several or the cable of similar rope that several groups of conducting wires [every group at least two] are twisted, every group
Mutually insulated between conducting wire, and be often twisted into around a center, entire outside is surrounded by the coating of high-insulation.Multi rack is located at
In the air or mounted in underground, the bottom, it to be used for telecommunication or power Transmission.1832, tsarist Russia's army officers were permitted woods lattice and are buried telegraphy line
Each other with, with being placed in glass tube, here it is an earliest in the world undergrounds after rubber-covered between underground, six conductors
Cable.The insulated conductor constituted in sealing sheath is placed in by the conducting wire center of one or more mutually insulated.It can add protection outside it
Coating is used for transmission, distributes electric energy or transmission electric signal.The difference of it and common wiring is mainly that cable dimension is larger, knot
Structure is more complex.
Special cable is the product of a series of unique energy and special construction, relative to the common wiring having a large capacity and a wide range
For cable, have the characteristics that technology content is higher, use condition is relatively stringent, batch is smaller, added value is higher.Oil resistant cable category
In one kind of special cable, oil resistant cable is suitable for the industrial and mining enterprises such as metallurgy, oil, chemical industry and power plant, in hot conditions
In lower and adverse circumstances（Such as acid, alkali, grease cryogenic conditions）As the connecting line of various electric appliances, instrument and automatic device, for handing over
It is used under 450/750 volt of rated voltage of stream and following control, monitoring and protection circuit luggage occasion.Conventional oil resistant cable it is resistance to
Oily intensity is relatively low, and after being tested by oil resistant, the parameters such as tensile strength and elongation at break decline significantly, restricts oil resistant electricity
The use of cable.
Invention content
In order to solve the above-mentioned technical problem, the invention discloses the preparation method of oil resistant flexible cable material, which will
Vinyltriethoxysilane, polymethylphenyl siloxane fluid, sodium pyrosulfite, cyclosiloxane fatty ester, repefral, acetic acid
The raw materials such as manganese, sodium chromate, hexa are prepared into after activation adhesive and high density polyethylene (HDPE), acrylonitrile, silicon rubber, poly-
Aklylene glycol, melamine phosphate, Ortho-Aminophenol -4- sulphonyl methylamine, metaboric acid, N- methyl tetrahydrochysene pyrroles Lip river, four chlorinations
The raw materials such as carbon, 1- phenyl -1- cyano pentamethylene, methyl methacrylate, dimercaprol dimercaptopropanol pass through high temperature mixing respectively, magnetic force stirs
Mix, casting die, stand cooling, water cooling drawing, solid solution aging and etc. oil resistant flexible cable material is prepared.It is prepared
Oil resistant flexible cable material, chemical property is good, it is elastic it is big, there is oil resistant corrosive nature, can be adapted for a variety of users
Demand.
Technical solution：To solve the above-mentioned problems, the present invention provides the preparation methods of oil resistant flexible cable material, including
Following steps：
（1）By 25-35 parts of high density polyethylene (HDPE), 15-24 parts of acrylonitrile, 10-16 parts of silicon rubber, 5-10 parts of polyalkylene glycol,
3-7 parts of melamine phosphate, 1-3 parts of Ortho-Aminophenol -4- sulphonyl methylamines, 2-4 parts of metaboric acid, N- methyl tetrahydrochysene pyrroles Lip river 2-3
Part, 2-5 parts of carbon tetrachloride, 1-4 parts of 1- phenyl -1- cyano pentamethylene, 3-4 parts of methyl methacrylate, 1-3 parts of dimercaprol dimercaptopropanol
Mixing, is added to and is preheated in 70 DEG C of sorbitol solution in advance, inject mixer after stirring evenly together, temperature is increased to 920-
950 DEG C, pyroreaction 150-180 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, then by mixture
It is cast to standing cooling in mold and obtains ingot casting；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, then carry out solid solution and at the beginning of timeliness obtains cable material
Product；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
Preferably, the step（1）In heating rate be 60 DEG C/min.
Preferably, the step（2）In supersound process frequency be 50-60KHz, power 500-800W, when ultrasonic
Between be 20-45 minutes.
Preferably, the step（3）In stirring use bilateral flow electromagnetic agitation, frequency 20-35Hz.
Preferably, the step（4）In drawing process use Water Cooling Technology, temperature be 0-4 DEG C.
Preferably, the step（4）In solid solubility temperature be 500-520 DEG C, time 12-15h.
Preferably, the step（4）In heat treatment timeliness be 170-175 DEG C, time 4-8h.
Compared with prior art, the present invention advantage is：
（1）The preparation method of the oil resistant flexible cable material of the present invention is by vinyltriethoxysilane, polymethylphenyl siloxane fluid, Jiao Ya
The raw materials such as sodium sulphate, cyclosiloxane fatty ester, repefral, manganese acetate, sodium chromate, hexa are prepared into
Activate adhesive after with high density polyethylene (HDPE), acrylonitrile, silicon rubber, polyalkylene glycol, melamine phosphate, 2- aminobenzenes
Phenol -4- sulphonyl methylamine, metaboric acid, N- methyl tetrahydrochysene pyrroles Lip river, carbon tetrachloride, 1- phenyl -1- cyano pentamethylene, methyl methacrylate
The raw materials such as ester, dimercaprol dimercaptopropanol pass through high temperature mixing, magnetic agitation, casting die, stand cooling, water cooling drawing, solid solution respectively
Timeliness and etc. oil resistant flexible cable material is prepared.The oil resistant flexible cable material being prepared, chemical property is good,
Elasticity is big, has oil resistant corrosive nature, can be adapted for a variety of user demands.
（2）The oil resistant flexible cable material feedstock of the present invention is easy to get, is simple for process, is suitable for heavy industrialization and uses, real
It is strong with property.
Specific implementation mode
Embodiment 1
（1）By 25 parts of high density polyethylene (HDPE), 15 parts of acrylonitrile, 10 parts of silicon rubber, 5 parts of polyalkylene glycol, melamine phosphoric acid
3 parts of ester, 1 part of Ortho-Aminophenol -4- sulphonyl methylamine, 2 parts of metaboric acid, 2 parts of N- methyl tetrahydrochysene pyrroles Lip river, 2 parts of carbon tetrachloride, 1- benzene
1 part of 1 part of base -1- cyano pentamethylene, 3 parts of methyl methacrylate, dimercaprol dimercaptopropanol mixing, are added to the advance mountain for being preheated to 70 DEG C
In pears alcoholic solution, mixer is injected after stirring evenly together, temperature is increased to 920 DEG C, and heating rate is 60 DEG C/min, and high temperature is anti-
Answer 150 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, the frequency of supersound process is 50KHz, and power 500W, ultrasonic time is 20 minutes, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, stirring is using two-way
Then mixture is cast to standing cooling in mold and obtains ingot casting by convection current electromagnetic agitation, frequency 20Hz；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, it is 0-4 DEG C that drawing process, which uses Water Cooling Technology, temperature,
Then it carries out solid solution and timeliness obtains cable material first product, solid solubility temperature is 500 DEG C, time 12h, and heat treatment timeliness is 170
DEG C, time 4h；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
The performance test results of oil resistant flexible cable material obtained are as shown in table 1.
Embodiment 2
（1）By 28 parts of high density polyethylene (HDPE), 18 parts of acrylonitrile, 12 parts of silicon rubber, 7 parts of polyalkylene glycol, melamine phosphoric acid
4 parts of ester, 2 parts of Ortho-Aminophenol -4- sulphonyl methylamine, 3 parts of metaboric acid, 2 parts of N- methyl tetrahydrochysene pyrroles Lip river, 3 parts of carbon tetrachloride, 1- benzene
2 parts of 2 parts of base -1- cyano pentamethylene, 3 parts of methyl methacrylate, dimercaprol dimercaptopropanol mixing, are added to the advance mountain for being preheated to 70 DEG C
In pears alcoholic solution, mixer is injected after stirring evenly together, temperature is increased to 930 DEG C, and heating rate is 60 DEG C/min, and high temperature is anti-
Answer 160 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, the frequency of supersound process is 52KHz, and power 600W, ultrasonic time is 25 minutes, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, stirring is using two-way
Then mixture is cast to standing cooling in mold and obtains ingot casting by convection current electromagnetic agitation, frequency 25Hz；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, it is 0-4 DEG C that drawing process, which uses Water Cooling Technology, temperature,
Then it carries out solid solution and timeliness obtains cable material first product, solid solubility temperature is 505 DEG C, time 13h, and heat treatment timeliness is 172
DEG C, time 5h；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
The performance test results of oil resistant flexible cable material obtained are as shown in table 1.
Embodiment 3
（1）By 32 parts of high density polyethylene (HDPE), 21 parts of acrylonitrile, 15 parts of silicon rubber, 9 parts of polyalkylene glycol, melamine phosphoric acid
6 parts of ester, 2 parts of Ortho-Aminophenol -4- sulphonyl methylamine, 3 parts of metaboric acid, 3 parts of N- methyl tetrahydrochysene pyrroles Lip river, 4 parts of carbon tetrachloride, 1- benzene
2 parts of 3 parts of base -1- cyano pentamethylene, 4 parts of methyl methacrylate, dimercaprol dimercaptopropanol mixing, are added to the advance mountain for being preheated to 70 DEG C
In pears alcoholic solution, mixer is injected after stirring evenly together, temperature is increased to 940 DEG C, and heating rate is 60 DEG C/min, and high temperature is anti-
Answer 170 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, the frequency of supersound process is 55KHz, and power 700W, ultrasonic time is 35 minutes, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, stirring is using two-way
Then mixture is cast to standing cooling in mold and obtains ingot casting by convection current electromagnetic agitation, frequency 30Hz；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, it is 0-4 DEG C that drawing process, which uses Water Cooling Technology, temperature,
Then it carries out solid solution and timeliness obtains cable material first product, solid solubility temperature is 515 DEG C, time 14h, and heat treatment timeliness is 174
DEG C, time 7h；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
The performance test results of oil resistant flexible cable material obtained are as shown in table 1.
Embodiment 4
（1）By 35 parts of high density polyethylene (HDPE), 24 parts of acrylonitrile, 16 parts of silicon rubber, 10 parts of polyalkylene glycol, melamine phosphoric acid
7 parts of ester, 3 parts of Ortho-Aminophenol -4- sulphonyl methylamine, 4 parts of metaboric acid, 3 parts of N- methyl tetrahydrochysene pyrroles Lip river, 5 parts of carbon tetrachloride, 1- benzene
3 parts of 4 parts of base -1- cyano pentamethylene, 4 parts of methyl methacrylate, dimercaprol dimercaptopropanol mixing, are added to the advance mountain for being preheated to 70 DEG C
In pears alcoholic solution, mixer is injected after stirring evenly together, temperature is increased to 950 DEG C, and heating rate is 60 DEG C/min, and high temperature is anti-
Answer 180 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, the frequency of supersound process is 60KHz, and power 800W, ultrasonic time is 45 minutes, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, stirring is using two-way
Then mixture is cast to standing cooling in mold and obtains ingot casting by convection current electromagnetic agitation, frequency 35Hz；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, it is 0-4 DEG C that drawing process, which uses Water Cooling Technology, temperature,
Then it carries out solid solution and timeliness obtains cable material first product, solid solubility temperature is 520 DEG C, time 15h, and heat treatment timeliness is 175
DEG C, time 8h；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
The performance test results of oil resistant flexible cable material obtained are as shown in table 1.
Comparative example 1
（1）By 25 parts of high density polyethylene (HDPE), 15 parts of acrylonitrile, 10 parts of silicon rubber, 5 parts of polyalkylene glycol, Ortho-Aminophenol -4-
1 part of sulphonyl methylamine, 2 parts of metaboric acid, 2 parts of N- methyl tetrahydrochysene pyrroles Lip river, 2 parts of carbon tetrachloride, 1 part of 1- phenyl -1- cyano pentamethylene, first
The 3 parts of mixing of base methyl acrylate, are added to and are preheated in 70 DEG C of sorbitol solution in advance, inject mixing after stirring evenly together
Machine, temperature are increased to 920 DEG C, and heating rate is 60 DEG C/min, pyroreaction 150 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, the frequency of supersound process is 50KHz, and power 500W, ultrasonic time is 20 minutes, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, stirring is using two-way
Then mixture is cast to standing cooling in mold and obtains ingot casting by convection current electromagnetic agitation, frequency 20Hz；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, it is 0-4 DEG C that drawing process, which uses Water Cooling Technology, temperature,
Then it carries out solid solution and timeliness obtains cable material first product, solid solubility temperature is 500 DEG C, time 12h, and heat treatment timeliness is 170
DEG C, time 4h；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
The performance test results of oil resistant flexible cable material obtained are as shown in table 1.
Comparative example 2
（1）By 35 parts of high density polyethylene (HDPE), 24 parts of acrylonitrile, 16 parts of silicon rubber, 10 parts of polyalkylene glycol, melamine phosphoric acid
7 parts of ester, 3 parts of Ortho-Aminophenol -4- sulphonyl methylamine, 4 parts of metaboric acid, 3 parts of N- methyl tetrahydrochysene pyrroles Lip river, 5 parts of carbon tetrachloride, 1- benzene
4 parts of base -1- cyano pentamethylene, 3 parts of dimercaprol dimercaptopropanol inject mixer together after mixing, and temperature is increased to 950 DEG C, heating
Rate be 60 DEG C/min, pyroreaction 180 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, the frequency of supersound process is 60KHz, and power 800W, ultrasonic time is 45 minutes, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, stirring is using two-way
Then mixture is cast to standing cooling in mold and obtains ingot casting by convection current electromagnetic agitation, frequency 35Hz；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, it is 0-4 DEG C that drawing process, which uses Water Cooling Technology, temperature,
Then it carries out solid solution and timeliness obtains cable material first product, solid solubility temperature is 520 DEG C, time 15h, and heat treatment timeliness is 175
DEG C, time 8h；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
The performance test results of oil resistant flexible cable material obtained are as shown in table 1.
The oil resistant flexible cable material obtained of embodiment 1-4 and comparative example 1-2 is subjected to elasticity modulus, creep resistant respectively
This several performance, surface resistivity performance tests.
Table 1
| Elasticity modulus MPa | Creep-resistant property % | Surface resistivity（Ω） | |
| Embodiment 1 | 87 | 362 | 1.54×1016 |
| Embodiment 2 | 85 | 377 | 1.63×1016 |
| Embodiment 3 | 90 | 367 | 1.58×1016 |
| Embodiment 4 | 86 | 372 | 1.63×1016 |
| Comparative example 1 | 15 | 279 | 3.51×1011 |
| Comparative example 2 | 23 | 227 | 2.07×1010 |
The preparation method of the oil resistant flexible cable material of the present invention is by vinyltriethoxysilane, polymethylphenyl siloxane fluid, burnt sulfurous
The preparation of the raw materials such as sour sodium, cyclosiloxane fatty ester, repefral, manganese acetate, sodium chromate, hexa survives
Change adhesive after with high density polyethylene (HDPE), acrylonitrile, silicon rubber, polyalkylene glycol, melamine phosphate, 2- aminobenzenes
Phenol -4- sulphonyl methylamine, metaboric acid, N- methyl tetrahydrochysene pyrroles Lip river, carbon tetrachloride, 1- phenyl -1- cyano pentamethylene, methyl methacrylate
The raw materials such as ester, dimercaprol dimercaptopropanol pass through high temperature mixing, magnetic agitation, casting die, stand cooling, water cooling drawing, solid solution respectively
Timeliness and etc. oil resistant flexible cable material is prepared.The oil resistant flexible cable material being prepared, chemical property is good,
Elasticity is big, has oil resistant corrosive nature, can be adapted for a variety of user demands.The oil resistant flexible cable material feedstock of the present invention is easy
It obtains, is simple for process, being suitable for heavy industrialization and use, it is highly practical.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (7)
1. the preparation method of oil resistant flexible cable material, which is characterized in that include the following steps：
（1）By 25-35 parts of high density polyethylene (HDPE), 15-24 parts of acrylonitrile, 10-16 parts of silicon rubber, 5-10 parts of polyalkylene glycol,
3-7 parts of melamine phosphate, 1-3 parts of Ortho-Aminophenol -4- sulphonyl methylamines, 2-4 parts of metaboric acid, N- methyl tetrahydrochysene pyrroles Lip river 2-3
Part, 2-5 parts of carbon tetrachloride, 1-4 parts of 1- phenyl -1- cyano pentamethylene, 3-4 parts of methyl methacrylate, 1-3 parts of dimercaprol dimercaptopropanol
Mixing, is added to and is preheated in 70 DEG C of sorbitol solution in advance, inject mixer after stirring evenly together, temperature is increased to 920-
950 DEG C, pyroreaction 150-180 minutes, be cooled to 350 DEG C it is spare；
（2）By 3 parts of vinyltriethoxysilane, 1 part of polymethylphenyl siloxane fluid, 4 parts of sodium pyrosulfite, 2 parts of cyclosiloxane fatty ester,
5 parts of repefral, 1 part of manganese acetate, 2 parts of sodium chromate, 4 parts of hexa carry out ultrasound point after mixing
It dissipates, prepares activation adhesive；
（3）By step（2）Activation adhesive be added to step（1）Mixture in, be uniformly mixed, then by mixture
It is cast to standing cooling in mold and obtains ingot casting；
（4）By step（3）Ingot casting extruding be drawn into linear or sheet, then carry out solid solution and at the beginning of timeliness obtains cable material
Product；
（5）By step（4）Cable material first product cut, plastotype, packaging are got product.
2. the preparation method of oil resistant flexible cable material according to claim 1, which is characterized in that the step（1）In
Heating rate be 60 DEG C/min.
3. the preparation method of oil resistant flexible cable material according to claim 1, which is characterized in that the step（2）In
Supersound process frequency be 50-60KHz, power 500-800W, ultrasonic time be 20-45 minutes.
4. the preparation method of oil resistant flexible cable material according to claim 1, which is characterized in that the step（3）In
Stirring use bilateral flow electromagnetic agitation, frequency 20-35Hz.
5. the preparation method of oil resistant flexible cable material according to claim 1, which is characterized in that the step（4）In
Drawing process use Water Cooling Technology, temperature be 0-4 DEG C.
6. the preparation method of oil resistant flexible cable material according to claim 1, which is characterized in that the step（4）In
Solid solubility temperature be 500-520 DEG C, time 12-15h.
7. the preparation method of oil resistant flexible cable material according to claim 1, which is characterized in that the step（4）In
Heat treatment timeliness be 170-175 DEG C, time 4-8h.
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| CN201810313919.4A CN108559156A (en) | 2018-04-10 | 2018-04-10 | The preparation method of oil resistant flexible cable material |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101417388A (en) * | 2008-12-12 | 2009-04-29 | 江苏大学 | Preparation method of light high-intensity aluminum base home-position composite material for cable bridge frame |
| CN102702598A (en) * | 2012-05-22 | 2012-10-03 | 常州大学 | Halogen-free flame-retardant polyolefin cable material capable of resisting 150 DEG C and preparation method thereof |
| CN106834838A (en) * | 2016-12-30 | 2017-06-13 | 中南大学 | A kind of Al Mg Si Cu Pr Nd rare earth aluminium alloy cable materials and preparation method thereof |
-
2018
- 2018-04-10 CN CN201810313919.4A patent/CN108559156A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101417388A (en) * | 2008-12-12 | 2009-04-29 | 江苏大学 | Preparation method of light high-intensity aluminum base home-position composite material for cable bridge frame |
| CN102702598A (en) * | 2012-05-22 | 2012-10-03 | 常州大学 | Halogen-free flame-retardant polyolefin cable material capable of resisting 150 DEG C and preparation method thereof |
| CN106834838A (en) * | 2016-12-30 | 2017-06-13 | 中南大学 | A kind of Al Mg Si Cu Pr Nd rare earth aluminium alloy cable materials and preparation method thereof |
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Application publication date: 20180921 |
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