CN108546865B - A kind of preparation method of high-strength Antioxidant alloy material - Google Patents
A kind of preparation method of high-strength Antioxidant alloy material Download PDFInfo
- Publication number
- CN108546865B CN108546865B CN201810442439.8A CN201810442439A CN108546865B CN 108546865 B CN108546865 B CN 108546865B CN 201810442439 A CN201810442439 A CN 201810442439A CN 108546865 B CN108546865 B CN 108546865B
- Authority
- CN
- China
- Prior art keywords
- core
- copper
- alloy material
- preparation
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 58
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 21
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000010949 copper Substances 0.000 claims abstract description 53
- 229910052802 copper Inorganic materials 0.000 claims abstract description 52
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 41
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229910052742 iron Inorganic materials 0.000 claims abstract description 25
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 16
- 239000011777 magnesium Substances 0.000 claims abstract description 16
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 16
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 15
- 229910052718 tin Inorganic materials 0.000 claims abstract description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004411 aluminium Substances 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 23
- 239000001257 hydrogen Substances 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 23
- 238000000465 moulding Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000000280 densification Methods 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 27
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000011162 core material Substances 0.000 description 69
- 239000011135 tin Substances 0.000 description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000289 melt material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910016334 Bi—In Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000001012 protector Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 101100313907 Caenorhabditis elegans tin-44 gene Proteins 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000010946 fine silver Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910000648 terne Inorganic materials 0.000 description 1
- -1 terne metal Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/04—Alloys containing less than 50% by weight of each constituent containing tin or lead
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/12—Making non-ferrous alloys by processing in a semi-solid state, e.g. holding the alloy in the solid-liquid phase
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
A kind of preparation method of high-strength Antioxidant alloy material provided by the invention, it is made of core and copper plate, wherein, core is grouped as by the group of following weight percent content: tin 42%~45%, copper 13%~16%, aluminium 0.5%~1.2%, magnesium 1.2%~1.8%, scandium 0.2%~0.5%, inevitable impurity content≤2wt%, remaining is iron.The problem of to improve the intensity and inoxidizability of melt alloy material, alloy melt effectively being avoided to deform because intensity is not high, and influencing because of oxidation melt resistance.
Description
The application is divisional application, original bill Patent No.: 201710355824.4, the applying date is on May 19th, 2017,
A kind of denomination of invention are as follows: high-strength Antioxidant alloy material and preparation method thereof.
Technical field
The present invention relates to melt alloy fields, specifically, being a kind of high strong anti-oxidation melt conjunction suitable for fuse
The preparation method of golden material.
Background technique
With the continuous social and economic development, electronic equipment is used widely, and the demand of fuse is consequently increased.It is molten
Disconnected device is according to electric current be more than specified value for a period of time after, Melt molten is made with the heat that its own is generated, to keep circuit disconnected
It opens；With a kind of current protector made of this principle.Fuse is widely used in high and low voltage electric distribution system and control system
It is using one of most common protection device as the protector of short circuit and overcurrent and in electrical equipment.
Fuse is generally made of insulator foot or supporter, contact, melt etc., and melt is the groundwork portion of fuse
Point, melt is equivalent to the one section of special conducting wire of series connection in circuit, and when short circuit or overload occur for circuit, electric current is excessive, melts
Body is melted because of overheat, to cut off circuit.Melt material has the characteristics that low relative melting points, stability of characteristics, is easy to fuse.Its
In, melt material mostly uses greatly the metals such as terne metal, sheffield plate, zinc, silver.
Since fuse is disposable product, and silver is natural currency, uses fine silver as melt material, cost compared with
Height, meanwhile, lead has biggish harm to human body and environment.Application No. is 200380100152.9 patents of invention to disclose Sn-
Bi-In alloy melt, the melt strength is lower, easily deforms, and the deformation of melt will lead to melt resistance and change, from
And influence the service performance of melt.On the other hand, melt will be chronically exposed in air, and alloy melt is due to oxidation in order to prevent
The resistance for influencing melt, needs to can be carried out promotion to the inoxidizability of alloy melt.
Summary of the invention
The main purpose of the present invention is to provide a kind of preparation methods of high-strength Antioxidant alloy material, to solve existing skill
The deficiency of art improves the intensity and inoxidizability of melt alloy material, so that alloy melt effectively be avoided to become because intensity is not high
Shape, and the problem of influence because of oxidation melt resistance.
To achieve the above objectives, the technical solution adopted by the present invention are as follows: a kind of high-strength Antioxidant alloy material by core and
Copper plate composition, wherein the core is grouped as by the group of following weight percent content: tin 42%~45%, copper 13%~
16%, aluminium 0.5%~1.2%, magnesium 1.2%~1.8%, scandium 0.2%~0.5%, inevitable impurity content≤2wt%,
Yu Weitie.
An embodiment according to the present invention, copper plate with a thickness of 0.10~0.15mm.
A kind of preparation method of high-strength Antioxidant alloy material comprising step:
(A) core forms, and the iron of corrresponding quality percentage, copper, aluminium, magnesium are uniformly mixed, and forms mixture；Tin is heated
To 520~550 DEG C, scandium is added and adds mixture after mixing evenly, is added in molding die after being again stirring for uniformly, temperature
150 DEG C are dropped to hereinafter, alloy material is able to be removed from the molds, completion molding obtains core blank；
(B) core is fine and close, and core blank is put into pressurizing mold, 210~220 DEG C are heated to together with pressurizing mold,
Then it pressurizeing to the core blank in pressurizing mold, pressure is 5MPa~8MPa, and 10~15min of pressure maintaining is cooled to room temperature,
Take out core blank；
(C) core blank obtained in step (B) is heated to 90 DEG C~110 DEG C by destressing, keeps the temperature 60~80min,
It is then cooled to room temperature；And
(D) layers of copper is electroplated, and carries out electro-coppering to the surface of core blank obtained in step (C), copper plate with a thickness of
0.10~0.15mm.
An embodiment according to the present invention, the core molding and the core densification of the step (B) of the step (A) are in hydrogen
Compression ring is completed under border, and hydrogen pressure is not more than 6000Pa.
An embodiment according to the present invention, iron, copper, aluminium, magnesium, scandium in the step (A) are powder, and granularity is not more than
350 mesh.
The present invention compared with the existing technology, mainly has the following advantages and beneficial effects:
(1) in core material, tin is low-melting-point metal, about 231 DEG C of fusing point, is easy fusing and fusing, the electric conductivity of copper
Can be good, copper is added, alloy melt is made to have good electric conductivity when unblown, in addition, the addition of copper can also improve conjunction
The intensity of golden melt；The addition of iron, so that alloy melt, when by larger current, local temperature is higher inside melt, at this moment
Iron can form alloy with tin, and copper can form alloy with aluminium, and magnesium can form alloy with tin, and resistance becomes larger, to accelerate to close
The fusing of golden melt, in addition, the addition of iron, can also reduce the cost of alloy melt；
(2) in preparation step (A), Sn is heated to 520~550 DEG C, the significantly larger than fusing point of Sn, is improved Sn's
Activity, so that the combination of Sn and Cu, Fe are improved, since Sn can form metallic compound, heating temperature at 550 DEG C or more with Fe
Degree should be not more than 550 DEG C；The step (A) and step (B) need to be completed under hydrogen environment, and hydrogen pressure is not more than 6000Pa,
It is that can generate oxide since Sn, Fe are when temperature is higher, the oxide of generation will affect the performance of alloy melt；It is added
Sc can be reacted with oxygen and impurity, purify matrix, and the oxygen that in addition a small amount of hydrogen can adhere to surfaces such as Fe, Cu carries out anti-
It answers, removes the oxygen on surface；
(3) in preparation step (B), core blank is put into pressurizing mold, certain temperature repressurization is heated to, is able to
The consistency for improving alloy melt, achievees the purpose that further increase intensity；
(4) in preparation step (C), destressing is able to the stress inside removal alloy melt, to extend alloy melt
Service life；
(5) since the surface in Sn is difficult direct copper plating, Cu, the Fe being added in core have with electro-coppering good
Compatibility can improve the plating performance of alloy melt, be able to carry out electricity directly on the core of alloy melt after Cu, Fe is added
Plating；Wherein, copper plate is able to that alloy melt is effectively prevent to aoxidize, and avoids being chronically exposed in air and aoxidizing, to influence molten
Bulk resistor；Copper plate cannot be too thick, and the too thick alloy melt that will lead to is difficult to break；Can not be too thin, coating is too thin, is transporting or is making
With when, layers of copper be easy polishing；Further, since the intensity of copper is greater than the intensity of tin, copper plate is also increased alloy melt
Intensity.
Specific embodiment
It is described below for disclosing the present invention so that those skilled in the art can be realized the present invention.It is excellent in being described below
Embodiment is selected to be only used as illustrating, it may occur to persons skilled in the art that other obvious modifications.
Embodiment 1
A kind of high-strength Antioxidant alloy material is made of core and copper plate, wherein the core is by following weight percent
It is grouped as than the group of content: tin 42%, copper 15%, aluminium 1.0%, magnesium 1.2%, scandium 0.2%, inevitable impurity content 2wt%,
Remaining is iron.
The preparation method of the high-strength Antioxidant alloy material comprising steps of
(A) core forms, and Fe, Cu, Al, Mg are uniformly mixed according to the proportion, forms mixture；Sn is heated to 520 DEG C,
Sc is added and adds mixture after mixing evenly, is added in molding die after being again stirring for uniformly, temperature drops to 150 DEG C or less
When, alloy material can be removed from the molds, complete molding, obtain core blank, this step is completed under hydrogen environment, hydrogen
Air pressure is not more than by force 6000Pa；Fe, Cu that this step is added are powder, and granularity is not more than 350 mesh；
(B) core is fine and close, and core blank is put into pressurizing mold, is heated to 210 DEG C together with pressurizing mold, then right
Core blank in pressurizing mold pressurizes, pressure 5MPa, and pressure maintaining 10 is then cooled to room temperature, and takes out core blank, this
Step is completed under hydrogen environment, and hydrogen pressure is not more than 6000Pa；
(C) core blank obtained in (B) is heated to 90 DEG C by destressing, is kept the temperature 60min, is then cooled to room temperature；
(D) layers of copper is electroplated, and core blank obtained in step (C), carries out electro-coppering on surface, thickness of coated copper layer is
0.10mm。
Embodiment 2
A kind of high-strength Antioxidant alloy material is made of core and copper plate, wherein the core is by following weight percent
It is grouped as than the group of content: tin 43%, copper 14%, aluminium 0.8%, magnesium 1.6%, scandium 0.5%, inevitable impurity content
1.8wt%, remaining is iron.
The preparation method of the high-strength Antioxidant alloy material comprising steps of
(A) core forms, and Fe, Cu, Al, Mg are uniformly mixed according to the proportion, forms mixture；Sn is heated to 530 DEG C,
Sc is added and adds mixture after mixing evenly, is added in molding die after being again stirring for uniformly, temperature drops to 150 DEG C or less
When, alloy material can be removed from the molds, complete molding, obtain core blank, this step is completed under hydrogen environment, hydrogen
Air pressure is not more than by force 6000Pa；Fe, Cu that this step is added are powder, and granularity is not more than 350 mesh；
(B) core is fine and close, and core blank is put into pressurizing mold, is heated to 215 DEG C together with pressurizing mold, then right
Core blank in pressurizing mold pressurizes, pressure 6MPa, and pressure maintaining 12min is then cooled to room temperature, and takes out core hair
Base, this step are completed under hydrogen environment, and hydrogen pressure is not more than 6000Pa；
(C) core blank obtained in (B) is heated to 95 DEG C by destressing, is kept the temperature 65min, is then cooled to room temperature；
(D) layers of copper is electroplated, and core blank obtained in step (C), carries out electro-coppering on surface, thickness of coated copper layer is
0.12mm。
Embodiment 3
A kind of high-strength Antioxidant alloy material is made of core and copper plate, wherein the core is by following weight percent
It is grouped as than the group of content: tin 44%, copper 13%, aluminium 0.5%, magnesium 1.8%, scandium 0.4%, inevitable impurity content
1.6wt%, remaining is iron.
The preparation method of the high-strength Antioxidant alloy material comprising steps of
(A) core forms, and Fe, Cu, Al, Mg are uniformly mixed according to the proportion, forms mixture；Sn is heated to 540 DEG C,
Sc is added and adds mixture after mixing evenly, is added in molding die after being again stirring for uniformly, temperature drops to 150 DEG C or less
When, alloy material can be removed from the molds, complete molding, obtain core blank, this step is completed under hydrogen environment, hydrogen
Air pressure is not more than by force 6000Pa；Fe, Cu that this step is added are powder, and granularity is not more than 350 mesh；
(B) core is fine and close, and core blank is put into pressurizing mold, is heated to 220 DEG C together with pressurizing mold, then right
Core blank in pressurizing mold pressurizes, pressure 7MPa, and pressure maintaining 14min is then cooled to room temperature, and takes out core hair
Base, this step are completed under hydrogen environment, and hydrogen pressure is not more than 6000Pa；
(C) core blank obtained in (B) is heated to 100 DEG C by destressing, is kept the temperature 70min, is then cooled to room temperature；
(D) layers of copper is electroplated, and core blank obtained in step (C), carries out electro-coppering on surface, thickness of coated copper layer is
0.14mm。
Embodiment 4
A kind of high-strength Antioxidant alloy material is made of core and copper plate, wherein the core is by following weight percent
It is grouped as than the group of content: tin 45%, copper 16%, aluminium 1.2%, magnesium 1.7%, scandium 0.3%, inevitable impurity content
1.9wt%, remaining is iron.
The preparation method of the high-strength Antioxidant alloy material comprising steps of
(A) core forms, and Fe, Cu, Al, Mg are uniformly mixed according to the proportion, forms mixture；Sn is heated to 550 DEG C,
Sc is added and adds mixture after mixing evenly, is added in molding die after being again stirring for uniformly, temperature drops to 150 DEG C or less
When, alloy material can be removed from the molds, complete molding, obtain core blank, this step is completed under hydrogen environment, hydrogen
Air pressure is not more than by force 6000Pa；Fe, Cu that this step is added are powder, and granularity is not more than 350 mesh；
(B) core is fine and close, and core blank is put into pressurizing mold, is heated to 220 DEG C together with pressurizing mold, then right
Core blank in pressurizing mold pressurizes, pressure 8MPa, and pressure maintaining 15min is then cooled to room temperature, and takes out core hair
Base, this step are completed under hydrogen environment, and hydrogen pressure is not more than 6000Pa；
(C) core blank obtained in (B) is heated to 110 DEG C by destressing, is kept the temperature 80min, is then cooled to room temperature；
(D) layers of copper is electroplated, and core blank obtained in step (C), carries out electro-coppering on surface, thickness of coated copper layer is
0.15mm。
The alloy melt of each embodiment preparation is tested for the property.Wherein tensile strength test method uses GB/
T228.1-2010 " metal material stretching test part 1: room temperature test method "；Testing equipment uses WDW-300A electronics ten thousand
It can testing machine；The actual density of the core material of alloy melt uses buoyancy method, and instrument uses metal material densitometer AU-
200ME。
The core performance test of the high-strength Antioxidant alloy material of embodiment 1 to embodiment 4 preparation is as shown in table 1.
The core performance parameter of the alloy material of 1 embodiment 1-4 of table
As shown in Table 1, the high-strength Antioxidant alloy material prepared by embodiment 1 to 4, core material tensile strength
Up to 75~85MPa, consistency is >=98%, and the integral strength of alloy melt can be different due to the size of alloy melt, but because
It is generally higher than 220MPa for the intensity of copper, so the integral strength of alloy melt is greater than core material intensity, therefore the present invention makes
Stated with core material intensity, consistency of the present invention, calculation method is, first according to core material it is various at
Divide ratio, density, calculate theoretical density, then using the actual density of core material divided by theoretical density.Wherein, using Shen
Please number for 200380100152.9 patent documents production Sn-Bi-In alloy melt, tensile strength be 20~30MPa.
To which the high-strength Antioxidant alloy material is without containing precious metals such as silver, cost is relatively low, while without containing lead etc.
Pollution element, it is environmentally protective.
Embodiment 5 is to embodiment 8
The preparation method of the high-strength Antioxidant alloy material in embodiment 5-8 is with embodiment 3, the difference is that institute
State the constituent content of core.The each component content of core material of the embodiment 5 into embodiment 8 is shown in Table 2, prepared by embodiment 5 to 8
The high-strength Antioxidant alloy material core performance test it is as shown in table 3.
The each component content of the core material of 2 embodiment 5-8 of table
The core performance parameter of the alloy material of 3 embodiment 5-8 of table
| Embodiment | Tensile strength MPa | Consistency |
| Example 5 | 38 | 85 |
| Example 6 | 30 | 82 |
| Example 7 | 28 | 84 |
| Example 8 | 15 | 78 |
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention
Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and
Improvement is both fallen in the range of claimed invention.The present invention claims protection scope by appended claims and its
Equivalent defines.
Claims (3)
1. a kind of preparation method of high-strength Antioxidant alloy material, which is characterized in that comprising steps of
(A) core forms, and the iron of corrresponding quality percentage, copper, aluminium, magnesium are uniformly mixed, and forms mixture；Tin is heated to
530 DEG C, scandium is added and adds mixture after mixing evenly, is added in molding die after being again stirring for uniformly, temperature drops to 150
DEG C hereinafter, alloy material is able to be removed from the molds, molding is completed, core blank is obtained；
(B) core is fine and close, and core blank is put into pressurizing mold, 215 DEG C are heated to together with pressurizing mold, then to pressurization
Core blank in mold pressurizes, pressure 6MPa, pressure maintaining 12min, is cooled to room temperature, takes out core blank；
(C) core blank obtained in step (B) is heated to 95 DEG C by destressing, is kept the temperature 65min, is then cooled to room temperature；
And
(D) layers of copper is electroplated, and carries out electro-coppering to the surface of core blank obtained in step (C), copper plate with a thickness of
0.12mm；
Wherein, the core is grouped as by the group of following weight percent content: tin 42%~45%, copper 13%~16%, aluminium
0.5%~1.2%, magnesium 1.2%~1.8%, scandium 0.2%~0.5%, inevitable impurity content≤2wt%, remaining is iron.
2. preparation method according to claim 1, which is characterized in that the core molding of the step (A) and the step
(B) core densification is completed under hydrogen environment, and hydrogen pressure is not more than 6000Pa.
3. preparation method according to claim 2, which is characterized in that iron, copper, aluminium, magnesium, scandium in the step (A) are
Powder, granularity are not more than 350 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810442439.8A CN108546865B (en) | 2017-05-19 | 2017-05-19 | A kind of preparation method of high-strength Antioxidant alloy material |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710355824.4A CN107164682B (en) | 2017-05-19 | 2017-05-19 | A kind of high-strength Antioxidant alloy material and preparation method thereof |
| CN201810442439.8A CN108546865B (en) | 2017-05-19 | 2017-05-19 | A kind of preparation method of high-strength Antioxidant alloy material |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710355824.4A Division CN107164682B (en) | 2017-05-19 | 2017-05-19 | A kind of high-strength Antioxidant alloy material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108546865A CN108546865A (en) | 2018-09-18 |
| CN108546865B true CN108546865B (en) | 2019-07-23 |
Family
ID=59815872
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810442439.8A Active CN108546865B (en) | 2017-05-19 | 2017-05-19 | A kind of preparation method of high-strength Antioxidant alloy material |
| CN201710355824.4A Active CN107164682B (en) | 2017-05-19 | 2017-05-19 | A kind of high-strength Antioxidant alloy material and preparation method thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710355824.4A Active CN107164682B (en) | 2017-05-19 | 2017-05-19 | A kind of high-strength Antioxidant alloy material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN108546865B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108546865B (en) * | 2017-05-19 | 2019-07-23 | 浙江明远眼镜有限公司 | A kind of preparation method of high-strength Antioxidant alloy material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102172994A (en) * | 2011-01-27 | 2011-09-07 | 王楚雯 | Metal composite wire, preparation method thereof and metal wire |
| JP2015155570A (en) * | 2014-02-21 | 2015-08-27 | 株式会社オートネットワーク技術研究所 | Wire for connector pin, method of producing the same and connector |
| CN105772878A (en) * | 2016-04-11 | 2016-07-20 | 尚成荣 | High-difficulty steel core wire electrode and manufacturing method thereof |
| CN107164682B (en) * | 2017-05-19 | 2018-11-02 | 杭州富阳星宇铜业有限公司 | A kind of high-strength Antioxidant alloy material and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103730298A (en) * | 2012-10-13 | 2014-04-16 | 温州市方为熔断器有限公司 | Fuse with anti-oxidation coating on surface of fuse body |
| CN204834074U (en) * | 2015-08-14 | 2015-12-02 | 河南天海电器有限公司 | Car aluminum alloy storage battery line |
-
2017
- 2017-05-19 CN CN201810442439.8A patent/CN108546865B/en active Active
- 2017-05-19 CN CN201710355824.4A patent/CN107164682B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102172994A (en) * | 2011-01-27 | 2011-09-07 | 王楚雯 | Metal composite wire, preparation method thereof and metal wire |
| JP2015155570A (en) * | 2014-02-21 | 2015-08-27 | 株式会社オートネットワーク技術研究所 | Wire for connector pin, method of producing the same and connector |
| CN105772878A (en) * | 2016-04-11 | 2016-07-20 | 尚成荣 | High-difficulty steel core wire electrode and manufacturing method thereof |
| CN107164682B (en) * | 2017-05-19 | 2018-11-02 | 杭州富阳星宇铜业有限公司 | A kind of high-strength Antioxidant alloy material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108546865A (en) | 2018-09-18 |
| CN107164682A (en) | 2017-09-15 |
| CN107164682B (en) | 2018-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2023106573A (en) | Copper alloy powder, layered/molded product, method for producing layered/molded product, and various metal parts | |
| CN105274386B (en) | High-performance complex multi-element phosphor bronze alloy material and preparation method thereof | |
| CN102719699A (en) | Novel high-elasticity low beryllium copper alloy and preparation method thereof | |
| CN105087981B (en) | Preparation method for welding-resistant ablation-resistant Cu-nano Al2O3 Cr contact material | |
| CN108193080A (en) | High intensity, highly conductive proof stress relaxation corson alloy material and preparation method thereof | |
| CN106636734A (en) | High-strength, high-electric-conductivity and high-stress relaxation-resistance copper alloy elastic material and preparation method thereof | |
| CN105088006A (en) | Low-cost and stress-relaxation-resistant copper alloy lead frame material and preparation method thereof | |
| CN114032479A (en) | Zr-based bulk amorphous alloy suitable for small electronic equipment and preparation method thereof | |
| JP5250388B2 (en) | Composite metal glass having both strength and conductivity and method for producing the same | |
| CN108546865B (en) | A kind of preparation method of high-strength Antioxidant alloy material | |
| CN102560192B (en) | A kind of High-strength high-plasticity copper alloy and preparation method thereof | |
| CN106591758B (en) | A kind of method electric arc spraying solid silk material and its prepare high temperature coatings | |
| CN106676318B (en) | A kind of asynchronous traction motor rotor bar brass material containing zirconium and preparation method thereof | |
| CN110508800B (en) | Pre-alloy powder used for composite binder grinding tool for grinding hard and brittle materials, preparation method of pre-alloy powder and grinding tool | |
| CN106282649B (en) | A kind of high-strength conductive Cu-base composites and preparation method thereof | |
| CN104032219B (en) | A kind of non-magnetic alloy and preparation method | |
| CN109321782A (en) | A kind of pure nickel gold plated, high temperature conductive filament and preparation method thereof | |
| CN104078249A (en) | Silver copper tungsten electrical contact and processing technology thereof | |
| CN114686747A (en) | Method for preparing copper stainless steel in-situ composite material by adopting vacuum consumable arc melting | |
| CN102816948A (en) | Copper alloy | |
| CN110257664B (en) | Copper-based composite material and preparation method thereof | |
| CN102306558A (en) | Copper alloy electric contact material for low-voltage electrical device and preparation method of copper alloy electric contact material | |
| CN104357707A (en) | Novel copper alloy and preparation method thereof | |
| CN102041407A (en) | High-strength high-conductivity micro-boron copper alloy material and preparation method thereof | |
| CN110527856A (en) | A kind of preparation method of great surface quality, high-intensity nickel alloy band |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190626 Address after: 325041 Louqiao Village, Louhai Louqiao Street, Wenzhou City, Zhejiang Province Applicant after: ZHEJIANG MINGYUAN GLASSES Co.,Ltd. Address before: 315040 B3 building, R & D Park, Ningbo hi tech Development Zone, Zhejiang 509-512 Applicant before: ZHEJIANG DIHENG INDUSTRY Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of a high-strength antioxidant alloy material Granted publication date: 20190723 Pledgee: Zhejiang Wenzhou Ouhai Rural Commercial Bank Co.,Ltd. Station Avenue Branch Pledgor: ZHEJIANG MINGYUAN GLASSES Co.,Ltd. Registration number: Y2024330000844 |