CN108530983A - A kind of ionomer ink - Google Patents

A kind of ionomer ink Download PDF

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Publication number
CN108530983A
CN108530983A CN201710122110.9A CN201710122110A CN108530983A CN 108530983 A CN108530983 A CN 108530983A CN 201710122110 A CN201710122110 A CN 201710122110A CN 108530983 A CN108530983 A CN 108530983A
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CN
China
Prior art keywords
parts
agent
ink
emulsion
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710122110.9A
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Chinese (zh)
Inventor
胡晓文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gansu Jinnuo Chemical Co Ltd
Original Assignee
Gansu Jinnuo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gansu Jinnuo Chemical Co Ltd filed Critical Gansu Jinnuo Chemical Co Ltd
Priority to CN201710122110.9A priority Critical patent/CN108530983A/en
Publication of CN108530983A publication Critical patent/CN108530983A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of ionomer ink, component includes by weight:Acrylic resin liquid, not filming emulsion, filming emulsion, waterborne wax emulsion, pigment, water, antifoaming agent, wetting agent, levelling agent, dispersant, titanate coupling agent, PH conditioning agents, zinc amine complex ion.The present invention rationally controls the content of each component, and proportioning is simple, and easy to use, one-component is easy to use, increases considerably the water resistance and other performances of ink, and water resistance improves 1000%, and resistance to ethyl alcohol improves 100%, and cost reduction 50%, rate of drying improves 30%.

Description

A kind of ionomer ink
Technical field
The present invention relates to printing technical field of ink more particularly to a kind of ionomer inks.
Background technology
With the development of economy, printing packaging industry development is swift and violent, as the indispensable material of printing packaging pattern printing, oil The demand of ink constantly increases, and the output of ink also constantly improves, and ink industry has huge development space, still Because the contained toxic solvent of ink itself and heavy metal have very bad shadow to the pollution of environment and to health It rings.So needing the developing direction that a kind of ink substitute harmless to environment and people's health is following.And ink is had Environment protection health the characteristics of by be ink substitute.
For ink due to being free of volatile organic solvent, the solvent used is water rather than organic solvent.It is nonflammable, Ink is stablized, bright in luster, does not corrode plate, easy to operate, cheap, adhesive force is good after print, greatly reduces organic wave The discharge of hair object VOC improves the environment of press operator, is conducive to worker health to alleviate atmosphere pollution.It can To completely eliminate certain poisonous and harmful substances in solvent-based ink, the harm to human body and the pollution to being packaged commodity are eliminated, Improve overall environmental quality, is required strictly especially suitable for sanitary conditions such as cigarette, wine, food, beverage, drug, toys for children Packaging Printing Product.It, can be in addition, it can not only reduce fire hazard and hidden danger caused by electrostatic and flammable solvent The toxicity of printing remained on surface is reduced, and is convenient for cleaning of graphic arts equipment.It is universally acknowledged environment-friendly type printing material, and at present The ink uniquely approved through international food drug association in all printing ink.
The current patented technology in relation to ink is more, and Related product is also more in the market, but we have tried out in the market A large amount of sample finds mainly there is Railway Project at present:At present all there is high, the good valence of use environment requirement in water-based ink Lattice are very expensive to be popularized, the drawbacks such as a bit cheaper not alkali resistant, not anti-second alcohol and water, dry slow, low in glossiness.These problems Principal element is that main material lotion and water-base resin cause in ink, and so that ink is dissolved in water just must hydrophilic carboxyl base Group, but this causes a series of defects and problem of ink again, solves the problems, such as that this main method uses certainly currently on the market The method of crosslinked emulsions and additional curing agent, self-crossing emulsion price height are higher to printing environment temperature requirement, and only temperature is high Self-crosslinking can just occur when certain value.Additional curing agent belongs to two-component materials at using very trouble inconvenient, and we What is done is exactly to solve the problems, such as this, manufactures that a kind of performance is good cheap to require low one-component to be crosslinked ink use environment Technology.
All there is use environment for ink currently on the market and require height, good price is very expensive to be popularized, cheaper Not alkali resistant, not anti-second alcohol and water, the drawbacks such as dry slow, low in glossiness.We are theoretically largely studied first, really A kind of fixed cheap, high performance formula for improving ink performance, then by a large amount of arduous again and again experiment, finally at Work(develops " ionomer ink " formula, efficiently solves the problems, such as that ink exists.
Invention content
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of ionomer ink proposed.
A kind of ionomer ink proposed by the present invention, component include by weight:
25-35 parts of acrylic resin liquid, not filming emulsion 8-12 parts, 17-23 parts of filming emulsion, 1-3 parts of waterborne wax emulsion, 12-18 parts of pigment, 14-18 parts of water, 0.3-0.8 parts of antifoaming agent, 0.1-0.5 parts of wetting agent, 0.1-0.4 parts of levelling agent, dispersant 0.5-1.5 parts, 0.5-1.5 parts of titanate coupling agent, 0.5-1.5 parts of PH conditioning agents, 1-5 parts of zinc amine complex ion.
Preferably, acrylic resin liquid, not filming emulsion, filming emulsion, waterborne wax emulsion weight ratio be 27-32:9- 11:19-21:1.5-2.5.
Preferably, pigment, water weight ratio be 14-16: 15-17.
Preferably, antifoaming agent, wetting agent, levelling agent, dispersant weight ratio be 0.4-0.6:0.2-0.4:0.2-0.3: 0.8-1.2。
Preferably, titanate coupling agent, PH conditioning agents, zinc amine complex ion weight ratio be 0.8-1.2:0.8-1.2:2-4.
Preferably, component includes by weight:
27-32 parts of acrylic resin liquid, not filming emulsion 9-11 parts, 19-21 parts of filming emulsion, waterborne wax emulsion 1.5- 2.5 parts, 14-16 parts of pigment, 15-17 parts of water, 0.4-0.6 parts of antifoaming agent, 0.2-0.4 parts of wetting agent, 0.2-0.3 parts of levelling agent, 0.8-1.2 parts of dispersant, 0.8-1.2 parts of titanate coupling agent, 0.8-1.2 parts of PH conditioning agents, 2-4 parts of zinc amine complex ion.
The present invention by adding said components, and rationally controls the content of each component, and proportioning is simple, easy to use, single group Part is easy to use, increases considerably the water resistance and other performances of ink, and water resistance improves 1000%, and resistance to ethyl alcohol improves 100%, Cost reduction 50%, rate of drying improve 30%.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of ionomer ink, component include by weight:
25 parts of acrylic resin liquid, not 8 parts of filming emulsion, 17 parts of filming emulsion, 1 part of waterborne wax emulsion, 12 parts of pigment, water 14 parts, 0.3 part of antifoaming agent, 0.1 part of wetting agent, 0.1 part of levelling agent, 0.5 part of dispersant, 0.5 part of titanate coupling agent, PH adjust 0.5 part of agent, 1 part of zinc amine complex ion.
Embodiment 2
A kind of ionomer ink, component include by weight:
28 parts of acrylic resin liquid, not 9 parts of filming emulsion, 18 parts of filming emulsion, 1.5 parts of waterborne wax emulsion, 13 parts of pigment, 15 parts of water, 0.4 part of antifoaming agent, 0.2 part of wetting agent, 0.15 part of levelling agent, 0.8 part of dispersant, 0.8 part of titanate coupling agent, PH 0.8 part of conditioning agent, 2 parts of zinc amine complex ion.
Embodiment 3
A kind of ionomer ink, component include by weight:
30 parts of acrylic resin liquid, not 10 parts of filming emulsion, 20 parts of filming emulsion, 15 parts of pigment, 16 parts of water, water-borne wax breast 2 parts of liquid, 0.5 part of antifoaming agent, 0.3 part of wetting agent, 0.2 part of levelling agent, 1 part of dispersant, 1 part of titanate coupling agent, PH conditioning agents 1 Part, 3 parts of zinc amine complex ion.
Embodiment 4
A kind of ionomer ink, component include by weight:
32 parts of acrylic resin liquid, not 11 parts of filming emulsion, 21 parts of filming emulsion, 2.5 parts of waterborne wax emulsion, pigment 15 Part, 17 parts of water, 0.6 part of antifoaming agent, 0.4 part of wetting agent, 0.3 part of levelling agent, 1.2 parts of dispersant, 1.2 parts of titanate coupling agent, 1.2 parts of PH conditioning agents, 4 parts of zinc amine complex ion.
Embodiment 5
A kind of ionomer ink, component include by weight:
35 parts of acrylic resin liquid, not 12 parts of filming emulsion, 23 parts of filming emulsion, 3 parts of waterborne wax emulsion, 18 parts of pigment, 18 parts of water, 0.8 part of antifoaming agent, 0.5 part of wetting agent, 0.4 part of levelling agent, 1.5 parts of dispersant, 1.5 parts of titanate coupling agent, PH tune Save 1.5 parts of agent, 5 parts of zinc amine complex ion.
In conclusion optimal component is:
30 parts of acrylic resin liquid, not 10 parts of filming emulsion, 20 parts of filming emulsion, 15 parts of pigment, 16 parts of water, water-borne wax breast 2 parts of liquid, 0.5 part of antifoaming agent, 0.3 part of wetting agent, 0.2 part of levelling agent, 1 part of dispersant, 1 part of titanate coupling agent, PH conditioning agents 1 Part, 3 parts of zinc amine complex ion.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of ionomer ink, which is characterized in that its component includes by weight:
25-35 parts of acrylic resin liquid, not filming emulsion 8-12 parts, 17-23 parts of filming emulsion, 1-3 parts of waterborne wax emulsion, pigment 12-18 parts, 14-18 parts of water, 0.3-0.8 parts of antifoaming agent, 0.1-0.5 parts of wetting agent, 0.1-0.4 parts of levelling agent, dispersant 0.5- 1.5 parts, 0.5-1.5 parts of titanate coupling agent, 0.5-1.5 parts of PH conditioning agents, 1-5 parts of zinc amine complex ion.
2. ionomer ink according to claim 1, which is characterized in that acrylic resin liquid, not filming emulsion, film forming Lotion, the weight ratio of waterborne wax emulsion are 27-32:9-11:19-21:1.5-2.5.
3. ionomer ink according to claim 1, which is characterized in that pigment, water weight ratio be 14-16:15- 17。
4. ionomer ink according to claim 1, which is characterized in that antifoaming agent, wetting agent, levelling agent, dispersant Weight ratio be 0.4-0.6:0.2-0.4:0.2-0.3:0.8-1.2.
5. ionomer ink according to claim 1, which is characterized in that titanate coupling agent, PH conditioning agents, zinc amine network The weight ratio of ion is 0.8-1.2: 0.8-1.2: 2-4.
6. according to claim 1-5 any one of them ionomer inks, which is characterized in that its component includes by weight:
27-32 parts of acrylic resin liquid, not filming emulsion 9-11 parts, 19-21 parts of filming emulsion, 1.5-2.5 parts of waterborne wax emulsion, 14-16 parts of pigment, 15-17 parts of water, 0.4-0.6 parts of antifoaming agent, 0.2-0.4 parts of wetting agent, 0.2-0.3 parts of levelling agent, dispersant 0.8-1.2 parts, 0.8-1.2 parts of titanate coupling agent, 0.8-1.2 parts of PH conditioning agents, 2-4 parts of zinc amine complex ion.
CN201710122110.9A 2017-03-03 2017-03-03 A kind of ionomer ink Pending CN108530983A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710122110.9A CN108530983A (en) 2017-03-03 2017-03-03 A kind of ionomer ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710122110.9A CN108530983A (en) 2017-03-03 2017-03-03 A kind of ionomer ink

Publications (1)

Publication Number Publication Date
CN108530983A true CN108530983A (en) 2018-09-14

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110481183A (en) * 2019-08-22 2019-11-22 冯明远 The technique that second-hand transfer printing paper produces fruit paper bag using ink printing technology

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183441A (en) * 1997-12-17 1998-06-03 朱麟勇 Hard surface glazing protectant
CN101665638A (en) * 2009-08-12 2010-03-10 江阴市兰天彩印包装有限公司 Aquosity optical variable ink and preparing method thereof
CN101760077A (en) * 2009-12-30 2010-06-30 东莞市英科水墨有限公司 Aqueous diphenyl-ethylene paper cup flexographic printing ink and preparation method thereof
CN104672982A (en) * 2015-03-15 2015-06-03 随州市三庆水性印刷材料有限公司 Preparation method of environmentally-friendly water-based ink
CN105062208A (en) * 2015-08-04 2015-11-18 山东布瑞特油墨有限公司 Flexographic plate water-based ink for high-speed printing and preparation method thereof
CN105086617A (en) * 2015-08-04 2015-11-25 山东布瑞特油墨有限公司 Water-based inner printing ink coated with PE and PP and preparation method thereof
US20160319141A1 (en) * 2013-12-27 2016-11-03 Dnp Fine Chemicals Co., Ltd. Inkjet recording ink composition, inkjet recording method, and method for producing printed material

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183441A (en) * 1997-12-17 1998-06-03 朱麟勇 Hard surface glazing protectant
CN101665638A (en) * 2009-08-12 2010-03-10 江阴市兰天彩印包装有限公司 Aquosity optical variable ink and preparing method thereof
CN101760077A (en) * 2009-12-30 2010-06-30 东莞市英科水墨有限公司 Aqueous diphenyl-ethylene paper cup flexographic printing ink and preparation method thereof
US20160319141A1 (en) * 2013-12-27 2016-11-03 Dnp Fine Chemicals Co., Ltd. Inkjet recording ink composition, inkjet recording method, and method for producing printed material
CN104672982A (en) * 2015-03-15 2015-06-03 随州市三庆水性印刷材料有限公司 Preparation method of environmentally-friendly water-based ink
CN105062208A (en) * 2015-08-04 2015-11-18 山东布瑞特油墨有限公司 Flexographic plate water-based ink for high-speed printing and preparation method thereof
CN105086617A (en) * 2015-08-04 2015-11-25 山东布瑞特油墨有限公司 Water-based inner printing ink coated with PE and PP and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110481183A (en) * 2019-08-22 2019-11-22 冯明远 The technique that second-hand transfer printing paper produces fruit paper bag using ink printing technology
CN110481183B (en) * 2019-08-22 2021-07-06 冯明远 Process for producing fruit bag paper by adopting ink printing process for second-hand transfer printing paper

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Application publication date: 20180914