CN108530976A - A kind of preparation method of micro-emulsion type detergent for ink - Google Patents
A kind of preparation method of micro-emulsion type detergent for ink Download PDFInfo
- Publication number
- CN108530976A CN108530976A CN201810342091.5A CN201810342091A CN108530976A CN 108530976 A CN108530976 A CN 108530976A CN 201810342091 A CN201810342091 A CN 201810342091A CN 108530976 A CN108530976 A CN 108530976A
- Authority
- CN
- China
- Prior art keywords
- parts
- micro
- ink
- preparation
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of preparation methods of micro-emulsion type detergent for ink, first by alkyl benzene sulphonate, sodium sulfate of polyethenoxy ether of fatty alcohol, N, N double hydroxyethyls laurylamide, lauryl glucosyl are added to and are mixed in the kerosene of dimethyl ether, and stirring obtains mixed liquor A；Alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, benzotriazole, sodium metasilicate, urea, rilanit special are added in sodium hydrate aqueous solution again, stirs to being completely dissolved, obtains mixed liquid B；Finally mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and the positive monobutyl ether of diethylene glycol mixed liquor, dispersion to get.The cleaning agent detergency of the present invention is up to 99% or more, and no flash-point can clean the heavy dirt of ink on printing machine surface, and using rear equipment surface without discoloration.
Description
Technical field
The invention belongs to cleaning agent technical fields, and in particular to a kind of preparation method of micro-emulsion type detergent for ink.
Background technology
The composition for printing dirt composition on parts is complex, essentially from following several respects：1, ink is micro- by pigment
Coloured colloid substance made of grain is evenly dispersed in link stuff, link stuff is mainly by vegetable oil, mineral oil, synthetic resin
And volatile solvent is formulated, also added with components such as suitable filler, drier, drying oil, drying oil is in drier
Effect is lower can rapid oxidation, polymerization and dry conjunctiva；2, the ash being deposited on during printing machinery use on parts and ink
Dirt；3, because of corrosion and vibration during printing machinery use, some rusts is caused to be scattering on printing parts and ink.
Although the component of ink is similar to greasy dirt, the drying oil in ink can by oxidation, polymerization film formation, make printing plate or
Bonding force between ink and parts on ink roller rises；The film that drying oil is formed simultaneously has certain compactness, can interfere cleaning
Liquid is permeated between internal ink or ink and parts, and printing equipment is made to be difficult to the aqueous cleaning agent cleaning of half.Print at present
The cleaning of brush parts curing ink relies primarily on the preferable organic solvent of volatility, such as gasoline, kerosene, and the use of organic solvent is not
Working environment can only be polluted, and there is also inflammable, explosive danger.Therefore, water base and resin emulsion paint ink scavenger has more extensive
Application prospect.
Invention content
The object of the present invention is to provide a kind of preparation methods of micro-emulsion type detergent for ink.
A kind of preparation method of micro-emulsion type detergent for ink, includes the following steps：
Step 1, in parts by weight, by 2-5 parts of alkyl benzene sulphonate, 1-2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, N, the bis- hydroxyl second of N-
1-2 parts of base laurylamide, 0.5-1 parts of lauryl glucosyl add to the kerosene 10-25 for being mixed with dimethyl ether
In part, stirring obtains mixed liquor A；
Step 2, in parts by weight, under stirring condition by 1-4 parts of alkyl phenol polyoxyethylene ether, 2-5 parts of fatty alcohol polyoxyethylene ether,
0.3-0.6 parts of benzotriazole, 0.2-0.5 parts of sodium metasilicate, 1-2 parts of urea, 0.3-0.6 parts of rilanit special add to sodium hydroxide
In 40-60 parts of aqueous solution, stirs to being completely dissolved, obtain mixed liquid B；
Step 3, in parts by weight, mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and
5-10 parts of the mixed liquor of the positive monobutyl ether of diethylene glycol, dispersion to get.
Preferably, the alkyl phenol polyoxyethylene ether is TX-10 or OP-10.
Preferably, the fatty alcohol polyoxyethylene ether is paregal O -10 or AEO-10.
Preferably, a concentration of 5-10wt.% of the sodium hydrate aqueous solution.
Preferably, it is stirred in a heated condition in step 2, heating temperature is 60-70 DEG C.
Preferably, dispersion condition is 800-1000rpm in step 3.
The present invention uses kerosene as primary solvent, and dimethyl ether is added, and has well to ink and polymeric membrane
Solubility property can destroy film-strength and weaken the cohesive force between ink and parts, ink is enable to be removed as grease.Fat
Fat alcohol polyethenoxy ether sodium sulfate, N, N- double hydroxyethyls laurylamide, lauryl glucosyl compounding, not only have compared with
Strong decontamination, emulsification and wetting, dispersion performance, can also enhance the antirust slow release effect of benzotriazole.And sodium metasilicate and hydrogen
The addition for changing castor oil can promote drying oil membrane part saponification in black dirt, and binding force and the ink for reducing ink dirt and parts are dirty
Compactness is conducive to the removal of black dirt.
Specific implementation mode
Embodiment 1
A kind of preparation method of micro-emulsion type detergent for ink, includes the following steps：
Step 1, in parts by weight, by 2 parts of alkyl benzene sulphonate, 1 part of sodium sulfate of polyethenoxy ether of fatty alcohol, N, N- double hydroxyethyls ten
1 part of dialkyl amide, 0.5 part of lauryl glucosyl add to and are mixed with dimethyl ether（10%, v/v）10 parts of kerosene
In, stirring obtains mixed liquor A；
Step 2, in parts by weight, by 1 part of alkyl phenol polyoxyethylene ether, 2 parts of fatty alcohol polyoxyethylene ether, benzo under stirring condition
0.3 part of triazole, 0.2 part of sodium metasilicate, 1 part of urea, 0.3 part of rilanit special add in 40 parts of sodium hydrate aqueous solution, stirring
To being completely dissolved, mixed liquid B is obtained；
Step 3, in parts by weight, mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and
5 parts of the mixed liquor of the positive monobutyl ether of diethylene glycol, dispersion to get.
Wherein, the alkyl phenol polyoxyethylene ether is TX-10.
The fatty alcohol polyoxyethylene ether is paregal O -10.
A concentration of 5wt.% of the sodium hydrate aqueous solution.
It is stirred in a heated condition in step 2, heating temperature is 60-70 DEG C.
Dispersion condition is 800rpm in step 3.
Embodiment 2
A kind of preparation method of micro-emulsion type detergent for ink, includes the following steps：
Step 1, in parts by weight, by 4 parts of alkyl benzene sulphonate, 2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, N, N- double hydroxyethyls ten
1 part of dialkyl amide, 0.5 part of lauryl glucosyl add to and are mixed with dimethyl ether（10%, v/v）10 parts of kerosene
In, stirring obtains mixed liquor A；
Step 2, in parts by weight, by 2 parts of alkyl phenol polyoxyethylene ether, 3 parts of fatty alcohol polyoxyethylene ether, benzo under stirring condition
0.5 part of triazole, 0.3 part of sodium metasilicate, 1 part of urea, 0.4 part of rilanit special add in 45 parts of sodium hydrate aqueous solution, stirring
To being completely dissolved, mixed liquid B is obtained；
Step 3, in parts by weight, mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and
7 parts of the mixed liquor of the positive monobutyl ether of diethylene glycol, dispersion to get.
Wherein, the alkyl phenol polyoxyethylene ether is TX-10.
The fatty alcohol polyoxyethylene ether is AEO-10.
A concentration of 8wt.% of the sodium hydrate aqueous solution.
It is stirred in a heated condition in step 2, heating temperature is 60-70 DEG C.
Dispersion condition is 800rpm in step 3.
Embodiment 3
A kind of preparation method of micro-emulsion type detergent for ink, includes the following steps：
Step 1, in parts by weight, by 3 parts of alkyl benzene sulphonate, 1 part of sodium sulfate of polyethenoxy ether of fatty alcohol, N, N- double hydroxyethyls ten
2 parts of dialkyl amide, 1 part of lauryl glucosyl add to and are mixed with dimethyl ether（10%, v/v）15 parts of kerosene in,
Stirring, obtains mixed liquor A；
Step 2, in parts by weight, by 3 parts of alkyl phenol polyoxyethylene ether, 3 parts of fatty alcohol polyoxyethylene ether, benzo under stirring condition
0.5 part of triazole, 0.4 part of sodium metasilicate, 2 parts of urea, 0.5 part of rilanit special add in 50 parts of sodium hydrate aqueous solution, stirring
To being completely dissolved, mixed liquid B is obtained；
Step 3, in parts by weight, mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and
8 parts of the mixed liquor of the positive monobutyl ether of diethylene glycol, dispersion to get.
Wherein, the alkyl phenol polyoxyethylene ether is OP-10.
The fatty alcohol polyoxyethylene ether is paregal O -10.
A concentration of 5wt.% of the sodium hydrate aqueous solution.
It is stirred in a heated condition in step 2, heating temperature is 60-70 DEG C.
Dispersion condition is 800rpm in step 3.
Embodiment 4
A kind of preparation method of micro-emulsion type detergent for ink, includes the following steps：
Step 1, in parts by weight, by 5 parts of alkyl benzene sulphonate, 2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, N, N- double hydroxyethyls ten
2 parts of dialkyl amide, 1 part of lauryl glucosyl add to and are mixed with dimethyl ether（10%, v/v）25 parts of kerosene in,
Stirring, obtains mixed liquor A；
Step 2, in parts by weight, by 4 parts of alkyl phenol polyoxyethylene ether, 5 parts of fatty alcohol polyoxyethylene ether, benzo under stirring condition
0.6 part of triazole, 0.5 part of sodium metasilicate, 2 parts of urea, 0.6 part of rilanit special add in 60 parts of sodium hydrate aqueous solution, stirring
To being completely dissolved, mixed liquid B is obtained；
Step 3, in parts by weight, mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and
10 parts of the mixed liquor of the positive monobutyl ether of diethylene glycol, dispersion to get.
Wherein, the alkyl phenol polyoxyethylene ether is TX-10.
The fatty alcohol polyoxyethylene ether is paregal O -10.
A concentration of 5wt.% of the sodium hydrate aqueous solution.
It is stirred in a heated condition in step 2, heating temperature is 60-70 DEG C.
Dispersion condition is 800rpm in step 3.
For the detergency of cleaning agent obtained as above up to 99% or more, no flash-point is all non-corrosive to No. 45 steel and duralumin.Using wiping
The heavy dirt of ink on printing machine surface can all be cleaned by washing and spraying, and using rear equipment surface without discoloration.
Claims (6)
1. a kind of preparation method of micro-emulsion type detergent for ink, it is characterised in that：Include the following steps：
Step 1, in parts by weight, by 2-5 parts of alkyl benzene sulphonate, 1-2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, N, the bis- hydroxyl second of N-
1-2 parts of base laurylamide, 0.5-1 parts of lauryl glucosyl add to the kerosene 10-25 for being mixed with dimethyl ether
In part, stirring obtains mixed liquor A；
Step 2, in parts by weight, under stirring condition by 1-4 parts of alkyl phenol polyoxyethylene ether, 2-5 parts of fatty alcohol polyoxyethylene ether,
0.3-0.6 parts of benzotriazole, 0.2-0.5 parts of sodium metasilicate, 1-2 parts of urea, 0.3-0.6 parts of rilanit special add to sodium hydroxide
In 40-60 parts of aqueous solution, stirs to being completely dissolved, obtain mixed liquid B；
Step 3, in parts by weight, mixed liquor A is added in mixed liquid B, emulsion is obtained after stirring, then be added n-butanol and
5-10 parts of the mixed liquor of the positive monobutyl ether of diethylene glycol, dispersion to get.
2. the preparation method of micro-emulsion type detergent for ink according to claim 1, it is characterised in that：The alkyl phenol polyoxy
Vinethene is TX-10 or OP-10.
3. the preparation method of micro-emulsion type detergent for ink according to claim 1, it is characterised in that：The fatty alcohol polyoxy
Vinethene is paregal O -10 or AEO-10.
4. the preparation method of micro-emulsion type detergent for ink according to claim 1, it is characterised in that：The sodium hydroxide water
A concentration of 5-10wt.% of solution.
5. the preparation method of micro-emulsion type detergent for ink according to claim 1, it is characterised in that：It is being heated in step 2
Under the conditions of stir, heating temperature be 60-70 DEG C.
6. the preparation method of micro-emulsion type detergent for ink according to claim 1, it is characterised in that：Disperse item in step 3
Part is 800-1000rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810342091.5A CN108530976A (en) | 2018-04-17 | 2018-04-17 | A kind of preparation method of micro-emulsion type detergent for ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810342091.5A CN108530976A (en) | 2018-04-17 | 2018-04-17 | A kind of preparation method of micro-emulsion type detergent for ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108530976A true CN108530976A (en) | 2018-09-14 |
Family
ID=63480398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810342091.5A Withdrawn CN108530976A (en) | 2018-04-17 | 2018-04-17 | A kind of preparation method of micro-emulsion type detergent for ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108530976A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
| CN103525163A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Cleaning agent of printing ink and preparation method thereof |
| CN104031461A (en) * | 2014-04-28 | 2014-09-10 | 南京信息工程大学 | Water-based printing ink cleaning compound and preparation method thereof |
| CN106675159A (en) * | 2015-11-11 | 2017-05-17 | 重庆宜福包装制品厂 | Cleaning solution for packing machine |
| CN107858037A (en) * | 2017-11-02 | 2018-03-30 | 中国标准化研究院 | A kind of O/W micro-emulsion types printing-ink environment-friendly cleaning agent |
-
2018
- 2018-04-17 CN CN201810342091.5A patent/CN108530976A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102952425A (en) * | 2012-11-19 | 2013-03-06 | 南京信息工程大学 | Water-based printing ink cleaning agent and preparation method thereof |
| CN103525163A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Cleaning agent of printing ink and preparation method thereof |
| CN104031461A (en) * | 2014-04-28 | 2014-09-10 | 南京信息工程大学 | Water-based printing ink cleaning compound and preparation method thereof |
| CN106675159A (en) * | 2015-11-11 | 2017-05-17 | 重庆宜福包装制品厂 | Cleaning solution for packing machine |
| CN107858037A (en) * | 2017-11-02 | 2018-03-30 | 中国标准化研究院 | A kind of O/W micro-emulsion types printing-ink environment-friendly cleaning agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6984269B2 (en) | Cleaning surfaces | |
| CN101538512B (en) | Water-based cleaner | |
| CN101824243A (en) | Micro-emulsion ink cleaning agent and preparation method thereof | |
| US20120309661A1 (en) | Low-voc solvent systems | |
| CN101760072B (en) | Water-base ink cleaning agent | |
| CN101323723B (en) | Environment-friendly type aqueous paint remover for removing polysiloxane paint | |
| CN105331179B (en) | Environment-friendly type water based cleaning agent and application | |
| CN106634163A (en) | Water-based cleaning agent, preparation method thereof and PCB ink cleaning method | |
| US4140647A (en) | Detergent composition | |
| CN106479258A (en) | A kind of preparation method of environment-friendlyink ink abluent | |
| CN102888140B (en) | Environment-friendly printing ink cleaning agent and preparation process of environment-friendly printing ink cleaning agent | |
| CN104313614A (en) | Low-foam detergent and preparation method thereof | |
| CN107326377A (en) | A kind of aqueous rustproof degreasing paraffin removal cleaning agent and its preparation method and application | |
| CN107338446A (en) | A kind of water base non-phosphor degreaser antirust wax removing agent and its preparation method and application | |
| CN108530976A (en) | A kind of preparation method of micro-emulsion type detergent for ink | |
| CN109183052A (en) | A kind of degreasing powder and preparation method thereof | |
| CN108892996A (en) | A kind of preparation method of environment-friendly type printing ink washing agent | |
| EP1287099B1 (en) | Cleaning surfaces | |
| CN106634161A (en) | Formula of UV-cured printing ink cleaning agent | |
| CN104451710A (en) | Water-based detergent for aluminum surface | |
| WO2000029527A2 (en) | Environmentally safe detergent composition and method of use | |
| CN105838516B (en) | Environmental protection exempts to wipe efficient car washing liquid and preparation method | |
| CN1923918A (en) | Detergent for water-based print ink | |
| CN108034952A (en) | Painting dressing automobiles table tune pre-treatment high temperature degreasing agent and its degreasing method | |
| US9657254B1 (en) | Paint, ink and resin remover composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180914 |