CN108522540A - Copper humate-containing antibacterial yield-increasing composition and preparation method thereof - Google Patents
Copper humate-containing antibacterial yield-increasing composition and preparation method thereof Download PDFInfo
- Publication number
- CN108522540A CN108522540A CN201810226440.7A CN201810226440A CN108522540A CN 108522540 A CN108522540 A CN 108522540A CN 201810226440 A CN201810226440 A CN 201810226440A CN 108522540 A CN108522540 A CN 108522540A
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- Prior art keywords
- parts
- antibacterial
- uniformly mixed
- copper
- humic acid
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- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 159
- 239000010949 copper Substances 0.000 title claims abstract description 95
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 94
- 239000000203 mixture Substances 0.000 title claims abstract description 88
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000000945 filler Substances 0.000 claims abstract description 61
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 52
- 239000000463 material Substances 0.000 claims abstract description 49
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 48
- 239000004626 polylactic acid Substances 0.000 claims abstract description 48
- 229920001661 Chitosan Polymers 0.000 claims abstract description 45
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000002994 raw material Substances 0.000 claims abstract description 26
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 claims abstract description 19
- 229960000458 allantoin Drugs 0.000 claims abstract description 19
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 16
- 229940116318 copper carbonate Drugs 0.000 claims abstract description 14
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims abstract description 14
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 89
- 239000004021 humic acid Substances 0.000 claims description 89
- 238000003756 stirring Methods 0.000 claims description 52
- 238000013270 controlled release Methods 0.000 claims description 50
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 45
- 229910000077 silane Inorganic materials 0.000 claims description 45
- 238000004519 manufacturing process Methods 0.000 claims description 40
- 239000011347 resin Substances 0.000 claims description 40
- 229920005989 resin Polymers 0.000 claims description 40
- 238000010792 warming Methods 0.000 claims description 36
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 30
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 28
- 239000004927 clay Substances 0.000 claims description 26
- 229960000892 attapulgite Drugs 0.000 claims description 24
- 229910052625 palygorskite Inorganic materials 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 19
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 229920001542 oligosaccharide Polymers 0.000 claims description 15
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims description 13
- 239000004615 ingredient Substances 0.000 claims description 13
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 12
- 238000006297 dehydration reaction Methods 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 11
- 241000192710 Microcystis aeruginosa Species 0.000 claims description 11
- 238000013268 sustained release Methods 0.000 claims description 11
- 239000012730 sustained-release form Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 10
- 239000012948 isocyanate Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 229940083466 soybean lecithin Drugs 0.000 claims description 10
- 241000894006 Bacteria Species 0.000 claims description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 8
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 230000001007 puffing effect Effects 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 8
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 claims description 7
- 238000007873 sieving Methods 0.000 claims description 7
- 229910052709 silver Inorganic materials 0.000 claims description 7
- 239000004332 silver Substances 0.000 claims description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 7
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 claims description 3
- 229940113088 dimethylacetamide Drugs 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 230000004048 modification Effects 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 5
- -1 amino-oligosaccharin Chemical compound 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- DARPYRSDRJYGIF-PTNGSMBKSA-N (Z)-3-ethoxy-2-naphthalen-2-ylsulfonylprop-2-enenitrile Chemical compound C1=CC=CC2=CC(S(=O)(=O)C(\C#N)=C/OCC)=CC=C21 DARPYRSDRJYGIF-PTNGSMBKSA-N 0.000 abstract 1
- PWVXXGRKLHYWKM-UHFFFAOYSA-N 5-[2-(benzenesulfonyl)ethyl]-3-[(1-methylpyrrolidin-2-yl)methyl]-1h-indole Chemical compound CN1CCCC1CC(C1=C2)=CNC1=CC=C2CCS(=O)(=O)C1=CC=CC=C1 PWVXXGRKLHYWKM-UHFFFAOYSA-N 0.000 abstract 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 abstract 1
- 239000005750 Copper hydroxide Substances 0.000 abstract 1
- 229910001956 copper hydroxide Inorganic materials 0.000 abstract 1
- RVKCCVTVZORVGD-UHFFFAOYSA-N trinexapac-ethyl Chemical group O=C1CC(C(=O)OCC)CC(=O)C1=C(O)C1CC1 RVKCCVTVZORVGD-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 28
- 230000000052 comparative effect Effects 0.000 description 22
- 230000003115 biocidal effect Effects 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- 230000000845 anti-microbial effect Effects 0.000 description 12
- 230000002787 reinforcement Effects 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 235000011121 sodium hydroxide Nutrition 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 238000001704 evaporation Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 235000012216 bentonite Nutrition 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 4
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 4
- 244000061458 Solanum melongena Species 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000004321 preservation Methods 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 230000000241 respiratory effect Effects 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 235000002597 Solanum melongena Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000012644 addition polymerization Methods 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 2
- 244000000000 soil microbiome Species 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000009870 specific binding Effects 0.000 description 2
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229910021512 zirconium (IV) hydroxide Inorganic materials 0.000 description 2
- AOJJSUZBOXZQNB-VTZDEGQISA-N 4'-epidoxorubicin Chemical group O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-VTZDEGQISA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 210000001643 allantois Anatomy 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- UTZZWINLZZXVCG-UHFFFAOYSA-N chembl251974 Chemical group C1=C(Cl)C(O)=CC(O)=C1C1=NNC=C1N1CCN(CC=2C=CC=CC=2)CC1 UTZZWINLZZXVCG-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- YDCPQRQGABOSRY-UHFFFAOYSA-N iron;urea Chemical compound [Fe].NC(N)=O YDCPQRQGABOSRY-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses an antibacterial yield-increasing composition containing copper humate and a preparation method thereof, and belongs to the technical field of preparation of antibacterial compositions. The copper humate-containing antibacterial yield-increasing composition comprises the following raw materials: allantoin, amino-oligosaccharin, copper humate, chlormequat chloride, trinexapac-ethyl, mepiquat chloride, copper hydroxide, basic copper carbonate, polylactic acid, chitosan, a silane coupling agent KH-550, an antibacterial modification auxiliary agent and a slow-release filler; the copper humate-containing antibacterial yield-increasing composition is prepared by the steps of preparing a main material, preparing a modified material, mixing and granulating the main material and the modified material and the like. The yield-increasing composition prepared by the invention contains copper humate, and has excellent antibacterial and yield-increasing performances.
Description
Technical field
The invention belongs to bactericidal composition preparing technical fields, and in particular to a kind of antibacterial of copper containing humic acid volume increase composition
And preparation method thereof.
Background technology
Humic acid copper (HA-Cu) belongs to the chelate of humic acid, and humic acid is that a kind of polynary organic acid mixes,
They can react to form chelate with metal ion, these chelates chemical property in alkaline solution is relatively stablized, it is not only
There is stronger sterilizing ability, and without poisoning.Humic acid chelate further includes：Humic acid magnesium, zinc humic acid, humic acid urea
Iron, sodium humate etc. can be compounded with super quick albumen.
A kind of Chinese patent application document " antibacterial volume increase composition (application publication number containing allantoin：
CN106305748 a kind of antibacterial volume increase composition containing allantoin) " is disclosed, effective active composition is active components A and activity
The antibacterial of ingredient B increases production composition, and active components A is allantoin, and active constituent B is selected from any one following compound：Amino
Oligosaccharide, humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine, the composition have higher work to the multiple diseases in various crop
Property, and there is apparent synergistic effect, fungicidal spectrum is expanded, while increasing effective absorption of the crop to fertilizer, supplemental crop is bad
Gesture part is well grown, and adjusts the balance of crop internal water, to activate the metabolic system of crop, crop cell is promoted to increase
The characteristics of length, root activity increases.But its antibiotic property is poor, drug effect release efficiency is low, cannot be satisfied crop it is practical plant want
It asks.
Invention content
The object of the present invention is to provide a kind of antibacterials of copper containing humic acid to increase production composition and preparation method thereof, to solve special
A kind of sharp application documents " antibacterial volume increase composition (application publication number containing allantoin：CN106305748 antibacterial disclosed in) " increases
On the basis of producing composition, how to optimize component, dosage, method etc., improves antibiotic property and the volume increase of antibacterial volume increase composition
The problem of effect.
In order to solve the above technical problems, the present invention uses following technical scheme：
A kind of antibacterial of copper containing humic acid volume increase composition, including following raw material：Allantoin, amino-oligosaccharide, humic acid copper,
Cycocel, TrinexAN_SNacethyl, first piperazine, Kocide SD, basic copper carbonate, polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial
Modified additive, Controlled-release filler；
The antibacterial modified auxiliary agent, as unit of parts by weight, including following raw material：4-8 parts of attapulgite clay, mass fraction
4-9 parts of lanthanum chloride solution that 5-15 parts of sodium chloride solution, mass fraction for 5-15% are 15-35%, mass fraction 4-8%
3-6 parts of silver nitrate solution, 2-5 parts of diatomite, 1-5 parts of DMAC N,N' dimethyl acetamide, 4-8 parts of ethyl acrylate, silane coupled
KH-5703-9 parts of agent；
The Controlled-release filler, as unit of parts by weight, including following raw material：4-8 parts of sodium hydroxide, 3-9 parts of polyethylene glycol,
5-15 parts of water, 4-8 parts of zeolite, 3-6 parts of activated carbon, 2-5 parts of Microcystis aeruginosa, 1-5 parts of bentonite, 4-8 parts of soybean lecithin, toluene two
3-6 parts of isocyanates, 2-5 parts of butyl titanate, KH-5605-15 parts of silane coupling agent；
The polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler weight ratio be (6-
9)：(4-8)：(1-3)：(15-25)：(16-36).
Further, the polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent weight ratio be
7.5：5.6：2.4：19.8：26.4.
Further, the antibacterial of copper containing humic acid increases production composition as unit of parts by weight, including following raw material：Allantois
80-120 parts plain, 20-30 parts of amino-oligosaccharide, 10-35 parts of humic acid copper, 10-30 parts of cycocel, 10-30 parts of TrinexAN_SNacethyl, first piperazine
10-30 parts, 8-16 parts of Kocide SD, 5-15 parts of basic copper carbonate, 6-9 parts of polylactic acid, 4-8 parts of chitosan, silane coupling agent
KH-5501-3 parts, auxiliary agent 15-25 parts antibacterial modified, 16-36 parts of Controlled-release filler.
Further, the antibacterial modified auxiliary agent is prepared by following technique：It is by attapulgite clay and mass fraction
The sodium chloride solution of 5-15% is uniformly mixed, and stirs 1-3h, filtering means dehydration, then drying roasts 0.5- in 450-550 DEG C
1.5h is subsequently placed in the lanthanum chloride solution that mass fraction is 15-35%, stirs 1-3h, filtering means dehydration, and drying is subsequently placed in
180-220 DEG C of roasting 0.5-1.5h, is subsequently placed in the silver nitrate solution that mass fraction is 4-8%, stirs 2-4h, after drying
To material A；Diatomite and n,N-dimethylacetamide are uniformly mixed, 20-40min is stirred in 650-850r/min rotating speeds, connects
It and is warming up to 75-85 DEG C, keep the temperature 1-3h, be then passed through nitrogen, material A is added and ethyl acrylate is uniformly mixed, in 450-
550r/min rotating speeds stir 10-14h, and Silane coupling reagent KH-570 is then added and is uniformly mixed, is warming up to 90-110 DEG C, keeps the temperature 5-
15min stirs 10-20min in 1500-2500r/min rotating speeds, is cooled to room temperature to obtain antibacterial modified auxiliary agent.
Further, the Controlled-release filler is prepared by following technique：Sodium hydroxide, polyethylene glycol and water are mixed equal
It is even, 65-75 DEG C is then heated to, zeolite, activated carbon, Microcystis aeruginosa and bentonite is subsequently added into and is uniformly mixed, stir 15-35min,
75-85 DEG C is then heated to, 1-3h is kept the temperature, soybean lecithin is subsequently added into and is uniformly mixed, be warming up to 85-95 DEG C, keep the temperature 20-
40min is then down to room temperature, washing, filters, evaporation, dry, cold that solidification is gone to obtain material a；By material a and toluene diisocyanate
Acid esters is uniformly mixed, and is stirred 20-40min in 850-950r/min rotating speeds, is subsequently added into butyl titanate and silane coupling agent KH-
560 are uniformly mixed, and stir 20-30min in 450-650r/min rotating speeds, are then placed in bulking machine, in 200-240 DEG C, 0.6-
0.7MPa, puffing, crushing, sieving, collects 250-350 mesh fine powders, is cooled to room temperature to obtain Controlled-release filler.
The present invention also provides the preparation methods that a kind of antibacterial of copper containing humic acid increases production composition, include the following steps：
S1：Allantoin and amino-oligosaccharide are uniformly mixed, and are warming up to 40-50 DEG C, 10-20min are kept the temperature, then in 450-
650r/min rotating speeds stir 15-25min, and cycocel, TrinexAN_SNacethyl and first piperazine is then added and is uniformly mixed, in 850-1050r/
Min rotating speeds stir 15-25min, are subsequently added into humic acid copper, Kocide SD and basic copper carbonate and are uniformly mixed, in 1500-
2500r/min rotating speeds stir 20-40min, are then cooled to room temperature and obtain major ingredient；
S2：Polylactic acid is warming up to 70-80 DEG C, keeps the temperature 20-30min, it is gentle to be subsequently added into chitosan, antibacterial modified auxiliary agent
It releases filler to be uniformly mixed, is continuously heating to 90-110 DEG C, keep the temperature 15-25min, 20- is stirred in 850-1050r/min rotating speeds
40min is then cooled to 60-70 DEG C, and silane resin acceptor kh-550 is added and is uniformly mixed, is stirred in 1200-1400r/min rotating speeds
1-2h is cooled to room temperature to obtain modified materials；
S3：Major ingredient is warming up to 80-90 DEG C, keeps the temperature 20-50min, modified materials is subsequently added into and is uniformly mixed, in 650-
850r/min rotating speeds stir 1-2h, and after comminutor is granulated, dry postcooling to room temperature obtains the antibacterial volume increase group of copper containing humic acid
Close object.
The invention has the advantages that：
(1) by the data of embodiment 1-3 and comparative example 7 as it can be seen that the antibacterial of copper containing humic acid volume increase group made from embodiment 1-3
It closes the antibiotic property of object and obvious effect of increasing production is higher than antibiotic property and effect of increasing production that antibacterial made from comparative example 7 increases production composition；
Simultaneously by the data of embodiment 1-3 as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-6 as it can be seen that polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial
Modified additive, Controlled-release filler play synergistic effect in preparing the antibacterial of copper containing humic acid volume increase composition, and collaboration, which improves, to be contained
Humic acid copper antibacterial increases production the antibiotic property and effect of increasing production of composition；This is：
Polylactic acid has degradability and adsorptivity, and a large amount of hydroxyl is contained on surface, can be chitosan, antibacterial modified help
Agent and the attachment of Controlled-release filler improve abundant attachment point so that polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial
Modified additive and Controlled-release filler can become an entirety and apply to the antibacterial of copper containing humic acid volume increase of the invention as reinforcement system
In the preparation of composition, at the same the grafting of silane resin acceptor kh-550 effect under, realize chitosan, antibacterial modified auxiliary agent and
The combination of Controlled-release filler and polylactic acid, is utilized the antibiotic property of chitosan and porous adsorptivity, and chitosan is easy in weakly acidic solvent
In dissolving, it is worth pointing out that containing amino (NH in dissolved solution2+), these amino are by combining negative electron, profit
Inhibit bacterial respiratory that bacterium is lost activity the inhibiting effect of bacterium surface respiratory enzyme with anion antibacterial to realize
Effect applies in the preparation that the antibacterial of copper containing humic acid of the invention increases production composition as reinforcement system, effectively increases antibacterial
Property, moreover it is possible to the combination of realization and polylactic acid under the grafting effect of silane resin acceptor kh-550, in the effect for improving antibiotic property effect
Under the premise of fruit, the efficiency and quality for improving antibiotic property drug release are further improved so that copper containing humic acid of the invention is anti-
Bacterium volume increase composition applies in practical plantation, the bactericidal property to soil can be effectively improved, wherein that adds is antibacterial modified
Auxiliary agent passes through modified modified attapulgite clay surface with the presence of a large amount of ball object using attapulgite clay as raw material, and
Attapulgite clay surface apertures are reduced compared with modified attapulgite clay, this may be due to being adsorbed on attapulgite clay particle surface
AgNO3It does not elute completely, the Ag being decomposed to form during the drying process2O reunites on its surface, causes attapulgite clay part small
Hole is blocked, therefore being removed in silver type antibacterial attapulgite clay has a certain number of silver to be present in antibacterial sorbing material in the form of an ion
Cation exchange site set and duct outside, also part Ag2O is present in the surface of material, to ensure that silver is harmful with soil
Bacterium has enough contacts area.In modified recombination process, most of sodium ion and silver ion enter concave convex rod by ion exchange
Inside clay, attapulgite clay denitrogenation is the cation such as sodium ion in attapulgite clay structure and NH4+Ion occurs to hand over
It changes, dephosphorization is the Electrostatic Absorption of the hydrous zirconia gel by attapulgite clay surface, and antibacterial is the loading because of Ag ions, silver ion
The specific binding of the mercapto (- SH) with negative electrical charge in protease will be attracted, effectively pierce through cell wall and cell membrane
Appearance further makes bacterial cell because of protein denaturation, and can not breathe, is metabolized and breed, until it is dead, reach the effect of sterilizing
Fruit realizes that a large amount of hydroxyl in its surface is combined with polylactic acid, applies to this hair under the grafting effect of silane resin acceptor kh-550
In prepared by the bright antibacterial of copper containing humic acid volume increase composition, its excellent anti-microbial property is imparted, wherein the Controlled-release filler added
By the way that sodium hydroxide, polyethylene glycol and water to be uniformly mixed, then heats up, be subsequently added into zeolite, activated carbon, Microcystis aeruginosa and swelling
Soil is uniformly mixed, and then stirring heats up, keep the temperature, and is subsequently added into soybean lecithin and is uniformly mixed, heats up, and room is then down in heat preservation
Temperature, washing filter, evaporation, dry, cold that solidification is gone to obtain material a；Material a and toluene di-isocyanate(TDI) are uniformly mixed, stirred
It mixes, is subsequently added into butyl titanate and silane coupling agent KH-560 is uniformly mixed, stirring is then placed in bulking machine, puffing, powder
Broken, sieving, collects fine powder, is cooled to room temperature to obtain, zeolite, activated carbon, Microcystis aeruginosa and bentonitic porous sustained-release is utilized
Filler, in soybean lecithin, the modification of fat polyethylene glycol, toluene di-isocyanate(TDI), butyl titanate and silane coupling agent KH-560
Under effect, the hydroxyl on porous sustained-release filler surface is utilized, realizes and the combination of polylactic acid, apply to the present invention containing corruption
It grows in sour copper antibacterial volume increase composition preparation, imparts its excellent sustained release performance so that the antibacterial of copper containing humic acid of the invention
Increase production composition in actually planting, drug release can be made more efficient, effectively purified soil environment, improve crop
Yield.
(3) by the data of comparative example 6-8 as it can be seen that polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent,
The weight ratio of Controlled-release filler is not at (6-9)：(4-8)：(1-3)：(15-25)：When in (16-36) range, antibacterial volume increase obtained
The antibiotic property of composition and the numerical value of effect of increasing production and the numerical value of embodiment 1-3 are very different, and are much smaller than the number of embodiment 1-3
Value is suitable with the numerical value of the prior art (comparative example 7).Polylactic acid of the present invention, chitosan, silane resin acceptor kh-550, antibacterial change
Property auxiliary agent, Controlled-release filler as reinforcement system, embodiment 1-3 controls are prepared when the antibacterial of copper containing humic acid increases production composition by adding
Addition polymerization lactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler weight ratio be (6-9)：(4-8)：
(1-3)：(15-25)：(16-36) is realized in reinforcement system using antibacterial modified auxiliary agent and Controlled-release filler as primary raw material, is utilized
The hydroxyl on the surface of polylactic acid realizes that antibacterial modified auxiliary agent is attached to poly- breast under the grafting effect of silane resin acceptor kh-550
The surface of acid realizes the reinforcement modification for increasing production composition anti-microbial property to the present invention antibacterial of copper containing humic acid, effectively increases
The present invention antibacterial of copper containing humic acid increases production the anti-microbial property of composition, in addition coordinates with the chitosan with excellent antibacterial performance,
It is attached to the surface of polylactic acid simultaneously, further improves and composition anti-microbial property is increased production to the present invention antibacterial of copper containing humic acid
Reinforcement is modified, and is effectively increased the anti-microbial property of the antibacterial of copper containing humic acid volume increase composition of the invention, is recycled Controlled-release filler
Superior sustained-release performance realizes polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler and applies to
The present invention antibacterial of copper containing humic acid is increased production in the preparation of composition, and it is excellent to impart the antibacterial of copper containing humic acid volume increase composition of the invention
Different anti-microbial property and sustained release performance so that the antibacterial of copper containing humic acid volume increase composition of the invention, can in actually planting
Keep drug release more efficient, effectively purified soil environment, improves the yield of crop.
Specific implementation mode
For ease of more fully understanding the present invention, it is illustrated by the following examples, these examples belong to the protection of the present invention
Range, but do not limit the scope of the invention.
In embodiment, the antibacterial of copper containing humic acid increases production composition, as unit of parts by weight, including following raw material：
80-120 parts of allantoin, 20-30 parts of amino-oligosaccharide, 10-35 parts of humic acid copper, 10-30 parts of cycocel, 10-30 parts of TrinexAN_SNacethyl,
10-30 parts of first piperazine, 8-16 parts of Kocide SD, 5-15 parts of basic copper carbonate, 6-9 parts of polylactic acid, 4-8 parts of chitosan, silane are even
Join KH-5501-3 parts of agent, auxiliary agent 15-25 parts antibacterial modified, 16-36 parts of Controlled-release filler.
The antibacterial modified auxiliary agent is prepared by following technique：By weight by 4-8 parts of attapulgite clays and 5-15 parts
The sodium chloride solution that mass fraction is 5-15% is uniformly mixed, and stirs 1-3h, filtering means dehydration, drying, then in 450-550 DEG C of roasting
0.5-1.5h is burnt, is subsequently placed in the lanthanum chloride solution that 4-9 parts of mass fractions are 15-35%, 1-3h is stirred, filtering means dehydration dries
It is dry, it is subsequently placed in 180-220 DEG C of roasting 0.5-1.5h, is subsequently placed in the silver nitrate solution that 3-6 parts of mass fractions are 4-8%,
2-4h is stirred, material A is obtained after drying；2-5 parts of diatomite and 1-5 parts of n,N-dimethylacetamide are uniformly mixed, in 650-
850r/min rotating speeds stir 20-40min, are then warming up to 75-85 DEG C, keep the temperature 1-3h, are then passed through nitrogen, be added material A and
4-8 parts of ethyl acrylates are uniformly mixed, and stir 10-14h in 450-550r/min rotating speeds, 3-9 parts of silane coupling agents are then added
KH-570 is uniformly mixed, and is warming up to 90-110 DEG C, keeps the temperature 5-15min, and 10-20min is stirred in 1500-2500r/min rotating speeds, cold
But antibacterial modified auxiliary agent is obtained to room temperature.
The Controlled-release filler is prepared by following technique：By weight by 4-8 parts of sodium hydroxides, 3-9 parts of polyethylene glycol
It is uniformly mixed with 5-15 parts of water, then heats to 65-75 DEG C, be subsequently added into 4-8 parts of zeolites, 3-6 parts of activated carbons, 2-5 parts of micro-capsules
Algae and 1-5 parts of bentonites are uniformly mixed, and are stirred 15-35min, are then heated to 75-85 DEG C, keep the temperature 1-3h, be subsequently added into 4-8 parts
Soybean lecithin is uniformly mixed, and is warming up to 85-95 DEG C, is kept the temperature 20-40min, is then down to room temperature, is washed, and is filtered, evaporation, is done
It is dry, it is cold that solidification is gone to obtain material a；A and 3-6 parts of toluene di-isocyanate(TDI)s of material are uniformly mixed, in 850-950r/min rotating speeds
20-40min is stirred, 2-5 parts of butyl titanates is subsequently added into and 5-15 parts of silane coupling agent KH-560 is uniformly mixed, in 450-
650r/min rotating speeds stir 20-30min, are then placed in bulking machine, in 200-240 DEG C, 0.6-0.7MPa, puffing, crushing, mistake
Sieve collects 250-350 mesh fine powders, is cooled to room temperature to obtain Controlled-release filler.
The preparation method of the antibacterial of copper containing the humic acid volume increase composition, includes the following steps：
S1：Allantoin and amino-oligosaccharide are uniformly mixed, and are warming up to 40-50 DEG C, 10-20min are kept the temperature, then in 450-
650r/min rotating speeds stir 15-25min, and cycocel, TrinexAN_SNacethyl and first piperazine is then added and is uniformly mixed, in 850-1050r/
Min rotating speeds stir 15-25min, are subsequently added into humic acid copper, Kocide SD and basic copper carbonate and are uniformly mixed, in 1500-
2500r/min rotating speeds stir 20-40min, are then cooled to room temperature and obtain major ingredient；
S2：Polylactic acid is warming up to 70-80 DEG C, keeps the temperature 20-30min, it is gentle to be subsequently added into chitosan, antibacterial modified auxiliary agent
It releases filler to be uniformly mixed, is continuously heating to 90-110 DEG C, keep the temperature 15-25min, 20- is stirred in 850-1050r/min rotating speeds
40min is then cooled to 60-70 DEG C, and silane resin acceptor kh-550 is added and is uniformly mixed, is stirred in 1200-1400r/min rotating speeds
1-2h is cooled to room temperature to obtain modified materials；
S3：Major ingredient is warming up to 80-90 DEG C, keeps the temperature 20-50min, modified materials is subsequently added into and is uniformly mixed, in 650-
850r/min rotating speeds stir 1-2h, and after comminutor is granulated, dry postcooling to room temperature obtains the antibacterial volume increase group of copper containing humic acid
Close object.
Embodiment 1
A kind of antibacterial of copper containing humic acid volume increase composition, as unit of parts by weight, including following raw material：113 parts of allantoin,
25.6 parts of amino-oligosaccharide, 18.9 parts of humic acid copper, 21.3 parts of cycocel, 22.5 parts of TrinexAN_SNacethyl, 23.6 parts of first piperazine, hydroxide
10.8 parts of copper, 8 parts of polylactic acid comparative example, 5.6 parts of chitosan, 2.4 parts of silane resin acceptor kh-550, resists 8.9 parts of basic copper carbonate
19.8 parts of bacterium modified additive, 26.4 parts of Controlled-release filler.
The antibacterial modified auxiliary agent is prepared by following technique：By weight by 6 parts of attapulgite clays and 13.5 parts of matter
It measures the sodium chloride solution that score is 8.6% to be uniformly mixed, stirs 2.4h, filtering means dehydration, then drying roasts 1.2h in 435 DEG C,
It is subsequently placed in the lanthanum chloride solution that 7.5 parts of mass fractions are 18.6%, stirs 2.2h, filtering means dehydration, drying is subsequently placed in
213 DEG C of roasting 1.3h, are subsequently placed in the silver nitrate solution that 5.2 parts of mass fractions are 6.3%, stir 3.5h, obtained after drying
Material A；3.4 parts of diatomite and 2.5 parts of n,N-dimethylacetamide are uniformly mixed, 32min is stirred in 786r/min rotating speeds, connects
It and is warming up to 81 DEG C, keep the temperature 2.3h, be then passed through nitrogen, material A is added and 5.7 parts of ethyl acrylates are uniformly mixed, in 486r/
Min rotating speeds stir 11.5h, and 8.4 parts of Silane coupling reagent KH-570s are then added and are uniformly mixed, and are warming up to 103 DEG C, heat preservation
9.6min stirs 14.6min in 2365r/min rotating speeds, is cooled to room temperature to obtain antibacterial modified auxiliary agent.
The Controlled-release filler is prepared by following technique：By weight by 7.4 parts of sodium hydroxides, 5.6 parts of polyethylene glycol
It is uniformly mixed with 12.3 parts of water, then heats to 72.6 DEG C, be subsequently added into 5.7 parts of zeolites, 4.6 parts of activated carbons, 3.2 parts of Microcystis aeruginosas
It is uniformly mixed with 2.7 parts of bentonites, stirs 28.6min, then heat to 79.6 DEG C, kept the temperature 2.2h, be subsequently added into 7.4 portions of soybean
Lecithin is uniformly mixed, and is warming up to 86.3 DEG C, is kept the temperature 32.4min, is then down to room temperature, is washed, and is filtered, evaporation, dry, cold to go
Solidification obtains material a；Material a and 5.2 parts of toluene di-isocyanate(TDI)s are uniformly mixed, 27min is stirred in 936r/min rotating speeds, connects
It 4.2 parts of butyl titanates of addition and 12.3 parts of silane coupling agent KH-560 is uniformly mixed, stirred in 569r/min rotating speeds
23.6min is then placed in bulking machine, and in 228 DEG C, 0.63MPa, puffing, crushing, sieving are collected 296 mesh fine powders, be cooled to
Room temperature obtains Controlled-release filler.
The preparation method of the antibacterial of copper containing the humic acid volume increase composition, includes the following steps：
S1：Allantoin and amino-oligosaccharide are uniformly mixed, and are warming up to 43 DEG C, 14min are kept the temperature, then in 575r/min rotating speeds
13.6min is stirred, cycocel, TrinexAN_SNacethyl and first piperazine is then added and is uniformly mixed, 19.6min is stirred in 948r/min rotating speeds,
It is subsequently added into humic acid copper, Kocide SD and basic copper carbonate to be uniformly mixed, 36min is stirred in 1986r/min rotating speeds, it is then cold
But major ingredient is obtained to room temperature；
S2：Polylactic acid is warming up to 74 DEG C, 26min is kept the temperature, is subsequently added into chitosan, antibacterial modified auxiliary agent and Controlled-release filler
It is uniformly mixed, is continuously heating to 106 DEG C, keep the temperature 22min, stir 34min in 963r/min rotating speeds, be then cooled to 68 DEG C, add
Enter silane resin acceptor kh-550 to be uniformly mixed, stirs 1.3h in 1364r/min rotating speeds, be cooled to room temperature to obtain modified materials；
S3：Major ingredient is warming up to 83 DEG C, keeps the temperature 36min, modified materials is subsequently added into and is uniformly mixed, stirred in 746r/min rotating speeds
1.3h is mixed, after comminutor is granulated, dry postcooling to room temperature obtains the antibacterial of copper containing humic acid volume increase composition.
Embodiment 2
A kind of antibacterial of copper containing humic acid volume increase composition, as unit of parts by weight, including following raw material：80 parts of allantoin,
30 parts of amino-oligosaccharide, 10 parts of humic acid copper, 30 parts of cycocel, 10 parts of TrinexAN_SNacethyl, 30 parts of first piperazine, 8 parts of Kocide SD, alkali formula
15 parts of copper carbonate, 6 parts of polylactic acid, 8 parts of chitosan, 1 part of silane resin acceptor kh-550,25 parts of antibacterial modified auxiliary agent, Controlled-release filler
16 parts.
The antibacterial modified auxiliary agent is prepared by following technique：By weight by 4 parts of attapulgite clays and 15 parts of quality
The sodium chloride solution that score is 5% is uniformly mixed, and stirs 3h, filtering means dehydration, then drying roasts 1.5h in 450 DEG C, then sets
In the lanthanum chloride solution that 4 parts of mass fractions are 35%, 1h, filtering means dehydration are stirred, drying is subsequently placed in 220 DEG C of roasting 0.5h,
It is subsequently placed in the silver nitrate solution that 6 parts of mass fractions are 4%, stirs 4h, material A is obtained after drying；By 2 parts of diatomite and 5
Part n,N-dimethylacetamide is uniformly mixed, and is stirred 40min in 650r/min rotating speeds, is then warming up to 75 DEG C, keeps the temperature 3h, then
It is passed through nitrogen, material A is added and 4 parts of ethyl acrylates are uniformly mixed, stirs 10h in 550r/min rotating speeds, 9 parts of silicon is then added
Alkane coupling agent kh-570 is uniformly mixed, and is warming up to 90 DEG C, keeps the temperature 15min, is stirred 20min in 1500r/min rotating speeds, is cooled to room
Temperature obtains antibacterial modified auxiliary agent.
The Controlled-release filler is prepared by following technique：By weight by 4 parts of sodium hydroxides, 9 parts of polyethylene glycol and 5 parts
Water is uniformly mixed, and then heats to 75 DEG C, is subsequently added into 4 parts of zeolites, 6 parts of activated carbons, 2 parts of Microcystis aeruginosas and 5 parts of bentonite mixing
Uniformly, 15min is stirred, then heats to 85 DEG C, keeps the temperature 1h, 8 parts of soybean lecithins is subsequently added into and is uniformly mixed, be warming up to 85
DEG C, 40min is kept the temperature, room temperature is then down to, is washed, is filtered, evaporation, it is dry, it is cold that solidification is gone to obtain material a；By material a and 3 parts
Toluene di-isocyanate(TDI) is uniformly mixed, and is stirred 20min in 950r/min rotating speeds, is subsequently added into 5 parts of butyl titanates and 5 parts of silane
Coupling agent KH-560 is uniformly mixed, and is stirred 20min in 650r/min rotating speeds, is then placed in bulking machine, in 240 DEG C, 0.6MPa,
Puffing, crushing, sieving, collect 350 mesh fine powders, are cooled to room temperature to obtain Controlled-release filler.
The preparation method of the antibacterial of copper containing the humic acid volume increase composition, includes the following steps：
S1：Allantoin and amino-oligosaccharide are uniformly mixed, and are warming up to 40 DEG C, 20min are kept the temperature, then in 450r/min rotating speeds
25min is stirred, cycocel, TrinexAN_SNacethyl and first piperazine is then added and is uniformly mixed, stirs 25min in 850r/min rotating speeds, then
Humic acid copper, Kocide SD and basic copper carbonate is added to be uniformly mixed, stirs 40min in 1500r/min rotating speeds, is then cooled to
Room temperature obtains major ingredient；
S2：Polylactic acid is warming up to 70 DEG C, 30min is kept the temperature, is subsequently added into chitosan, antibacterial modified auxiliary agent and Controlled-release filler
It is uniformly mixed, is continuously heating to 90 DEG C, keep the temperature 25min, stir 40min in 850r/min rotating speeds, be then cooled to 60 DEG C, be added
Silane resin acceptor kh-550 is uniformly mixed, and is stirred 1h in 1400r/min rotating speeds, is cooled to room temperature to obtain modified materials；
S3：Major ingredient is warming up to 80 DEG C, keeps the temperature 50min, modified materials is subsequently added into and is uniformly mixed, stirred in 650r/min rotating speeds
2h is mixed, after comminutor is granulated, dry postcooling to room temperature obtains the antibacterial of copper containing humic acid volume increase composition.
Embodiment 3
A kind of antibacterial of copper containing humic acid volume increase composition, as unit of parts by weight, including following raw material：120 parts of allantoin,
20 parts of amino-oligosaccharide, 35 parts of humic acid copper, 10 parts of cycocel, 30 parts of TrinexAN_SNacethyl, 10 parts of first piperazine, 16 parts of Kocide SD, alkali
5 parts of formula copper carbonate, 9 parts of polylactic acid, 4 parts of chitosan, 3 parts of silane resin acceptor kh-550,15 parts of antibacterial modified auxiliary agent, Controlled-release filler
36 parts.
The antibacterial modified auxiliary agent is prepared by following technique：By weight by 8 parts of attapulgite clays and 5 parts of quality point
Number is uniformly mixed for 15% sodium chloride solution, stirs 1h, filtering means dehydration, then drying roasts 0.5h in 550 DEG C, then sets
In the lanthanum chloride solution that 9 parts of mass fractions are 15%, 3h, filtering means dehydration are stirred, drying is subsequently placed in 180 DEG C of roasting 1.5h,
It is subsequently placed in the silver nitrate solution that 3 parts of mass fractions are 8%, stirs 2h, material A is obtained after drying；By 5 parts of diatomite and 1
Part n,N-dimethylacetamide is uniformly mixed, and is stirred 20min in 850r/min rotating speeds, is then warming up to 85 DEG C, keeps the temperature 1h, then
It is passed through nitrogen, material A is added and 8 parts of ethyl acrylates are uniformly mixed, stirs 14h in 450r/min rotating speeds, 3 parts of silicon is then added
Alkane coupling agent kh-570 is uniformly mixed, and is warming up to 110 DEG C, keeps the temperature 5min, is stirred 10min in 2500r/min rotating speeds, is cooled to room
Temperature obtains antibacterial modified auxiliary agent.
The Controlled-release filler is prepared by following technique：By weight by 8 parts of sodium hydroxides, 3 parts of polyethylene glycol and 15
Part water is uniformly mixed, and then heats to 65 DEG C, and it is mixed to be subsequently added into 8 parts of zeolites, 3 parts of activated carbons, 5 parts of Microcystis aeruginosas and 1 part of bentonite
Uniform, stirring 35min is closed, then heats to 75 DEG C, heat preservation 3h is subsequently added into 4 parts of soybean lecithins and is uniformly mixed, is warming up to 95
DEG C, 20min is kept the temperature, room temperature is then down to, is washed, is filtered, evaporation, it is dry, it is cold that solidification is gone to obtain material a；By material a and 6 parts
Toluene di-isocyanate(TDI) is uniformly mixed, and is stirred 40min in 850r/min rotating speeds, is subsequently added into 2 parts of butyl titanates and 15 parts of silicon
Alkane coupling agent KH-560 is uniformly mixed, and is stirred 30min in 450r/min rotating speeds, is then placed in bulking machine, in 200 DEG C,
0.7MPa, puffing, crushing, sieving, collects 250 mesh fine powders, is cooled to room temperature to obtain Controlled-release filler.
The preparation method of the antibacterial of copper containing the humic acid volume increase composition, includes the following steps：
S1：Allantoin and amino-oligosaccharide are uniformly mixed, and are warming up to 50 DEG C, 10min are kept the temperature, then in 650r/min rotating speeds
15min is stirred, cycocel, TrinexAN_SNacethyl and first piperazine is then added and is uniformly mixed, stirs 15min in 1050r/min rotating speeds, then
Humic acid copper, Kocide SD and basic copper carbonate is added to be uniformly mixed, stirs 20min in 2500r/min rotating speeds, is then cooled to
Room temperature obtains major ingredient；
S2：Polylactic acid is warming up to 80 DEG C, 20min is kept the temperature, is subsequently added into chitosan, antibacterial modified auxiliary agent and Controlled-release filler
It is uniformly mixed, is continuously heating to 110 DEG C, keep the temperature 15min, stir 20min in 1050r/min rotating speeds, be then cooled to 70 DEG C, add
Enter silane resin acceptor kh-550 to be uniformly mixed, stirs 2h in 1200r/min rotating speeds, be cooled to room temperature to obtain modified materials；
S3：Major ingredient is warming up to 90 DEG C, keeps the temperature 20min, modified materials is subsequently added into and is uniformly mixed, stirred in 850r/min rotating speeds
1h is mixed, after comminutor is granulated, dry postcooling to room temperature obtains the antibacterial of copper containing humic acid volume increase composition.
Comparative example 1
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in lack polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler.
Comparative example 2
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in lack polylactic acid.
Comparative example 3
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in lack chitosan.
Comparative example 4
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in lack silane resin acceptor kh-550.
Comparative example 5
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in lack antibacterial modified auxiliary agent.
Comparative example 6
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in lack Controlled-release filler.
Comparative example 7
Using a kind of Chinese patent application document " antibacterial volume increase composition (application publication number containing allantoin：
CN106305748 the method in) " described in specific embodiment 1-81 prepares antibacterial and increases production composition.
Comparative example 8
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in polylactic acid be 5 parts, chitosan is 9 parts, silane resin acceptor kh-550 is 0.6 part, antibacterial modified auxiliary agent is 28 parts, slow
It is 14 parts to release filler.
Comparative example 9
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in polylactic acid be 11 parts, chitosan is 3 parts, silane resin acceptor kh-550 is 4 parts, antibacterial modified auxiliary agent is 12 parts, slow
It is 39 parts to release filler.
Comparative example 10
It is essentially identical with the preparation process of embodiment 1, it has only the difference is that preparing the antibacterial of copper containing humic acid volume increase composition
Raw material in polylactic acid be 12 parts, chitosan is 2 parts, silane resin acceptor kh-550 is 5 parts, antibacterial modified auxiliary agent is 13 parts, slow
It is 38 parts to release filler.
Antibiotic property experiment is carried out to product made from embodiment 1-3 and comparative example 1-10, and worth product is applied to
In the plantation of eggplant, and plantation eggplant ties eggplant on single plant eggplant quantity after 6 months is counted, the results are shown in table below.
As seen from the above table：(1) by the data of embodiment 1-3 and comparative example 7 as it can be seen that containing humic acid made from embodiment 1-3
Copper antibacterial increases production the antibiotic property of composition and obvious effect of increasing production is higher than the antibiotic property that antibacterial made from comparative example 7 increases production composition
And effect of increasing production；Simultaneously by the data of embodiment 1-3 as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-6 as it can be seen that polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial
Modified additive, Controlled-release filler play synergistic effect in preparing the antibacterial of copper containing humic acid volume increase composition, and collaboration, which improves, to be contained
Humic acid copper antibacterial increases production the antibiotic property and effect of increasing production of composition；This is：
Polylactic acid has degradability and adsorptivity, and a large amount of hydroxyl is contained on surface, can be chitosan, antibacterial modified help
Agent and the attachment of Controlled-release filler improve abundant attachment point so that polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial
Modified additive and Controlled-release filler can become an entirety and apply to the antibacterial of copper containing humic acid volume increase of the invention as reinforcement system
In the preparation of composition, at the same the grafting of silane resin acceptor kh-550 effect under, realize chitosan, antibacterial modified auxiliary agent and
The combination of Controlled-release filler and polylactic acid, is utilized the antibiotic property of chitosan and porous adsorptivity, and chitosan is easy in weakly acidic solvent
In dissolving, it is worth pointing out that containing amino (NH in dissolved solution2+), these amino are by combining negative electron, profit
Inhibit bacterial respiratory that bacterium is lost activity the inhibiting effect of bacterium surface respiratory enzyme with anion antibacterial to realize
Effect applies in the preparation that the antibacterial of copper containing humic acid of the invention increases production composition as reinforcement system, effectively increases antibacterial
Property, moreover it is possible to the combination of realization and polylactic acid under the grafting effect of silane resin acceptor kh-550, in the effect for improving antibiotic property effect
Under the premise of fruit, the efficiency and quality for improving antibiotic property drug release are further improved so that copper containing humic acid of the invention is anti-
Bacterium volume increase composition applies in practical plantation, the bactericidal property to soil can be effectively improved, wherein that adds is antibacterial modified
Auxiliary agent passes through modified modified attapulgite clay surface with the presence of a large amount of ball object using attapulgite clay as raw material, and
Attapulgite clay surface apertures are reduced compared with modified attapulgite clay, this may be due to being adsorbed on attapulgite clay particle surface
AgNO3It does not elute completely, the Ag being decomposed to form during the drying process2O reunites on its surface, causes attapulgite clay part small
Hole is blocked, therefore being removed in silver type antibacterial attapulgite clay has a certain number of silver to be present in antibacterial sorbing material in the form of an ion
Cation exchange site set and duct outside, also part Ag2O is present in the surface of material, to ensure that silver is harmful with soil
Bacterium has enough contacts area.In modified recombination process, most of sodium ion and silver ion enter concave convex rod by ion exchange
Inside clay, attapulgite clay denitrogenation is the cation such as sodium ion in attapulgite clay structure and NH4+Ion occurs to hand over
It changes, dephosphorization is the Electrostatic Absorption of the hydrous zirconia gel by attapulgite clay surface, and antibacterial is the loading because of Ag ions, silver ion
The specific binding of the mercapto (- SH) with negative electrical charge in protease will be attracted, effectively pierce through cell wall and cell membrane
Appearance further makes bacterial cell because of protein denaturation, and can not breathe, is metabolized and breed, until it is dead, reach the effect of sterilizing
Fruit realizes that a large amount of hydroxyl in its surface is combined with polylactic acid, applies to this hair under the grafting effect of silane resin acceptor kh-550
In prepared by the bright antibacterial of copper containing humic acid volume increase composition, its excellent anti-microbial property is imparted, wherein the Controlled-release filler added
By the way that sodium hydroxide, polyethylene glycol and water to be uniformly mixed, then heats up, be subsequently added into zeolite, activated carbon, Microcystis aeruginosa and swelling
Soil is uniformly mixed, and then stirring heats up, keep the temperature, and is subsequently added into soybean lecithin and is uniformly mixed, heats up, and room is then down in heat preservation
Temperature, washing filter, evaporation, dry, cold that solidification is gone to obtain material a；Material a and toluene di-isocyanate(TDI) are uniformly mixed, stirred
It mixes, is subsequently added into butyl titanate and silane coupling agent KH-560 is uniformly mixed, stirring is then placed in bulking machine, puffing, powder
Broken, sieving, collects fine powder, is cooled to room temperature to obtain, zeolite, activated carbon, Microcystis aeruginosa and bentonitic porous sustained-release is utilized
Filler, in soybean lecithin, the modification of fat polyethylene glycol, toluene di-isocyanate(TDI), butyl titanate and silane coupling agent KH-560
Under effect, the hydroxyl on porous sustained-release filler surface is utilized, realizes and the combination of polylactic acid, apply to the present invention containing corruption
It grows in sour copper antibacterial volume increase composition preparation, imparts its excellent sustained release performance so that the antibacterial of copper containing humic acid of the invention
Increase production composition in actually planting, drug release can be made more efficient, effectively purified soil environment, improve crop
Yield.
(3) by the data of comparative example 6-8 as it can be seen that polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent,
The weight ratio of Controlled-release filler is not at (6-9)：(4-8)：(1-3)：(15-25)：When in (16-36) range, antibacterial volume increase obtained
The antibiotic property of composition and the numerical value of effect of increasing production and the numerical value of embodiment 1-3 are very different, and are much smaller than the number of embodiment 1-3
Value is suitable with the numerical value of the prior art (comparative example 7).Polylactic acid of the present invention, chitosan, silane resin acceptor kh-550, antibacterial change
Property auxiliary agent, Controlled-release filler as reinforcement system, embodiment 1-3 controls are prepared when the antibacterial of copper containing humic acid increases production composition by adding
Addition polymerization lactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler weight ratio be (6-9)：(4-8)：
(1-3)：(15-25)：(16-36) is realized in reinforcement system using antibacterial modified auxiliary agent and Controlled-release filler as primary raw material, is utilized
The hydroxyl on the surface of polylactic acid realizes that antibacterial modified auxiliary agent is attached to poly- breast under the grafting effect of silane resin acceptor kh-550
The surface of acid realizes the reinforcement modification for increasing production composition anti-microbial property to the present invention antibacterial of copper containing humic acid, effectively increases
The present invention antibacterial of copper containing humic acid increases production the anti-microbial property of composition, in addition coordinates with the chitosan with excellent antibacterial performance,
It is attached to the surface of polylactic acid simultaneously, further improves and composition anti-microbial property is increased production to the present invention antibacterial of copper containing humic acid
Reinforcement is modified, and is effectively increased the anti-microbial property of the antibacterial of copper containing humic acid volume increase composition of the invention, is recycled Controlled-release filler
Superior sustained-release performance realizes polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler and applies to
The present invention antibacterial of copper containing humic acid is increased production in the preparation of composition, and it is excellent to impart the antibacterial of copper containing humic acid volume increase composition of the invention
Different anti-microbial property and sustained release performance so that the antibacterial of copper containing humic acid volume increase composition of the invention, can in actually planting
Keep drug release more efficient, effectively purified soil environment, improves the yield of crop.
The above content is it cannot be assumed that present invention specific implementation is confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all answers
When being considered as belonging to present invention scope of patent protection determined by the appended claims.
Claims (6)
1. a kind of antibacterial of copper containing humic acid increases production composition, which is characterized in that including following raw material：Allantoin, amino-oligosaccharide,
Humic acid copper, cycocel, TrinexAN_SNacethyl, first piperazine, Kocide SD, basic copper carbonate, polylactic acid, chitosan, silane coupling agent KH-
550, antibacterial modified auxiliary agent, Controlled-release filler；
The antibacterial modified auxiliary agent, as unit of parts by weight, including following raw material：4-8 parts of attapulgite clay, mass fraction 5-
The nitre that 4-9 parts of lanthanum chloride solution that 15% 5-15 parts of sodium chloride solution, mass fraction are 15-35%, mass fraction are 4-8%
Sour 3-6 parts of solution of silver, 2-5 parts of diatomite, 1-5 parts of DMAC N,N' dimethyl acetamide, 4-8 parts of ethyl acrylate, silane coupling agent KH-
5703-9 parts；
The Controlled-release filler, as unit of parts by weight, including following raw material：4-8 parts of sodium hydroxide, 3-9 parts of polyethylene glycol, water 5-
15 parts, 4-8 parts of zeolite, 3-6 parts of activated carbon, 2-5 parts of Microcystis aeruginosa, 1-5 parts of bentonite, 4-8 parts of soybean lecithin, toluene diisocyanate
3-6 parts of acid esters, 2-5 parts of butyl titanate, KH-5605-15 parts of silane coupling agent；
The polylactic acid, chitosan, silane resin acceptor kh-550, antibacterial modified auxiliary agent, Controlled-release filler weight ratio be (6-9)：
(4-8)：(1-3)：(15-25)：(16-36).
2. the antibacterial of copper containing humic acid according to claim 1 increases production composition, which is characterized in that the polylactic acid, shell are poly-
Sugar, silane resin acceptor kh-550, antibacterial modified auxiliary agent weight ratio be 7.5：5.6：2.4：19.8：26.4.
3. the antibacterial of copper containing humic acid according to claim 1 increases production composition, which is characterized in that the copper containing humic acid is anti-
Bacterium increases production composition as unit of parts by weight, including following raw material：80-120 parts of allantoin, 20-30 parts of amino-oligosaccharide, humic
Sour copper 10-35 parts, 10-30 parts of cycocel, 10-30 parts of TrinexAN_SNacethyl, 10-30 parts of first piperazine, 8-16 parts of Kocide SD, basic carbonate
It is 5-15 parts of copper, 6-9 parts of polylactic acid, 4-8 parts of chitosan, 1-3 parts of silane resin acceptor kh-550, auxiliary agent 15-25 parts antibacterial modified, slow
Release 16-36 parts of filler.
4. the antibacterial of copper containing humic acid according to claim 1 increases production composition, which is characterized in that the antibacterial modified auxiliary agent
It is prepared by following technique：Attapulgite clay and mass fraction are uniformly mixed for the sodium chloride solution of 5-15%, stir 1-
Then 3h, filtering means dehydration, drying roast 0.5-1.5h in 450-550 DEG C, be subsequently placed in the chlorination that mass fraction is 15-35%
In lanthanum solution, 1-3h, filtering means dehydration are stirred, drying is subsequently placed in 180-220 DEG C of roasting 0.5-1.5h, is subsequently placed in quality point
Number is to stir 2-4h in the silver nitrate solution of 4-8%, material A is obtained after drying；Diatomite and DMAC N,N' dimethyl acetamide are mixed
It closes uniformly, stirs 20-40min in 650-850r/min rotating speeds, be then warming up to 75-85 DEG C, keep the temperature 1-3h, be then passed through nitrogen
Gas, is added material A and ethyl acrylate is uniformly mixed, and 10-14h is stirred in 450-550r/min rotating speeds, and it is even that silane is then added
Join agent KH-570 to be uniformly mixed, be warming up to 90-110 DEG C, keep the temperature 5-15min, 10- is stirred in 1500-2500r/min rotating speeds
20min is cooled to room temperature to obtain antibacterial modified auxiliary agent.
5. the antibacterial of copper containing humic acid according to claim 1 increases production composition, which is characterized in that the Controlled-release filler is by such as
It is prepared by lower technique：Sodium hydroxide, polyethylene glycol and water are uniformly mixed, then heat to 65-75 DEG C, is subsequently added into boiling
Stone, activated carbon, Microcystis aeruginosa and bentonite are uniformly mixed, and stir 15-35min, then heat to 75-85 DEG C, keep the temperature 1-3h, then
Soybean lecithin is added to be uniformly mixed, is warming up to 85-95 DEG C, keeps the temperature 20-40min, is then down to room temperature, washs, filters, steam
Hair, it is dry, it is cold that solidification is gone to obtain material a；Material a and toluene di-isocyanate(TDI) are uniformly mixed, in 850-950r/min rotating speeds
20-40min is stirred, butyl titanate is subsequently added into and silane coupling agent KH-560 is uniformly mixed, in 450-650r/min rotating speeds
20-30min is stirred, is then placed in bulking machine, in 200-240 DEG C, 0.6-0.7MPa, 250- is collected in puffing, crushing, sieving
350 mesh fine powders, are cooled to room temperature to obtain Controlled-release filler.
6. a kind of preparation method for increasing production composition according to claim 1-5 any one of them antibacterial of copper containing humic acid, special
Sign is, includes the following steps：
S1：Allantoin and amino-oligosaccharide are uniformly mixed, and are warming up to 40-50 DEG C, 10-20min are kept the temperature, then in 450-650r/
Min rotating speeds stir 15-25min, and cycocel, TrinexAN_SNacethyl and first piperazine is then added and is uniformly mixed, in 850-1050r/min rotating speeds
15-25min is stirred, humic acid copper, Kocide SD and basic copper carbonate is subsequently added into and is uniformly mixed, turn in 1500-2500r/min
Speed stirring 20-40min, is then cooled to room temperature and obtains major ingredient；
S2：Polylactic acid is warming up to 70-80 DEG C, 20-30min is kept the temperature, is subsequently added into chitosan, antibacterial modified auxiliary agent and sustained release and fills out
Material is uniformly mixed, and is continuously heating to 90-110 DEG C, keeps the temperature 15-25min, is stirred 20-40min in 850-1050r/min rotating speeds, is connect
It and is cooled to 60-70 DEG C, silane resin acceptor kh-550 is added and is uniformly mixed, 1-2h is stirred in 1200-1400r/min rotating speeds, it is cold
But modified materials are obtained to room temperature；
S3：Major ingredient is warming up to 80-90 DEG C, keeps the temperature 20-50min, modified materials is subsequently added into and is uniformly mixed, in 650-850r/min
Rotating speed stirs 1-2h, and after comminutor is granulated, dry postcooling to room temperature obtains the antibacterial of copper containing humic acid volume increase composition.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113750651A (en) * | 2021-09-26 | 2021-12-07 | 杭州巴贝克科技有限公司 | Filter material with antibacterial and deodorizing functions and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106305748A (en) * | 2015-06-30 | 2017-01-11 | 陕西美邦农药有限公司 | Antimicrobial yield-increasing composition containing allantoin |
| CN107118502A (en) * | 2017-06-19 | 2017-09-01 | 合肥斯科尔智能科技有限公司 | A kind of medical product antibacterial 3D printing material |
| CN107466771A (en) * | 2017-08-28 | 2017-12-15 | 芜湖浪尖山生态林业有限公司 | A kind of high-yield disease resisting implantation methods of yellow peach |
-
2018
- 2018-03-19 CN CN201810226440.7A patent/CN108522540A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106305748A (en) * | 2015-06-30 | 2017-01-11 | 陕西美邦农药有限公司 | Antimicrobial yield-increasing composition containing allantoin |
| CN107118502A (en) * | 2017-06-19 | 2017-09-01 | 合肥斯科尔智能科技有限公司 | A kind of medical product antibacterial 3D printing material |
| CN107466771A (en) * | 2017-08-28 | 2017-12-15 | 芜湖浪尖山生态林业有限公司 | A kind of high-yield disease resisting implantation methods of yellow peach |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113750651A (en) * | 2021-09-26 | 2021-12-07 | 杭州巴贝克科技有限公司 | Filter material with antibacterial and deodorizing functions and preparation method thereof |
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Application publication date: 20180914 |