CN108517418A - A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation and application - Google Patents
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation and application Download PDFInfo
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- CN108517418A CN108517418A CN201810338680.6A CN201810338680A CN108517418A CN 108517418 A CN108517418 A CN 108517418A CN 201810338680 A CN201810338680 A CN 201810338680A CN 108517418 A CN108517418 A CN 108517418A
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- incineration
- refuse flyash
- fly ash
- copper
- domestic garbage
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- 239000010881 fly ash Substances 0.000 title claims abstract description 74
- 239000010949 copper Substances 0.000 title claims abstract description 73
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 70
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000010813 municipal solid waste Substances 0.000 title claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000012141 concentrate Substances 0.000 claims abstract description 19
- 238000005406 washing Methods 0.000 claims abstract description 16
- 238000002844 melting Methods 0.000 claims abstract description 15
- 230000008018 melting Effects 0.000 claims abstract description 15
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 12
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 12
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 12
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 9
- 238000001035 drying Methods 0.000 claims abstract description 7
- 239000002893 slag Substances 0.000 claims description 12
- 238000003723 Smelting Methods 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000007670 refining Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 239000003500 flue dust Substances 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims 1
- 239000000428 dust Substances 0.000 abstract description 17
- 238000004064 recycling Methods 0.000 abstract description 6
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 description 11
- 238000004056 waste incineration Methods 0.000 description 7
- 235000019738 Limestone Nutrition 0.000 description 6
- 229910052745 lead Inorganic materials 0.000 description 6
- 239000006028 limestone Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- 239000002956 ash Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000009853 pyrometallurgy Methods 0.000 description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 description 4
- 239000006004 Quartz sand Substances 0.000 description 3
- 241001062472 Stokellia anisodon Species 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 241000722270 Regulus Species 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 238000007499 fusion processing Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011451 fired brick Substances 0.000 description 1
- 239000008398 formation water Substances 0.000 description 1
- -1 haydite Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B2101/00—Type of solid waste
- B09B2101/30—Incineration ashes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation provided by the invention and application, are related to technical field of resource recovery.A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, including：Incineration of refuse flyash after washing and drying is subjected to melting with copper concentrate, incineration of refuse flyash main component includes CaO and SiO2, contain bioxin and heavy metal element simultaneously, K, Na, Cl content are low, are not impacted to Copper making process and product while collaboration handles flying dust.This method is easy to operate, realizes harmless treatment and the recycling of incineration of refuse flyash, reduces the cost of Copper making, reduce environmental pollution.
Description
Technical field
The present invention relates to technical field of resource recovery, and more particularly to a kind of Copper making collaboration processing consumer waste incineration flies
The method of ash and application.
Background technology
With the raising of Chinese Urban Residents living standard and urban modernization degree, Chinese Disposal of Domestic is just located
In the transitional period from based on landfill to based on burning.Year ends 2015, national consumer waste incineration processing total amount reach 6577
Ten thousand tons, account for the 34% of harmless treatment total amount.According to relevant report, the year two thousand twenty is arrived, consumer waste incineration processing capacity accounts for innoxious
The ratio of processing capacity reaches 50%, and house refuse is averaged day output up to 59.1 tons, then can generate 650~11,000,000 every year
The incineration of refuse flyash of ton.
Since a large amount of bioxin and heavy metal can be enriched in flying dust in Refuse Incineration Process, both at home and abroad all rubbish
Rubbish flying ash is disposed as dangerous solid waste.In incineration of refuse flyash solubility salt typically constitute from 10%~
25%, including chloride, sulfate, carbonate etc..It is waste incineration that dioxins materials are enriched in incineration of refuse flyash
The strongest substance of flying dust Poisoning, content generally in 0.034~7.53ng-TEQ/g, be 100 times of general soil background value with
On.In addition, also contain heavy metal element in incineration of refuse flyash, such as Zn, Pb, Cu.Disposition waste incineration both at home and abroad flies at present
The method of ash fills after mainly curing or seal, but has many researchs by incineration of refuse flyash for cement, pitch, sintering
The auxiliary material of the energy saving building materials such as haydite, fired brick.And can not degrade bioxin as construction material doping auxiliary material, Dui bioxin
Certain diluting effect can only be played with heavy metal element, the degree of recycling is also restrained.
Invention content
The purpose of the present invention is to provide a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, this method behaviour
Make simply, to realize harmless treatment and the recycling of incineration of refuse flyash, reduces the cost of Copper making, it is dirty to reduce environment
Dye.
The present invention solves its technical problem using following technical scheme to realize：
The present invention proposes a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, including：
Incineration of refuse flyash after washing and drying is subjected to melting with copper concentrate, incineration of refuse flyash main component includes
CaO and SiO2, contain bioxin and heavy metal element simultaneously.
The present invention proposes that a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation is comprehensive in metal smelt and resource
Close the application in utilizing.
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation of the embodiment of the present invention and the beneficial effect of application
Fruit is：
Incineration of refuse flyash is used as Copper making slag former by the present invention, mixed with copper concentrate instead of lime stone and quartz sand etc.
Close melting, by the high temperature that is generated in fusion process can efficient-decomposition incineration of refuse flyash Zhong bioxin, reach waste incineration
The purpose of flying dust removing toxic substances, reduces processing cost, the copper pyrometallurgy cost of incineration of refuse flyash, reduces environmental pollution.This method
Easy to operate, process cleans realize harmless treatment and the recycling of incineration of refuse flyash, turn waste into wealth, reduce stack,
The environmental problem that landfill etc. is brought.
Specific implementation mode
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, builds according to normal condition or manufacturer
The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase
Product.
Below the method to a kind of Copper making treating incinerated fly ash of domestic garbage with cooperation of the embodiment of the present invention and application into
Row illustrates.
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation provided in an embodiment of the present invention, including：
The incineration of refuse flyash of certain municipal solid waste incinerator is chosen, in the present invention, the ingredient such as table of incineration of refuse flyash
1。
1 chemical component table of table
In the present invention, the research through inventor finds to contain a certain amount of CaO and SiO in incineration of refuse flyash2, can
To substitute the lime stone and quartz sand during Copper making, the cost of Copper making can be not only reduced, can also turn waste into wealth, subtract
The environmental problem that few stacking, landfill etc. are brought.The high temperature generated during Copper making simultaneously can efficient-decomposition waste incineration
Flying dust Zhong bioxin achievees the purpose that incineration of refuse flyash detoxifies, reduces the processing cost to incineration of refuse flyash, reduces ring
Border is polluted, and realizes the harmless treatment of incineration of refuse flyash.
In order to improve CaO and SiO in incineration of refuse flyash2Content, to copper concentrate carry out melting before, washed
It is dry.Specifically, after incineration of refuse flyash is washed 0.5~1.5 hour under conditions of 20~30 DEG C, in 60~80 DEG C of item
It is 1~3 hour dry under part.Washing can elute a large amount of solubility salt in flying dust, by Ca in the incineration of refuse flyash of washing,
Si equal sizes increase, and K, Na, Cl equal size reduce, and will not be impacted to melting slagging process.Specific ingredient such as table 2.
2 chemical component table of table
Incineration of refuse flyash after washing and drying is subjected to melting with copper concentrate under conditions of 1200~1400 DEG C, preferably
Ground, smelting temperature are 1250~1350 DEG C.In the embodiment of the present invention, washing incineration of refuse flyash is CaO-FeO- for slag type
SiO2The copper pyrometallurgy of ternary system clinker, the CaO in flying dust can improve the fusing point and viscosity of clinker, promote clinker and sulfonium phase
Separation, while the SiO in flying dust2, CaO and metal oxide slag making occurs and reacts, into slag phase, to Copper making process and production
The copper matte regulus gone out does not impact, and can improve slag viscosity with the basicity of working the slag.In other embodiments of the invention,
Washing incineration of refuse flyash can be used for matte smelting and pyro-refining, and the copper pyrometallurgy type of furnace used includes blast furnace, reflection
Stove, electric furnace, converter, flash smelting furnace and bath smelting furnace etc..The high temperature generated during Copper making can decompose in flying dust
Bioxin achievees the purpose that flying dust detoxifies the study found that degradation rate is up to 99.9%.
Enter the Contents of Main Components of the component content and treating capacity design clinker of stove raw and auxiliary material, meter in being smelted according to copper fire
Calculating needs the amount of calcium to be added in slag former, further according to the charge ratio of the content calculation flying dust of the calcium in flying dust, in the present invention
In embodiment, the mass ratio of incineration of refuse flyash and copper concentrate is 1~10:100.Preferably, can be 1:100、1:50、3:
100、1:25。
Contain a small amount of heavy metal, such as Zn, Pb, Cu in incineration of refuse flyash, it is harmful to environment, Copper making can be passed through
Process enriching and recovering, centralized processing reduce the pollution to environment.Wherein, the heavy metals such as Pb, Zn are volatized into flue dust and are enriched with back
It receives, Cu, Ni etc. enter copper matte regulus enriching and recovering, and Mn, Fe, Cr etc. enter slag phase formation Water Quenching Slag and can be used for construction material.
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation provided in an embodiment of the present invention, it is easy to operate,
Harmless treatment and the recycling for realizing incineration of refuse flyash, reduce the cost of Copper making, reduce environmental pollution, Ke Yiying
For metal smelt.Preferably, metal smelt includes matte smelting and pyro-refining.
The feature and performance of the present invention are described in further detail with reference to embodiments.
Embodiment 1
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation is present embodiments provided, includes mainly following step
Suddenly：
The ingredient of certain municipal solid waste incinerator：CaO 32.74%, Al2O31.55%, SiO28.79%, K2O
4.67%, Na2O 4.84%, Cl 14.12%.Above-mentioned incineration of refuse flyash is taken, is washed 1.5 hours under conditions of 20 DEG C,
It is 2 hours dry under conditions of 60 DEG C.Winged ash composition after washing：CaO 45.91%, Al2O33.26%, SiO2
14.15%, K2O 0.29%, Na2O 0.41%, Cl 0.46%.
The ingredient for entering stove copper concentrate during copper weld pool is Cu 25.90%, Fe 24.51%, S 33.27%, Zn
6.15%, Pb 2.25%.The amount that flying dust is added in 1 ton of concentrate is 0.01 ton, and (mass ratio of flying dust and copper concentrate is 1:100), exist
Melting , bioxin is carried out under conditions of 1200 DEG C decomposes complete, 0.54 ton of clinker of generation.Obtained matte ingredient is：CuS
68.9%, FeS 22.1%.
Embodiment 2
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation is present embodiments provided, includes mainly following step
Suddenly：
The ingredient of certain municipal solid waste incinerator：CaO 32.74%, Al2O31.55%, SiO28.79%, K2O
4.67%, Na2O 4.84%, Cl 14.12%.Above-mentioned incineration of refuse flyash is taken, is washed 0.5 hour under conditions of 30 DEG C,
It is 1 hour dry under conditions of 80 DEG C.Winged ash composition after washing：CaO 41.95%, Al2O32.43%, SiO2
14.24%, K2O 0.25%, Na2O 0.40%, Cl 0.42%.
The ingredient for entering stove copper concentrate during copper weld pool is Cu 25.90%, Fe 24.51%, S 33.27%, Zn
6.15%, Pb 2.25%.0.1 ton of flying dust is added in 1 ton of concentrate, and (mass ratio of incineration of refuse flyash and copper concentrate is 1:10), exist
Melting , bioxin is carried out under conditions of 1400 DEG C decomposes complete, 0.58 ton of clinker of generation.Obtained matte ingredient is：CuS
68.3%, FeS 23.6%.
Comparative example 1
This comparative example provides a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, includes mainly following step
Suddenly：
The ingredient for entering stove copper concentrate during copper weld pool is Cu 25.90%, Fe 24.51%, S 33.27%, Zn
6.15%, Pb 2.25% selects CaO-FeO-SiO2It is clinker and designs main component as CaO 8%, FeO 35%, SiO2
40%.It is incorporated a certain proportion of lime stone and quartz (by copper smelting plant prior art), is melted under conditions of 1300 DEG C
Refining generates 0.54 ton of clinker.Obtained matte ingredient is：CuS 69.0%, FeS 23.3%.
By Examples 1 to 2 and comparative example 1 it is found that carrying out melting using the flying dust after washing in embodiment 1, embodiment 2,
Comparative example 1 carries out melting, the matte ingredient and stove obtained by the method for embodiment 1 and embodiment 2 using lime stone, quartz
Slag content is more close compared with comparative example 1, illustrates that flying dust can substitute lime stone, quartz carries out melting to copper concentrate, and
Smelting Effect is close, illustrates that the method for the Copper making treating incinerated fly ash of domestic garbage with cooperation that embodiment 1 and embodiment 2 provide can
It goes and effect meets needs.
In conclusion incineration of refuse flyash is used as Copper making slag former by the present invention, instead of lime stone and quartz sand etc., with
Copper concentrate mixed smelting, by the high temperature that is generated in fusion process can efficient-decomposition incineration of refuse flyash Zhong bioxin, simultaneously
Enriching and recovering heavy metal element therein achievees the purpose that incineration of refuse flyash detoxifies, reduces being processed into for incineration of refuse flyash
Originally, copper pyrometallurgy cost, reduces environmental pollution.This method is easy to operate, process cleans, realizes the harmless of incineration of refuse flyash
Change processing and recycling, turn waste into wealth, reduces the environmental problem stacked, filled etc. and bring.
Embodiments described above is a part of the embodiment of the present invention, instead of all the embodiments.The reality of the present invention
The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of the selected implementation of the present invention
Example.Based on the embodiments of the present invention, those of ordinary skill in the art are obtained without creative efforts
Every other embodiment, shall fall within the protection scope of the present invention.
Claims (10)
1. a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, which is characterized in that including：
Incineration of refuse flyash after washing and drying is mixed with copper concentrate and carries out melting, the incineration of refuse flyash main component packet
Include CaO and SiO2, contain bioxin and heavy metal element simultaneously.
2. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that described
The mass ratio of incineration of refuse flyash and the copper concentrate is 1~10:100, it is preferable that the incineration of refuse flyash and copper essence
The mass ratio of mine is 1~4:100.
3. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that washing
Method include：The incineration of refuse flyash is washed 0.5~1.5 hour under conditions of 20~30 DEG C.
4. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 3, which is characterized in that dry
Method include：The incineration of refuse flyash after washing is 1~3 hour dry under conditions of 60~80 DEG C.
5. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that washing
In the incineration of refuse flyash after drying, the mass percentage of the CaO is 40~50%, it is preferable that the matter of the CaO
It is 45~50% to measure percentage composition.
6. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 5, which is characterized in that washing
In the incineration of refuse flyash after drying, the SiO2Mass percentage be 10~20%, it is preferable that the SiO2's
Mass percentage is 15~20%.
7. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that it is special
Sign is that quality percentage of the mass percentage of K less than 0.3%, Na contains in the incineration of refuse flyash after washing and drying
Mass percentage of the amount less than 0.5%, Cl is less than 0.6%.
8. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that described
Incineration of refuse flyash carries out melting with the copper concentrate under conditions of 1200~1400 DEG C, it is preferable that smelting temperature 1250
~1350 DEG C.
9. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that described
Include after incineration of refuse flyash and the copper concentrate melting：Melting by-product (flue dust, slag etc.) is separated and recovered respectively.
10. if the method for claim 1~9 any one of them Copper making treating incinerated fly ash of domestic garbage with cooperation is in metal smelting
Application in refining and comprehensive utilization of resources.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111378844A (en) * | 2020-04-27 | 2020-07-07 | 中国恩菲工程技术有限公司 | Method and system for treating copper-containing sludge |
| CN111635218A (en) * | 2020-07-06 | 2020-09-08 | 江西理工大学 | Sintered brick based on copper smelting waste residues and preparation method thereof |
| CN113564381A (en) * | 2021-07-26 | 2021-10-29 | 广东飞南资源利用股份有限公司 | Synergistic copper smelting method and building material |
| CN113667827A (en) * | 2021-08-24 | 2021-11-19 | 上海康恒环境股份有限公司 | Method for co-processing waste incineration fly ash and copper-containing sludge |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101074457A (en) * | 2006-05-16 | 2007-11-21 | 重庆大学 | Method for smelting and separating refuse-combustion fly-ash heavy metal |
| CN103215441A (en) * | 2013-04-19 | 2013-07-24 | 首钢总公司 | Method for treating grate furnace garbage incineration flyash by using metallurgical sintering process |
| CN106048248A (en) * | 2016-07-06 | 2016-10-26 | 中国恩菲工程技术有限公司 | Method for treating waste incineration fly ash |
| CN106048237A (en) * | 2016-07-06 | 2016-10-26 | 中国恩菲工程技术有限公司 | Waste incineration fly ash treatment method |
-
2018
- 2018-04-16 CN CN201810338680.6A patent/CN108517418A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101074457A (en) * | 2006-05-16 | 2007-11-21 | 重庆大学 | Method for smelting and separating refuse-combustion fly-ash heavy metal |
| CN103215441A (en) * | 2013-04-19 | 2013-07-24 | 首钢总公司 | Method for treating grate furnace garbage incineration flyash by using metallurgical sintering process |
| CN106048248A (en) * | 2016-07-06 | 2016-10-26 | 中国恩菲工程技术有限公司 | Method for treating waste incineration fly ash |
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Application publication date: 20180911 |