CN108517418A - A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation and application - Google Patents

A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation and application Download PDF

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Publication number
CN108517418A
CN108517418A CN201810338680.6A CN201810338680A CN108517418A CN 108517418 A CN108517418 A CN 108517418A CN 201810338680 A CN201810338680 A CN 201810338680A CN 108517418 A CN108517418 A CN 108517418A
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China
Prior art keywords
incineration
refuse flyash
fly ash
copper
domestic garbage
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CN201810338680.6A
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Chinese (zh)
Inventor
王文祥
王晓阳
李宝花
方红生
黄玲
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Guangdong Vocational College of Environmental Protection Engineering
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Guangdong Vocational College of Environmental Protection Engineering
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Priority to CN201810338680.6A priority Critical patent/CN108517418A/en
Publication of CN108517418A publication Critical patent/CN108517418A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00Obtaining copper
    • C22B15/0026Pyrometallurgy
    • C22B15/0028Smelting or converting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B2101/00Type of solid waste
    • B09B2101/30Incineration ashes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation provided by the invention and application, are related to technical field of resource recovery.A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, including:Incineration of refuse flyash after washing and drying is subjected to melting with copper concentrate, incineration of refuse flyash main component includes CaO and SiO2, contain bioxin and heavy metal element simultaneously, K, Na, Cl content are low, are not impacted to Copper making process and product while collaboration handles flying dust.This method is easy to operate, realizes harmless treatment and the recycling of incineration of refuse flyash, reduces the cost of Copper making, reduce environmental pollution.

Description

A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation and application
Technical field
The present invention relates to technical field of resource recovery, and more particularly to a kind of Copper making collaboration processing consumer waste incineration flies The method of ash and application.
Background technology
With the raising of Chinese Urban Residents living standard and urban modernization degree, Chinese Disposal of Domestic is just located In the transitional period from based on landfill to based on burning.Year ends 2015, national consumer waste incineration processing total amount reach 6577 Ten thousand tons, account for the 34% of harmless treatment total amount.According to relevant report, the year two thousand twenty is arrived, consumer waste incineration processing capacity accounts for innoxious The ratio of processing capacity reaches 50%, and house refuse is averaged day output up to 59.1 tons, then can generate 650~11,000,000 every year The incineration of refuse flyash of ton.
Since a large amount of bioxin and heavy metal can be enriched in flying dust in Refuse Incineration Process, both at home and abroad all rubbish Rubbish flying ash is disposed as dangerous solid waste.In incineration of refuse flyash solubility salt typically constitute from 10%~ 25%, including chloride, sulfate, carbonate etc..It is waste incineration that dioxins materials are enriched in incineration of refuse flyash The strongest substance of flying dust Poisoning, content generally in 0.034~7.53ng-TEQ/g, be 100 times of general soil background value with On.In addition, also contain heavy metal element in incineration of refuse flyash, such as Zn, Pb, Cu.Disposition waste incineration both at home and abroad flies at present The method of ash fills after mainly curing or seal, but has many researchs by incineration of refuse flyash for cement, pitch, sintering The auxiliary material of the energy saving building materials such as haydite, fired brick.And can not degrade bioxin as construction material doping auxiliary material, Dui bioxin Certain diluting effect can only be played with heavy metal element, the degree of recycling is also restrained.
Invention content
The purpose of the present invention is to provide a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, this method behaviour Make simply, to realize harmless treatment and the recycling of incineration of refuse flyash, reduces the cost of Copper making, it is dirty to reduce environment Dye.
The present invention solves its technical problem using following technical scheme to realize:
The present invention proposes a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, including:
Incineration of refuse flyash after washing and drying is subjected to melting with copper concentrate, incineration of refuse flyash main component includes CaO and SiO2, contain bioxin and heavy metal element simultaneously.
The present invention proposes that a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation is comprehensive in metal smelt and resource Close the application in utilizing.
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation of the embodiment of the present invention and the beneficial effect of application Fruit is:
Incineration of refuse flyash is used as Copper making slag former by the present invention, mixed with copper concentrate instead of lime stone and quartz sand etc. Close melting, by the high temperature that is generated in fusion process can efficient-decomposition incineration of refuse flyash Zhong bioxin, reach waste incineration The purpose of flying dust removing toxic substances, reduces processing cost, the copper pyrometallurgy cost of incineration of refuse flyash, reduces environmental pollution.This method Easy to operate, process cleans realize harmless treatment and the recycling of incineration of refuse flyash, turn waste into wealth, reduce stack, The environmental problem that landfill etc. is brought.
Specific implementation mode
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, builds according to normal condition or manufacturer The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase Product.
Below the method to a kind of Copper making treating incinerated fly ash of domestic garbage with cooperation of the embodiment of the present invention and application into Row illustrates.
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation provided in an embodiment of the present invention, including:
The incineration of refuse flyash of certain municipal solid waste incinerator is chosen, in the present invention, the ingredient such as table of incineration of refuse flyash 1。
1 chemical component table of table
In the present invention, the research through inventor finds to contain a certain amount of CaO and SiO in incineration of refuse flyash2, can To substitute the lime stone and quartz sand during Copper making, the cost of Copper making can be not only reduced, can also turn waste into wealth, subtract The environmental problem that few stacking, landfill etc. are brought.The high temperature generated during Copper making simultaneously can efficient-decomposition waste incineration Flying dust Zhong bioxin achievees the purpose that incineration of refuse flyash detoxifies, reduces the processing cost to incineration of refuse flyash, reduces ring Border is polluted, and realizes the harmless treatment of incineration of refuse flyash.
In order to improve CaO and SiO in incineration of refuse flyash2Content, to copper concentrate carry out melting before, washed It is dry.Specifically, after incineration of refuse flyash is washed 0.5~1.5 hour under conditions of 20~30 DEG C, in 60~80 DEG C of item It is 1~3 hour dry under part.Washing can elute a large amount of solubility salt in flying dust, by Ca in the incineration of refuse flyash of washing, Si equal sizes increase, and K, Na, Cl equal size reduce, and will not be impacted to melting slagging process.Specific ingredient such as table 2.
2 chemical component table of table
Incineration of refuse flyash after washing and drying is subjected to melting with copper concentrate under conditions of 1200~1400 DEG C, preferably Ground, smelting temperature are 1250~1350 DEG C.In the embodiment of the present invention, washing incineration of refuse flyash is CaO-FeO- for slag type SiO2The copper pyrometallurgy of ternary system clinker, the CaO in flying dust can improve the fusing point and viscosity of clinker, promote clinker and sulfonium phase Separation, while the SiO in flying dust2, CaO and metal oxide slag making occurs and reacts, into slag phase, to Copper making process and production The copper matte regulus gone out does not impact, and can improve slag viscosity with the basicity of working the slag.In other embodiments of the invention, Washing incineration of refuse flyash can be used for matte smelting and pyro-refining, and the copper pyrometallurgy type of furnace used includes blast furnace, reflection Stove, electric furnace, converter, flash smelting furnace and bath smelting furnace etc..The high temperature generated during Copper making can decompose in flying dust Bioxin achievees the purpose that flying dust detoxifies the study found that degradation rate is up to 99.9%.
Enter the Contents of Main Components of the component content and treating capacity design clinker of stove raw and auxiliary material, meter in being smelted according to copper fire Calculating needs the amount of calcium to be added in slag former, further according to the charge ratio of the content calculation flying dust of the calcium in flying dust, in the present invention In embodiment, the mass ratio of incineration of refuse flyash and copper concentrate is 1~10:100.Preferably, can be 1:100、1:50、3: 100、1:25。
Contain a small amount of heavy metal, such as Zn, Pb, Cu in incineration of refuse flyash, it is harmful to environment, Copper making can be passed through Process enriching and recovering, centralized processing reduce the pollution to environment.Wherein, the heavy metals such as Pb, Zn are volatized into flue dust and are enriched with back It receives, Cu, Ni etc. enter copper matte regulus enriching and recovering, and Mn, Fe, Cr etc. enter slag phase formation Water Quenching Slag and can be used for construction material.
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation provided in an embodiment of the present invention, it is easy to operate, Harmless treatment and the recycling for realizing incineration of refuse flyash, reduce the cost of Copper making, reduce environmental pollution, Ke Yiying For metal smelt.Preferably, metal smelt includes matte smelting and pyro-refining.
The feature and performance of the present invention are described in further detail with reference to embodiments.
Embodiment 1
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation is present embodiments provided, includes mainly following step Suddenly:
The ingredient of certain municipal solid waste incinerator:CaO 32.74%, Al2O31.55%, SiO28.79%, K2O 4.67%, Na2O 4.84%, Cl 14.12%.Above-mentioned incineration of refuse flyash is taken, is washed 1.5 hours under conditions of 20 DEG C, It is 2 hours dry under conditions of 60 DEG C.Winged ash composition after washing:CaO 45.91%, Al2O33.26%, SiO2 14.15%, K2O 0.29%, Na2O 0.41%, Cl 0.46%.
The ingredient for entering stove copper concentrate during copper weld pool is Cu 25.90%, Fe 24.51%, S 33.27%, Zn 6.15%, Pb 2.25%.The amount that flying dust is added in 1 ton of concentrate is 0.01 ton, and (mass ratio of flying dust and copper concentrate is 1:100), exist Melting , bioxin is carried out under conditions of 1200 DEG C decomposes complete, 0.54 ton of clinker of generation.Obtained matte ingredient is:CuS 68.9%, FeS 22.1%.
Embodiment 2
A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation is present embodiments provided, includes mainly following step Suddenly:
The ingredient of certain municipal solid waste incinerator:CaO 32.74%, Al2O31.55%, SiO28.79%, K2O 4.67%, Na2O 4.84%, Cl 14.12%.Above-mentioned incineration of refuse flyash is taken, is washed 0.5 hour under conditions of 30 DEG C, It is 1 hour dry under conditions of 80 DEG C.Winged ash composition after washing:CaO 41.95%, Al2O32.43%, SiO2 14.24%, K2O 0.25%, Na2O 0.40%, Cl 0.42%.
The ingredient for entering stove copper concentrate during copper weld pool is Cu 25.90%, Fe 24.51%, S 33.27%, Zn 6.15%, Pb 2.25%.0.1 ton of flying dust is added in 1 ton of concentrate, and (mass ratio of incineration of refuse flyash and copper concentrate is 1:10), exist Melting , bioxin is carried out under conditions of 1400 DEG C decomposes complete, 0.58 ton of clinker of generation.Obtained matte ingredient is:CuS 68.3%, FeS 23.6%.
Comparative example 1
This comparative example provides a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, includes mainly following step Suddenly:
The ingredient for entering stove copper concentrate during copper weld pool is Cu 25.90%, Fe 24.51%, S 33.27%, Zn 6.15%, Pb 2.25% selects CaO-FeO-SiO2It is clinker and designs main component as CaO 8%, FeO 35%, SiO2 40%.It is incorporated a certain proportion of lime stone and quartz (by copper smelting plant prior art), is melted under conditions of 1300 DEG C Refining generates 0.54 ton of clinker.Obtained matte ingredient is:CuS 69.0%, FeS 23.3%.
By Examples 1 to 2 and comparative example 1 it is found that carrying out melting using the flying dust after washing in embodiment 1, embodiment 2, Comparative example 1 carries out melting, the matte ingredient and stove obtained by the method for embodiment 1 and embodiment 2 using lime stone, quartz Slag content is more close compared with comparative example 1, illustrates that flying dust can substitute lime stone, quartz carries out melting to copper concentrate, and Smelting Effect is close, illustrates that the method for the Copper making treating incinerated fly ash of domestic garbage with cooperation that embodiment 1 and embodiment 2 provide can It goes and effect meets needs.
In conclusion incineration of refuse flyash is used as Copper making slag former by the present invention, instead of lime stone and quartz sand etc., with Copper concentrate mixed smelting, by the high temperature that is generated in fusion process can efficient-decomposition incineration of refuse flyash Zhong bioxin, simultaneously Enriching and recovering heavy metal element therein achievees the purpose that incineration of refuse flyash detoxifies, reduces being processed into for incineration of refuse flyash Originally, copper pyrometallurgy cost, reduces environmental pollution.This method is easy to operate, process cleans, realizes the harmless of incineration of refuse flyash Change processing and recycling, turn waste into wealth, reduces the environmental problem stacked, filled etc. and bring.
Embodiments described above is a part of the embodiment of the present invention, instead of all the embodiments.The reality of the present invention The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of the selected implementation of the present invention Example.Based on the embodiments of the present invention, those of ordinary skill in the art are obtained without creative efforts Every other embodiment, shall fall within the protection scope of the present invention.

Claims (10)

1. a kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation, which is characterized in that including:
Incineration of refuse flyash after washing and drying is mixed with copper concentrate and carries out melting, the incineration of refuse flyash main component packet Include CaO and SiO2, contain bioxin and heavy metal element simultaneously.
2. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that described The mass ratio of incineration of refuse flyash and the copper concentrate is 1~10:100, it is preferable that the incineration of refuse flyash and copper essence The mass ratio of mine is 1~4:100.
3. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that washing Method include:The incineration of refuse flyash is washed 0.5~1.5 hour under conditions of 20~30 DEG C.
4. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 3, which is characterized in that dry Method include:The incineration of refuse flyash after washing is 1~3 hour dry under conditions of 60~80 DEG C.
5. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that washing In the incineration of refuse flyash after drying, the mass percentage of the CaO is 40~50%, it is preferable that the matter of the CaO It is 45~50% to measure percentage composition.
6. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 5, which is characterized in that washing In the incineration of refuse flyash after drying, the SiO2Mass percentage be 10~20%, it is preferable that the SiO2's Mass percentage is 15~20%.
7. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that it is special Sign is that quality percentage of the mass percentage of K less than 0.3%, Na contains in the incineration of refuse flyash after washing and drying Mass percentage of the amount less than 0.5%, Cl is less than 0.6%.
8. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that described Incineration of refuse flyash carries out melting with the copper concentrate under conditions of 1200~1400 DEG C, it is preferable that smelting temperature 1250 ~1350 DEG C.
9. the method for Copper making treating incinerated fly ash of domestic garbage with cooperation according to claim 1, which is characterized in that described Include after incineration of refuse flyash and the copper concentrate melting:Melting by-product (flue dust, slag etc.) is separated and recovered respectively.
10. if the method for claim 1~9 any one of them Copper making treating incinerated fly ash of domestic garbage with cooperation is in metal smelting Application in refining and comprehensive utilization of resources.
CN201810338680.6A 2018-04-16 2018-04-16 A kind of method of Copper making treating incinerated fly ash of domestic garbage with cooperation and application Pending CN108517418A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111635218A (en) * 2020-07-06 2020-09-08 江西理工大学 Sintered brick based on copper smelting waste residues and preparation method thereof
CN113564381A (en) * 2021-07-26 2021-10-29 广东飞南资源利用股份有限公司 Synergistic copper smelting method and building material
CN113667827A (en) * 2021-08-24 2021-11-19 上海康恒环境股份有限公司 Method for co-processing waste incineration fly ash and copper-containing sludge

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101074457A (en) * 2006-05-16 2007-11-21 重庆大学 Method for smelting and separating refuse-combustion fly-ash heavy metal
CN103215441A (en) * 2013-04-19 2013-07-24 首钢总公司 Method for treating grate furnace garbage incineration flyash by using metallurgical sintering process
CN106048237A (en) * 2016-07-06 2016-10-26 中国恩菲工程技术有限公司 Waste incineration fly ash treatment method
CN106048248A (en) * 2016-07-06 2016-10-26 中国恩菲工程技术有限公司 Method for treating waste incineration fly ash

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101074457A (en) * 2006-05-16 2007-11-21 重庆大学 Method for smelting and separating refuse-combustion fly-ash heavy metal
CN103215441A (en) * 2013-04-19 2013-07-24 首钢总公司 Method for treating grate furnace garbage incineration flyash by using metallurgical sintering process
CN106048237A (en) * 2016-07-06 2016-10-26 中国恩菲工程技术有限公司 Waste incineration fly ash treatment method
CN106048248A (en) * 2016-07-06 2016-10-26 中国恩菲工程技术有限公司 Method for treating waste incineration fly ash

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111635218A (en) * 2020-07-06 2020-09-08 江西理工大学 Sintered brick based on copper smelting waste residues and preparation method thereof
CN113564381A (en) * 2021-07-26 2021-10-29 广东飞南资源利用股份有限公司 Synergistic copper smelting method and building material
CN113667827A (en) * 2021-08-24 2021-11-19 上海康恒环境股份有限公司 Method for co-processing waste incineration fly ash and copper-containing sludge

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Application publication date: 20180911