CN108517178B - Environment-friendly UV (ultraviolet) hand-wiping filling coloring paint and preparation method thereof - Google Patents
Environment-friendly UV (ultraviolet) hand-wiping filling coloring paint and preparation method thereof Download PDFInfo
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- CN108517178B CN108517178B CN201810387790.1A CN201810387790A CN108517178B CN 108517178 B CN108517178 B CN 108517178B CN 201810387790 A CN201810387790 A CN 201810387790A CN 108517178 B CN108517178 B CN 108517178B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/06—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2502/00—Acrylic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/02—Inorganic fillers used for pigmentation effect, e.g. metallic effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2602/00—Organic fillers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention provides an environment-friendly UV hand-wiping filling coloring coating which comprises the following components in parts by weight: 15-25 parts of functional monomer; 13-30 parts of aliphatic polyurethane acrylic resin; 25-32 parts of polyether modified polyester acrylic resin; 15-25 parts of pigment and filler; 0.5-5 parts of wetting dispersant; 0.1-1 part of defoaming agent; 4-8 parts of a photoinitiator; wherein the functional monomer is one or a mixture of polyethylene glycol 400 diacrylate and glycerol methoxyl monoacrylate; the photoinitiator is 2-hydroxy-2-methyl-1-phenyl-1-acetone matched with 2,4, 6-trimethylbenzoyl-diphenyl phosphine oxide or phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide. The low-viscosity UV resin is matched with a special UV monomer, a proper amount of filler with higher smoothness and photoinitiators with different wavelengths are added, so that a good construction effect and no stimulation to human skin are achieved, the adhesive force between the low-viscosity UV resin and a base material and the upper paint film is good, the next procedure can be performed after the color wiping is completed, and the construction efficiency is remarkably improved.
Description
Technical Field
The invention belongs to the technical field of UV (ultraviolet) curing coatings, and particularly relates to an environment-friendly UV hand-wiping filling coloring coating and a preparation method thereof.
Background
The furniture industry wants to make a coating effect with transparent color, distinct gradation and strong three-dimensional sense, which is realized by the first degree coloring of materials, and the used coating is filling coloring coating which is commonly called filler. The filling coloring paint used in the industry at present mainly adopts solvent type products, the solvent type products have the disadvantages of large smell, high VOC content, great harm to human health and serious pollution to the atmosphere, the construction efficiency is extremely low, the next procedure can be carried out after the color wiping is finished and the products are placed in the environment of 15-25 ℃ for 12 hours, and the products need to be placed for a longer time due to low temperature in winter. The conventional solvent-based hand-wiping filling coloring paint also has the problem of poor adhesion with an upper layer paint.
Disclosure of Invention
Aiming at the problems of large smell, high VOC (volatile organic compounds) emission, skin irritation, low construction efficiency and poor adhesion of a paint film of the conventional solvent type filling coloring paint, the invention aims to provide the environment-friendly UV hand-wiping filling coloring paint, which adopts low-viscosity UV resin, is matched with a special UV monomer, is added with a proper amount of filler with higher smoothness and photoinitiators with different wavelengths to achieve good construction effect and no irritation to human skin, achieves real environment protection, has good adhesion with a base material and an upper paint film, can enter the next procedure after color wiping is completed, and remarkably improves the construction efficiency.
The invention is realized by the following technical scheme:
the environment-friendly UV hand-wiping filling coloring coating comprises the following components in parts by weight:
wherein the functional monomer is one or a mixture of polyethylene glycol 400 diacrylate and glycerol methoxyl monoacrylate; the photoinitiator is 2-hydroxy-2-methyl-1-phenyl-1-acetone matched with 2,4, 6-trimethylbenzoyl-diphenyl phosphine oxide or phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide.
Further, the mixture is prepared from polyethylene glycol 400 diacrylate and glycerol methoxy monoacrylate according to a ratio of 4: (1-5) in terms of mass ratio.
Further, the mixture consists of polyethylene glycol 400 diacrylate and glycerol methoxy monoacrylate in a mass ratio of 3: 2.
The polyethylene glycol 400 diacrylate belongs to a macromolecular active monomer, has high curing speed and good flexibility, but has large viscosity, and the glycerol methoxyl monoacrylate has low viscosity, good diluting capacity and low drying speed, is mixed according to the proportion, can ensure the curing speed and also can provide proper viscosity, thus not only reaching the physical property of a paint film, but also ensuring better construction wiping performance.
Further, the proportion of 2-hydroxy-2-methyl-1-phenyl-1-acetone in the photoinitiator is 85-93 wt%.
Further, the photoinitiator is selected from at least one of 2-hydroxy-2-methyl-1-phenyl-1-acetone, 2,4, 6-trimethylbenzoyl-diphenyl phosphine oxide and phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide. 2-hydroxy-2-methyl-1-phenyl-1-propanone, e.g. the double bond company 1173; 2,4, 6-trimethylbenzoyl-diphenylphosphine oxide, such as GR-TPO from the firm Rou of Hubei; phenylbis (2,4, 6-trimethylbenzoyl) phosphine oxide, such as 819 from Ciba.
Furthermore, the pigment filler is talcum powder, wax powder and gas-phase silica, and the mass ratio of the talcum powder to the wax powder to the gas-phase silica is 30:1: 2.
The preparation method of the environment-friendly UV hand-wiping filling coloring coating comprises the steps of mixing and stirring functional monomers, aliphatic urethane acrylic resin, polyether modified polyester acrylic resin, photoinitiator 2,4, 6-trimethylbenzoyl-diphenylphosphine oxide, a defoaming agent, a wetting dispersant, talcum powder, wax powder and fumed silica, adding the photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone after fully dispersing, and stirring until the mixture is fully dispersed uniformly without hard blocks.
According to the coating method for filling the environment-friendly UV hand wiping coloring coating, the oily color concentrates are uniformly dispersed in the coating and are uniformly coated on the coating by using the brushWiping the surface of the wood by using a rag, wherein the coating weight is 20-40 g/square meter, and then carrying out ultraviolet curing; semi-curing ultraviolet energy: 800 to 120mj/cm2。
Has the advantages that: the environment-friendly UV hand-wiping filling coloring coating provided by the invention has the advantages that (1) the odor is low, the skin is not irritated, and the environment is protected; (2) the adhesive force between the paint film and the base material and the upper paint film is good; (3) the curing is fast, the next procedure can be carried out after the color wiping is finished, and the construction efficiency is obviously improved; (4) the preparation method is simple.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
The aliphatic polyurethane acrylate adopted in the following examples is a product with Shenzhenjikaifu brand CF-3301; the polyether modified polyester acrylate is a product with the Jiangxi KunLongbrand number of HM-326; the wetting dispersant is a BYK-2009 product from Bike company; the defoaming agent is a product with the brand number of TEGO920 of winning companies. The photoinitiator was selected from the group consisting of 1173 from double bond company, GR-TPO from Hubei Gurun company, 819 from Ciba company. KB-13-1 from Talc powder K brand
Example 1
15 kg of polyethylene glycol 400 diacrylate (PEG400DA), 13 kg of aliphatic urethane acrylic resin, 30 kg of polyether modified polyester acrylic resin, 0.5 kg of trimethyl benzoyl-diphenyl phosphine oxide as a photoinitiator, 0.1 kg of a defoaming agent (TEGO920), 0.5 kg of a wetting dispersant, 15 kg of talcum powder, 1 kg of wax powder and 2 kg of fumed silica, mixing and stirring, after full dispersion, adding 5 kg of 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) as a photoinitiator, and stirring until the mixture is fully dispersed uniformly without hard blocks. The experimental results for this example are: the product has basically moderate viscosity, moderate hardness of paint film, deep curing effect and good wiping performance.
Example 2
25 kg of functional monomer glycerol methoxy monoacrylate (TPGMEMA), 28 kg of aliphatic urethane acrylic resin, 32 kg of polyether modified polyester acrylic resin, 0.5 kg of photoinitiator phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide (819), 0.1 kg of defoaming agent, 1 kg of dispersing agent, 15 kg of talcum powder, 0.5 kg of wax powder and 1 kg of fumed silica are mixed and stirred, 7 kg of photoinitiator phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide is added after full dispersion, and the mixture is stirred and fully dispersed uniformly without hard blocks. The experimental results for this example are: the product has basically moderate viscosity, moderate film hardness, deep curing effect and good wiping performance.
Example 3
Taking 15 kg of functional monomer polyethylene glycol 400 diacrylate (PEG400DA), 5 kg of glycerol methoxy monoacrylate (TPGMEMA), 20 kg of aliphatic urethane acrylic resin, 25 kg of polyether modified polyester acrylic resin, 0.5 kg of phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide (819), 0.1 kg of defoaming agent, 1 kg of dispersing agent, 15 kg of KB-121 talcum powder, 0.5 kg of wax powder and 1 kg of fumed silica, mixing and stirring, adding 5 kg of photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) after full dispersion, and stirring and fully dispersing uniformly without hard blocks. The experimental results for this example are: the product has basically moderate viscosity, moderate hardness of paint film, deep curing effect and good wiping performance.
Example 4
Taking 15 kg of functional monomer polyethylene glycol 400 diacrylate (PEG400DA), 10 kg of glycerol methoxy monoacrylate (TPGMEMA), 15 kg of aliphatic urethane acrylic resin, 25 kg of polyether modified polyester acrylic resin, 0.5 kg of phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide (819), 0.1 kg of defoaming agent, 1 kg of dispersing agent, 15 kg of talcum powder, 0.5 kg of wax powder and 1 kg of fumed silica, mixing and stirring, adding 5 kg of photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) after full dispersion, and stirring and fully dispersing uniformly without hard blocks. The experimental results for this example are: the product has basically moderate viscosity, moderate hardness of paint film, deep curing effect and good wiping performance.
Example 5
Taking 15 kg of functional monomer polyethylene glycol 400 diacrylate (PEG400DA), 10 kg of glycerol methoxy monoacrylate (TPGMEMA), 13 kg of aliphatic urethane acrylic resin (CF-3301), 28 kg of polyether modified polyester acrylic resin (HM-326), 0.5 kg of photoinitiator phenyl bis (2,4, 6-trimethylbenzoyl) phosphine oxide (819), 0.1 kg of defoaming agent, 1 kg of dispersing agent, 15 kg of talcum powder, 1 kg of wax powder and 1 kg of fumed silica, mixing and stirring, adding 5 kg of photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone (1173) after full dispersion, and stirring and fully dispersing uniformly without hard blocks. The experimental results for this example are: the product has moderate viscosity, moderate hardness of a paint film, good deep curing effect, good wiping performance and best overall performance.
The environment-friendly UV hand-wiping filling coloring coating is milky semitransparent jelly-like liquid, has the viscosity of 110-120 k mu (30 ℃), has the solid content of 98.5-99 wt% of the paint, and has extremely low odor. The storage stability (50 ℃/7d) of the product is tested, and the result is no abnormity.
When coating, adding a proper amount of oily color concentrate, dispersing the product, uniformly coating the product on the surface of wood by using a brush, wiping the wood by using a wiping cloth, wherein the coating amount is 20-40 g/square meter, and then carrying out ultraviolet curing. Semi-curing ultraviolet energy: 80-120 MJ/cm2. Through testing, the adhesive force (the space between every two adjacent grids is 2mm) is less than or equal to grade 1. And when the room temperature is lower than 10 ℃, heating the concrete to 20-35 ℃ by adopting a water bath, and then constructing. And after the color wiping is finished, ultraviolet light curing is carried out, and then the coating of the UV spraying primer is directly carried out.
The environment-friendly UV hand-wiping filling coloring paint has the characteristics of good coating effect, extremely low smell, high production efficiency and no human skin irritation.
The above-mentioned embodiments are merely illustrative of the preferred embodiments of the present invention, and do not limit the scope of the present invention, and various modifications and improvements made to the technical solution of the present invention by those skilled in the art without departing from the spirit of the present invention shall fall within the protection scope defined by the claims of the present invention.
Claims (6)
1. The environment-friendly UV hand-wiping filling coloring coating is characterized by comprising the following components in parts by weight:
wherein the functional monomer is one or a mixture of polyethylene glycol 400 diacrylate and glycerol methoxyl monoacrylate; the mixture is prepared from polyethylene glycol 400 diacrylate and glycerol methoxy monoacrylate according to a weight ratio of 4: (1-5) mass ratio; the photoinitiator is 2-hydroxy-2-methyl-1-phenyl-1-acetone matched with 2,4, 6-trimethylbenzoyl-diphenyl phosphine oxide; the pigment and filler is talcum powder, wax powder and gas-phase silicon dioxide.
2. The coating according to claim 1, characterized in that said mixture consists of polyethylene glycol 400 diacrylate and glycerol methoxy monoacrylate in a mass ratio of 3: 2.
3. The coating of claim 1, wherein the photoinitiator comprises 2-hydroxy-2-methyl-1-phenyl-1-propanone in an amount of 85-93 wt%.
4. The paint as claimed in claim 1, wherein the mass ratio of the talcum powder, the wax powder and the fumed silica in the pigment and filler is 30:1: 2.
5. The method for preparing environment-friendly UV hand-wiping filling coloring paint according to any one of claims 1-4, characterized in that functional monomer, aliphatic urethane acrylic resin, polyether modified polyester acrylic resin, photoinitiator 2,4, 6-trimethylbenzoyl-diphenylphosphine oxide, defoaming agent, wetting dispersant, talcum powder, wax powder and fumed silica are mixed and stirred, fully dispersed, added with photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone, and stirred until fully dispersed uniformly without hard blocks.
6. The coating method of the environment-friendly UV hand-wiping filling coloring paint according to any one of claims 1 to 4, characterized in that the oily color concentrate is uniformly dispersed in the paint, uniformly coated on the surface of the wood by a brush, and wiped clean by a rag, wherein the coating weight is 20-40 g/m2Then ultraviolet light curing is carried out; semi-curing ultraviolet energy: 80-120 MJ/cm2。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810387790.1A CN108517178B (en) | 2018-04-26 | 2018-04-26 | Environment-friendly UV (ultraviolet) hand-wiping filling coloring paint and preparation method thereof |
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| CN201810387790.1A CN108517178B (en) | 2018-04-26 | 2018-04-26 | Environment-friendly UV (ultraviolet) hand-wiping filling coloring paint and preparation method thereof |
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| CN108517178A CN108517178A (en) | 2018-09-11 |
| CN108517178B true CN108517178B (en) | 2020-05-12 |
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Families Citing this family (2)
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| CN110256905B (en) * | 2019-06-13 | 2022-06-21 | 东莞大宝化工制品有限公司 | Filling type UV coloring agent and preparation method thereof |
| CN116063918B (en) * | 2022-11-24 | 2024-01-30 | 长沙广欣新材料科技有限公司 | Excimer skin-feel UV coating and preparation method and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080001259A (en) * | 2006-06-29 | 2008-01-03 | 주식회사 옴니켐 | A coating composition for preventing electrification, an antistatic triacetyl cellulose film thus prepared and a method for preparing the same |
| CN101153127A (en) * | 2007-09-06 | 2008-04-02 | 湖南阳光新材料有限公司 | White composition capable of solidifying by ultraviolet light |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| CN103589295A (en) * | 2013-10-24 | 2014-02-19 | 惠州市长润发涂料有限公司 | Leveling-free ultraviolet curing primer |
| KR20140074505A (en) * | 2012-12-10 | 2014-06-18 | 건설화학공업주식회사 | UV-Curable Coating Composition of High-Elongation |
| CN104073040A (en) * | 2014-07-15 | 2014-10-01 | 苏州市明大高分子科技材料有限公司 | UV-cured white curtaining paint and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060088674A1 (en) * | 2004-10-27 | 2006-04-27 | Hladik Molly L | Ultraviolet curable barrier layers |
-
2018
- 2018-04-26 CN CN201810387790.1A patent/CN108517178B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080001259A (en) * | 2006-06-29 | 2008-01-03 | 주식회사 옴니켐 | A coating composition for preventing electrification, an antistatic triacetyl cellulose film thus prepared and a method for preparing the same |
| CN101153127A (en) * | 2007-09-06 | 2008-04-02 | 湖南阳光新材料有限公司 | White composition capable of solidifying by ultraviolet light |
| CN102153899A (en) * | 2011-01-28 | 2011-08-17 | 创兴精细化学(上海)有限公司 | Ultraviolet-curable water-based colored paint composition |
| KR20140074505A (en) * | 2012-12-10 | 2014-06-18 | 건설화학공업주식회사 | UV-Curable Coating Composition of High-Elongation |
| CN103589295A (en) * | 2013-10-24 | 2014-02-19 | 惠州市长润发涂料有限公司 | Leveling-free ultraviolet curing primer |
| CN104073040A (en) * | 2014-07-15 | 2014-10-01 | 苏州市明大高分子科技材料有限公司 | UV-cured white curtaining paint and preparation method thereof |
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