CN108515185A - Graphene coated flake metal powder material and preparation method thereof - Google Patents
Graphene coated flake metal powder material and preparation method thereof Download PDFInfo
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- CN108515185A CN108515185A CN201810382873.1A CN201810382873A CN108515185A CN 108515185 A CN108515185 A CN 108515185A CN 201810382873 A CN201810382873 A CN 201810382873A CN 108515185 A CN108515185 A CN 108515185A
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- metal powder
- graphene
- graphene oxide
- oxide
- flake metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/06—Metallic powder characterised by the shape of the particles
- B22F1/068—Flake-like particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/16—Metallic particles coated with a non-metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
- B22F2009/042—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling using a particular milling fluid
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses a kind of graphene coated flake metal powder materials and preparation method thereof, belong to metal powder material preparation and surface modification technologies field.Spherical metal powder, graphite oxide or graphene oxide composite material, auxiliary agent, solvent and abrasive media are added in ball mill according to a certain ratio first, ball milling 3~18 hours under 20~200 revs/min of rotational speed of ball-mill, then slurry is taken out and is detached, drying and classification processing, obtain the scaled metal powder body material of graphene coated.After mediating reduction moditied processing to material, the lipophilic graphene scaled metal powder body material of different hydrophilic can be obtained.Graphene is used as the surface capping agents of scaled metal powder body material by the present invention, solves the conductivity issues of dispersion problem and covering of the graphene in coating, simple for process, efficient, product stability is good, suitable industrialized production.
Description
Technical field
The present invention relates to the preparation field of Metal Substrate color stuffing more particularly to a kind of graphene coated flake metal powder materials
Material and preparation method thereof.
Background technology
Graphene is a kind of new material being concerned in recent years, and graphene since shielding is good, lead by large specific surface area
It is electrically good, the corrosion resistance of coating can be effectively improved as additive, and there is wide application in metal anti-corrosive paint field
Foreground receives the concern of researcher.Application No. is the patents of 201510497999.X to disclose a kind of two-component graphene
The formula of anticorrosive paint, the formula can substantially reduce the thickness of coating paint film, improve anti-corrosion effect, while reducing zinc powder
Dosage.Application No. is 201510203553.1 patent disclose a kind of anticorrosive coating that nano-graphene fragment is modified and its
Preparation method, the anticorrosive paint that 0.1~20% nano-graphene fragment is added have good anticorrosion effect.When by graphite
When in alkene and zinc powder common modulation to zinc-rich paint, graphene is in addition to playing the role of obstructing corrosive medium intrusion steel substrate
Outside, moreover it is possible to the cathodic protection of zinc powder be promoted to act on.But it modulates when by the spherical zinc powder of zinc flake replacement and graphene and to form richness
When spelter coating, due to the grease insulating effect on zinc flake surface, graphene can not play effective conductive communication effect, made
Standby coating is still based on bridging effect, it is difficult to play the role of the double protection effect of masking and cathodic protection.In addition to this,
Scattering problem, interface problem etc. of the graphene in coating are also the technical barrier for hindering graphene to be modified zinc-rich paint exploitation.
Invention content
Based on the problems of prior art, the object of the present invention is to provide a kind of graphene coated flake metal powders
Material and preparation method thereof, the metal powder material are modulated into the anticorrosion effect that coating can be effectively improved after corrosion-inhibiting coating.
The purpose of the present invention is what is be achieved through the following technical solutions：
Embodiment of the present invention provides a kind of graphene coated flake metal powder material, which set in grinding
The flake metal powder material of ground manufactured flake metal powder surface clad surface protective layer in standby, wherein the surface
Protective layer is the graphene oxide of graphene oxide or composite assistant.
Embodiment of the present invention also provides a kind of preparation method of graphene coated flake metal powder material, is used to prepare
Graphene coated flake metal powder material of the present invention, including：
Any one of graphite oxide material or graphene oxide composite material and spherical metal powder, solvent and abrasive media are pressed
Ratio is added in milling apparatus, is ground 3~18 hours under 20~200 revs/min of rotating speed and is obtained slurry, then by the material
It starches and takes out, drying and classification are handled to get being graphene oxide or the graphene oxide packet of composite assistant to surface protecting layer
The flake metal powder material covered.
As seen from the above technical solution provided by the invention, graphene coated flakey provided in an embodiment of the present invention
Metal powder material and preparation method thereof, advantage are：
Due to the graphene layer in graphite oxide contain can with metal occur bonding action carboxyl functional group.When will aoxidize
Graphite and spherical metal powder are modulated to when preparing flake metal powder under grinding condition together, high shear of the graphite oxide in ball milling
It can be removed under the action of power and form the single-layer graphene oxide containing a large amount of carboxyl functional groups, carboxyl functional group energy and spherical metal
Powder be calendered to flake metal powder formation fresh metal face combine form bonding action, to from generate pinning effect, firmly according to
It is attached to flake metal powder surface, one layer of stable protective film, the as surface protecting layer of flake metal powder is formed, can effectively carry
The stability of high flake metal powder material.Simultaneously because graphene oxide is pinned at flake metal powder table by bonding action
Oxidation stone may be implemented the shortcomings that avoiding later stage difficulty dispersion when flake metal powder is modulated in zinc-rich paint, easily reunite in face
The cathodic protection of the composite highly effective shadowing effect of black alkene and flake metal powder, the conductive effect of graphene and scaled metal powder is imitated
It answers multiple-effect to unify, coating corrosion resistance is enable to be substantially improved, novel high-performance gold is provided for a new generation's anticorrosive paint
Belong to base color stuffing.
Specific implementation mode
With reference to the particular content of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts,
Belong to protection scope of the present invention.The content not being described in detail in the embodiment of the present invention belongs to professional and technical personnel in the field
The well known prior art.
The embodiment of the present invention provides a kind of graphene coated flake metal powder material, which is in milling apparatus
In it is ground made of flake metal powder surface clad surface protective layer flake metal powder material, wherein the surface is anti-
Sheath is the graphene oxide of graphene oxide or composite assistant.
In above-mentioned sheet metal powder material, graphene oxide is the graphene oxide containing carboxyl functional group.
In above-mentioned sheet metal powder material, auxiliary agent includes：It is polysiloxane polyether copolymer, aliphatic acid, polyether-modified poly-
It is one or more in dimethyl siloxane, fatty acid zinc, silicone oil.
In above-mentioned sheet metal powder material, metal powder includes：Zinc powder, aluminium powder, Zinc-tin alloy powder, zinc aluminium alloy powder, copper
Zinc alloy powder any one or more of.
Above-mentioned sheet metal powder material is：Dry powder, or the creamy material containing 5~50wt.% solvents or slurry material.
The solvent uses：One in n-butyl acetate, ethyl acetate, n-butanol, ethyl alcohol, propyl alcohol, solvent naphtha, acetone, benzene, dimethylbenzene
Kind is a variety of.
The embodiment of the present invention provides a kind of preparation method of graphene coated flake metal powder material, is used to prepare above-mentioned
Graphene coated flake metal powder material, including：
Any one of graphite oxide material or graphene oxide composite material and spherical metal powder, solvent and abrasive media are pressed
Ratio is added in milling apparatus (preferably using ball mill), is ground 3~18 hours and is obtained under 20~200 revs/min of rotating speed
Then slurry takes out the slurry, drying and classification processing are to get being graphene oxide to surface protecting layer or compound help
The flake metal powder material of the graphene oxide cladding of agent.
In above-mentioned preparation method, any one of the graphite oxide material or graphene oxide composite material are：Graphite oxide,
The graphite oxide of composite assistant, any one of the graphene oxide of graphene oxide, composite assistant；
It is any one of the graphite oxide being added in ball mill or graphene oxide composite material and spherical metal powder, molten
The ratio of agent and abrasive media is：
When the graphite oxide material uses graphene oxide using graphite oxide or the graphene oxide composite material, institute
It states graphite oxide or graphene oxide accounts for 0.1~10wt.% of the spherical metal powder quality；
The graphite oxide material is helped using the graphite oxide or the graphene oxide composite material of composite assistant using compound
When the graphene oxide of agent, the graphite oxide or graphene oxide account for 0.1~10wt.% of the spherical metal powder quality,
The auxiliary agent accounts for 0.1~10wt.% of the spherical metal powder quality；The mass ratio of the solvent and the spherical metal powder is
0.1~5；The mass ratio of the abrasive media and the spherical metal powder is 2~30.
In above-mentioned preparation method, the graphene oxide cladding that surface protecting layer is graphene oxide or composite assistant is made
Flake metal powder material is：Dry powder, or the creamy material containing 5~50wt.% solvents or slurry material.
In above-mentioned preparation method, the solvent uses：N-butyl acetate, ethyl acetate, n-butanol, ethyl alcohol, propyl alcohol, solvent
It is one or more in oil, acetone, benzene, dimethylbenzene.
The present invention is a kind of surface treatment method of metal color stuffing, can realize and prepare the metal as metal color stuffing
Its surface treatment can be completed during powder material, directly use graphene oxide as cladding raw material, the few, method with step
Simply, product good conductivity, it is easy to accomplish the advantages that prepare with scale.The metal powder material is modulated into after corrosion-inhibiting coating can be with
The anticorrosion effect of coating is effectively improved, there is good commercial value and application prospect.
The embodiment of the present invention is specifically described in further detail below.
The embodiment of the present invention provides a kind of preparation method of graphene coated flake metal powder material, and concrete operations are such as
Under：
Spherical metal powder, graphite oxide, auxiliary agent, solvent and abrasive media are added in ball mill according to a certain ratio,
It is ground under 20~200 revs/min of rotational speed of ball-mill 3~18 hours, then slurry is taken out and is detached, drying and classification processing obtain
The flake metal powder material of graphene oxide cladding.To the graphene oxide cladding sheet metal powder material through mediating
After surface reduction moditied processing, the lipophilic graphene coated flake metal powder material of different hydrophilic can be obtained.
Above-mentioned graphene coated flake metal powder material refers to the surface protecting layer that zinc flake is served as by graphene,
Or the surface protecting layer of zinc flake is served as by the compound auxiliary agent of graphene.
Above-mentioned metal powder includes zinc powder, aluminium powder, Zinc-tin alloy powder, zinc aluminium alloy powder, one kind of cu-zn alloy powder or more
Kind.
Above-mentioned solvent includes n-butyl acetate, ethyl acetate, n-butanol, ethyl alcohol, propyl alcohol, solvent naphtha, acetone, benzene, two
It is one or more in toluene.
Above-mentioned certain proportioning refers to 0.1~10wt.% that the graphite oxide accounts for the metal powder quality.
Above-mentioned auxiliary agent accounts for 0~10wt.% of the metal powder quality.
Above-mentioned graphene coated flake metal powder material be paste or slurry material containing 5~50wt.% solvents,
Can also be the dry powder after drying.
In the above-mentioned methods, the graphene layer in graphene oxide contains the carboxyl-functional that bonding action can occur with metal
Group.When graphite oxide and metal powder are modulated to prepare flake metal powder under grinding condition together when, graphite oxide is cut in height
It can be removed under the action of shear force and form the graphene oxide containing a large amount of carboxyl functional groups, carboxyl functional group can be with metal powder calendering
The fresh metal face of formation combines and forms bonding action, to from pinning effect is generated, firmly be attached to flake metal powder surface,
One layer of stable protective film is formed, the stability of flake metal powder material is can effectively improve.Simultaneously because graphene oxide
It is pinned at flake metal powder surface by bonding action, avoids later stage difficulty point when flake metal powder is modulated in zinc-rich paint
The shortcomings that dissipating, easily reuniting, may be implemented the composite highly effective shadowing effect of graphene and flake metal powder, the conductive effect of graphene
Unify with the cathodic protection effect multiple-effect of scaled metal powder, coating corrosion resistance is enable to be substantially improved, for a new generation's weight
Anticorrosive paint provides novel high-performance zinc-base color stuffing.
Embodiment 1：
The present embodiment provides a kind of preparation methods of graphene coated flake zinc powder, specifically include：
The mill ball of 10kg spherical shapes zinc powder, 0.08kg graphite oxides, 0.4kg stearic acid, 30L ethyl alcohol and 150kg are added
Into ball mill, is ground under 70 revs/min of rotational speed of ball-mill 10 hours, grinding is then obtained into slurry and takes out separation, after separation
Sheet metal cream drying and classification processing, obtain the flake zinc powder material of graphene oxide cladding.
Embodiment 2：
The present embodiment provides a kind of preparation method of graphene coated flake zinc slurry, this method specifically includes：
The zirconia ball of 10kg atomizing aluminium powders, 0.15kg graphite oxides, 30L solvent naphthas and 150kg are added to ball mill
In, grind 10 hours under 70 revs/min of rotational speed of ball-mill, then slurry taken out and is detached, to separation after be added in obtained aluminium paste
0.5kg vitamin Cs after fully mediating 3h, obtain the flakey aluminium powder body slurry material of graphene oxide cladding.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in,
It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims
Subject to enclosing.
Claims (10)
1. a kind of graphene coated flake metal powder material, which is characterized in that the powder body material is in milling apparatus through grinding
The flake metal powder material for the flake metal powder surface clad surface protective layer being milled into, wherein the surface protecting layer is
The graphene oxide of graphene oxide or composite assistant.
2. graphene coated flake metal powder material according to claim 1, which is characterized in that the graphene oxide
For the graphene oxide containing carboxyl functional group.
3. graphene coated flake metal powder material according to claim 1 or 2, which is characterized in that the auxiliary agent packet
It includes：Polysiloxane polyether copolymer, aliphatic acid, polyether-modified dimethyl silicone polymer, fatty acid zinc, one kind in silicone oil or more
Kind.
4. graphene coated flake metal powder material according to claim 1 or 2, which is characterized in that the metal powder
Including：Zinc powder, aluminium powder, Zinc-tin alloy powder, zinc aluminium alloy powder, cu-zn alloy powder any one or more of.
5. graphene coated flake metal powder material according to claim 1 or 2, which is characterized in that the lamellar gold
Belonging to powder body material is：Dry powder, or the creamy material containing 5~50wt.% solvents or slurry material.
6. graphene coated flake metal powder material according to claim 5, which is characterized in that the solvent uses：
It is one or more in n-butyl acetate, ethyl acetate, n-butanol, ethyl alcohol, propyl alcohol, solvent naphtha, acetone, benzene, dimethylbenzene.
7. a kind of preparation method of graphene coated flake metal powder material, which is characterized in that be used to prepare claim 1 to
4 any one of them graphene coated flake metal powder materials, including：
In proportion with spherical metal powder, solvent and abrasive media by any one of graphite oxide material or graphene oxide composite material
It is added in milling apparatus, is ground 3~18 hours under 20~200 revs/min of rotating speed and obtain slurry, then take the slurry
Go out, drying and classification are handled to get being the graphene oxide of graphene oxide or composite assistant cladding to surface protecting layer
Flake metal powder material.
8. the preparation method of graphene coated flake metal powder material according to claim 7, which is characterized in that described
In method, any one of the graphite oxide material or graphene oxide composite material are：The oxidation stone of graphite oxide, composite assistant
Any one of the graphene oxide of ink, graphene oxide, composite assistant；
Any one of the graphite oxide being added in ball mill or graphene oxide composite material and spherical metal powder, solvent and
The ratio of abrasive media is：
When the graphite oxide material uses graphene oxide using graphite oxide or the graphene oxide composite material, the oxygen
Graphite or graphene oxide account for 0.1~10wt.% of the spherical metal powder quality；
The graphite oxide material is using the graphite oxide or the graphene oxide composite material of composite assistant using composite assistant
When graphene oxide, the graphite oxide or graphene oxide account for 0.1~10wt.% of the spherical metal powder quality, described
Auxiliary agent accounts for 0.1~10wt.% of the spherical metal powder quality；The mass ratio of the solvent and the spherical metal powder is 0.1
~5；The mass ratio of the abrasive media and the spherical metal powder is 2~30.
9. the preparation method of graphene coated flake metal powder material according to claim 7 or 8, which is characterized in that
In the method, the flake metal powder for the graphene oxide cladding that surface protecting layer is graphene oxide or composite assistant is made
Material is：Dry powder, or the creamy material containing 5~50wt.% solvents or slurry material.
10. the preparation method of graphene coated flake metal powder material according to claim 7 or 8, which is characterized in that
The solvent uses：One in n-butyl acetate, ethyl acetate, n-butanol, ethyl alcohol, propyl alcohol, solvent naphtha, acetone, benzene, dimethylbenzene
Kind is a variety of.
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| CN201810382873.1A CN108515185A (en) | 2018-04-25 | 2018-04-25 | Graphene coated flake metal powder material and preparation method thereof |
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| CN201810382873.1A CN108515185A (en) | 2018-04-25 | 2018-04-25 | Graphene coated flake metal powder material and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109065213A (en) * | 2018-06-29 | 2018-12-21 | 北京梦之墨科技有限公司 | A kind of room temperature self-curing conducting pigment and preparation method thereof, store method |
| CN109836986A (en) * | 2018-12-29 | 2019-06-04 | 江苏冠军科技集团股份有限公司 | One kind is based on modified corrosion resistance coating of watersoluble plumbago alkene multicomponent alloy and preparation method thereof |
| CN109852220A (en) * | 2019-01-08 | 2019-06-07 | 徐州易尚饰家装饰工程有限责任公司 | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method |
| CN110157950A (en) * | 2019-06-28 | 2019-08-23 | 江西理工大学 | A kind of zinc-base medical material and preparation method thereof of redox graphene enhancing |
| CN115491056A (en) * | 2022-10-08 | 2022-12-20 | 刘东北 | Water-based paint and preparation method thereof |
| CN115895390A (en) * | 2022-11-22 | 2023-04-04 | 浙江绿环新材料科技有限公司 | Preparation process of composite graphene anticorrosive powder coating |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999058274A1 (en) * | 1998-05-08 | 1999-11-18 | Savin Roland R | Modification of metallic particles |
| CN104070162A (en) * | 2014-07-11 | 2014-10-01 | 北方工业大学 | Surface modification preparation method of flaky metal powder. |
| CN104711443A (en) * | 2015-03-18 | 2015-06-17 | 上海和伍新材料科技有限公司 | Graphene/copper composite and preparation method thereof |
| EP2964574A1 (en) * | 2013-03-08 | 2016-01-13 | Garmor, Inc. | Large scale oxidized graphene production for industrial applications |
| CN105821227A (en) * | 2016-06-01 | 2016-08-03 | 哈尔滨理工大学 | Method for preparing graphene reinforced copper base composite material |
| CN106513694A (en) * | 2016-12-14 | 2017-03-22 | 中国航空工业集团公司北京航空材料研究院 | Preparation method of graphene/ metal composite powder |
| CN107460423A (en) * | 2017-08-15 | 2017-12-12 | 常州市碳索新材料科技有限公司 | A kind of preparation method of graphene/metal composite conductive coating |
| CN107598175A (en) * | 2017-07-27 | 2018-01-19 | 中国航发北京航空材料研究院 | A kind of graphene and titanium alloy composite powder ball-milling preparation method |
-
2018
- 2018-04-25 CN CN201810382873.1A patent/CN108515185A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999058274A1 (en) * | 1998-05-08 | 1999-11-18 | Savin Roland R | Modification of metallic particles |
| EP2964574A1 (en) * | 2013-03-08 | 2016-01-13 | Garmor, Inc. | Large scale oxidized graphene production for industrial applications |
| CN104070162A (en) * | 2014-07-11 | 2014-10-01 | 北方工业大学 | Surface modification preparation method of flaky metal powder. |
| CN104711443A (en) * | 2015-03-18 | 2015-06-17 | 上海和伍新材料科技有限公司 | Graphene/copper composite and preparation method thereof |
| CN105821227A (en) * | 2016-06-01 | 2016-08-03 | 哈尔滨理工大学 | Method for preparing graphene reinforced copper base composite material |
| CN106513694A (en) * | 2016-12-14 | 2017-03-22 | 中国航空工业集团公司北京航空材料研究院 | Preparation method of graphene/ metal composite powder |
| CN107598175A (en) * | 2017-07-27 | 2018-01-19 | 中国航发北京航空材料研究院 | A kind of graphene and titanium alloy composite powder ball-milling preparation method |
| CN107460423A (en) * | 2017-08-15 | 2017-12-12 | 常州市碳索新材料科技有限公司 | A kind of preparation method of graphene/metal composite conductive coating |
Non-Patent Citations (2)
| Title |
|---|
| CHIH-CHIA CHENA 等: "Microwave absorbing properties of flake-shaped carbonyl iron/reduced", 《MATERIALS RESEARCH BULLETIN》 * |
| 洪起虎等: "氧化石墨烯/铜基复合材料的微观结构及力学性能", 《材料工程》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109065213A (en) * | 2018-06-29 | 2018-12-21 | 北京梦之墨科技有限公司 | A kind of room temperature self-curing conducting pigment and preparation method thereof, store method |
| CN109065213B (en) * | 2018-06-29 | 2019-12-10 | 北京梦之墨科技有限公司 | room-temperature self-curing conductive pigment and preparation method and storage method thereof |
| CN109836986A (en) * | 2018-12-29 | 2019-06-04 | 江苏冠军科技集团股份有限公司 | One kind is based on modified corrosion resistance coating of watersoluble plumbago alkene multicomponent alloy and preparation method thereof |
| CN109852220A (en) * | 2019-01-08 | 2019-06-07 | 徐州易尚饰家装饰工程有限责任公司 | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method |
| CN110157950A (en) * | 2019-06-28 | 2019-08-23 | 江西理工大学 | A kind of zinc-base medical material and preparation method thereof of redox graphene enhancing |
| CN115491056A (en) * | 2022-10-08 | 2022-12-20 | 刘东北 | Water-based paint and preparation method thereof |
| CN115895390A (en) * | 2022-11-22 | 2023-04-04 | 浙江绿环新材料科技有限公司 | Preparation process of composite graphene anticorrosive powder coating |
| CN115895390B (en) * | 2022-11-22 | 2024-01-30 | 浙江绿环新材料科技有限公司 | Preparation process of composite graphene anticorrosive powder coating |
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Application publication date: 20180911 |