CN104327680A - Method for preparing corrosion-resistant antibacterial epoxy coating - Google Patents
Method for preparing corrosion-resistant antibacterial epoxy coating Download PDFInfo
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- CN104327680A CN104327680A CN201410703643.2A CN201410703643A CN104327680A CN 104327680 A CN104327680 A CN 104327680A CN 201410703643 A CN201410703643 A CN 201410703643A CN 104327680 A CN104327680 A CN 104327680A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a method for preparing a corrosion-resistant antibacterial epoxy coating. The method comprises the following steps: (1) respectively weighing 15-23 percent of deionized water, 30-40 percent of bisphenol A epoxy resin, 8-15 percent of phenolic amine, 5-10 percent of antibacterial modified resin and nano silicon solution with the mass ratio of 30 to 1, 5-10 percent of polyurethane, 10-18 percent of nitrile butadiene rubber, 0.5-0.9 percent of dispersing agent, 0.4-0.8 percent of defoaming agent and 0.4-0.8 percent of preservative, and dispersing and stirring, thereby obtaining a mixture; and (2) adding 10-17 percent of highly wear-resistant flake pigment and filler and 0.2-0.5 percent of flatting agent to into the mixture, and dispersing and stirring in a dispersing tank at a rotating speed of 1000-1500 revolutions per minute for 10-15 minutes. According to the method disclosed by the invention, the corrosion-resistant antibacterial epoxy coating with the advantages of good corrosion-resistant performance, high impact resistance, high toughness and good antibacterial performance can be prepared.
Description
Technical field
The present invention relates to the preparation method of epoxy anticorrosion antibiotic paint.
Background technology
The effect of protective system mainly contains three kinds: the shielding effect of paint film and sheet material pigment, alkalescence or the Low corrison effect of oxidisability pigment and the electro-chemical protection of zinc powder.Wherein, can the shielding effect that the corrosive mediums such as water, oxygen and ion are isolated is the most key.Heavy-duty Coatings In Ocean Chemical Industry conventional mostly at present is solvent based coating.In its film process, the pin hole that solvent evaporates stays, can make corrosive medium ooze and cause corrosion to film.Gained corrosion product expands and racks coating, corrosive medium is spread, makes coating fall in flakes lose efficacy eventually.In addition, for the dope layer of special occasions, require that it is shock-resistant, resistance to elevated temperatures will could meet the demands well, meanwhile, the toughness of paint film is better, then be more not easy damaged and even come off.Now, the requirement of coating to anti-microbial property is also more and more higher.
Summary of the invention
The object of this invention is to provide a kind of preparation method of epoxy anticorrosion antibiotic paint, utilize preparation method of the present invention, the epoxy anticorrosion antibiotic paint that a kind of antiseptic property is good, impact resistance is good, good toughness, anti-microbial property are good can be prepared, and technique is simple.
For achieving the above object, a kind of preparation method of epoxy anticorrosion antibiotic paint, according to weight percent meter, comprises the steps:
(1) take 15%-23% deionized water respectively, antibacterial modified resin and nano-silicon solution, 5%-10% urethane, 10%-18% nitrile rubber, 0.5%-0.9% dispersion agent, 0.4%-0.8% defoamer, 0.4%-0.8% sanitas that 30%-40% bisphenol A epoxide resin, 8%-15% phenolic aldehyde amine, 5%-10% weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture;
(2) the sheet high abrasion color stuffing and the 0.2%-0.5% flow agent that take 10%-17% join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.
Further, described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 2%-4%, the sericite in powder of 160 orders and content to be the glass flake of 3%-6% and content be 5%-7% forms; Above per-cent is all weight percentage.
Further, described dispersion agent is TH-904 or SN-5040.
Further, described defoamer is SN-154 or A10.
Further, described flow agent is RM-2020.
The invention has the beneficial effects as follows: phenolic aldehyde amine, can fast setting at low ambient temperatures as solidifying agent, and has good antiseptic property; The benzene ring structure of this solidifying agent and bisphenol A epoxide resin have better consistency, thus can reduce the viscosity of system further, improve the compatibility of host and solidifying agent.Bisphenol A epoxide resin and paracril first carry out pre-reaction, adding of a small amount of paracril can not form two phase structure, the formation when paracril content reaches certain limit is only had to have being separated of island structure, this can meet uncured front rubber and bisphenol A epoxide resin well miscible, low viscosity characteristics, can rubber phase be separated out after can solidifying again again, produce micron-scale phase separation, improve impact resistance.Urethane and bisphenol A epoxide resin can form semi-intercrossing network (SIPN) and interpenetrating(polymer)networks (IPN) polymkeric substance, SIPN and IPN structure desirable " forcing mutual tolerance " and " synergy " make the snappiness of urethane and the good heat resistance of bisphenol A epoxide resin and cementability organically combine, and obtain good toughening effect.By coatings of the present invention on body of wall, due to the interaction of antibacterial modified resin, nano-silicon solution and bisphenol A epoxide resin, make the anti-microbial property of this coating good, and have good heat-proof quality, the hardness of paint film is high, good toughness.And technique is simple.
Embodiment
Below in conjunction with embodiment, the present invention is further elaborated.
According to weight percent meter, epoxy anticorrosion antibiotic paint is that the antibacterial modified resin of 30:1 and nano-silicon solution, 5%-10% urethane, 10%-18% nitrile rubber, 10%-17% sheet high abrasion color stuffing, 0.5%-0.9% dispersion agent, 0.4%-0.8% defoamer, 0.4%-0.8% sanitas, 0.2%-0.5% flow agent, 15%-23% deionized water form by 30%-40% bisphenol A epoxide resin, 8%-15% phenolic aldehyde amine, 5%-10% weight percent.
Wherein, described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 2%-4%, the sericite in powder of 160 orders and content to be the glass flake of 3%-6% and content be 5%-7% forms.Described dispersion agent is TH-904 or SN-5040.Described defoamer is SN-154 or A10.Described flow agent is RM-2020.
Embodiment 1.
The preparation method of epoxy anticorrosion antibiotic paint is:
(1) take 150g deionized water by weight, respectively, antibacterial modified resin and nano-silicon solution, 85g urethane, 100g nitrile rubber, 5g dispersion agent, 4g defoamer, 4g sanitas that 300g bisphenol A epoxide resin, 150g phenolic aldehyde amine, 100g weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture.
(2) the sheet high abrasion color stuffing and the 2g flow agent that take 100g join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.Described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 2g, the sericite in powder of 160 orders and content to be the glass flake of 3g and content be 5g forms.
Embodiment 2.
The preparation method of epoxy anticorrosion antibiotic paint is:
(1) take 160g deionized water by weight, respectively, antibacterial modified resin and nano-silicon solution, 50g urethane, 120g nitrile rubber, 9g dispersion agent, 8g defoamer, 8g sanitas that 400g bisphenol A epoxide resin, 80g phenolic aldehyde amine, 50g weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture.
(2) the sheet high abrasion color stuffing and the 5g flow agent that take 110g join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.Described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 2g, the sericite in powder of 160 orders and content to be the glass flake of 3g and content be 6g forms.
Embodiment 3.
The preparation method of epoxy anticorrosion antibiotic paint is:
(1) take 150g deionized water by weight, respectively, antibacterial modified resin and nano-silicon solution, 100g urethane, 120g nitrile rubber, 9g dispersion agent, 8g defoamer, 8g sanitas that 300g bisphenol A epoxide resin, 80g phenolic aldehyde amine, 50g weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture.
(2) the sheet high abrasion color stuffing and the 5g flow agent that take 170g join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.Described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 4g, the sericite in powder of 160 orders and content to be the glass flake of 6g and content be 7g forms.
Embodiment 4.
The preparation method of epoxy anticorrosion antibiotic paint is:
(1) take 230g deionized water by weight, respectively, antibacterial modified resin and nano-silicon solution, 60g urethane, 100g nitrile rubber, 6g dispersion agent, 5g defoamer, 5g sanitas that 310g bisphenol A epoxide resin, 80g phenolic aldehyde amine, 70g weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture.
(2) the sheet high abrasion color stuffing and the 4g flow agent that take 130g join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.Described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 3g, the sericite in powder of 160 orders and content to be the glass flake of 5g and content be 5g forms.
Embodiment 5.
The preparation method of epoxy anticorrosion antibiotic paint is:
(1) take 225g deionized water by weight, respectively, antibacterial modified resin and nano-silicon solution, 50g urethane, 180g nitrile rubber, 5g dispersion agent, 4g defoamer, 4g sanitas that 300g bisphenol A epoxide resin, 80g phenolic aldehyde amine, 50g weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture.
(2) the sheet high abrasion color stuffing and the 2g flow agent that take 100g join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.Described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 2g, the sericite in powder of 160 orders and content to be the glass flake of 3g and content be 5g forms.
In the present invention, phenolic aldehyde amine, can fast setting at low ambient temperatures as solidifying agent, and has good antiseptic property; The benzene ring structure of this solidifying agent and bisphenol A epoxide resin have better consistency, thus can reduce the viscosity of system further, improve the compatibility of host and solidifying agent.Bisphenol A epoxide resin and paracril first carry out pre-reaction, adding of a small amount of paracril can not form two phase structure, the formation when paracril content reaches certain limit is only had to have being separated of island structure, this can meet uncured front rubber and bisphenol A epoxide resin well miscible, low viscosity characteristics, can rubber phase be separated out after can solidifying again again, produce micron-scale phase separation, improve impact resistance.Urethane and bisphenol A epoxide resin can form semi-intercrossing network (SIPN) and interpenetrating(polymer)networks (IPN) polymkeric substance, SIPN and IPN structure desirable " forcing mutual tolerance " and " synergy " make the snappiness of urethane and the good heat resistance of bisphenol A epoxide resin and cementability organically combine, and obtain good toughening effect.By coatings of the present invention on body of wall, due to the interaction of antibacterial modified resin, nano-silicon solution and bisphenol A epoxide resin, make the anti-microbial property of this coating good, and have good heat-proof quality, the hardness of paint film is high, good toughness.And technique is simple.
Claims (5)
1. a preparation method for epoxy anticorrosion antibiotic paint, is characterized in that: according to weight percent meter, comprises the steps:
(1) take 15%-23% deionized water respectively, antibacterial modified resin and nano-silicon solution, 5%-10% urethane, 10%-18% nitrile rubber, 0.5%-0.9% dispersion agent, 0.4%-0.8% defoamer, 0.4%-0.8% sanitas that 30%-40% bisphenol A epoxide resin, 8%-15% phenolic aldehyde amine, 5%-10% weight percent are 30:1, and together join in dispersion tank, under the rotating speed of dispersion tank 300-500r/min, dispersion is stirred after 5-10 minute and is obtained mixture;
(2) the sheet high abrasion color stuffing and the 0.2%-0.5% flow agent that take 10%-17% join in described mixture, and under the rotating speed of dispersion tank 1000-1500r/min, dispersion is stirred after 10-15 minute and obtained epoxy anticorrosion antibiotic paint.
2. the preparation method of epoxy anticorrosion antibiotic paint according to claim 1, is characterized in that: described sheet high abrasion color stuffing by 320 orders and content be the glass flake of 2%-4%, the sericite in powder of 160 orders and content to be the glass flake of 3%-6% and content be 5%-7% forms; Above per-cent is all weight percentage.
3. the preparation method of epoxy anticorrosion antibiotic paint according to claim 1, is characterized in that: described dispersion agent is TH-904 or SN-5040.
4. the preparation method of epoxy anticorrosion antibiotic paint according to claim 1, is characterized in that: described defoamer is SN-154 or A10.
5. the preparation method of epoxy anticorrosion antibiotic paint according to claim 1, is characterized in that: described flow agent is RM-2020.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410703643.2A CN104327680B (en) | 2014-11-30 | 2014-11-30 | Method for preparing corrosion-resistant antibacterial epoxy coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410703643.2A CN104327680B (en) | 2014-11-30 | 2014-11-30 | Method for preparing corrosion-resistant antibacterial epoxy coating |
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| CN104327680A true CN104327680A (en) | 2015-02-04 |
| CN104327680B CN104327680B (en) | 2017-01-18 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315745A (en) * | 2015-11-16 | 2016-02-10 | 中国船舶重工集团公司第七二五研究所 | Preparation method for carboxyl-terminated nitrilo butadiene rubber coated and modified glass flakes |
| CN108703436A (en) * | 2018-05-17 | 2018-10-26 | 浙江三益鞋业有限公司 | A kind of protective footwear |
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| JP2009102314A (en) * | 2007-10-05 | 2009-05-14 | Kochi Prefecture | Antifouling or antimicrobial agent, antifouling or antimicrobial composition and method for antifouling or antimicrobial treatment |
| CN102578147A (en) * | 2011-12-16 | 2012-07-18 | 邯郸派瑞电器有限公司 | Deodorant and antibacterial resin material and preparation method thereof |
| CN102775863A (en) * | 2012-07-19 | 2012-11-14 | 洛阳七维防腐工程材料有限公司 | Method for preparing anticorrosive paint for directly-buried thermal power pipeline insulating layer |
| CN104017441A (en) * | 2014-05-06 | 2014-09-03 | 阜阳市光普照明科技有限公司 | Antibacterial heat dissipation coating containing nanosilver |
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2014
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| JP2009102314A (en) * | 2007-10-05 | 2009-05-14 | Kochi Prefecture | Antifouling or antimicrobial agent, antifouling or antimicrobial composition and method for antifouling or antimicrobial treatment |
| CN102578147A (en) * | 2011-12-16 | 2012-07-18 | 邯郸派瑞电器有限公司 | Deodorant and antibacterial resin material and preparation method thereof |
| CN102775863A (en) * | 2012-07-19 | 2012-11-14 | 洛阳七维防腐工程材料有限公司 | Method for preparing anticorrosive paint for directly-buried thermal power pipeline insulating layer |
| CN104017441A (en) * | 2014-05-06 | 2014-09-03 | 阜阳市光普照明科技有限公司 | Antibacterial heat dissipation coating containing nanosilver |
Non-Patent Citations (1)
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| 李芝华等: "弹性体增韧环氧树脂研究进展", 《广州化学》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315745A (en) * | 2015-11-16 | 2016-02-10 | 中国船舶重工集团公司第七二五研究所 | Preparation method for carboxyl-terminated nitrilo butadiene rubber coated and modified glass flakes |
| CN105315745B (en) * | 2015-11-16 | 2017-09-08 | 中国船舶重工集团公司第七二五研究所 | A kind of glass flake preparation method of nbr carboxyl terminal coating modification |
| CN108703436A (en) * | 2018-05-17 | 2018-10-26 | 浙江三益鞋业有限公司 | A kind of protective footwear |
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| CN104327680B (en) | 2017-01-18 |
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