CN108504805A - A method of control blast furnace short route casts graphite floatation - Google Patents

A method of control blast furnace short route casts graphite floatation Download PDF

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Publication number
CN108504805A
CN108504805A CN201810460856.5A CN201810460856A CN108504805A CN 108504805 A CN108504805 A CN 108504805A CN 201810460856 A CN201810460856 A CN 201810460856A CN 108504805 A CN108504805 A CN 108504805A
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CN
China
Prior art keywords
molten iron
graphite
carbon
content
blast furnace
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CN201810460856.5A
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Chinese (zh)
Inventor
李从发
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Wuhu Xinxing New Material Industrial Park Co Ltd
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Wuhu Xinxing New Material Industrial Park Co Ltd
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Priority to CN201810460856.5A priority Critical patent/CN108504805A/en
Publication of CN108504805A publication Critical patent/CN108504805A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B5/00Making pig-iron in the blast furnace
    • C21B5/02Making special pig-iron, e.g. by applying additives, e.g. oxides of other metals
    • C21B5/023Injection of the additives into the melting part
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/08Manufacture of cast-iron

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

The invention discloses a kind of methods that control blast furnace short route casts graphite floatation, and this method comprises the following steps:Step 1:It is blast-melted it is middle be added a certain amount of steel scrap increase it is blast-melted in oxygen content;Step 2:1,500 1550 DEG C are reached to blast-melted progress heating temperature, keeps hot metal composition uniform;Step 3:Carbon content in control molten iron is 3.0% 3.5%, carbon equivalent is 4.0% 4.3%;Step 4:Molten iron taps a blast furnace into pouring ladle, and to skimming at packet mouth, Slag conglomeration agent is spread after skimming totally;Step 5:Random inoculant is added into molten iron;Step 6:Cast.Steel scrap is added in molten iron of the present invention and increases oxygen content, improve the burn out rate of graphite, reduce the content of graphite in molten iron, to avoid graphite aggregation and graphite floatation phenomenon, high-duty iron part is produced, is not only realized using the blast-melted high-end casting of casting, reduce casting smelting cost, labor intensity and environmental pollution are reduced, steel scrap can also be largely used, avoid secondary pollution and energy waste.

Description

A method of control blast furnace short route casts graphite floatation
Technical field
The invention belongs to metallurgical casting technical fields, and in particular to a kind of side of control blast furnace short route casting graphite floatation Method.
Background technology
Currently, Foundry Works is a complete independent system, after Large Steel ironworks melt iron, face is cast by casting machine Iron clad (ingot iron), then by long short-distance transport to Foundry Works, while Foundry Works will also purchase coke, scrap iron and steel, waste residue and molten Then these substances are smelted into molten iron again using furnace cupola or intermediate frequency furnace, then are cast as after being cast to mold by the substances such as agent Casting.This conventional cast factory needs to buy largely and stores the substance of melt iron, but also it is molten to have molten iron The big mini-plants such as refining tool such as furnace cupola or intermediate frequency furnace, these not only need to put into a large amount of fund, manpower and time, And a prodigious workshop or place is needed, and melt iron is secondary operation, greatly consume social resources, pollution ring Border.
" short route " technique is one of the optimisation technique that casting association of country emphasis is promoted, so-called " short route " founder Skill, exactly with it is blast-melted be directly entered intermediate frequency furnace carry out heating and adjusting component, the pouring cast part after Metamorphism treatment save use Remelting efficiently uses blast-melted heat to pig iron at the process of molten iron again;Short route casting project is a kind of energy saving, height Effect, low cost, the method for casting production of of low pollution are not only able to be greatly lowered the consumption of coke or electric energy and pollutant Discharge capacity has good environmental protection benefit, while can bring the huge energy, economy and environmental benefit.
But since short-flow melting is to be used for Foundry Production directly as furnace charge by blast-melted, graphite is easily assembled, very It is susceptible to graphite floatation, especially at the big position of the thickness of casting and upper surface, graphite floatation causes solidified structure uneven, Casting mechanical performance is low, and this phenomenon is more prominent when especially carbon content is high, therefore leads to blast-melted be directly used in The abbreviated system technology of casting can be only applied to the cast product of not quality requirement, cannot be answered in high-end castings production With.
Invention content
For deficiency existing for abbreviated system technology in the prior art, the purpose of the present invention is to provide a kind of control height The method that stove short route casts graphite floatation, this method increase oxygen content, increase stone in molten iron by the way that steel scrap is added in molten iron Black burn out rate solves in the prior art since graphite aggregation or graphite floatation cause casting mechanical performance low, abbreviated system Technology can not be applied to the problem of high-end castings production.
To achieve the above object, the technical scheme is that:A kind of side of control blast furnace short route casting graphite floatation Method, this method comprises the following steps:Step 1:It is blast-melted it is middle be added a certain amount of steel scrap increase it is blast-melted in oxygen contain Amount;Step 2:1500-1550 DEG C is reached to blast-melted progress heating temperature, keeps hot metal composition uniform;Step 3:Control molten iron In carbon content be 3.0%-3.5%, carbon equivalent 4.0%-4.3%;Step 4:Molten iron taps a blast furnace into pouring ladle, at packet mouth It skims, Slag conglomeration agent is spread after skimming totally;Step 5:Random inoculant is added into molten iron;Step 6:Cast.
Further, the computational methods of the carbon equivalent are:The one third of silicone content is plus the carbon in molten iron in molten iron Content.
Further, the addition of the inovulant is 0.1%-0.2%, and the inovulant is that silicon barium calcium is compound inoculated Agent.
Further, the concrete operations of the step 3 are:A. the temperature for measuring molten iron, when temperature reaches 1400-1450 DEG C when, sample spoon is extend into molten iron center liquid level, be deep within the scope of liquid level or less 10-200mm sample;B. the sample liquid to being taken Polishing is composed, and carbon content and silicone content in molten iron are detected;C. worked as according to the carbon content and silicone content, the carbon for calculating molten iron discharging that detect Amount;D. judge whether carbon content in molten iron and carbon equivalent are qualified, if unqualified, continue that steel scrap is added into molten iron, repeat to walk Rapid a, b, c are until carbon content and carbon equivalent qualification in molten iron.
Further, the operation principle of the step 1 is:Oxygen is reacted with graphite under hot conditions, and graphite is burnt.
Further, the ingredient for the Slag conglomeration agent added in the step 4 includes pearl salt.
The advantages of using technical solution of the present invention for:
1. the present invention it is blast-melted it is middle a certain amount of steel scrap is added, can increase it is blast-melted in oxygen content, in height Under the conditions of temperature, oxygen content are sufficient, oxygen is fully reacted with graphite generates carbon dioxide and water, increases the burning of graphite in molten iron Loss rate reduces the content of graphite in molten iron, to avoid graphite aggregation and graphite floatation phenomenon, improves the quality of casting.
2. the present invention increases blast-melted oxygen content by the way that steel scrap is added into molten iron, to increase the shape of cast iron graphite nuclei At, and the more tiny rounding of Graphite Morphology in Cast Iron under low-carbon amount and low-carbon-equivalent.
3. steel scrap is added in the abbreviated system of the present invention in molten iron, the content of carbon content and carbon equivalent, Ke Yixian are controlled Writing improves since graphite aggregation and graphite floatation lead to that casting mechanical performance is low, ropy phenomenon, and final production goes out complete symbol Close the high-duty iron part that performance requires, not only realize using the high-end casting of blast-melted casting, reduce casting smelting at This, reduces labor intensity and the environmental pollution of foundry enterprise melting work, can also largely use steel scrap, turn waste into wealth, avoided Secondary pollution and energy waste.
Specific implementation mode
A method of control blast furnace short route casts graphite floatation, includes the following steps:
Step 1:It is blast-melted it is middle be added a certain amount of steel scrap increase it is blast-melted in oxygen content, graphite it is main at Timesharing carbon, under the conditions of high temperature, oxygen content are sufficient, oxygen is fully reacted with carbon generates carbon dioxide and water, increases molten iron The burn out rate of middle graphite reduces the content of graphite in molten iron, to avoid graphite aggregation and graphite floatation phenomenon, improves casting Quality.
Step 2:1500-1550 DEG C is reached to blast-melted progress heating temperature, molten iron is heated at high temperature, on the one hand The steel scrap being added in step 1 can be made fully to melt to be integrated with molten iron dissolving, so that hot metal composition is homogenized, another aspect high temperature item Graphite can be made fully to burn under part, reduce the residual of graphite.
Step 3:Control molten iron in carbon content be 3.0%-3.5%, carbon equivalent 4.0%-4.3%, wherein carbon equivalent Computational methods be:The one third of silicone content is plus the carbon content in molten iron in molten iron.
The specific detection method of carbon content and carbon equivalent is in molten iron in step 3:
Sample spoon is extend into molten iron center liquid level by the temperature for a. measuring molten iron when temperature reaches 1400-1450 DEG C, deep Enter into 10-200mm below liquid level and sample, in the preferred embodiment of the present invention, when sampling is deep into liquid level or less 50- It is sampled within the scope of 100mm;
B. the sample liquid polishing taken is composed, detects carbon content and silicone content in molten iron;
C. according to the carbon content and silicone content detected, the carbon equivalent of molten iron discharging is calculated, carbon equivalent is equal to silicon in molten iron and contains The one third of amount adds the carbon content in molten iron;
D. judge whether carbon content in molten iron and carbon equivalent are qualified, if unqualified, continue that steel scrap is added into molten iron, weight Multiple step a, b, c are until carbon content and carbon equivalent qualification in molten iron, after carbon content and carbon equivalent reach requirement in molten iron Carry out step 4.
Step 4:Molten iron taps a blast furnace into pouring ladle, and to skimming at packet mouth, Slag conglomeration agent is spread after skimming totally;In the present invention Preferred embodiment in, the main component of the Slag conglomeration agent is pearl salt.
Step 5:Random inoculant is added into molten iron;In the preferred embodiment of the present invention, the addition of the random inoculant Amount is 0.1%-0.2%, that is, the random inoculant being added accounts for the 0.1%-0.2% of molten iron, general when the part of casting is smallclothes By the addition control of inovulant 0.1%, generally the addition of inovulant is controlled when the part of casting is big part 0.2%.Preferably, the inovulant being added in molten iron is silicon barium calcium composite inoculant, and wherein silicone content control is 70% or so, barium Content controls between 4%-5%, and calcium content controls between 2%-3%, remaining is the other objects added according to practical application Matter, such as carbon, phosphorus, sulphur, aluminium etc..
Step 6:Cast, pours into a mould and opens within first 10 minutes cast vacuum, and control pouring pressure is -0.05~0.07Mpa;Cast It crosses range request speed and follows slow, fast, slow sequence, terminate to cast to terminate from reaction is bred, time control was at 10-15 minutes; Choose Slag conglomeration agent after casting complete, otherwise under the influence of a packet casting quality.
The present invention increases blast-melted oxygen content by the way that steel scrap is added into molten iron, to increase the shape of cast iron graphite nuclei At, and the more tiny rounding of Graphite Morphology in Cast Iron under low-carbon amount and low-carbon-equivalent.
It is stringent to control carbon content and carbon equivalent in molten iron the study found that adjust to the blast-melted ratio that steel scrap is added Content, heating temperature, the type of inovulant and additive amount, pouring temperature and the duration of pouring etc..Abbreviated system adds in molten iron Enter steel scrap, control the content of carbon content and carbon equivalent, can significantly improve since graphite aggregation and graphite floatation lead to casting machine Tool performance is low, ropy phenomenon, and final production goes out to comply fully with the high-duty iron part of performance requirement, and not only realizing makes With the blast-melted high-end casting of casting, casting smelting cost is reduced, the labor intensity and environment of foundry enterprise melting work are reduced Pollution, can also largely use steel scrap, turn waste into wealth, avoid secondary pollution and energy waste.
The present invention is exemplarily described in above example, it is clear that the present invention implements not by aforesaid way Limitation, as long as using the improvement of the various unsubstantialities of technical solution of the present invention progress, or the not improved structure by the present invention Think and technical solution directly applies to other occasions, within protection scope of the present invention.

Claims (6)

1. a kind of method of control blast furnace short route casting graphite floatation, it is characterised in that:This method comprises the following steps:Step 1:It is blast-melted it is middle be added a certain amount of steel scrap increase it is blast-melted in oxygen content;Step 2:It is heated to blast-melted Temperature reaches 1500-1550 DEG C, keeps hot metal composition uniform;Step 3:Carbon content in control molten iron is 3.0%-3.5%, carbon is worked as Amount is 4.0%-4.3%;Step 4:Molten iron taps a blast furnace into pouring ladle, and to skimming at packet mouth, Slag conglomeration agent is spread after skimming totally; Step 5:Random inoculant is added into molten iron;Step 6:Cast.
2. a kind of method of control blast furnace short route casting graphite floatation as described in claim 1, it is characterised in that:The carbon The computational methods of equivalent are:The one third of silicone content is plus the carbon content in molten iron in molten iron.
3. a kind of method of control blast furnace short route casting graphite floatation as described in claim 1, it is characterised in that:It is described pregnant The addition for educating agent is 0.1%-0.2%, and the inovulant is silicon barium calcium composite inoculant.
4. a kind of method of control blast furnace short route casting graphite floatation as described in claims 1 to 3 any one, feature It is:The concrete operations of the step 3 are:A. the temperature for measuring molten iron stretches sample spoon when temperature reaches 1400-1450 DEG C Enter to molten iron center liquid level, is deep within the scope of liquid level or less 10-200mm and samples;B. the sample liquid polishing taken is composed, detects iron Carbon content and silicone content in water;C. according to the carbon content and silicone content detected, the carbon equivalent of molten iron discharging is calculated;D. judge molten iron In carbon content and carbon equivalent it is whether qualified, if unqualified, continue that steel scrap is added into molten iron, repeat step a, b, c until iron Until carbon content and carbon equivalent qualification in water.
5. a kind of method of control blast furnace short route casting graphite floatation as claimed in claim 4, it is characterised in that:The step Rapid 1 operation principle is:Oxygen is reacted with graphite under hot conditions, and graphite is burnt.
6. a kind of method of control blast furnace short route casting graphite floatation as claimed in claim 4, it is characterised in that:The step The ingredient for the Slag conglomeration agent added in rapid 4 includes pearl salt.
CN201810460856.5A 2018-05-15 2018-05-15 A method of control blast furnace short route casts graphite floatation Pending CN108504805A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101348846A (en) * 2008-09-10 2009-01-21 林州市合鑫铸业有限公司 Blast furnace-intermediate frequency furnace duplexing smelting short process production technology
CN101768691A (en) * 2009-12-29 2010-07-07 青州豪章铸造有限公司 Productive technology of short flow of structure type cast iron part
CN102586666A (en) * 2012-03-09 2012-07-18 青州豪章铸造有限公司 Special cleansing agent for short-flow high-strength cast iron and manufacturing process thereof
CN107119168A (en) * 2017-06-13 2017-09-01 磐石华兴汽车零部件制造有限公司 A kind of method that blast-melted short route casts high-quality casting

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101348846A (en) * 2008-09-10 2009-01-21 林州市合鑫铸业有限公司 Blast furnace-intermediate frequency furnace duplexing smelting short process production technology
CN101768691A (en) * 2009-12-29 2010-07-07 青州豪章铸造有限公司 Productive technology of short flow of structure type cast iron part
CN102586666A (en) * 2012-03-09 2012-07-18 青州豪章铸造有限公司 Special cleansing agent for short-flow high-strength cast iron and manufacturing process thereof
CN107119168A (en) * 2017-06-13 2017-09-01 磐石华兴汽车零部件制造有限公司 A kind of method that blast-melted short route casts high-quality casting

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Application publication date: 20180907