CN108493322A - The thermocouple unit of annular thermoelectric material electric organ and annular thermoelectric material electric organ - Google Patents

The thermocouple unit of annular thermoelectric material electric organ and annular thermoelectric material electric organ Download PDF

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Publication number
CN108493322A
CN108493322A CN201810424462.4A CN201810424462A CN108493322A CN 108493322 A CN108493322 A CN 108493322A CN 201810424462 A CN201810424462 A CN 201810424462A CN 108493322 A CN108493322 A CN 108493322A
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China
Prior art keywords
thermoelectric material
annular
supporting leg
material supporting
thermocouple
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CN201810424462.4A
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CN108493322B (en
Inventor
庞丹丹
张爱兵
宋忠贤
李洁冰
延旭
毛艳丽
康海彦
郭飞
郭一飞
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Ningbo University
Henan University of Urban Construction
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Henan University of Urban Construction
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N10/00Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
    • H10N10/80Constructional details
    • H10N10/81Structural details of the junction
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N19/00Integrated devices, or assemblies of multiple devices, comprising at least one thermoelectric or thermomagnetic element covered by groups H10N10/00 - H10N15/00
    • H10N19/101Multiple thermocouples connected in a cascade arrangement

Abstract

The thermocouple unit of annular thermoelectric material electric organ of the invention, including thermoelectric material supporting leg and metal connecting sheet/electrode, the thermocouple unit both ends of the surface are isocentric circular arc end face, with the circumferential angle for thermoelectric material supporting leg, r1And r2Respectively radial distance of the center of circle of cylinder body heat source to thermoelectric material supporting leg top and bottom, p-type is connected with N-shaped thermoelectric material supporting leg by metal connecting sheet/electrode, constitute annular thermocouple, p-type and N-shaped thermoelectric material supporting leg radial width are directly proportional to radius, thickness is inversely proportional with radius, and p-type and N-shaped thermoelectric material supporting leg are equal in radial direction sectional area.Annular thermoelectric material electric organ of the invention, it is made of ring pipe and a certain number of thermocouple units and extraction electrode, annular inside pipe wall is temperature end, outer wall is low-temperature end, thermocouple unit is clipped in annular inside pipe wall, among two layers of heat-conduction electric insulation ceramic wafer of outer wall, and each thermocouple unit is sequentially connected by metal connecting sheet/electrode.The present invention is significantly improved relative to existing leg-type annular thermoelectric material electric organ, specific power.

Description

The thermocouple unit of annular thermoelectric material electric organ and annular thermoelectric material electric organ
Technical field
The present invention relates to a kind of temperature difference electricity generation devices, more particularly, to a kind of annular thermocouple unit of thermoelectric material power generation And annular thermoelectric material electric organ.
Background technology
Thermoelectric material has Seebeck effect, when there are the temperature difference in thermoelectric material both sides, can generate potential difference in its both sides, i.e., Electric energy can be converted heat into.It mutually converts with thermal energy since thermo-electric device can be directly realized by electric energy, is primarily used in early days Detection temperature was widely used in electron temperature-control, waste-heat power generation and space flight battery pack later with the exploitation of high performance thermoelectric material Equal fields.
Thermoelectric material power generator is easy maintenance, energy conservation and environmental protection, simple and stable.More than pyroelectric technology progress industry The thermo-electric generation of heat or vehicle exhaust, gradually shows vast market prospect.However the efficiency of thermo-electric generation and power also have It waits further increasing, constantly demand is widely applied to adapt to it.
Invention content
In order to improve the specific power of thermoelectric material power generation(The output power of unit mass thermoelectric material), the present invention proposes A kind of the thermocouple unit and its annular thermoelectric material electric organ of thermoelectric material power generation, are cylinders suitable for heat source, especially When heat source is coal-burning boiler and automobile exhaust cylinder, it can be achieved that waste heat efficiently uses.
The technical solution adopted in the present invention:
A kind of thermocouple unit of annular thermoelectric material electric organ, including p-type thermoelectric material supporting leg(3), N-shaped thermoelectric material supporting leg (4)And metal connecting sheet/electrode(6), the thermocouple unit both ends of the surface are isocentric circular arc end face, with for thermoelectric material branch The circumferential angle of leg, r1And r2The respectively center of circle of cylinder body heat source is to the radial distance of thermoelectric material supporting leg top and bottom, institute State p-type thermoelectric material supporting leg(3)With N-shaped thermoelectric material supporting leg(4)Pass through high conduction performance metal connecting sheet/electrode(6)Connection, Constitute annular thermocouple, p-type and N-shaped thermoelectric material supporting leg radial width are directly proportional to radius in the thermocouple unit, thickness It is inversely proportional with radius, keeps p-type and N-shaped thermoelectric material supporting leg equal in radial direction sectional area.
A kind of annular thermoelectric material electric organ using thermocouple unit as previously described, by ring pipe and a certain number of heat Galvanic couple unit and extraction electrode are constituted, and the inner and outer wall of ring pipe uses heat-conduction electric insulation ceramic wafer, the annular inside pipe wall (5)For temperature end, inside flows through high temperature heat source(1), annular pipe outer wall(2)For low-temperature end, thermocouple unit is clipped in ring pipe Among two layers wall, outer wall of heat-conduction electric insulation ceramic wafer, each thermocouple unit is sequentially connected by metal connecting sheet/electrode.
Beneficial effects of the present invention:
1, the thermocouple unit of thermoelectric material power generation of the present invention, it is reasonable in design, improve the ratio work(of annular thermoelectric generator Rate.The annular thermoelectric material supporting leg is directly proportional to radius in radial width, when thickness is inversely proportional with radius, can make p-type and N-shaped Thermoelectric material supporting leg is equal in radial direction sectional area, its specific power, the i.e. output power of unit mass can at this time reached most Greatly.It provides the foundation for high-power, dynamical temperature difference electricity generation device.
2, the annular thermoelectric material electric organ of the present invention, is cylinder suitable for heat source, especially when heat source is coal-burning boiler With when automobile exhaust cylinder, it can be achieved that waste heat efficiently uses.Using the thermoelectric material leg-type annular thermoelectric power generation of cross-section area Device, compares existing thermoelectric material leg-type annular thermoelectric generator, and specific power significantly improves.
Description of the drawings
Fig. 1 is the structural schematic diagram of annular thermoelectric material electric organ of the invention;
Fig. 2 is the planar structure schematic diagram of the thermocouple unit of thermoelectric material power generation of the present invention;
Fig. 3 is the dimensional structure diagram of the thermocouple unit of thermoelectric material power generation of the present invention;
Fig. 4 is the ratio of the annular thermoelectric generator specific power of cross-section area and the annular thermoelectric generator specific power of equal thickness pm/pm0With r2/r1Relational graph.
Specific implementation mode
Below by specific implementation mode, technical scheme of the present invention will be described in further detail.
Embodiment 1
Referring to Fig. 1, Fig. 2, Fig. 3, the thermocouple unit of present invention annular thermoelectric material electric organ, including p-type thermoelectric material supporting leg 3, N-shaped thermoelectric material supporting leg 4 and metal connecting sheet/electrode 6, the thermocouple unit both ends of the surface are isocentric circular arc end face, with For the circumferential angle of thermoelectric material supporting leg, r1And r2Respectively the center of circle of cylinder body heat source to thermoelectric material supporting leg upper end and under The radial distance at end, the p-type thermoelectric material supporting leg 3 and N-shaped thermoelectric material supporting leg 4 by high conduction performance metal connecting sheet/ Electrode 6 connects, and constitutes annular thermocouple, and the p-type and N-shaped thermoelectric material supporting leg radial width are directly proportional to radius, thickness and Radius is inversely proportional, and keeps p-type and N-shaped thermoelectric material supporting leg equal in radial direction sectional area.
Embodiment 2
Referring to Fig. 1, Fig. 2, Fig. 3, the present embodiment is the annular thermoelectric material electric organ using thermocouple unit described in embodiment 1, It is made of ring pipe and a certain number of thermocouple units and extraction electrode, the inner and outer wall of ring pipe uses heat-conduction electric insulation Ceramic wafer, the annular inside pipe wall 5 are temperature end, and inside flows through high temperature heat source 1, and annular pipe outer wall 2 is low-temperature end, thermocouple list Member is clipped in annular inside pipe wall, among two layers of heat-conduction electric insulation ceramic wafer of outer wall, and each thermocouple unit passes through metal connecting sheet/electrode It is sequentially connected.
Annular thermoelectric material electric organ of the invention, is cylinder suitable for heat source, especially when heat source be coal-burning boiler and , it can be achieved that waste heat efficiently uses when automobile exhaust cylinder.Referring to Fig. 1, Fig. 2,5 be heat-conduction electric insulation ceramic wafer in figure, and 6 connect for metal Contact pin, the high temperature heat source end 1 when center and outermost low-temperature end(Annular pipe outer wall 2 is equipped with radiating fin)When having the temperature difference(I.e.), the p-type semiconductor thermoelectric material 3 and n-type semiconductor thermoelectric material 4 being connected to as shown in Figure 2 then exist Electric current is generated in annular thermoelectric material electric organ, realizes thermal energy to electric transformation of energy.
The annular thermocouple unit that Fig. 2 is shown in Fig. 1, is the circumferential angle of thermoelectric material supporting leg, T1For position High temperature heat source end temperature in center, T2The temperature difference for outermost low-temperature end temperature, the two is DT, r1And r2Respectively cylinder To the radial distance of thermoelectric material supporting leg top and bottom, p-type and N-shaped thermoelectric material supporting leg pass through highly conductive in the center of circle of body heat source Function metals connection sheet connects, and constitutes annular thermocouple, is clipped among two heat-conduction electric insulation ceramic wafers, forms sandwich structure Annular thermoelectric generator, I is electric current, for counterclockwise, RLIt is outer string resistance, represents external electricity consumption device, such as micro- electricity Sub- device.Annular thermoelectric material electric organ is used as microelectronic component power supply, also can be to charge the battery.
As shown in figure 3, annular thermoelectric generator radial width is directly proportional to radius, thickness is inversely proportional with radius, make p-type and N-shaped thermoelectric material supporting leg is equal in radial direction sectional area, at this point, the specific power of annular thermoelectric generator is maximum.
The annular thermoelectric generator for the annular thermoelectric generator specific power and equal thickness that Fig. 4 show cross-section area compares work( The ratio p of ratem/pm0With r2/r1Relational graph(Specific power correlation curve).Abscissa is the outer diameter and internal diameter ratio r of thermocouple2/ r1;Ordinate is the ratio of the specific power of cross-section area annular thermoelectric generator and the specific power of equal thickness annular thermoelectric generator Value pm/pm0, which is more than 1, and with r2/r1Increase, ratio pm/pm0It is increased.This explanation, cross-section area ring The specific power of shape thermoelectric generator obtains larger raising, and as the radical length of thermocouple increases, specific power constantly increases.

Claims (3)

1. a kind of thermocouple unit of annular thermoelectric material electric organ, including p-type thermoelectric material supporting leg(3), N-shaped thermoelectric material branch Leg(4)And metal connecting sheet/electrode(6), it is characterised in that:The thermocouple unit both ends of the surface are isocentric circular arc end face, with For the circumferential angle of thermoelectric material supporting leg, r1And r2Respectively the center of circle of cylinder body heat source to thermoelectric material supporting leg upper end and under The radial distance at end, the p-type thermoelectric material supporting leg(3)With N-shaped thermoelectric material supporting leg(4)It is connected by high conduction performance metal Piece/electrode(6)Connection constitutes annular thermocouple, and the p-type and N-shaped thermoelectric material supporting leg radial width are directly proportional to radius, thick Degree is inversely proportional with radius, keeps p-type and N-shaped thermoelectric material supporting leg equal in radial direction sectional area.
2. a kind of annular thermoelectric material electric organ using thermocouple unit described in claim 1, by ring pipe and certain amount Thermocouple unit and extraction electrode constitute, the inner and outer wall of ring pipe uses heat-conduction electric insulation ceramic wafer, it is characterised in that: The annular inside pipe wall(5)For temperature end, inside flows through high temperature heat source(1), annular pipe outer wall(2)For low-temperature end, thermocouple list Member is clipped in annular inside pipe wall, among two layers of heat-conduction electric insulation ceramic wafer of outer wall, and each thermocouple unit passes through metal connecting sheet/electrode It is sequentially connected.
3. annular thermoelectric material electric organ according to claim 2, it is characterised in that:The annular pipe outer wall is equipped with heat dissipation Fin.
CN201810424462.4A 2018-05-07 2018-05-07 Thermocouple unit of annular thermoelectric material generator and annular thermoelectric material generator Active CN108493322B (en)

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Cited By (3)

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CN111106230A (en) * 2019-12-31 2020-05-05 中国电子科技集团公司第十八研究所 Micro-temperature difference power generation device with planar radiation structure
CN112532110A (en) * 2020-11-20 2021-03-19 中国核动力研究设计院 Heat source suitable for temperature difference type thermoelectric conversion
CN116059533A (en) * 2023-02-20 2023-05-05 湖南安泰康成生物科技有限公司 Active heat dissipation electrode slice and electrode device

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Publication number Priority date Publication date Assignee Title
CN111106230A (en) * 2019-12-31 2020-05-05 中国电子科技集团公司第十八研究所 Micro-temperature difference power generation device with planar radiation structure
CN112532110A (en) * 2020-11-20 2021-03-19 中国核动力研究设计院 Heat source suitable for temperature difference type thermoelectric conversion
CN116059533A (en) * 2023-02-20 2023-05-05 湖南安泰康成生物科技有限公司 Active heat dissipation electrode slice and electrode device
CN116059533B (en) * 2023-02-20 2023-11-21 湖南安泰康成生物科技有限公司 Active heat dissipation electrode slice and electrode device

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