CN110729393A - High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof - Google Patents

High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof Download PDF

Info

Publication number
CN110729393A
CN110729393A CN201911162601.1A CN201911162601A CN110729393A CN 110729393 A CN110729393 A CN 110729393A CN 201911162601 A CN201911162601 A CN 201911162601A CN 110729393 A CN110729393 A CN 110729393A
Authority
CN
China
Prior art keywords
thermoelectric material
type
material supporting
thermocouple
supporting leg
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911162601.1A
Other languages
Chinese (zh)
Inventor
庞丹丹
张爱兵
闻振菲
孙炎
金育安
吴增文
王骥
杜建科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo University
Henan University of Urban Construction
Original Assignee
Ningbo University
Henan University of Urban Construction
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo University, Henan University of Urban Construction filed Critical Ningbo University
Priority to CN201911162601.1A priority Critical patent/CN110729393A/en
Publication of CN110729393A publication Critical patent/CN110729393A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N19/00Integrated devices, or assemblies of multiple devices, comprising at least one thermoelectric or thermomagnetic element covered by groups H10N10/00 - H10N15/00
    • H10N19/101Multiple thermocouples connected in a cascade arrangement
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N10/00Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
    • H10N10/10Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
    • H10N10/17Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the structure or configuration of the cell or thermocouple forming the device
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N10/00Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
    • H10N10/80Constructional details
    • H10N10/81Structural details of the junction

Landscapes

  • Measuring Temperature Or Quantity Of Heat (AREA)

Abstract

The invention relates to a temperature difference power generation device. A thermocouple unit of an annular thermoelectric material generator comprises p-type and n-type thermoelectric material supporting legs, wherein the p-type and n-type thermoelectric material supporting legs are of a segmented structure and are connected through a high-conductivity metal connecting sheet/electrode, two end faces of the thermocouple unit are concentric arc end faces, theta is used as a circumferential included angle of the thermoelectric material supporting legs, and r is used as a circumferential included angle of the thermoelectric material supporting legs1And r2The radial distances from the circle center of the cylindrical heat source to the upper end and the lower end of the thermoelectric material supporting leg are respectively, the radial widths of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg in the thermocouple unit are in direct proportion to the radius, and the thicknesses of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are in inverse proportion to the radius, so that the sectional areas of the p-type thermoelectric material supporting leg and the. A high-temp difference ring-shaped segmented thermoelectric material generator is composed of ring tube, thermocouple units and leading-out electrodes, and features that the heat-conducting electrically-insulating ceramic plate is used for internal and external walls of said ring tube, and said thermocouple units are clamped between said thermocouple unitsThe middle of two layers of heat-conducting electric-insulating ceramic plates on the inner wall and the outer wall of the annular tube.

Description

High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof
Technical Field
The invention relates to a thermoelectric power generation device, in particular to an annular thermocouple unit for thermoelectric material power generation and an annular thermoelectric material power generator.
Background
The thermoelectric material has a Seebeck effect, and when the temperature difference exists on two sides of the thermoelectric material, the potential difference can be generated on the two sides of the thermoelectric material, so that the heat energy can be converted into electric energy. Since the thermoelectric device can directly realize the interconversion between electric energy and heat energy, the thermoelectric device is mainly used for detecting temperature in the early stage, and is widely applied to the fields of electronic temperature control, waste heat power generation, aerospace battery packs and the like with the development of high-performance thermoelectric materials later.
The thermoelectric material power generation device is easy to maintain, energy-saving, environment-friendly, simple and stable. At present, thermoelectric technology is utilized to generate electricity by using industrial waste heat or temperature difference of automobile exhaust, and wide market prospect is gradually shown. In order to improve the specific power (output power per unit mass of thermoelectric material) of thermoelectric material power generation, we propose a thermocouple unit of an annular thermoelectric material power generator and an annular thermoelectric material power generator (patent number: 201820664895.2), which are suitable for cylindrical heat sources, and can realize effective utilization of waste heat especially when the heat sources are coal-fired boilers and automobile exhaust pipes. Because the optimal power generation efficiency of each thermoelectric material is only specific temperature range, the large-temperature-difference working environment cannot be met, and the power generation device formed by a single high-temperature thermoelectric material has lower efficiency. Therefore, the efficiency and power of thermoelectric power generation need to be further improved to meet the increasingly wide application requirements.
Disclosure of Invention
The invention provides a thermocouple unit using thermoelectric material supporting legs with a segmented structure aiming at the defects of the prior art, and accordingly provides a high-temperature-difference annular thermoelectric material generator with the same radial sectional area of the thermoelectric material supporting legs. The segmented design can enable high-temperature, medium-temperature and low-temperature thermoelectric materials to work in the temperature range with the highest efficiency, and compared with the existing leg type annular thermoelectric material generator, the high-temperature differential section annular thermoelectric generator not only has obviously improved specific power, but also has higher energy conversion efficiency.
The technical scheme adopted by the invention is as follows:
the utility model provides a thermocouple unit of annular thermoelectric material generator, includes p type thermoelectric material landing leg (3), n type thermoelectric material landing leg (4) and metal connecting piece/electrode (6), p type, n type thermoelectric material landing leg all adopt the segment structure, p type thermoelectric material landing leg (3) and n type thermoelectric material landing leg (4) are connected through high-conductivity metal connecting piece/electrode (6), constitute annular thermocouple unit, thermocouple unit both ends face is concentric circular arc terminal surface to theta is the circumference contained angle of thermoelectric material landing leg, r1And r2The radial distances from the circle center of the cylindrical heat source to the upper end and the lower end of the thermoelectric material supporting leg are respectively, the radial widths of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg in the thermocouple unit are in direct proportion to the radius, and the thicknesses of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are in inverse proportion to the radius, so that the sectional areas of the p-type thermoelectric material supporting leg and the.
The thermocouple unit of the annular thermoelectric material generator comprises p-type high-temperature thermoelectric materials (800-; the inner side end faces of the p-type thermoelectric material supporting legs and the n-type thermoelectric material supporting legs are connected by adopting electrode plates (6) which are also concentric arc end faces, and the outer side end faces of the thermoelectric material supporting legs of two adjacent thermocouple units are provided with the electrode plates (6) which are also concentric arc end faces.
Since the generating efficiency of the annular thermoelectric generator is in direct proportion to the temperature difference between two ends of the device, the output power is in direct proportion to the square of the temperature difference. In order for a thermoelectric generator to have a large power generation capacity, the thermoelectric generator needs to operate under a large temperature difference condition. The p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are made of three sections of high-temperature thermoelectric materials, medium-temperature thermoelectric materials and low-temperature thermoelectric materials, so that the annular thermocouple can obtain a larger optimal value in the whole temperature range, the average optimal value of the thermocouple in the whole working temperature area can be improved, and the power generation performance is improved.
The p-type thermoelectric material leg and the n-type thermoelectric material leg have equal cross sections in the radial direction, and have the maximum specific power at the moment according to the theoretical calculation of heat transfer.
A high-temperature-difference annular segmented thermoelectric material generator adopting the thermocouple units comprises an annular tube, a certain number of thermocouple units and leading-out electrodes, wherein the inner wall and the outer wall of the annular tube are made of heat-conducting electric-insulation ceramic plates, p-type and n-type thermoelectric material supporting legs of the thermocouple units are of segmented structures, connecting electrode plates (6) on the inner side end faces of the p-type and n-type thermoelectric material supporting legs are concentric arc end faces with the inner wall of the annular tube, the other ends of the two supporting legs of each thermocouple unit are respectively connected with the previous or subsequent thermocouple unit through the electrode plates (6), the connecting electrode plates (6) on the outer side end faces of the p-type and n-type thermoelectric material supporting legs are concentric arc end faces with the outer wall of the annular tube, and the thermocouple units are clamped on the inner wall of the annular tube, the middle of the two layers of heat-conducting electric-insulating ceramic plates on the outer wall forms an annular thermocouple.
The radial sectional areas of the thermoelectric material supporting legs of the thermocouple units are equal; taking theta as a circumferential included angle of the thermoelectric material supporting legs, wherein the total heights of the thermoelectric material supporting legs and the electrode plates are respectively the radial distance from the inner wall of the annular tube to the outer wall of the annular tube of the cylindrical heat source; the inner wall (5) of the annular pipe is a high-temperature end, a high-temperature heat source (1) flows through the inner part of the annular pipe, and the outer wall (2) of the annular pipe is a low-temperature end.
In the high-temperature-difference annular segmented thermoelectric material generator, all the thermocouple units are sequentially connected through the metal connecting sheet/electrode, and the initial end and the tail end are respectively connected with the extraction electrode; and the outer wall of the annular tube is provided with radiating fins (2).
The invention has the beneficial effects that:
1. the thermocouple unit of the annular thermoelectric material generator has reasonable structural design and improves the specific power of the annular thermoelectric material generator. Compared with the existing leg type annular thermoelectric material generator, the thermocouple unit has the advantages that the specific power of the high-temperature segmented annular thermoelectric material generator is obviously improved, and the energy conversion efficiency is higher. When the radial width of the p-type thermoelectric material leg and the radial width of the n-type thermoelectric material leg are in direct proportion to the radius, and the thickness of the p-type thermoelectric material leg and the n-type thermoelectric material leg are in inverse proportion to the radius, the sectional areas of the p-type thermoelectric material leg and the n-type thermoelectric material leg in the radial direction are equal, and the specific power of the annular thermoelectric generator is the highest. At the moment, the specific power, namely the output power of unit mass can reach the maximum, and a foundation is provided for a high-power and high-efficiency temperature difference power generation device.
2. The thermocouple unit of the annular thermoelectric material generator and the high-temperature-difference annular thermoelectric material generator thereof adopt a segmented structure to ensure that the annular thermocouple can obtain a larger optimal value in the whole temperature range. Since the generating efficiency of the annular thermoelectric generator is in direct proportion to the temperature difference between two ends of the device, the output power is in direct proportion to the square of the temperature difference. In order for a thermoelectric generator to have a large power generation capacity, the thermoelectric generator needs to operate under a large temperature difference condition. The p-type thermoelectric material support leg and the n-type thermoelectric material support leg are respectively designed in a segmented mode and are respectively high-temperature thermoelectric materials, medium-temperature thermoelectric materials and low-temperature thermoelectric materials, and each thermoelectric material has higher energy conversion efficiency in a proper temperature range, so that the high-temperature segmented annular thermoelectric generator formed by the thermoelectric support legs with the segmented structures formed by connecting the three thermoelectric materials in series has higher energy conversion efficiency than the annular thermoelectric generator formed by a single thermoelectric material.
3. The invention relates to a high-temperature-difference annular thermoelectric material generator which comprises an annular pipe, a certain number of high-temperature-difference thermoelectric couple units with segmented structures and extraction electrodes, wherein the inner wall of the annular pipe is a high-temperature end, the outer wall of the annular pipe is a low-temperature end, and each thermoelectric couple unit is clamped between two layers of heat-conducting electrically-insulating ceramic plates on the inner wall and the outer wall of the annular pipe and is sequentially connected through a metal connecting sheet/electrode. The heat source is a cylinder, and especially when the heat source is a coal-fired boiler or an automobile exhaust pipe, the waste heat can be effectively utilized. Compared with the existing leg type annular thermoelectric material generator, the leg type annular thermoelectric material generator adopts the thermoelectric material leg with the segmented structure with the same radial sectional area, so that the specific power of the generator is obviously improved, and the energy conversion efficiency is higher.
Drawings
FIG. 1 is a schematic view of an assembled configuration of an annular thermoelectric material power generator of the present invention;
FIG. 2 is a schematic plan view of a thermocouple unit for generating electricity using a thermoelectric material according to the present invention;
FIG. 3 is a schematic perspective view of a thermoelectric element for generating electricity using a thermoelectric material according to the present invention;
figure 4 is a graph of the efficiency of an annular segmented thermoelectric generator with legs of thermoelectric material of equal cross-sectional area in the radial direction versus a non-segmented thermoelectric generator.
Detailed Description
The technical solution of the present invention is further described in detail by the following embodiments. The following examples are merely illustrative of the present invention and should not be construed as limiting the scope of the invention. The skilled person is well within the scope of the prior art, and substitutions by conventional means and simple combinations with the prior art are possible without departing from the scope of the invention.
Example 1
Referring to fig. 1, 2 and 3, the thermocouple unit of the annular thermoelectric material generator of the present invention includes a p-type thermoelectric material leg 3, an n-type thermoelectric material leg 4 and a metal connecting sheet/electrode 6, wherein the p-type and n-type thermoelectric material legs are in a segmented structure, the p-type thermoelectric material leg 3 and the n-type thermoelectric material leg 4 are connected through a high-conductivity metal connecting sheet/electrode, one end of the p-type thermoelectric material leg 3 and one end of the n-type thermoelectric material leg 4 are connected through an electrode sheet 6, the other end of the two legs are respectively connected with a previous or subsequent thermocouple unit through the electrode sheet 6 to form an annular thermocouple, the two end surfaces of the thermocouple unit are concentric arc end surfaces, θ is a circumferential included angle of the thermoelectric material legs, and r is a circumferential included angle of the thermoelectric material1And r2The radial distances from the center of a cylinder heat source to the upper end and the lower end of the thermoelectric material supporting leg are respectively, the radial widths of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg in the thermocouple unit are in direct proportion to the radius, and the thicknesses of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are in inverse proportion to the radius, so that the p-And the sectional areas of the legs of the n-type thermoelectric material in the radial direction are equal.
The invention is different from the existing leg-type annular thermoelectric material thermocouple unit: the p-type thermoelectric material supporting legs 3 and the n-type thermoelectric material supporting legs 4 are of a segmented structure, the radial width of the p-type thermoelectric material supporting legs and the radial width of the n-type thermoelectric material supporting legs are in direct proportion to the radius, the thickness of the p-type thermoelectric material supporting legs and the radial width of the n-type thermoelectric material supporting legs are in inverse proportion to the radius, and the sectional areas of the p-type thermoelectric material supporting legs and the n.
Example 2
Referring to fig. 1 to 3, the thermocouple unit of the ring-shaped thermoelectric material generator of the present embodiment is different from that of embodiment 1 in that: the p-type segmented thermoelectric material leg 3 of the thermocouple unit is composed of p-type high-temperature thermoelectric materials 10 (800-.
The legs of the thermoelectric material of the thermocouple unit may be of a multi-segmented design, such as 3-segment, 4-segment, 5-terminal, etc. In the embodiment, three sections are divided on the basis of uniform cross section in the radial direction. The p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are made of three sections of high-temperature thermoelectric materials, medium-temperature thermoelectric materials and low-temperature thermoelectric materials, so that the annular thermocouple can obtain a larger optimal value in the whole temperature range, the average optimal value of the high-temperature-difference thermocouple in the whole working temperature area can be improved by adopting the sectional structure, and the power generation performance is improved.
Since the generating efficiency of the annular thermoelectric generator is in direct proportion to the temperature difference between two ends of the device, the output power is in direct proportion to the square of the temperature difference. In order for a thermoelectric generator to have a large power generation capacity, the thermoelectric generator needs to operate under a large temperature difference condition. The adoption of the segmented structure can ensure that the annular thermocouple obtains a larger figure of merit in the whole temperature range.
The p-type thermoelectric material leg and the n-type thermoelectric material leg have equal cross sections in the radial direction, and have the maximum specific power at the moment according to the theoretical calculation of heat transfer.
Example 3
Referring to fig. 1 to 3, the present embodiment is one of the embodiments of a high temperature difference ring-type segmented thermoelectric material generator using the aforementioned thermocouple units, and is composed of a ring-shaped tube, a certain number of thermocouple units and lead-out electrodes, wherein the inner wall and the outer wall of the ring-shaped tube are made of heat-conducting electrically-insulating ceramic plates, the p-type and n-type thermoelectric material legs of the thermocouple units are made of segmented structures, the connecting electrode plates 6 at the inner side end surfaces of the p-type and n-type thermoelectric material legs are made of concentric arc end surfaces with the inner wall of the ring-shaped tube, the other ends of the two legs of each thermocouple unit are respectively connected with the previous or subsequent thermocouple unit through the electrode plates 6, the connecting electrode plates 6 at the outer side end surfaces of the p-type and n-type thermoelectric material legs are made of concentric arc end surfaces with the outer wall of the ring-, forming a ring thermocouple.
The thermocouple units adopting the thermoelectric material supporting legs with the segmented structures are clamped between two layers of heat-conducting electric-insulating ceramic plates on the inner wall and the outer wall of the annular tube, the thermocouple units are sequentially connected through metal connecting sheets/electrodes, and the starting ends and the tail ends of the thermocouple units are respectively connected with the leading-out electrodes.
Example 4
Referring to fig. 1 to 3, in the high temperature difference annular segmented thermoelectric material power generator of the present embodiment, as shown in fig. 3, the radial cross-sectional areas of the thermoelectric material legs of the thermocouple units are equal; taking theta as a circumferential included angle of the thermoelectric material supporting legs, wherein the total heights of the thermoelectric material supporting legs and the electrode plates are respectively the radial distance from the inner wall of the annular tube to the outer wall of the annular tube of the cylindrical heat source; the inner wall 5 of the annular tube is a high-temperature end, a high-temperature heat source 1 flows through the inner wall, and the outer wall 2 of the annular tube is a low-temperature end.
The adoption of the segmented structure can improve the average optimal value of the thermoelectric couple in the whole working temperature area and improve the power generation performance. Compared with the existing leg type annular thermoelectric material generator, the high-temperature segmented annular thermoelectric material generator has the advantages that the specific power is obviously improved, and the energy conversion efficiency is higher. The outer wall of the annular tube is provided with a radiating fin 2.
The annular thermoelectric material generator is suitable for a cylindrical heat source, and can realize effective utilization of waste heat particularly when the heat source is a coal-fired boiler or an automobile exhaust funnel. Referring to fig. 1 and 2, in the figure, 5 is a heat-conducting and electrically-insulating ceramic plate, 6 is a metal connecting sheet, and when the temperature difference exists between the central high-temperature heat source end 1 and the outermost low-temperature end (the outer wall 2 of the annular tube is provided with radiating fins), namely, the temperature difference exists between the central high-temperature heat source end 1 and the outermost low-temperature end (the outer wall 2
Figure 915234DEST_PATH_IMAGE001
) When the p-type semiconductor thermoelectric material 3 and the n-type semiconductor thermoelectric material 4 are connected as shown in fig. 2, electric current is generated in the ring-shaped thermoelectric material generator, and the conversion of thermal energy into electric energy is realized.
FIG. 2 shows an annular thermocouple unit of FIG. 1, theta being the circumferential angle of the legs of the thermoelectric material, T1For a centrally located high temperature heat source end temperature, T2The temperature of the outermost low-temperature end is delta T, r1And r2The radial distances from the circle center of the cylindrical heat source to the upper end and the lower end of the thermoelectric material supporting leg are respectively, the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are connected through the high-conductivity metal connecting sheet to form an annular thermocouple, and the annular thermocouple is clamped between the two heat-conducting electric insulation ceramic plates to form an annular thermoelectric generator with a sandwich structure. The annular thermoelectric material generator is used as a power supply of microelectronic devices and can also charge a storage battery.
As shown in fig. 3, the radial width of the ring-shaped thermoelectric generator is proportional to the radius, and the thickness is inversely proportional to the radius, so that the p-type and n-type thermoelectric material legs have the same cross-sectional area in the radial direction, and the specific power of the ring-shaped thermoelectric generator is the maximum.
Figure 4 is a graph showing a comparison of the efficiency of an annular segmented thermoelectric generator and a non-segmented thermoelectric generator with legs of thermoelectric material of equal cross-sectional area in the radial direction. Curve 1 is the efficiency of the annular segmented thermoelectric generatorηLength ratio to thermoelectric materialH 1/HH 2/HH 3/HThe segmented thermocouple arms are made of a high-temperature thermoelectric material CeFe4Sb12Medium-temperature thermoelectric materialMaterial TAGS-85, low-temperature thermoelectric material Bi2Te3Are composed in series, the corresponding lengths are respectively expressed asH 1H 2H 3Total length of segmented thermocouple armH=H 1+H 2+H 3The solid line, the broken line and the chain line respectively representH 3/H=0.01, 0.1 and 0.25, and the temperature difference between the two ends of the annular segmented thermoelectric generator is 1000K. Curves 2-4 represent the respective compositions by CeFe4Sb12、TAGS-85、Bi2Te3The power generator efficiency of the constructed non-segmented annular thermoelectric power generator is that the temperature difference between two ends of the device is the temperature difference of corresponding materials in the corresponding annular segmented thermoelectric power generator. As shown in fig. 4, compared with the non-segmented thermoelectric generator, the segmented design can significantly improve the efficiency of the ring device and the environmental temperature difference, and can improve the power generation performance.

Claims (6)

1. Thermocouple unit of a ring-shaped thermoelectric material generator comprising legs of p-type thermoelectric material (3), legs of n-type thermoelectric material (4) and metal connection tabs/electrodes (6), characterized in that: the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are of segmented structures, the p-type thermoelectric material supporting leg (3) and the n-type thermoelectric material supporting leg (4) are connected through a high-conductivity metal connecting sheet/electrode (6) to form an annular thermocouple unit, two end faces of the thermocouple unit are concentric arc end faces, theta is used as a circumferential included angle of the thermoelectric material supporting leg, and r is a circumferential included angle of the thermoelectric material supporting leg1And r2The radial distances from the circle center of the cylindrical heat source to the upper end and the lower end of the thermoelectric material supporting leg are respectively, the radial widths of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg in the thermocouple unit are in direct proportion to the radius, and the thicknesses of the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are in inverse proportion to the radius, so that the sectional areas of the p-type thermoelectric material supporting leg and the.
2. The thermocouple unit of the ring-shaped thermoelectric material power generator of claim 1, wherein: the p-type segmented thermoelectric material leg of the thermocouple unit is composed of a p-type high-temperature thermoelectric material (10), a p-type intermediate-temperature thermoelectric material (11) and a p-type low-temperature thermoelectric material (12), and the n-type segmented thermoelectric leg (4) of the thermocouple unit is composed of an n-type high-temperature thermoelectric material (7), an n-type intermediate-temperature thermoelectric material (8) and an n-type low-temperature thermoelectric material (9); the inner side end faces of the p-type thermoelectric material supporting legs and the n-type thermoelectric material supporting legs are connected by adopting electrode plates (6) which are also concentric arc end faces, and the outer side end faces of the thermoelectric material supporting legs of two adjacent thermocouple units are provided with the electrode plates (6) which are also concentric arc end faces.
3. The thermocouple unit of the ring-shaped thermoelectric material power generator according to claim 1 or 2, wherein: the p-type thermoelectric material supporting leg and the n-type thermoelectric material supporting leg are designed in n sections, and n is a natural number which is more than or equal to 2.
4. A high temperature difference ring-segmented thermoelectric material power generator using the thermoelectric element as claimed in claim 1, which is composed of a ring-shaped tube, a certain number of thermoelectric elements and extraction electrodes, and heat-conductive and electrically insulating ceramic plates are used for the inner wall and the outer wall of the ring-shaped tube, wherein: the p-type and n-type thermoelectric material supporting legs of the thermocouple units are of segmented structures, connecting electrode plates (6) on the inner side end faces of the p-type and n-type thermoelectric material supporting legs are concentric arc end faces with the inner wall of the annular pipe, the other ends of the two supporting legs of each thermocouple unit are respectively connected with a preceding thermocouple unit or a following thermocouple unit through the electrode plates (6), the connecting electrode plates (6) on the outer side end faces of the p-type and n-type thermoelectric material supporting legs are concentric arc end faces with the outer wall of the annular pipe, and the thermocouple units are clamped between two layers of heat-conducting electric-insulating ceramic plates on the inner wall and the outer wall of the annular pipe to form the.
5. The high temperature differential ring segmented thermoelectric material power generator of claim 4 wherein: the radial sectional areas of the thermoelectric material supporting legs of the thermocouple units are equal; taking theta as a circumferential included angle of the thermoelectric material supporting legs, wherein the total heights of the thermoelectric material supporting legs and the electrode plates are respectively the radial distance from the inner wall of the annular tube to the outer wall of the annular tube of the cylindrical heat source; the inner wall (5) of the annular pipe is a high-temperature end, a high-temperature heat source (1) flows through the inner part of the annular pipe, and the outer wall (2) of the annular pipe is a low-temperature end.
6. The high temperature differential ring segmented thermoelectric material power generator of claim 4 or 5, wherein: all the thermocouple units are sequentially connected through metal connecting sheets/electrodes, and the initial end and the tail end of each thermocouple unit are respectively connected with an extraction electrode; and the outer wall of the annular tube is provided with radiating fins (2).
CN201911162601.1A 2019-11-25 2019-11-25 High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof Pending CN110729393A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911162601.1A CN110729393A (en) 2019-11-25 2019-11-25 High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911162601.1A CN110729393A (en) 2019-11-25 2019-11-25 High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof

Publications (1)

Publication Number Publication Date
CN110729393A true CN110729393A (en) 2020-01-24

Family

ID=69224788

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911162601.1A Pending CN110729393A (en) 2019-11-25 2019-11-25 High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof

Country Status (1)

Country Link
CN (1) CN110729393A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114464725A (en) * 2022-02-07 2022-05-10 中国航空发动机研究院 Thermoelectric film, manufacturing method thereof and thermoelectric device
CN116059533A (en) * 2023-02-20 2023-05-05 湖南安泰康成生物科技有限公司 Active heat dissipation electrode slice and electrode device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114464725A (en) * 2022-02-07 2022-05-10 中国航空发动机研究院 Thermoelectric film, manufacturing method thereof and thermoelectric device
CN114464725B (en) * 2022-02-07 2024-05-24 中国航空发动机研究院 Thermoelectric film, thermoelectric film manufacturing method and thermoelectric device
CN116059533A (en) * 2023-02-20 2023-05-05 湖南安泰康成生物科技有限公司 Active heat dissipation electrode slice and electrode device
CN116059533B (en) * 2023-02-20 2023-11-21 湖南安泰康成生物科技有限公司 Active heat dissipation electrode slice and electrode device

Similar Documents

Publication Publication Date Title
CN108493322B (en) Thermocouple unit of annular thermoelectric material generator and annular thermoelectric material generator
CN102208885A (en) Phase change heat exchanger thermoelectric generation device
CN105576112B (en) Annular thermo-electric device
CN110729393A (en) High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof
CN107612426B (en) Ship Waste Heat recycles two-stage temperature difference electricity generation device
CN101882898A (en) Low temperature smoke temperature difference generator
WO2020181568A1 (en) Asymmetrical p-n junction thermocouple structure and parameter determination method therefor
CN202004695U (en) Phase-change heat exchanger temperature difference generating device
CN101436838A (en) Apparatus for thermo-electric generation using vehicle exhaust pipe
CN210535693U (en) High-temperature-difference annular segmented thermoelectric material generator and radial equal-sectional-area thermocouple unit thereof
CN201398163Y (en) Water tube type temperature difference generating tube and temperature difference generating device
CN208078022U (en) The thermocouple unit of annular thermoelectric material electric organ and annular thermoelectric material electric organ
CN109271673B (en) Method for calculating equivalent thermal conductivity of thermoelectric generation piece
KR20150136455A (en) Thermoelectric generation system and hybrid boiler using the same
CN102025295A (en) Semiconductor thermoelectric generator capable of realizing efficient integration and manufacturing method thereof
CN109360119A (en) It is a kind of become pin cross-sectional area thermoelectric generation film and its cross-sectional area determination method
WO2020186582A1 (en) High-power thermoelectric conversion module and thermoelectric conversion system
CN202217708U (en) Semiconductor temperature-difference power generation assembly
CN104702153A (en) Semiconductor temperature difference power generation device
WO2020118815A1 (en) In situ thermovoltaic power generation device
CN207554191U (en) A kind of micro-free-piston power plant with UTILIZATION OF VESIDUAL HEAT IN
CN107623464A (en) Thermoelectric generator
CN2067363U (en) Power generating range using waste heat
CN208820705U (en) A kind of electricity generation system using residual heat from kiln furnace
CN202308071U (en) Heat-conductive type semiconductor thermopile

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination