CN108486600A - High-purity hydrogen gas generating system - Google Patents

High-purity hydrogen gas generating system Download PDF

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Publication number
CN108486600A
CN108486600A CN201810543810.XA CN201810543810A CN108486600A CN 108486600 A CN108486600 A CN 108486600A CN 201810543810 A CN201810543810 A CN 201810543810A CN 108486600 A CN108486600 A CN 108486600A
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China
Prior art keywords
hydrogen
water
hydrogen gas
generation system
formation apparatus
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Pending
Application number
CN201810543810.XA
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Chinese (zh)
Inventor
李国强
丁佳力
李燕飞
姚宇希
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NEKSON POWER TECHNOLOGY Co Ltd
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NEKSON POWER TECHNOLOGY Co Ltd
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Priority to CN201810543810.XA priority Critical patent/CN108486600A/en
Publication of CN108486600A publication Critical patent/CN108486600A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/02Process control or regulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Combustion & Propulsion (AREA)
  • Automation & Control Theory (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention provides a kind of high-purity hydrogen gas generating system, belongs to hydrogen generation technique field.The present invention proposes a kind of high-purity hydrogen gas generating system; including hydrogen formation apparatus; the moisture separator that hydrogen in hydrogen aqueous mixtures caused by the hydrogen formation apparatus and water are detached, to the pressure protective device of dry purifying plant and real time monitoring Hydrogen Line pressure;The moisture separator includes with separation chamber and being placed in the indoor water proof air-permeable member that can be obstructed water, gas is allowed to penetrate of separation.The purity of hydrogen can be improved under the collective effect of the configuration of the present invention is simple, purifying plant and moisture separator, it is simple in structure, it is safe.Pressure protective device can ensure that system operational security is reliable, cuts off, powers in time.

Description

High-purity hydrogen gas generating system
Technical field
The present invention relates to hydrogen generation technique field, specially a kind of high-purity hydrogen gas generating system.
Background technology
Hydrogen is the gas of known density minimum in the world, only the 1/14 of air.Hydrogen also can be used as filling out for balloon Inflatable body is widely used in meteorological field.Hydrogen is as a kind of clean energy resource, its application field will with the development of science and technology Constantly extension.The safe handling of hydrogen is to influence hydrogen one key factor of use scope, and hydrogen is impure to bring prodigious peace Full hidden danger.
Same type hydrogen generator mostly uses greatly water electrolysis hydrogen producing in the market, and the hydrogen manufacturing of current electrolysis water all has process can be real Show full-automation, using more convenient advantage, but has equipment volume and weight larger, expensive disadvantage.It needs to add Add 30%KOH solution, complex technical process, energy consumption is big, and hydrogen manufacturing is of high cost, produces hydrogen purity 99.7%, purity is relatively low.Every 12 The moon must replace the electrolyte solution in electrolytic cell.The electrolyte used is KOH(Potassium hydroxide), sodium hydroxide is corrosive goods Matter, it is necessary to be handled with care.Replacement process at least needs the startup time of the cooling time and 4 hours of 8 hours.It must be in advance Empty all electrolyte solutions used before.Potassium hydroxide meeting etching apparatus, can damage in the course of time.It is unstable to produce hydrogen Fixed, pressure stability accuracy rating is more than 0.001MPa, cannot realize flow entirely certainly according to hydrogen usage size needed for instrument It is dynamic to adjust.There are electrolyte leakage risks, can skin ambustion.The Chinese patent of Patent No. CN103387210A discloses one kind Methanol water hydrogen production system and method, including:Liquid container, raw material conveying device, hydrogen producer, membrane separation device;Liquid The first alcohol and water of liquid is stored in storage container, raw material conveying device provides power;Hydrogen made from hydrogen producer is delivered to Membrane separation device is detached, and the difference of the inside and outside pressure of the membrane separation device for detaching hydrogen is more than or equal to 1.1MPa.Methanol Volatile and harmful, safety is poor in use for the invention, and membrane separation device is palladium-silver input Of high cost, obtained hydrogen purity is low.
Invention content
Poor to solve process for making hydrogen safety in the prior art, the hydrogen purity of preparation is not high, and production hydrogen is unstable, uses The disadvantage present invention of journey complexity proposes a kind of high-purity hydrogen gas generating system, including hydrogen formation apparatus, and the hydrogen is occurred The moisture separator of hydrogen and water separation in hydrogen aqueous mixtures caused by device, to dry purifying plant and real time monitoring The pressure protective device of Hydrogen Line pressure;The moisture separator includes with separation chamber and being placed in separation and indoor capable of hindering Water proof, the water proof air-permeable member for allowing gas to penetrate.
Preferably, the hydrogen formation apparatus is SPE membrane electrolysis cells.
Preferably, the hydrogen formation apparatus further includes fuzzy control tracking system, to control hydrogen generation Rate.
Preferably, the moisture separator further includes reaching maximum water level time control in the indoor liquid of separation The water level sensor of liquid discharge processed.
Preferably, the purifying plant is multilevel hierarchy, the first order is water-absorbent material, and the second level is molecular sieve, the Three-level is gas catalyst, and the fourth stage is water-absorbent material.
Preferably, the water-absorbent material is one or more in water-absorbing resin, absorbent cotton, silica gel, sponge.
Preferably, the gas catalyst is dehydrogenation catalyst.
Preferably, further include safety monitoring equipment, for detecting the gas production in the hydrogen manufacture in time, And alarm.
The present invention utilizes the purity that hydrogen can be improved under the collective effect of purifying plant and moisture separator, structure letter It is single, it is safe;Pressure protective device can ensure that system operational security is reliable, cuts off, powers in time.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of high-purity hydrogen gas generating system in the embodiment of the present invention.
Wherein, 1- hydrogen formation apparatus;2- moisture separators;3- pressure protective devices;4- purifying plants;5- security monitorings Equipment;11-SPE membrane electrolysis cells;12- fuzzy control tracking systems;The separation chambers 21-;22- water proof air-permeable members;23- level sensors Device.
Specific implementation mode
Referring to Fig. 1, the high-purity hydrogen gas generating system of the embodiment of the present invention, including hydrogen formation apparatus 1, by the hydrogen The moisture separator 2 of hydrogen and vapor separation, fills to dry purification in hydrogen aqueous mixtures caused by gas generating means 1 The pressure protective device 3 of 4 and real time monitoring Hydrogen Line pressure is set, the moisture separator 2 includes with separation chamber 21 and housing In the water proof air-permeable member 22 that can be obstructed water, gas is allowed to penetrate in separation chamber 21.
Contain certain moisture in the gas prepared in hydrogen formation apparatus 1, the impurities affect of hydrogen, which hydrogen, to be made With safety in the process.Therefore setting moisture separator 2, in the separation chamber 21 that hydrogen aqueous mixtures enter moisture separator 2 Hydrogen and vapor are separated by water proof air-permeable member 22 afterwards.The action principle of water proof air-permeable member 22 has superfine close Hole, vapor upwards spring up when can be hindered, be attached in water proof air-permeable member 22, stop under gravity to Upper movement, and hydrogen will not affected by gravity and water proof air-permeable member 22 inhibition, continue up, realize hydrogen The separation of gas and vapor.
Hydrogen formation apparatus 1 can be SPE membrane electrolysis cells 11, solid polymer electrolyte water electrolysis technology, abbreviation SPE Water electrolysis technology, with the arriving of hydrogen energy era, it shows new vitality again.SPE water electrolysis technologies are mainly characterized by Traditional caustic solution electrolyte is replaced with solid polymer electrolyte.So-called solid polymer is generally perfluorinated sulfonic acid matter Proton exchange, sulfonic group have the property for transmitting hydrogen ion, become good conductor after immersion, have good lead to hydrogen ion Logical effect.
When supplying deionized water to the anode of electrolytic cell proton exchange membrane and passing to direct current, water is just electrolysed, in sun Extremely upper to generate oxygen, the proton generated on anode is conducted by proton exchange membrane and is combined to form hydrogen with the electronics generated on cathode Gas, the mechanism such as reaction equation of reaction process(1)With(2).
Anode:2H2O = 4H+ + O2 + 4e-(1)
Cathode:4H+ + 4e- = 2H2(2)
The mixed flow of the hydrogen and vapor that are generated in cathode enters in moisture separator 2, completes aqueous vapor separation.
Can also include fuzzy control tracking system 12 in hydrogen formation apparatus 1, to control the rate of hydrogen generation. Automatic constant-pressure, constant current are realized using fuzzy control tracking system 12, so that pressure stability accuracy rating is less than 0.001MPa, and can root Flow full-automatic regulation is realized according to hydrogen usage size needed for instrument.
When 2 part of moisture separator may be provided for the arrival maximum water level of the liquid in the separation chamber 21 Control the water level sensor 23 of liquid discharge.Ensureing that the liquid in separation chamber 21 is discharged in time, maximum water level is unsuitable excessively high, with Ensure that moisture separator 2 can achieve the effect that good aqueous vapor separation.
The foreign gas when main function of purifying plant 4 in Adsorption hydrogen, the purifying plant 4 are multistage tie Structure, the first order are water-absorbent material, and the second level is molecular sieve, and the third level is gas catalyst, and the fourth stage is water-absorbent material.Through excessive Grade purification can ensure that hydrogen has good purity.Wherein, water-absorbent material is in water-absorbing resin, absorbent cotton, silica gel, sponge It is one or more.This level-one is to further remove the vapor mixed in hydrogen.The gas catalyst is urged for deoxidation Agent.
Further include safety monitoring equipment 5, for detecting hydrogen gas production and Times in the hydrogen manufacture in time It is alert.Safety monitoring equipment 5 can monitor hydrogen gas production and alarm in reaction system pipeline in time, ensure whole system Safety in hydrogen production process.
Pure water electrolytic hydrogen production is realized using the technical program, and hydrogen purification is realized using multistage hydrogen purification device, is carried Hydrogen purity is up to 99.999% after pure;
Can also include fuzzy control tracking system in hydrogen formation apparatus, to control the rate of hydrogen generation, and can root Flow full-automatic regulation is realized according to hydrogen usage size needed for instrument;
It is low to produce hydrogen humidity, uses SPE membrane separation techniques and effective dehumidification device, reduces original humidity, is inhaled using multistage It is attached, it ensure that the purity and humidity of hydrogen.
The present invention is not limited to above-mentioned specific embodiment, and the invention may be variously modified and varied.Every foundation The technical spirit of the present invention should be included in the present invention to embodiment of above any modification, equivalent replacement, improvement and so on Protection domain.

Claims (8)

1. high-purity hydrogen gas generating system, which is characterized in that including hydrogen formation apparatus, produced by the hydrogen formation apparatus Hydrogen aqueous mixtures in hydrogen and water separation moisture separator, to dry purifying plant and real time monitoring Hydrogen Line pressure The pressure protective device of power;The moisture separator include with separation chamber and be placed in separation it is indoor can obstruct water, allow The water proof air-permeable member that gas penetrates.
2. hydrogen gas generation system according to claim 1, which is characterized in that the hydrogen formation apparatus is electrolysed for SPE films Slot.
3. hydrogen gas generation system according to claim 2, which is characterized in that the hydrogen formation apparatus further includes Fuzzy Control Tracking system processed, to control the rate of hydrogen generation.
4. hydrogen gas generation system according to claim 1, which is characterized in that the moisture separator further includes at described point The water level sensor of control liquid discharge when reaching maximum water level from indoor liquid.
5. hydrogen gas generation system according to claim 1, which is characterized in that the purifying plant be multilevel hierarchy, first Grade is water-absorbent material, and the second level is molecular sieve, and the third level is gas catalyst, and the fourth stage is water-absorbent material.
6. hydrogen gas generation system according to claim 5, which is characterized in that the water-absorbent material is water-absorbing resin, degreasing It is one or more in cotton, silica gel, sponge.
7. hydrogen gas generation system according to claim 6, which is characterized in that the gas catalyst is dehydrogenation catalyst.
8. hydrogen gas generation system according to claim 1, which is characterized in that further include safety monitoring equipment, for timely Detect the gas production and alarm in the hydrogen manufacture.
CN201810543810.XA 2018-05-31 2018-05-31 High-purity hydrogen gas generating system Pending CN108486600A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110656341A (en) * 2019-10-31 2020-01-07 李媛媛 Hydrogen energy intelligent water-connection hydrogen production equipment
CN111020618A (en) * 2019-11-28 2020-04-17 北京中氢源工程科技有限公司 Multifunctional hydrogen absorption machine

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102703920A (en) * 2011-03-28 2012-10-03 陆敏慧 Generator for hydrogen preparation
CN202808344U (en) * 2012-09-13 2013-03-20 上海合既得动氢机器有限公司 Efficient methanol-water hydrogen production system
CN103337645A (en) * 2013-06-28 2013-10-02 江苏中靖新能源科技有限公司 Improved hydrogen production and power generation all-in-one machine
CN103601149A (en) * 2013-11-08 2014-02-26 宁波工程学院 Work system for preparing and purifying hydrogen energy resource and control method thereof
CN205193558U (en) * 2015-12-18 2016-04-27 廊坊黎明气体有限公司 Water electrolytic hydrogen production's hydrogen, oxygen separator protection device
CN205556102U (en) * 2016-02-03 2016-09-07 辽宁华科石油设备科技有限公司 Nitrogen gas air producer
CN106086928A (en) * 2016-08-26 2016-11-09 孙铭远 A kind of hydrogen generating device
CN106532087A (en) * 2016-09-30 2017-03-22 李连博 Fuel power battery electricity generator and electricity generation method
CN208362478U (en) * 2018-05-31 2019-01-11 浙江高成绿能科技有限公司 High-purity hydrogen gas generating system

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102703920A (en) * 2011-03-28 2012-10-03 陆敏慧 Generator for hydrogen preparation
CN202808344U (en) * 2012-09-13 2013-03-20 上海合既得动氢机器有限公司 Efficient methanol-water hydrogen production system
CN103337645A (en) * 2013-06-28 2013-10-02 江苏中靖新能源科技有限公司 Improved hydrogen production and power generation all-in-one machine
CN103601149A (en) * 2013-11-08 2014-02-26 宁波工程学院 Work system for preparing and purifying hydrogen energy resource and control method thereof
CN205193558U (en) * 2015-12-18 2016-04-27 廊坊黎明气体有限公司 Water electrolytic hydrogen production's hydrogen, oxygen separator protection device
CN205556102U (en) * 2016-02-03 2016-09-07 辽宁华科石油设备科技有限公司 Nitrogen gas air producer
CN106086928A (en) * 2016-08-26 2016-11-09 孙铭远 A kind of hydrogen generating device
CN106532087A (en) * 2016-09-30 2017-03-22 李连博 Fuel power battery electricity generator and electricity generation method
CN208362478U (en) * 2018-05-31 2019-01-11 浙江高成绿能科技有限公司 High-purity hydrogen gas generating system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110656341A (en) * 2019-10-31 2020-01-07 李媛媛 Hydrogen energy intelligent water-connection hydrogen production equipment
CN111020618A (en) * 2019-11-28 2020-04-17 北京中氢源工程科技有限公司 Multifunctional hydrogen absorption machine

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