CN111020618A - Multifunctional hydrogen absorption machine - Google Patents
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- CN111020618A CN111020618A CN201911190039.3A CN201911190039A CN111020618A CN 111020618 A CN111020618 A CN 111020618A CN 201911190039 A CN201911190039 A CN 201911190039A CN 111020618 A CN111020618 A CN 111020618A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M16/00—Devices for influencing the respiratory system of patients by gas treatment, e.g. mouth-to-mouth respiration; Tracheal tubes
- A61M16/0003—Accessories therefor, e.g. sensors, vibrators, negative pressure
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- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
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- C25B13/00—Diaphragms; Spacing elements
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- C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61M2202/00—Special media to be introduced, removed or treated
- A61M2202/02—Gases
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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Abstract
The invention discloses a multifunctional hydrogen absorption machine which is characterized by comprising a shell, a water tank, an electrolytic cell and a gas-water separator, wherein the water tank, the electrolytic cell and the gas-water separator are arranged in the shell; the shell is provided with a hydrogen outlet and a water outlet, and the water tank is provided with a water filling port; the electrolytic cell comprises a cell body, and an electrolytic cell anode chamber, an electrolytic cell cathode chamber, an SPE diaphragm, a cathode plate and an anode plate which are arranged in the cell body; the bottom of the water tank is communicated with an anode chamber of the electrolytic cell through a water feeding pipe, and the anode chamber of the electrolytic cell is communicated with the side wall of the water tank through an oxygen discharging pipe; the cathode chamber of the electrolytic cell is communicated with the side wall of the gas-water separator through a hydrogen discharge pipe; the top of the gas-water separator is communicated with the hydrogen outlet through a hydrogen outlet pipe; the bottom of the gas-water separator is communicated with the side wall of the water tank through a water delivery pipe; the electrolytic bath body is communicated with the water outlet through a water discharge pipe. The hydrogen absorption machine disclosed by the invention is beneficial to human health, high in safety, dry-burning prevention, low in cost and high in hydrogen generation efficiency and purity.
Description
Technical Field
The invention relates to the technical field of hydrogen generating equipment, in particular to a multifunctional hydrogen absorption machine.
Background
Oxygen is a substance essential for aerobic organisms to sustain life. Oxygen is important and indispensable because oxygen is the only final acceptor of electrons in the human body, and without oxygen, cells cannot continuously carry out substance and energy metabolism, and cannot obtain energy required for all life activities of the organism from nutrient substances. However, when a human body breathes oxygen for a long time, oxygen accumulated in the body generates certain toxicity due to excessive active oxygen generated in the body. Meanwhile, haze, computer radiation, solar ultraviolet rays, dust in the air, staying up all night and the like all generate active oxygen in the body, and the active oxygen accumulated in the body is a cause of aging of the human body and becomes a disease of various diseases. Hydrogen molecules have extremely strong permeability and selective antioxidation, and are nontoxic, colorless and tasteless. After the human body replenishes hydrogen molecules, active oxygen free radicals can be neutralized, generated water is discharged out of the body, and the method is safe and effective.
A large number of researches show that hydrogen molecules can play a role in treating and improving various tissue and organ injuries such as brains and spinal cords and various 160 diseases such as diabetes, arteriosclerosis, malignant tumors and cardiovascular and cerebrovascular diseases, generally, the hydrogen molecules have the following characteristics that ① has the activity of selectively removing toxic free radicals and resisting oxidative damage, ② has excellent tissue diffusion capacity which is not possessed by other drug molecules, ③ has the functions of wide prevention, treatment or health care for various injuries, ④ hydrogen molecules can be flexibly combined with other prevention and treatment technical means, and ⑤ hydrogen molecule products are safe, simple and convenient to use.
In the prior art, a plurality of methods for replenishing hydrogen molecules to human bodies mainly comprise drinking hydrogen water and breathing hydrogen, and compared with the traditional drinking hydrogen water, the breathing hydrogen can provide higher dosage and is suitable for treatment; breathe hydrogen and have stronger pertinence to respiratory system disease, improve the aspect to the sleep, breathe hydrogen's effect more obvious than drinking hydrogen water effect. One of the devices essential in the process of breathing hydrogen is a hydrogen absorption machine, and the quality of the structure and the performance of the hydrogen absorption machine directly determines the treatment effect of diseases.
The existing hydrogen absorbers start electrolysis when a switch is started, but in practice, a pipeline has some air before water enters an electrolytic cell, and if electrolysis is started when air is exhausted, the electrolytic cell has a period of dry burning, so that the service life of the electrolytic cell is greatly shortened due to the dry burning. In addition, some hydrogen absorbers on the market are used directly after generating hydrogen, and if hydrogen is absorbed for a long time, water and gas can be accumulated to enter an air passage, and choking can be caused. In addition, the existing hydrogen absorption machine usually adopts a platinum membrane electrode to enable the hydrogen absorption machine to have higher electrolytic efficiency, and platinum is a noble metal, so that the hydrogen absorption machine has higher manufacturing cost and is only suitable for being applied in experiments, public medical treatment or scenes without considering cost.
Therefore, it is very important to develop a hydrogen absorber with low cost, capable of generating high-purity hydrogen and preventing dry burning.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the hydrogen absorption machine which is beneficial to human health, high in safety, dry-burning prevention, low in cost, high in hydrogen generation efficiency and high in purity.
In order to achieve the purpose, the invention adopts the technical scheme that:
a multifunctional hydrogen absorption machine is characterized by comprising a shell, a water tank, an electrolytic cell and a gas-water separator, wherein the water tank, the electrolytic cell and the gas-water separator are arranged in the shell; the shell is provided with a hydrogen outlet and a water outlet, and the water tank is provided with a water filling port; the electrolytic cell comprises a cell body, and an electrolytic cell anode chamber, an electrolytic cell cathode chamber, an SPE diaphragm, a cathode plate and an anode plate which are arranged in the cell body; the bottom of the water tank is communicated with an anode chamber of the electrolytic cell through a water feeding pipe, and the anode chamber of the electrolytic cell is communicated with the side wall of the water tank through an oxygen discharging pipe; the cathode chamber of the electrolytic cell is communicated with the side wall of the gas-water separator through a hydrogen discharge pipe; the top of the gas-water separator is communicated with the hydrogen outlet through a hydrogen outlet pipe; the bottom of the gas-water separator is communicated with the side wall of the water tank through a water delivery pipe; the electrolytic bath body is communicated with the water outlet through a water discharge pipe.
Furthermore, a one-way valve is arranged on the water discharge pipe and can control the discharge of water in the electrolytic bath.
Furthermore, a one-way valve is arranged on the water adding pipe and can control water in the water tank to enter the electrolytic bath.
Furthermore, a pressure limiting valve, a barometer and a flow display are arranged on the hydrogen outlet pipe.
Furthermore, the electrolytic cell also comprises a power supply, and the power supply is connected with the cathode plate and the anode plate in series through conducting wires.
Further, the SPE diaphragm is a proton exchange membrane, and the preparation method comprises the following steps: mixing 2,3,4,5, 6-pentafluoro-1-vinyl phenyl sulfonate, acrylonitrile, vinyl benzene sulfonic acid, dodecafluoro-1, 9-decadiene, an emulsifier and a photoinitiator, carrying out ultrasonic treatment for 5-10 minutes, then pouring into a template, placing in a nitrogen or inert gas atmosphere, and irradiating for 30-50 minutes under ultraviolet light with the wavelength of 200-260nm to obtain the SPE diaphragm.
Preferably, the mass ratio of the 2,3,4,5, 6-pentafluoro-1-vinylsulfonic acid phenyl ester to the acrylonitrile to the vinylbenzenesulfonic acid to the dodecafluoro-1, 9-decadiene to the emulsifier to the photoinitiator is 1:2:1:0.3:0.1 (0.03-0.05).
Preferably, the emulsifier is one selected from sodium dodecyl benzene sulfonate, polyoxypropylene polyoxyethylene glycerol ether and nonylphenol polyoxyethylene ether.
Preferably, the photoinitiator is at least one of benzoin ethyl ether and benzoin isopropyl ether.
Preferably, the inert gas is one of helium, neon and argon.
The working principle of the hydrogen absorption machine related by the invention is as follows: pure water or distilled water meeting the requirements (sent into an anode chamber of an electrolytic cell) is decomposed by taking electrons at the anode immediately after being electrified by SPE technology (2H)2O-4e=O2↑+4H+) Hydrogen ions and oxygen gas are generated, and the oxygen gas is discharged from the anode. Hydrogen ion as hydrate ion (H)3O+) Reach the cathode through SPE ion membrane under the action of electric field force to absorb electrons to form hydrogen (H)2) And the hydrogen is discharged from the cathode chamber, enters a gas-water separator to generate wet high-concentration hydrogen, and is subjected to quantum treatment to obtain the hydrogen with more comfortable inhalation feeling.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages: the multifunctional hydrogen absorption machine provided by the invention is beneficial to human health, high in safety, dry-burning prevention, low in cost, high in hydrogen generation efficiency and purity, simple in structure, convenient to use and convenient to maintain and repair.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only one embodiment of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a schematic view showing the overall structure of a hydrogen absorbing machine produced in the example;
wherein the reference numerals are: 1. a housing; 2. a water tank; 3. an electrolytic cell; 4. a gas-water separator; 5. a hydrogen outlet; 6. a water outlet; 7. a water filling port; 8. a trough body; 9. an anode chamber of the electrolytic cell; 10 electrolytic cell cathode chamber; 11. an SPE membrane; 12. a cathode plate; 13. an anode plate; 14. a water feeding pipe; 15 oxygen discharge pipes; 16. a hydrogen discharge pipe; 17. a hydrogen outlet pipe; 18. a water delivery pipe; 19. a drain pipe; 20 a pressure limiting valve; 21. a barometer; 22. and a flow display.
Detailed Description
The following provides a detailed description of preferred embodiments of the invention.
A multifunctional hydrogen absorption machine is characterized by comprising a shell, a water tank, an electrolytic cell and a gas-water separator, wherein the water tank, the electrolytic cell and the gas-water separator are arranged in the shell; the shell is provided with a hydrogen outlet and a water outlet, and the water tank is provided with a water filling port; the electrolytic cell comprises a cell body, and an electrolytic cell anode chamber, an electrolytic cell cathode chamber, an SPE diaphragm, a cathode plate and an anode plate which are arranged in the cell body; the bottom of the water tank is communicated with an anode chamber of the electrolytic cell through a water feeding pipe, and the anode chamber of the electrolytic cell is communicated with the side wall of the water tank through an oxygen discharging pipe; the cathode chamber of the electrolytic cell is communicated with the side wall of the gas-water separator through a hydrogen discharge pipe; the top of the gas-water separator is communicated with the hydrogen outlet through a hydrogen outlet pipe; the bottom of the gas-water separator is communicated with the side wall of the water tank through a water delivery pipe; the electrolytic bath body is communicated with the water outlet through a water discharge pipe.
Furthermore, a one-way valve is arranged on the water discharge pipe and can control the discharge of water in the electrolytic bath; the water feeding pipe is provided with a one-way valve which can control water in the water tank to enter the electrolytic bath; the hydrogen outlet pipe is provided with a pressure limiting valve, a barometer and a flow display; the electrolytic cell also comprises a power supply, and the power supply is connected with the cathode plate and the anode plate in series through conducting wires.
Further, the SPE diaphragm is a proton exchange membrane, and the preparation method comprises the following steps: mixing 2,3,4,5, 6-pentafluoro-1-vinyl phenyl sulfonate, acrylonitrile, vinyl benzene sulfonic acid, dodecafluoro-1, 9-decadiene, an emulsifier and a photoinitiator, carrying out ultrasonic treatment for 5-10 minutes, then pouring into a template, placing in a nitrogen or inert gas atmosphere, and irradiating for 30-50 minutes under ultraviolet light with the wavelength of 200-260nm to obtain the SPE diaphragm.
Preferably, the mass ratio of the 2,3,4,5, 6-pentafluoro-1-vinylsulfonic acid phenyl ester to the acrylonitrile to the vinylbenzenesulfonic acid to the dodecafluoro-1, 9-decadiene to the emulsifier to the photoinitiator is 1:2:1:0.3:0.1 (0.03-0.05); the emulsifier is selected from one of sodium dodecyl benzene sulfonate, polyoxypropylene polyoxyethylene glycerol ether and nonylphenol polyoxyethylene ether; the photoinitiator is at least one of benzoin ethyl ether and benzoin isopropyl ether; the inert gas is one of helium, neon and argon.
The working principle of the hydrogen absorption machine related by the invention is as follows: pure water or distilled water meeting the requirements (sent into an anode chamber of an electrolytic cell) is decomposed by taking electrons at the anode immediately after being electrified by SPE technology (2H)2O-4e=O2↑+4H+) Hydrogen ions and oxygen gas are generated, and the oxygen gas is discharged from the anode. Hydrogen ion as hydrate ion (H)3O+) Reach the cathode through SPE ion membrane under the action of electric field force to absorb electrons to form hydrogen (H)2) And the hydrogen is discharged from the cathode chamber, enters a gas-water separator to generate wet high-concentration hydrogen, and is subjected to quantum treatment to obtain the hydrogen with more comfortable inhalation feeling.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages: the hydrogen absorption machine provided by the invention is beneficial to human health, high in safety, dry-burning prevention, low in cost, high in hydrogen generation efficiency and purity, simple in structure, convenient to use and convenient to maintain and repair.
The invention will be further described with reference to specific examples, but the scope of the invention is not limited thereto.
Example 1
A hydrogen absorption machine is characterized by comprising a shell 1, a water tank 2, an electrolytic cell 3 and a gas-water separator 4, wherein the water tank 2, the electrolytic cell 3 and the gas-water separator 4 are arranged in the shell 1; a hydrogen outlet 5 and a water outlet 6 are arranged on the shell 1, and a water filling port 7 is arranged on the water tank 2; the electrolytic cell 3 comprises a cell body 8, and an electrolytic cell anode chamber 9, an electrolytic cell cathode chamber 10, an SPE diaphragm 11, a cathode plate 12 and an anode plate 13 which are arranged in the cell body 8; the bottom of the water tank 2 is communicated with an anode chamber 9 of the electrolytic cell through a water adding pipe 14, and the anode chamber 9 of the electrolytic cell is communicated with the side wall of the water tank 2 through an oxygen discharge pipe 15; the cathode chamber 10 of the electrolytic cell is communicated with the side wall of the gas-water separator 4 through a hydrogen discharge pipe 16; the top of the gas-water separator 4 is communicated with the hydrogen outlet 5 through a hydrogen outlet pipe 17; the bottom of the gas-water separator 4 is communicated with the side wall of the water tank 2 through a water conveying pipe 18; the electrolytic cell body 8 is communicated with the water outlet 6 through a water discharge pipe 19.
The water discharge pipe 19 is provided with a check valve which can control the discharge of water in the electrolytic bath 3.
The water feeding pipe 14 is provided with a one-way valve which can control the water in the water tank 2 to enter the electrolytic bath 3.
The hydrogen outlet pipe 17 is provided with a pressure limiting valve 20, a barometer 21 and a flow display 22.
The electrolytic tank 3 also comprises a power supply which is connected with the cathode plate 12 and the anode plate 13 in series through conducting wires.
The SPE diaphragm is a proton exchange membrane, and the preparation method comprises the following steps: mixing 2,3,4,5, 6-pentafluoro-1-vinyl phenyl sulfonate, acrylonitrile, vinyl benzene sulfonic acid, dodecafluoro-1, 9-decadiene, an emulsifier and a photoinitiator, carrying out ultrasonic treatment for 5 minutes, then pouring the mixture into a template, placing the template in a nitrogen atmosphere, and irradiating the template for 30 to 50 minutes under ultraviolet light with the wavelength of 200nm to obtain an SPE diaphragm; the mass ratio of the 2,3,4,5, 6-pentafluoro-1-vinylsulfonic acid phenyl ester to the acrylonitrile to the vinylbenzenesulfonic acid to the dodecafluoro-1, 9-decadiene to the emulsifier to the photoinitiator is 1:2:1:0.3:0.1: 0.03; the emulsifier is sodium dodecyl benzene sulfonate; the photoinitiator is benzoin ethyl ether.
The above embodiments are merely illustrative of the technical ideas and features of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement the present invention, and not to limit the protection scope of the present invention. All equivalent changes and modifications made according to the spirit of the present invention should be covered within the protection scope of the present invention.
Claims (10)
1. A multifunctional hydrogen absorption machine is characterized by comprising a shell, a water tank, an electrolytic cell and a gas-water separator, wherein the water tank, the electrolytic cell and the gas-water separator are arranged in the shell; the shell is provided with a hydrogen outlet and a water outlet, and the water tank is provided with a water filling port; the electrolytic cell comprises a cell body, and an electrolytic cell anode chamber, an electrolytic cell cathode chamber, an SPE diaphragm, a cathode plate and an anode plate which are arranged in the cell body; the bottom of the water tank is communicated with an anode chamber of the electrolytic cell through a water feeding pipe, and the anode chamber of the electrolytic cell is communicated with the side wall of the water tank through an oxygen discharging pipe; the cathode chamber of the electrolytic cell is communicated with the side wall of the gas-water separator through a hydrogen discharge pipe; the top of the gas-water separator is communicated with the hydrogen outlet through a hydrogen outlet pipe; the bottom of the gas-water separator is communicated with the side wall of the water tank through a water delivery pipe; the electrolytic bath body is communicated with the water outlet through a water discharge pipe.
2. The multifunctional hydrogen absorption machine as claimed in claim 1, wherein the water discharge pipe is provided with a check valve for controlling the discharge of water from the electrolysis bath.
3. The multifunctional hydrogen absorption machine as claimed in claim 1, wherein the water feeding pipe is provided with a one-way valve for controlling water in the water tank to enter the electrolytic bath.
4. The multifunctional hydrogen absorption machine as claimed in claim 1, wherein the hydrogen outlet pipe is provided with a pressure limiting valve, a barometer and a flow display.
5. The multi-functional hydrogen absorption machine according to claim 1, wherein the electrolysis tank further comprises a power supply, and the power supply is connected in series with the cathode plate and the anode plate through leads.
6. The multifunctional hydrogen getter of claim 1, wherein the SPE membrane is a proton exchange membrane, and the preparation method thereof comprises the following steps: mixing 2,3,4,5, 6-pentafluoro-1-vinyl phenyl sulfonate, acrylonitrile, vinyl benzene sulfonic acid, dodecafluoro-1, 9-decadiene, an emulsifier and a photoinitiator, carrying out ultrasonic treatment for 5-10 minutes, then pouring into a template, placing in a nitrogen or inert gas atmosphere, and irradiating for 30-50 minutes under ultraviolet light with the wavelength of 200-260nm to obtain the SPE diaphragm.
7. The multifunctional hydrogen absorption machine as claimed in claim 6, wherein the mass ratio of the 2,3,4,5, 6-pentafluoro-1-vinylsulfonic acid phenyl ester, the acrylonitrile, the vinylbenzenesulfonic acid, the dodecafluoro-1, 9-decadiene, the emulsifier and the photoinitiator is 1:2:1:0.3:0.1 (0.03-0.05).
8. The multifunctional hydrogen absorption machine according to claim 6, wherein the emulsifier is selected from one of sodium dodecyl benzene sulfonate, polyoxypropylene polyoxyethylene glycerol ether and nonylphenol polyoxyethylene ether.
9. The multifunctional hydrogen getter of claim 6, wherein the photoinitiator is at least one of benzoin ethyl ether and benzoin isopropyl ether.
10. The multifunctional hydrogen getter of claim 6 wherein the inert gas is one of helium, neon, and argon.
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| CN111658926A (en) * | 2020-06-16 | 2020-09-15 | 山东卫康生物医药科技有限公司 | Preparation method of hydrogen absorption machine |
| CN112354054A (en) * | 2020-11-30 | 2021-02-12 | 杭州粟源科技有限公司 | Safety hydrogen absorption machine |
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