CN108486582A - A kind of stainless steel work-piece paraffin removal cleaning agent and preparation method thereof that adds lustre to - Google Patents

A kind of stainless steel work-piece paraffin removal cleaning agent and preparation method thereof that adds lustre to Download PDF

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Publication number
CN108486582A
CN108486582A CN201810570377.9A CN201810570377A CN108486582A CN 108486582 A CN108486582 A CN 108486582A CN 201810570377 A CN201810570377 A CN 201810570377A CN 108486582 A CN108486582 A CN 108486582A
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CN
China
Prior art keywords
stainless steel
paraffin removal
acid amide
steel work
removal cleaning
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Pending
Application number
CN201810570377.9A
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Chinese (zh)
Inventor
盘茂东
陈喜良
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YANGJIANG WEIYI POLISHING MATERIAL CO Ltd
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YANGJIANG WEIYI POLISHING MATERIAL CO Ltd
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Priority to CN201810570377.9A priority Critical patent/CN108486582A/en
Publication of CN108486582A publication Critical patent/CN108486582A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/088Iron or steel solutions containing organic acids

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention discloses a kind of stainless steel work-piece paraffin removal cleaning agents and preparation method thereof that adds lustre to.The stainless steel work-piece raw material that the paraffin removal cleaning agent that adds lustre to includes following weight percent:Straight chain fatty acid amide 17 35%, organic acid 10 25%, softening agent 2 21%, builder 0.5 3%, the water of surplus.The stainless steel work-piece of the present invention is with the paraffin removal cleaning agent that adds lustre to using the principle and similar compatibility principle reacted using acid ion as foundation, the activating agent of paraffin removal compound preferably, and the processing that adds lustre to is carried out to stainless steel surface using organic acid, to realize paraffin removal and bright difunctional effect;Preparation method is simple, is advantageously implemented industrialized production.

Description

A kind of stainless steel work-piece paraffin removal cleaning agent and preparation method thereof that adds lustre to
Technical field
The present invention relates to a kind of cleaning agent, specifically a kind of stainless steel work-piece paraffin removal cleaning agent and its preparation side of adding lustre to Method.
Background technology
Stainless steel work-piece needs to clean up the wax dirt for being adhered to workpiece surface after scutching cotton piece buff and wax polishing; Sometimes stainless steel kettle inner wall adds lustre to without polishing and by the way of directly cleaning, and reaches customer demand.Currently, city Common stainless steel paraffin removal cleaning agent has polyethenoxy ether class, oleate soap, coconut oil diethanol amide and its phosphate ester salt on field, Sulfonates;These stainless steel paraffin removal cleaning agents are neutral a bit or alkalinity, primarily serve paraffin removal cleaning performance, do not have Light enhancing effect;Also some stainless steel paraffin removal cleaning agents are acid, primarily serve degreasing and rust removal light enhancing effect, but paraffin removal is clear Wash power deficiency.Therefore, the present invention provides a kind of not only with degreasing and rust removal light enhancing effect but also with the stainless steel of paraffin removal cleaning performance The workpiece paraffin removal cleaning agent and preparation method thereof that adds lustre to.
Invention content
The purpose of the present invention is to provide a kind of stainless steel work-piece paraffin removal cleaning agents and preparation method thereof that adds lustre to, to solve The problems mentioned above in the background art.
To achieve the above object, the present invention provides the following technical solutions:
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 17-35%, organic acid 10-25%, softening agent 2-21%, builder 0.5- 3%, the water of surplus.
As a further solution of the present invention:The straight chain fatty acid amide includes cerinic acid amide, lignin acid amide, flower Raw acid amide, stearic amide, oleamide, rosin acid amide, floating oleamide, palmitamide, lauric amide, Pork and beans The composition of cool acid amide, cocinic acid amide, certain herbaceous plants with big flowers acid amide and the 2-4 kinds in n-nonanoic acid amide.
As a further solution of the present invention:The organic acid includes formic acid, glacial acetic acid, tartaric acid, citric acid and fourth two One or more compositions in acid.
As a further solution of the present invention:The builder includes one in boric acid, EDTA-2 sodium and sodium gluconate Kind or a variety of compositions.
As a further solution of the present invention:The softening agent is using in OP10, peregal, a conduit made of long bamboo oil and polyethers activating agent One or more compositions.
As a further solution of the present invention:Further include catalyst, the mass ratio of catalyst and straight chain fatty acid amide is (5-10):(17-35);The catalyst uses inorganic base.
As a further solution of the present invention:The inorganic base uses sodium hydroxide or potassium hydroxide.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 2-3h, dispensed after standing to obtain the final product.
As a further solution of the present invention:Step (2) is sufficiently stirred curing 2.5h, is dispensed after standing 0.5h.
Compared with prior art, the beneficial effects of the invention are as follows:
The principle and similar compatibility that the stainless steel work-piece of the present invention is reacted with paraffin removal cleaning agent is added lustre to using acid ion Principle is foundation, to the activating agent of paraffin removal compound preferably, and carry out the processing that adds lustre to stainless steel surface using organic acid, from And realize paraffin removal and bright difunctional effect;Preparation method is simple, is advantageously implemented industrialized production.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 17%, organic acid 10%, softening agent 8%, builder 0.5%, surplus Water.The straight chain fatty acid amide includes cerinic acid amide and certain herbaceous plants with big flowers acid amide, and the mass ratio of cerinic acid amide and certain herbaceous plants with big flowers acid amide is 12:5; The organic acid includes formic acid, glacial acetic acid and citric acid, and the mass ratio of formic acid, glacial acetic acid and citric acid is 2:3:5;Described help is washed Agent includes EDTA-2 sodium;The softening agent is oily using peregal and an a conduit made of long bamboo, and the mass ratio of peregal and a conduit made of long bamboo oil is 5:3.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 2h, dispensed after standing to obtain the final product.
Embodiment 2
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 25%, organic acid 16%, softening agent 14%, builder 1%, the water of surplus. The straight chain fatty acid amide includes cerinic acid amide and certain herbaceous plants with big flowers acid amide, and the mass ratio of cerinic acid amide and certain herbaceous plants with big flowers acid amide is 15:10;Institute It includes formic acid, glacial acetic acid and citric acid to state organic acid, and the mass ratio of formic acid, glacial acetic acid and citric acid is 3:5:8;The builder Including EDTA-2 sodium;The softening agent is oily using peregal and an a conduit made of long bamboo, and the mass ratio of peregal and a conduit made of long bamboo oil is 8:6.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 3h, dispensed after standing to obtain the final product.
Embodiment 3
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 20%, organic acid 15%, softening agent 8%, builder 1.5%, surplus Water.The straight chain fatty acid amide includes lignin acid amide, rosin acid amide and certain herbaceous plants with big flowers acid amide, lignin acid amide, rosin The mass ratio of sour amide and certain herbaceous plants with big flowers acid amide is 12:5:3;The organic acid includes formic acid and citric acid;The matter of formic acid and citric acid Amount is than being 5:10;The builder includes boric acid and EDTA-2 sodium, and the mass ratio of boric acid and EDTA-2 sodium is 1:0.5;It is described soft Agent uses OP10 and polyethers activating agent, and the mass ratio of OP10 and polyethers activating agent is 5:3.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 2.5h, dispensed after standing to obtain the final product.
Embodiment 4
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 30%, organic acid 23%, softening agent 14%, builder 3%, the water of surplus. The straight chain fatty acid amide includes lignin acid amide, rosin acid amide and certain herbaceous plants with big flowers acid amide, lignin acid amide, rosin acid acyl The mass ratio of amine and certain herbaceous plants with big flowers acid amide is 15:10:5;The organic acid includes formic acid and citric acid;The mass ratio of formic acid and citric acid It is 8:15;The builder includes boric acid and EDTA-2 sodium, and the mass ratio of boric acid and EDTA-2 sodium is 2:1;The softening agent is adopted With OP10 and polyethers activating agent, the mass ratio of OP10 and polyethers activating agent is 8:6.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 2.1h, dispensed after standing to obtain the final product.
Embodiment 5
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 17%, organic acid 15%, softening agent 13%, builder 0.5%, surplus Water.The straight chain fatty acid amide includes rosin acid amide and floating oleamide, the quality of rosin acid amide and floating oleamide Than being 12:5;The organic acid includes glacial acetic acid and citric acid, and the mass ratio of glacial acetic acid and citric acid is 10:5;The builder Including EDTA-2 sodium;The softening agent is using peregal, a conduit made of long bamboo oil and polyethers activating agent, peregal, a conduit made of long bamboo oil and polyethers activating agent Mass ratio is 5:3:5.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 2.3h, dispensed after standing to obtain the final product.
Embodiment 6
A kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece include following with the paraffin removal cleaning agent that adds lustre to The raw material of weight percent:Straight chain fatty acid amide 25%, organic acid 25%, softening agent 21%, builder 1%, the water of surplus. The straight chain fatty acid amide includes rosin acid amide and floating oleamide, and the mass ratio of rosin acid amide and floating oleamide is 15:10;The organic acid includes glacial acetic acid and citric acid, and the mass ratio of glacial acetic acid and citric acid is 15:10;The builder packet Include EDTA-2 sodium;The softening agent using peregal, an a conduit made of long bamboo oil and polyethers activating agent, peregal, an a conduit made of long bamboo oil and polyethers activating agent matter Amount is than being 8:5:8.
A kind of stainless steel work-piece preparation method for the paraffin removal cleaning agent that adds lustre to, includes the following steps:(1) according to above-mentioned formula Each raw material is weighed, it is spare;(2) water is added into reaction kettle, adds other in addition to straight chain fatty acid amide and softening agent Material, the stirring and dissolving in addition, then adds softening agent, finally adds straight chain fatty acid amide and is filled after the completion of material addition Divide stirring curing 2.7h, dispensed after standing to obtain the final product.
Embodiment 7
As different from Example 1, a kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece is with adding lustre to Paraffin removal cleaning agent includes the raw material of following weight percent:Straight chain fatty acid amide 35%, organic acid 12%, catalyst 5% are soft Agent 2%, builder 1.2%, the water of surplus;The catalyst uses inorganic base.The straight chain fatty acid amide includes peanut The composition that sour amide, stearic amide, oleamide and palmitamide are mixed according to arbitrary proportion.The organic acid uses Tartaric acid.The builder includes the composition that boric acid, EDTA-2 sodium and sodium gluconate are mixed according to arbitrary proportion.The nothing Machine alkali uses sodium hydroxide.The softening agent uses OP10.
Embodiment 8
As different from Example 1, a kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece is with adding lustre to Paraffin removal cleaning agent includes the raw material of following weight percent:Straight chain fatty acid amide 28%, organic acid 22%, catalyst 10%, Softening agent 5%, builder 2%, the water of surplus;The catalyst uses inorganic base.The straight chain fatty acid amide includes bay The composition that sour amide, myristic acid amide, cocinic acid amide and n-nonanoic acid amide are mixed according to arbitrary proportion.The organic acid The composition mixed according to arbitrary proportion including formic acid, glacial acetic acid, citric acid and succinic acid.The builder include boric acid, The composition that EDTA-2 sodium and sodium gluconate are mixed according to arbitrary proportion.The inorganic base uses potassium hydroxide.The softening The composition that agent is mixed using OP10, peregal, a conduit made of long bamboo oil and polyethers activating agent according to arbitrary proportion.
Embodiment 9
As different from Example 1, a kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, the stainless steel work-piece is with adding lustre to Paraffin removal cleaning agent includes the raw material of following weight percent:Straight chain fatty acid amide 30%, organic acid 19%, catalyst 6% are soft Agent 10%, builder 0.8%, the water of surplus;The catalyst uses inorganic base.The straight chain fatty acid amide includes rosin The composition that sour amide, floating oleamide, palmitamide, cocinic acid amide are mixed according to arbitrary proportion.The organic acid The composition mixed according to arbitrary proportion including formic acid, glacial acetic acid, tartaric acid, citric acid and succinic acid.The builder includes The composition that boric acid and sodium gluconate are mixed according to arbitrary proportion.The inorganic base uses sodium hydroxide.The softening agent is adopted The composition mixed according to arbitrary proportion with OP10, a conduit made of long bamboo oil and polyethers activating agent.
Experimental example
Test comparison is carried out to embodiment 1-6 and conventional wax removing agent, as a result see the table below shown.
Table test comparison result
To sum up test, embodiment 1-6 is compared with conventional wax removing agent, not only shortens the paraffin removal time, and deoiling effect and Luminosity also reaches requirement, and wherein embodiment 1-2 integration capabilities are preferable.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective Various changes can be made.

Claims (9)

1. a kind of stainless steel work-piece paraffin removal cleaning agent that adds lustre to, which is characterized in that the stainless steel work-piece is cleaned with the paraffin removal that adds lustre to Agent includes the raw material of following weight percent:Straight chain fatty acid amide 17-35%, organic acid 10-25%, softening agent 2-21% are helped and are washed Agent 0.5-3%, the water of surplus.
2. the stainless steel work-piece according to claim 1 paraffin removal cleaning agent that adds lustre to, which is characterized in that the straight chain fatty acid Amide includes cerinic acid amide, lignin acid amide, arachidamide, stearic amide, oleamide, rosin acid amide, oil slick In sour amide, palmitamide, lauric amide, myristic acid amide, cocinic acid amide, certain herbaceous plants with big flowers acid amide and n-nonanoic acid amide The composition of 2-4 kinds.
3. the stainless steel work-piece according to claim 1 paraffin removal cleaning agent that adds lustre to, which is characterized in that the organic acid includes One or more compositions in formic acid, glacial acetic acid, tartaric acid, citric acid and succinic acid.
4. the stainless steel work-piece according to claim 1 paraffin removal cleaning agent that adds lustre to, which is characterized in that the builder includes One or more compositions in boric acid, EDTA-2 sodium and sodium gluconate.
5. the stainless steel work-piece according to claim 1 paraffin removal cleaning agent that adds lustre to, which is characterized in that the softening agent uses One or more compositions in OP10, peregal, a conduit made of long bamboo oil and polyethers activating agent.
6. the stainless steel work-piece according to claim 1 paraffin removal cleaning agent that adds lustre to, which is characterized in that further include catalyst, The mass ratio of catalyst and straight chain fatty acid amide is(5-10):(17-35);The catalyst uses inorganic base.
7. the stainless steel work-piece according to claim 6 paraffin removal cleaning agent that adds lustre to, which is characterized in that the inorganic base uses Sodium hydroxide or potassium hydroxide.
8. a kind of preparation method according to any stainless steel work-piece paraffin removal cleaning agents that add lustre to of claim 1-7, special Sign is, includes the following steps:(1)Each raw material is weighed according to above-mentioned formula, it is spare;(2)Water is added into reaction kettle, is added Unclassified stores in addition to straight chain fatty acid amide and softening agent, the stirring and dissolving in addition, then adds softening agent, finally adds Add straight chain fatty acid amide, after the completion of material addition, be sufficiently stirred curing 2-3h, dispensed after standing to obtain the final product.
9. the stainless steel work-piece according to claim 8 preparation method for the paraffin removal cleaning agent that adds lustre to, which is characterized in that step (2)It is sufficiently stirred curing 2.5h, is dispensed after standing 0.5h.
CN201810570377.9A 2018-06-05 2018-06-05 A kind of stainless steel work-piece paraffin removal cleaning agent and preparation method thereof that adds lustre to Pending CN108486582A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110305643A (en) * 2019-06-21 2019-10-08 西安石油大油气科技有限公司 A kind of environment-friendly type oil field Wax removing agent and preparation method thereof
CN111234965A (en) * 2020-01-15 2020-06-05 东莞市四辉表面处理科技有限公司 Novel oleic soap for efficient industrial wax removal and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555440A (en) * 2008-12-08 2009-10-14 东莞市松山湖微电子材料研发中心 Method for producing cleaning agent for removing wax and oil
CN103215611A (en) * 2013-03-27 2013-07-24 沈阳帕卡濑精有限总公司 Phosphorus-free water-based metal cleaning agent
CN103603001A (en) * 2013-11-06 2014-02-26 天津圳鹏清洗技术开发有限公司 Copper alloy low-temperature cleaning agent
CN104674249A (en) * 2013-11-28 2015-06-03 青岛科润塑料机械有限公司 Improved cleaning agent
CN106367764A (en) * 2016-10-13 2017-02-01 武汉杰生润滑科技有限公司 Water-based detergent for aluminum alloy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101555440A (en) * 2008-12-08 2009-10-14 东莞市松山湖微电子材料研发中心 Method for producing cleaning agent for removing wax and oil
CN103215611A (en) * 2013-03-27 2013-07-24 沈阳帕卡濑精有限总公司 Phosphorus-free water-based metal cleaning agent
CN103603001A (en) * 2013-11-06 2014-02-26 天津圳鹏清洗技术开发有限公司 Copper alloy low-temperature cleaning agent
CN104674249A (en) * 2013-11-28 2015-06-03 青岛科润塑料机械有限公司 Improved cleaning agent
CN106367764A (en) * 2016-10-13 2017-02-01 武汉杰生润滑科技有限公司 Water-based detergent for aluminum alloy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110305643A (en) * 2019-06-21 2019-10-08 西安石油大油气科技有限公司 A kind of environment-friendly type oil field Wax removing agent and preparation method thereof
CN111234965A (en) * 2020-01-15 2020-06-05 东莞市四辉表面处理科技有限公司 Novel oleic soap for efficient industrial wax removal and preparation method thereof

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Application publication date: 20180904