CN108485839A - One kind is except mould wash bottle additive and its preparation method and application method - Google Patents

One kind is except mould wash bottle additive and its preparation method and application method Download PDF

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Publication number
CN108485839A
CN108485839A CN201810155715.2A CN201810155715A CN108485839A CN 108485839 A CN108485839 A CN 108485839A CN 201810155715 A CN201810155715 A CN 201810155715A CN 108485839 A CN108485839 A CN 108485839A
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CN
China
Prior art keywords
parts
mould wash
wash bottle
additive
sodium
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Pending
Application number
CN201810155715.2A
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Chinese (zh)
Inventor
高倩
李洋
杜明辉
林俊彬
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An Jiekang Bio Tech Ltd Beijing
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An Jiekang Bio Tech Ltd Beijing
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Publication date
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Priority to CN201810155715.2A priority Critical patent/CN108485839A/en
Publication of CN108485839A publication Critical patent/CN108485839A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/12Carbonates bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/06Hydroxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/16Phosphates including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3245Aminoacids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/36Organic compounds containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/18Glass; Plastics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides one kind removing mould wash bottle additive, includes the raw material composition of following parts by weight:40 85 parts of sodium bicarbonate, 10 30 parts of SODIUM PERCARBONATE, 5 30 parts of chelating agent.Present invention simultaneously provides this preparation method and application methods except mould wash bottle additive.The vial bottle label using the present invention cleaned except mould wash bottle additive falls off no glue trace by original state, body clear transparent, does not hang droplet inside and outside bottle, mildew cleans rate and reaches 99.5% or more.

Description

One kind is except mould wash bottle additive and its preparation method and application method
Technical field
The present invention relates to one kind except mould wash bottle additive and its preparation method and application method, belongs to the clear of recycling vial Field is washed, particular for the cleaning field of mildew bottle.
Background technology
Beer, beverage, dairy industry are quickly grown in recent years, have a large amount of vial, porcelain vase recycling to put into production every year It uses, generally has normal returnable bottle and stacking accumulation bottle more than half a year, especially there was dampness in the air in southern temperature height, bottle The case where sub- turnaround time long environment, a large amount of vials can form weathercock bottle and can also have mould growth, worm's ovum, wherein mould Spot bottle is reached the standard grade direct cleaning, and most of is that cleaning is sordid.
When clean-in-place can multiple backwash mildew bottle, and can increase in process detergent concentration or improve cleaning temperature Degree, but temperature is excessively high to make mildew cure, high temperature, it is high-alkali can also damage bottle, cause bottle to hang white, it is brightless, be easy broken bottle, Bottle explosion,.It is clear dangerous bigger.Technique hardly possible is washed, it is not easy to operate to become the big problem for cleaning mildew bottle, while in cleaning process The middle consumption that can increase the energy such as water, electricity also has a large amount of sewage and generates.
Invention content
It is an object of the invention to solve above-mentioned technical problem, the present invention provides a kind of novel, highly effective and safe, high decontamination Ability, focus on the application are in except mould wash bottle additive.
The present invention provides one kind removing mould wash bottle additive, including the raw material group of following parts by weight becomes:Sodium bicarbonate 40- 85 parts, 10-30 parts of SODIUM PERCARBONATE, 5-30 parts of chelating agent.
The present invention's removes mould wash bottle additive, and the raw material group of further preferred parts by weight becomes:60 parts of sodium bicarbonate, mistake 30 parts of sodium carbonate, 10 parts of chelating agent.
Further, the chelating agent in above-mentioned raw materials is preferably sodium gluconate, sodium tripolyphosphate, ethylenediamine tetra-acetic acid two Sodium(EDTA-2Na), tetrasodium ethylenediamine tetraacetate(EDTA-4Na), 1-hydroxy ethylidene-1,1-diphosphonic acid(HEDP)Or aminotrimethylene phosphine Acid(ATMP), solid 1-hydroxy ethylidene-1,1-diphosphonic acid(HEDP)Or solid aminotrimethylenephoacidnic acidnic (ATMP)(ATMP)
Present invention simultaneously provides a kind of preparation method except mould wash bottle additive, the specific steps are:
First, sodium bicarbonate, SODIUM PERCARBONATE and each raw material of chelating agent component ratio by weight are weighed, then by above-mentioned all originals Material is added to together, is uniformly mixed;
Above-mentioned material component is:40-85 parts of sodium bicarbonate, 10-30 parts of SODIUM PERCARBONATE, 5-30 parts of chelating agent.
Further, the preparation method of mould wash bottle additive is preferably removed, material component therein is preferably:Sodium bicarbonate 60 parts, 30 parts of SODIUM PERCARBONATE, 10 parts of chelating agent.
Further, the preparation method of mould wash bottle additive is preferably removed, chelating agent therein preferably is selected from gluconic acid Sodium, sodium tripolyphosphate, disodium ethylene diamine tetraacetate(EDTA-2Na), tetrasodium ethylenediamine tetraacetate(EDTA-4Na), solid hydroxyl Ethylene-diphosphonic acid(HEDP)Or solid aminotrimethylenephoacidnic acidnic (ATMP)(ATMP).
The present invention also provides a kind of application method except mould wash bottle additive, the specific steps are:
First prepare to be sufficiently mixed and be uniformly prepared by sodium bicarbonate, SODIUM PERCARBONATE and each raw material of chelating agent component ratio by weight Remove mould wash bottle additive, this is sufficiently mixed uniformly except mould wash bottle additive is added to alkaline cleaner then, is then applied In the wash cycles to mildew bottle, finally cleaned again with water;
The above-mentioned material component except mould wash bottle additive is:40-85 parts of sodium bicarbonate, 10-30 parts of SODIUM PERCARBONATE, chelating agent 5-30 Part.
Further, the application method of mould wash bottle additive, the raw material group therein except mould wash bottle additive are preferably removed Part it is preferably:60 parts of sodium bicarbonate, 30 parts of SODIUM PERCARBONATE, 10 parts of chelating agent.
Further, the application method of mould wash bottle additive is preferably removed, it is therein except mould wash bottle additive and alkalinity The mixed proportion of cleaning agent is most preferably mass percent 0.5 ~ 1.0%;
Alkaline cleaner therein is preferably 2% sodium hydroxide solution;And temperature in use is preferably 70-85 DEG C, to mildew beer Bottle wash cycles, then cleaned with water.
The present invention's generates a kind of oxide of high activity substance-hydroxyl free except mould wash bottle additive can react in use Base can almost aoxidize all organic matters, so the effect used is very good.
The present invention's removes mould wash bottle additive during concrete application, is preferably added to 2% alkaline cleaner cooperation and makes With.It may insure once to clean in place in this way, without cleaning operation repeatedly, cleaning requirement can be rapidly achieved, can be reduced Sewage discharge reduces water consumption, saves time and the energy, make cleaning more quickly, energy-saving and environmental protection.
The present invention's can reach following effect except mould wash bottle additive:
The vial bottle label cleaned falls off no glue trace by original state, body clear transparent, does not hang droplet inside and outside bottle, mildew is washed Net rate reaches 99.5% or more.
The present invention's is used cooperatively with alkaline cleaner except mould wash bottle additive, can effectively remove mildew in vial, Worm's ovum, bottle mark.
The mould wash bottle additive that removes of the present invention is suitable for various water quality, and cleaning performance is not by water quality impact.
The present invention's crosses water except easy after the cleaning of mould wash bottle additive, does not have residual.
Specific implementation mode
The present invention is further explained in the light of specific embodiments, so that those skilled in the art can be better Understand the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.
Embodiment 1
It is provided in this embodiment to remove mould wash bottle additive, it is made of the ingredient of following parts by weight:
Sodium bicarbonate 60
SODIUM PERCARBONATE 30
Chelating agent 10
Production technology
Application method:
It is added to mould wash bottle additive is removed made from the present embodiment in the sodium hydroxide solution that effective alkali content is 2% by 0.5%, Under the conditions of 70 DEG C -85 DEG C, mildew beer bottle wash cycles after twenty minutes, then with water are cleaned.
Prepared by the present embodiment except mould wash bottle additive using effect:
The vial bottle label cleaned falls off no glue trace by original state, body clear transparent, does not hang droplet inside and outside bottle, mildew is washed Net rate reaches 99.9%.
It demonstrates and is exclusively used in being used cooperatively with alkaline cleaner except mould wash bottle additive by the present invention, glass can be effectively removed Mildew, worm's ovum and bottle mark in bottle.And the present invention except the cleaning performance of mould wash bottle additive is not by water quality impact, and adopt Easy water excessively after mould wash bottle additive cleans is removed with the present invention, does not have residual.
Embodiment 2
The offer of the present embodiment removes mould wash bottle additive, is made of the ingredient of following parts by weight:
Sodium bicarbonate 55
SODIUM PERCARBONATE 30
Chelating agent 15
Production technology:With embodiment 1, wherein chelating agent uses sodium tripolyphosphate.
Application method:With embodiment 1
Prepared by the present embodiment except mould wash bottle additive using effect:
The vial bottle label cleaned falls off no glue trace by original state, body clear transparent, does not hang droplet inside and outside bottle, mildew is washed Net rate reaches 99.6%.
It demonstrates and is exclusively used in being used cooperatively with alkaline cleaner except mould wash bottle additive by the present invention, glass can be effectively removed Mildew, worm's ovum and bottle mark in bottle.And the present invention except the cleaning performance of mould wash bottle additive is not by water quality impact, and adopt Easy water excessively after mould wash bottle additive cleans is removed with the present invention, does not have residual.
Embodiment 3
The beer industry beer bottle of the offer of the present embodiment removes mould wash bottle additive, is made of the ingredient of following parts by weight:
Sodium bicarbonate 70
SODIUM PERCARBONATE 25
Chelating agent 5
Production technology:With embodiment 1, wherein chelating agent uses EDTA-4Na.
Application method:With embodiment 1
Prepared by the present embodiment except mould wash bottle additive using effect:
The vial bottle label cleaned falls off no glue trace by original state, body clear transparent, does not hang droplet inside and outside bottle, mildew is washed Net rate reaches 99.8%.
It demonstrates and is exclusively used in being used cooperatively with alkaline cleaner except mould wash bottle additive by the present invention, glass can be effectively removed Mildew, worm's ovum and bottle mark in bottle.And the present invention except the cleaning performance of mould wash bottle additive is not by water quality impact, and adopt Easy water excessively after mould wash bottle additive cleans is removed with the present invention, does not have residual.
Embodiment 4
The beer industry beer bottle of the offer of the present embodiment removes mould wash bottle additive, is made of the ingredient of following parts by weight:
Sodium bicarbonate 65.0
SODIUM PERCARBONATE 20.0
Chelating agent 15.0
Production technology:With embodiment 1, wherein chelating agent uses solid HEDP.
Application method:With embodiment 1
Prepared by the present embodiment except mould wash bottle additive using effect:
The vial bottle label cleaned falls off no glue trace by original state, body clear transparent, does not hang droplet inside and outside bottle, mildew is washed Net rate reaches 99.7%.
It demonstrates and is exclusively used in being used cooperatively with alkaline cleaner except mould wash bottle additive by the present invention, glass can be effectively removed Mildew, worm's ovum and bottle mark in bottle.And the present invention except the cleaning performance of mould wash bottle additive is not by water quality impact, and adopt Easy water excessively after mould wash bottle additive cleans is removed with the present invention, does not have residual.
Embodiment described above is only to absolutely prove preferred embodiment that is of the invention and being lifted, protection model of the invention It encloses without being limited thereto.Those skilled in the art on the basis of the present invention made by equivalent substitute or transformation, in the present invention Protection domain within.Protection scope of the present invention is subject to claims.

Claims (9)

1. one kind removing mould wash bottle additive, which is characterized in that the raw material composition including following parts by weight:40-85 parts of sodium bicarbonate, 10-30 parts of SODIUM PERCARBONATE, 5-30 parts of chelating agent.
2. according to claim 1 remove mould wash bottle additive, which is characterized in that the raw material composition including following parts by weight: 60 parts of sodium bicarbonate, 30 parts of SODIUM PERCARBONATE, 10 parts of chelating agent.
3. according to claim 1 or 2 remove mould wash bottle additive, which is characterized in that the chelating agent is selected from gluconic acid Sodium, sodium tripolyphosphate, disodium ethylene diamine tetraacetate(EDTA-2Na), tetrasodium ethylenediamine tetraacetate(EDTA-4Na), hydroxy ethylidene Di 2 ethylhexyl phosphonic acid(HEDP)Or aminotrimethylenephosphonic acid(ATMP).
4. a kind of preparation method except mould wash bottle additive, which is characterized in that by sodium bicarbonate, SODIUM PERCARBONATE and each original of chelating agent Material component ratio by weight is weighed, and is then added to together above-mentioned all raw materials, is uniformly mixed;
Above-mentioned material component is:40-85 parts of sodium bicarbonate, 10-30 parts of SODIUM PERCARBONATE, 5-30 parts of chelating agent.
5. the preparation method according to claim 4 except mould wash bottle additive, which is characterized in that the material component For:60 parts of sodium bicarbonate, 30 parts of SODIUM PERCARBONATE, 10 parts of chelating agent.
6. the preparation method according to claim 4 or 5 except mould wash bottle additive, which is characterized in that the chelating agent choosing From sodium gluconate, sodium tripolyphosphate, disodium ethylene diamine tetraacetate(EDTA-2Na), tetrasodium ethylenediamine tetraacetate(EDTA- 4Na), solid 1-hydroxy ethylidene-1,1-diphosphonic acid(HEDP)Or solid aminotrimethylenephoacidnic acidnic (ATMP)(ATMP).
7. a kind of application method except mould wash bottle additive, which is characterized in that include the following steps:
First prepare to be sufficiently mixed and be uniformly prepared by sodium bicarbonate, SODIUM PERCARBONATE and each raw material of chelating agent component ratio by weight Remove mould wash bottle additive, this is sufficiently mixed uniformly except mould wash bottle additive is added to alkaline cleaner then, is then applied In the wash cycles to mildew bottle, finally cleaned again with water;
The above-mentioned material component except mould wash bottle additive is:40-85 parts of sodium bicarbonate, 10-30 parts of SODIUM PERCARBONATE, chelating agent 5-30 Part.
8. the application method according to claim 7 except mould wash bottle additive, which is characterized in that described except mould wash bottle is added The material component of agent is:60 parts of sodium bicarbonate, 30 parts of SODIUM PERCARBONATE, 10 parts of chelating agent.
9. the application method according to claim 7 or 8 except mould wash bottle additive, it is characterised in that:
The mould wash bottle additive and the mixed proportion of alkaline cleaner of removing is mass percent 0.5 ~ 1.0%;
The alkaline cleaner is selected from 2% sodium hydroxide solution;
Temperature in use is 70-85 DEG C.
CN201810155715.2A 2018-02-23 2018-02-23 One kind is except mould wash bottle additive and its preparation method and application method Pending CN108485839A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810155715.2A CN108485839A (en) 2018-02-23 2018-02-23 One kind is except mould wash bottle additive and its preparation method and application method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810155715.2A CN108485839A (en) 2018-02-23 2018-02-23 One kind is except mould wash bottle additive and its preparation method and application method

Publications (1)

Publication Number Publication Date
CN108485839A true CN108485839A (en) 2018-09-04

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110846143A (en) * 2019-11-26 2020-02-28 河南昊化黎明智能清洗科技有限公司 Bottle washing additive and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1305523A (en) * 1998-06-16 2001-07-25 艾尔·赛厄蒙 Cleaning solution and method
CN1981023A (en) * 2004-06-25 2007-06-13 埃科莱布有限公司 Warewashing composition for use in automatic dishwashing machines
CN101611128A (en) * 2006-12-29 2009-12-23 索尔维公司 The blend that contains percarbonate is used for the purposes of washing composition and dishwashing formulations
CN103849498A (en) * 2012-11-29 2014-06-11 埃科莱布美国股份有限公司 Cleaning additive and cleaning method adopting the cleaning additive
CN105802744A (en) * 2016-04-18 2016-07-27 江南大学 Washing liquid for washing glass vessels

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1305523A (en) * 1998-06-16 2001-07-25 艾尔·赛厄蒙 Cleaning solution and method
CN1981023A (en) * 2004-06-25 2007-06-13 埃科莱布有限公司 Warewashing composition for use in automatic dishwashing machines
CN101611128A (en) * 2006-12-29 2009-12-23 索尔维公司 The blend that contains percarbonate is used for the purposes of washing composition and dishwashing formulations
CN103849498A (en) * 2012-11-29 2014-06-11 埃科莱布美国股份有限公司 Cleaning additive and cleaning method adopting the cleaning additive
CN105802744A (en) * 2016-04-18 2016-07-27 江南大学 Washing liquid for washing glass vessels

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110846143A (en) * 2019-11-26 2020-02-28 河南昊化黎明智能清洗科技有限公司 Bottle washing additive and preparation method thereof

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