CN108485454A - Fast thawing environment-friendly type hot melt gage mark coating and preparation method - Google Patents
Fast thawing environment-friendly type hot melt gage mark coating and preparation method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The present invention provides a kind of fast thawing environment-friendly type hot melt gage mark coating and preparation method, the parts by weight group of raw material becomes：110 120 parts of Petropols, modified 8 10 parts of plasticizer, 10 12 parts of wax, 15 30 parts of pigment, 0 350 parts of glass microballoon, 550 850 parts of filler, 1 1.5 parts of water, 0.2 1.5 parts of antioxidant.Water in component forms emulsification azeotropic mixture with oily matter in process of production, improves the compatibility between component, can reduce the additive amount of Petropols；In work progress, as temperature increases, emulsification azeotropic mixture extend water hot stage residence time, even heat is conducted in the volatilization of water, stirring resistance is also reduced while accelerating coating material melt, so that coating is not easy coking, final water can volatilize completely, oily matter comes back in component, so the performance of coating is unaffected, while energy saving, improve the stain resistance of coating, the decomposition product that Petropols are generated through ultraviolet light irradiation can also be reduced, reduces the discharge of VOC so that coating is more environmentally-friendly.
Description
【Technical field】
The present invention relates to road administration technical field of coatings more particularly to a kind of fast thawing environment-friendly type hot melt gage mark coating and preparation sides
Method.
【Background technology】
In recent years, with the development that field of traffic makes rapid progress, roadmarking has been widely used for the highway of each grade
It is the important component of traffic trip and traffic safety in airport environment.Road traffic marking to be subjected to wind, solarization,
Drench with rain, the evils such as high temperature, high humility, low temperature omit environment, wheel rolls abrasion, notably northerly winter also often to face anti-
The tearing of slot, the erosion etc. of snow-melting agent.Therefore due to the particularity of traffic marking application environment, determines and prepare roadmarking material
The particularity of material itself.
The material component of existing gage mark coating would generally include oleophilic substances and the fillers such as resinae, wax class, plasticizer
The hydrophilic substances such as class, so compatibility of the coating when heating fusing is poor, so cause coating in heating fusion process
Time is longer, and stirring resistance is big, and localized hyperthermia causes coating coking knot carbon, so finally formed graticule exist wear no resistance,
The technical problems such as color is not bright-coloured, service life is short.Furthermore it is the indices about gage mark coating that are up to state standards, it is existing
There is in the material component of gage mark coating organic matter account for relatively high, waste of resource while increases the pollution to environment.
Therefore, the performance for how improving gage mark coating, to promote the development of gage mark coating, be those skilled in the art urgently
The technical issues of solution.
【Invention content】
In view of this, an embodiment of the present invention provides a kind of fast thawing environment-friendly type hot melt gage mark coating and preparation method, the mark
Line coating property is excellent, and compatibility is preferable, is not easy coking in heating fusion process, difficulty of construction is relatively low, enables to most end form
At graticule have beautiful color, higher wearability, excellent environmental suitability and longer usage time, be suitable for I
The most areas of state.
On the one hand, an embodiment of the present invention provides a kind of fast thawing environment-friendly type hot melt gage mark coating, the parts by weight groups of raw material
Become：110-120 parts of Petropols, modified 8-10 parts of plasticizer, 10-12 parts of wax, 15-30 parts of pigment, glass microballoon 0-350
Part, 550-850 parts of filler, 1-1.5 parts of water, 0.2-1.5 parts of antioxidant.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the oil tree
Fat is one or both of modified C 5 petroleum resin, modified m-pentadiene petro-resin and modified saturation C 9 petroleum resin
Mixture.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the modified increasing
Modeling agent raw material is grouped as by mass fraction by following group：
92% paraffinic base white oil and/or naphthenic base white oil, 5% alkene acid anhydride, 2.5% emulsifier, 0.35% inhibition
Agent and 0.25% anticorrosion and bactericidal agent；
Preparation method includes the following steps：
(1) it takes 30% paraffinic base white oil and/or naphthenic base white oil to squeeze into reaction kettle by mass fraction, is uniformly mixed, adds
Heat to 45 DEG C, then press mass fraction be added 5% alkene acid anhydride, 2.5% emulsifier, 0.35% corrosion inhibiter and 0.25% it is anti-
After rotten fungicide, stirring 15min obtains A liquid；
(2) remaining 62% paraffinic base white oil and/or naphthenic base white oil is taken to be added in A liquid by mass fraction, stirring
30min is uniformly mixed, filtering, and it is for use to obtain modified plasticizer.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the wax are poly-
One or both of ethylene waxes, oxidized polyethylene wax, polypropylene wax, husky rope wax, ethylene bis stearic amide or octadecanoid acid with
On mixture.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the pigment are
Titanium dioxide, chrome yellow, iron oxide yellow, iron oxide black, carbon black, phthalocyanine blue, organic yellow, everbright fast yellow, permanent yellow or permanent bordeaux metal network
Close one or more kinds of mixtures of dyestuff.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the antioxidant
For phenolic antioxidant or phosphite ester kind antioxidant.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the weight of raw material
Amount part group becomes：120 parts of modified C 5 petroleum resin, modified 10 parts of plasticizer, 7 parts of polyethylene wax, ethylene bis stearic amide 5
Part, 20 parts of pigment, 400 parts of Paris white, 60 438 parts of mesh powdered whiting sand, 1.5 parts of water, 1.5 parts of antioxidant.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the weight of raw material
Amount part group becomes：115 parts of modified m-pentadiene petro-resin, modified 9 parts of plasticizer, 10 parts of polypropylene wax, 2 parts of octadecanoid acid,
25 parts of pigment, 250 parts of glass microballoon, 400 parts of Paris white, 190 parts of 60 mesh quartz sand, 1.5 parts of water, 0.5 part of antioxidant.
The aspect and any possible implementation manners as described above, it is further provided a kind of realization method, the weight of raw material
Amount part group becomes：115 parts of modified m-pentadiene petro-resin, modified 9 parts of plasticizer, 10 parts of polyethylene wax, 2 parts of octadecanoid acid,
25 parts of pigment, 250 parts of glass microballoon, 400 parts of Paris white, 190 parts of 60 mesh quartz sand, 1.5 parts of water, 0.5 part of antioxidant.
On the other hand, an embodiment of the present invention provides the preparation method of fast thawing environment-friendly type hot melt gage mark coating, including it is as follows
Step：
Open air purifying dust remover, pulse recovery type deduster, vertical elevator and the mixing of horizontal ribbon in workshop
Machine chooses filler, pigment, wax, modified plasticizer and water and Horizontal type helical ribbon mixer stirring 20in, mixing is added successively by weight
Uniformly, glass microballoon, Petropols are then added by weight, continues to stir 3-5min, be uniformly mixed, discharging packaging.
A technical solution in above-mentioned technical proposal has the advantages that：
The present invention provides a kind of fast thawing environment-friendly type hot melt gage mark coating and preparation methods, few by being added in component
The water of amount is allowed to form emulsification azeotropic mixture with oily matter in process of production, increases the compatibility between component, carry simultaneously
The boiling point of water in high emulsification azeotropic mixture so that mixing and react more abundant, higher compatibility can reduce Petropols
Additive amount while energy saving, Petropols can also be reduced in ultraviolet light so improving the stain resistance of coating
The decomposition product generated is irradiated, reduces the discharge of VOC so that coating components are more environmentally friendly.
In the construction process, as temperature increases, the steam of water and emulsification azeotropic mixture formation is run in coating makes coating
Uniformly heating, avoids due to coating coking phenomenon caused by localized hyperthermia, in addition, due to the boiling point of water in emulsification azeotropic mixture
It improves, water can be extended to a certain extent in the residence time of hot stage, to accelerate the burn-off rate of coating, while by
The increase of mobility between coating components reduces stirring resistance, and the continuous volatilization of water can also take away partial heat, and to apply
Material be less susceptible to coking, when temperature increase to a certain extent, water can volatilize completely, and the higher oil droplet that can be condensed into of oily matter boiling point returns
It returns in coating components, so the performance of coating will not be negatively affected by water.
【Specific implementation mode】
It will be appreciated that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art obtained without creative efforts it is all its
Its embodiment, shall fall within the protection scope of the present invention.
The term used in embodiments of the present invention is the purpose only merely for description specific embodiment, is not intended to be limiting
The present invention.In the embodiment of the present invention and "an" of singulative used in the attached claims, " described " and "the"
It is also intended to including most forms, unless context clearly shows that other meanings.
It should be appreciated that term "and/or" used herein is only a kind of incidence relation of description affiliated partner, indicate
There may be three kinds of relationships, for example, A and/or B, can indicate：Individualism A, exists simultaneously A and B, individualism B these three
Situation.In addition, character "/" herein, it is a kind of relationship of "or" to typically represent forward-backward correlation object.
An embodiment of the present invention provides a kind of fast thawing environment-friendly type hot melt gage mark coating, the parts by weight group of raw material becomes：
110-120 parts of Petropols, modified 8-10 parts of plasticizer, 10-12 parts of wax, 15-30 parts of pigment, glass microballoon 0-
350 parts, 550-850 parts of filler, 1-1.5 parts of water, 0.2-1.5 parts of antioxidant.
Wherein, Petropols are nine stone of modified C 5 petroleum resin, modified m-pentadiene petro-resin and modified saturated carbon
The mixture of one or both of oleoresin.
It should be noted that it is to reduce the cohesion of Petropols to use the purpose of modified petroleum resin in the present invention
Power, to improve the mobility and dispersibility of Petropols.
Modified petroleum resin is first to use destilling tower prolapse solvent, then steamed in high temperature through rectifying column after the completion of resin polymerization
The small molecule product in resin liquid is extracted through vacuum under the drive of vapour, phenols and phosphorous acid esters antioxygen are added in molten-bath
Each 2-3 ‰ of agent, polyisobutylene butanedioic anhydride 1.1-1.3%, modified petroleum resin is obtained after stirring evenly through comminutor cooling granulation.
Its key technical indexes is as follows：100 DEG C of softening point ＞, melt viscosity 160-250mpa.s, iron cobalt is than chroma color 4-5 numbers, acid value
＜ 1 (KOHmg/g).
Wherein, the modified plasticizer raw material is grouped as by mass fraction by following group：
92% paraffinic base white oil and/or naphthenic base white oil, 5% alkene acid anhydride, 2.5% emulsifier, 0.35% inhibition
Agent and 0.25% anticorrosion and bactericidal agent；
Preparation method includes the following steps：
(1) it takes 30% paraffinic base white oil and/or naphthenic base white oil to squeeze into reaction kettle by mass fraction, is uniformly mixed, adds
Heat to 45 DEG C, then press mass fraction be added 5% alkene acid anhydride, 2.5% emulsifier, 0.35% corrosion inhibiter and 0.25% it is anti-
After rotten fungicide, stirring 15min obtains A liquid；
(2) remaining 62% paraffinic base white oil and/or naphthenic base white oil is taken to be added in A liquid by mass fraction, stirring
30min is uniformly mixed, filtering, and it is for use to obtain modified plasticizer.
It should be noted that the use of modified plasticizer improves the compatibility between coating each component, coating is increased
Mobility, while Petropols dosage is reduced, the VOC emission generated is decomposed to effectively reduce organic matter, is reduced to sky
The pollution of gas and surrounding enviroment；Furthermore it is possible to ensure that coating in storage, transport and construction period constant color, improves institute's shape
At graticule for a long time be in extreme environment when discoloration-resisting.
It is by the purpose that paraffinic base white oil and/or naphthenic base white oil are added in two portions in preparation method：In step (1),
Temperature maintains 45 DEG C, is above room temperature, needs to carry out discharging packaging in step (2), can have efficiency of expanding with heat and contract with cold, cause
It packs ineffective, if the paraffinic base white oil and/or naphthenic base white oil under room temperature state are added in the step (2), can accelerate
Product is cooled to environment actual temperature, alleviates the volume change expanded with heat and contract with cold and brought.
Wax is in polyethylene wax, oxidized polyethylene wax, polypropylene wax, husky rope wax, ethylene bis stearic amide or octadecanoid acid
One or more kinds of mixtures.
Pigment is titanium dioxide, chrome yellow, iron oxide yellow, iron oxide black, carbon black, phthalocyanine blue, organic yellow, everbright fast yellow, permanent yellow
Or one or more kinds of mixtures of permanent bordeaux premetallized dye.
Filler is the mixture of one or more of natural heavy calcium carbonate miberal powder, quartz sand or talcum powder.
Antioxidant is phenolic antioxidant or phosphite ester kind antioxidant.
Embodiment 1
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：Penta between modification
110 parts of diene Petropols, modified 8 parts of plasticizer, 10 parts of wax, 15 parts of pigment, 850 parts of filler, 1 part of water, 0.2 part of antioxidant.
Embodiment 2
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：Penta between modification
115 parts of diene Petropols, modified 9 parts of plasticizer, 11 parts of wax, 25 parts of pigment, 250 parts of glass microballoon, 590 parts of filler, water
1.25 parts, 0.9 part of antioxidant.
Embodiment 3
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：Penta between modification
120 parts of diene Petropols, modified 10 parts of plasticizer, 12 parts of wax, 30 parts of pigment, 350 parts of glass microballoon, 490 parts of filler, water
1.5 parts, 1.5 parts of antioxidant.
Embodiment 4
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：Carbon modified five
120 parts of Petropols, modified 10 parts of plasticizer, 7 parts of polyethylene wax, 5 parts of ethylene bis stearic amide, 20 parts of pigment, Paris white
400 parts, 60 438 parts of mesh powdered whiting sand, 1.5 parts of water, 1.5 parts of antioxidant.
Embodiment 5
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：Penta between modification
115 parts of diene Petropols, modified 9 parts of plasticizer, 10 parts of polypropylene wax, 2 parts of octadecanoid acid, 25 parts of pigment, glass microballoon 250
Part, 400 parts of Paris white, 190 parts of 60 mesh quartz sand, 1.5 parts of water, 0.5 part of antioxidant.
Embodiment 6
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：Penta between modification
115 parts of diene Petropols, modified 9 parts of plasticizer, 10 parts of polyethylene wax, 2 parts of octadecanoid acid, 25 parts of pigment, glass microballoon 250
Part, 400 parts of Paris white, 190 parts of 60 mesh quartz sand, 1.5 parts of water, 0.5 part of antioxidant
The fast thawing environment-friendly type hot melt gage mark coating of the present embodiment, in terms of parts by weight, primary raw material group becomes：
The present invention provides a kind of fast thawing environment-friendly type hot melt gage mark coating and preparation methods, few by being added in component
The water of amount is allowed to form emulsification azeotropic mixture with oily matter in process of production, increases the compatibility between component, carry simultaneously
The boiling point of water in high emulsification azeotropic mixture so that mixing and react more abundant, higher compatibility can reduce Petropols
Additive amount while energy saving, Petropols can also be reduced in ultraviolet light so improving the stain resistance of coating
The decomposition product generated is irradiated, reduces the discharge of VOC so that coating components are more environmentally friendly.
In the construction process, as temperature increases, the steam of water and emulsification azeotropic mixture formation is run in coating makes coating
Uniformly heating, avoids due to coating coking phenomenon caused by localized hyperthermia, in addition, due to the boiling point of water in emulsification azeotropic mixture
It improves, water can be extended to a certain extent in the residence time of hot stage, to accelerate the burn-off rate of coating, while by
The increase of mobility between coating components reduces stirring resistance, and the continuous volatilization of water can also take away partial heat, and to apply
Material be less susceptible to coking, when temperature increase to a certain extent, water can volatilize completely, and the higher oil droplet that can be condensed into of oily matter boiling point returns
It returns in coating components, so the performance of coating will not be negatively affected by water.
It should be noted that the weight of composition described above raw material is using parts by weight as proportioning, it can be proportionally in production
Increase or reduce, as large-scale production can by kilogram as unit of, or as unit of ton, small-scale production can also with gram or milli
Gram it is unit, weight can increase or reduce, but the constant rate of the weight proportion between each composition.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent substitution, improvement and etc. done should be included within the scope of protection of the invention god.
Claims (10)
1. a kind of fast thawing environment-friendly type hot melt gage mark coating, which is characterized in that the parts by weight group of its raw material becomes：Petropols 110-
120 parts, modified 8-10 parts of plasticizer, 10-12 parts of wax, 15-30 parts of pigment, 0-350 parts of glass microballoon, 550-850 parts of filler, water
1-1.5 parts, 0.2-1.5 parts of antioxidant.
2. fast thawing environment-friendly type hot melt gage mark coating according to claim 1, which is characterized in that the Petropols are to be modified
The mixing of one or both of C 5 petroleum resin, modified m-pentadiene petro-resin and modified saturation C 9 petroleum resin
Object.
3. fast thawing environment-friendly type hot melt gage mark coating according to claim 2, which is characterized in that the modified plasticizer raw material
It is grouped as by following group by mass fraction：
92% paraffinic base white oil and/or naphthenic base white oil, 5% alkene acid anhydride, 2.5% emulsifier, 0.35% corrosion inhibiter and
0.25% anticorrosion and bactericidal agent；
Preparation method includes the following steps：
(1) it takes 30% paraffinic base white oil and/or naphthenic base white oil to squeeze into reaction kettle by mass fraction, is uniformly mixed, is heated to
45 DEG C, 5% alkene acid anhydride, 2.5% emulsifier, 0.35% corrosion inhibiter and 0.25% anti-corrosion then is added by mass fraction and kills
After microbial inoculum, stirring 15min obtains A liquid；
(2) it takes remaining 62% paraffinic base white oil and/or naphthenic base white oil to be added in A liquid by mass fraction, stirs 30min, mix
Uniform, filtering is closed, it is for use to obtain modified plasticizer.
4. fast thawing environment-friendly type hot melt gage mark coating according to claim 3, which is characterized in that the wax be polyethylene wax,
The mixing of one or more of oxidized polyethylene wax, polypropylene wax, husky rope wax, ethylene bis stearic amide or octadecanoid acid
Object.
5. fast thawing environment-friendly type hot melt gage mark coating according to claim 4, which is characterized in that the pigment be titanium dioxide,
Chrome yellow, iron oxide yellow, iron oxide black, carbon black, phthalocyanine blue, organic yellow, everbright fast yellow, permanent yellow or permanent bordeaux premetallized dye
One or more kinds of mixtures.
6. fast thawing environment-friendly type hot melt gage mark coating according to claim 5, which is characterized in that the antioxidant is anti-for phenols
Oxygen agent or phosphite ester kind antioxidant.
7. fast thawing environment-friendly type hot melt gage mark coating according to claim 6, which is characterized in that the parts by weight of its raw material form
For：120 parts of modified C 5 petroleum resin, modified 10 parts of plasticizer, 7 parts of polyethylene wax, 5 parts of ethylene bis stearic amide, pigment 20
Part, 400 parts of Paris white, 60 438 parts of mesh powdered whiting sand, 1.5 parts of water, 1.5 parts of antioxidant.
8. fast thawing environment-friendly type hot melt gage mark coating according to claim 6, which is characterized in that the parts by weight of its raw material form
For：115 parts of modified m-pentadiene petro-resin, modified 9 parts of plasticizer, 10 parts of polypropylene wax, 2 parts of octadecanoid acid, 25 parts of pigment,
250 parts of glass microballoon, 400 parts of Paris white, 190 parts of 60 mesh quartz sand, 1.5 parts of water, 0.5 part of antioxidant.
9. fast thawing environment-friendly type hot melt gage mark coating according to claim 6, which is characterized in that the parts by weight of its raw material form
For：115 parts of modified m-pentadiene petro-resin, modified 9 parts of plasticizer, 10 parts of polyethylene wax, 2 parts of octadecanoid acid, 25 parts of pigment,
250 parts of glass microballoon, 400 parts of Paris white, 190 parts of 60 mesh quartz sand, 1.5 parts of water, 0.5 part of antioxidant.
10. according to the preparation method of claim 1-9 any one of them fast thawing environment-friendly type hot melt gage mark coatings, including walking as follows
Suddenly：
Air purifying dust remover, pulse recovery type deduster, vertical elevator and the Horizontal type helical ribbon mixer in workshop are opened, is pressed
Parts by weight choose filler, pigment, wax, modified plasticizer and water and Horizontal type helical ribbon mixer stirring 20in are added successively, are uniformly mixed,
Then glass microballoon, Petropols are added by weight, continues to stir 3-5min, be uniformly mixed, discharging packaging.
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| CN201810302554.5A CN108485454B (en) | 2018-04-05 | 2018-04-05 | Quick-melting environment-friendly hot-melt marking paint and preparation method thereof |
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| CN201810302554.5A CN108485454B (en) | 2018-04-05 | 2018-04-05 | Quick-melting environment-friendly hot-melt marking paint and preparation method thereof |
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| CN108485454B CN108485454B (en) | 2020-08-21 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110724431A (en) * | 2019-10-22 | 2020-01-24 | 厦门闽路通建设工程有限公司 | Road marking paint and preparation method thereof |
| CN114806319A (en) * | 2022-04-18 | 2022-07-29 | 山西中涂交通科技股份有限公司 | Cold-resistant high-toughness hot-melt type marking paint |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387891A (en) * | 2014-11-06 | 2015-03-04 | 浙江兄弟路标涂料有限公司 | Environment-friendly heating liner paint |
| CN106280663A (en) * | 2016-08-09 | 2017-01-04 | 王建周 | A kind of hot melt type gage mark coating yellowing-resistant plasticizer and preparation method thereof |
-
2018
- 2018-04-05 CN CN201810302554.5A patent/CN108485454B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387891A (en) * | 2014-11-06 | 2015-03-04 | 浙江兄弟路标涂料有限公司 | Environment-friendly heating liner paint |
| CN106280663A (en) * | 2016-08-09 | 2017-01-04 | 王建周 | A kind of hot melt type gage mark coating yellowing-resistant plasticizer and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| A.R别克林: "《有机化学实验操作技术》", 30 November 1964, 中国工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110724431A (en) * | 2019-10-22 | 2020-01-24 | 厦门闽路通建设工程有限公司 | Road marking paint and preparation method thereof |
| CN110724431B (en) * | 2019-10-22 | 2021-06-01 | 厦门闽路通建设工程有限公司 | Road marking paint and preparation method thereof |
| CN114806319A (en) * | 2022-04-18 | 2022-07-29 | 山西中涂交通科技股份有限公司 | Cold-resistant high-toughness hot-melt type marking paint |
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| CN108485454B (en) | 2020-08-21 |
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