CN108483681A - 污水处理微生物营养液的制备方法 - Google Patents
污水处理微生物营养液的制备方法 Download PDFInfo
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- 235000015097 nutrients Nutrition 0.000 title claims abstract description 20
- 230000000813 microbial effect Effects 0.000 title claims abstract description 14
- 239000010865 sewage Substances 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000243 solution Substances 0.000 claims abstract description 30
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 24
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 240000008042 Zea mays Species 0.000 claims abstract description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 4
- 235000005822 corn Nutrition 0.000 claims abstract description 4
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 239000011259 mixed solution Substances 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 230000035484 reaction time Effects 0.000 claims abstract description 4
- 238000003860 storage Methods 0.000 claims abstract description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 20
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 7
- 239000010842 industrial wastewater Substances 0.000 abstract description 5
- 244000005700 microbiome Species 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
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- 235000009566 rice Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
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- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Treatment Of Biological Wastes In General (AREA)
Abstract
本发明公开了一种污水处理微生物营养液的制备方法,具体包含以下步骤:(1).室温条件下,按液体原料废玉米浆:甲醇=7:3 的比例将原料混合均匀;(2).将步骤(1)混合的溶液用泵打入密闭反应容器内,同时每立方混合溶液加入磷酸溶液10kg,反应时间为3‑4小时、反应温度为30‑90℃,从而完成原料间发生的氧化、聚合反应;(3). 稳定熟化3小时后,经过板框过滤后,制成液体微生物营养液,存放暂储罐。本发明由本发明制得的营养液非常符合微生物生长的需要,脱氮效果好,微生物活性强,而且对于含氮量高的工业废水、难处理工业废水具有很好的处理效果。
Description
技术领域
本发明涉及净水剂技术领域,具体涉及一种污水处理微生物营养液的制备方法。
背景技术
目前,污水处理过程中脱氮和菌种培养需要使用大量的碳源和磷源,包括工业级葡萄糖、乙酸钠、甲醇、磷酸二氢钾等微生物生存需要物质。目前脱氮碳源多采用葡萄糖、乙酸钠和甲醇,在应用过程中存在一定的问题,在水处理中葡萄糖长期使用易引起污泥沉降性能差,二沉池出水携带污泥,影响出水;乙酸钠作为碳源使用因含有7个结晶水,可使用的碳源成份低,性价比低,运行成本高;虽然甲醇是比较好的碳源,但因消防、安全措施要求严格,限制了甲醇在水处理工业的应用;随着国家环保部门对总氮指标要求越来越严,微生物营养液的是污水处理厂的迫切需要,将会有广泛的市场;综上所述生产一种价格低廉、安全、性价比高的微生物营养液势在必行。
发明内容
本发明目的是提供一种污水处理微生物营养液的制备方法,制得的营养液在水处理中对总氮去除效果好,且成本低、稳定性好,微生物活性、吸附性能增强。
污水处理微生物营养液的制备方法,具体包含以下步骤:
1.室温条件下,按液体原料废玉米浆:甲醇=7:3的比例将原料混合均匀;
2.将步骤1混合的溶液用泵打入密闭反应容器内,同时每立方混合溶液加入磷酸溶液10kg,反应时间为3-4小时、反应温度为30-90℃,从而完成原料间发生的氧化、聚合反应;
3.稳定熟化3小时后,经过板框过滤后,制成液体微生物营养液,存放暂储罐。
由于采用了以上技术方案,本发明具有以下有益效果:由本发明制得的营养液在水处理的过程中,投加到生物池内,碳、氮、磷比例适中,非常符合微生物生长的需要,脱氮效果好,微生物活性强,而且对于含氮量高的工业废水、难处理工业废水具有很好的处理效果,即本发明制备的微生物营养液与传统碳源相比,不仅去除废水中的总氮,对COD的去除效果也有一定的提升,具有广泛的开发价值和应用前景。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例,对本发明进行进一步详细说明,应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
实施例
污水处理微生物营养液的制备方法,具体包含以下步骤:
1.室温条件下,按液体原料废玉米浆:甲醇=7:3的比例将原料混合均匀;
2.将步骤1混合的溶液用泵打入密闭反应容器内,同时每立方混合溶液加入磷酸溶液10kg,反应时间为3-4小时、反应温度为30-90℃,从而完成原料间发生的氧化、聚合反应;
3.稳定熟化3小时后,经过板框过滤后,制成液体微生物营养液,存放暂储罐。
利用上述制备方法制得的营养液的产物指标为:微生物营养液1ml溶解在1L水中指标为:碳源690.1mg/L,氮源30.1mg/L,总磷1.5mg/L,不溶物低于0.1%,密度1.05克/厘米3。
实施例2
取一工业企业的生产废水水样,原水样COD150mg/l、总氮40.8mg/l,总磷0.6mg/l,添加2.5ml/l,搅拌沉淀后,水样的COD降低到73mg/l、总氮10.4mg/l,总磷0.28mg/l,污泥沉降性能好,活性强,除磷、脱氮等处理指标达标,成本低,特别对工业废水总氮的去除效果尤为显著。
最后应说明的是:以上实施例仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施例对本发明进行了详细的说明,本领域的普通技术人员应当理解,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。
Claims (1)
1.污水处理微生物营养液的制备方法,其特征在于具体包含以下步骤:
(1).室温条件下,按液体原料废玉米浆:甲醇=7:3的比例将原料混合均匀;
(2).将步骤(1)混合的溶液用泵打入密闭反应容器内,同时每立方混合溶液加入磷酸溶液10kg,反应时间为3-4小时、反应温度为30-90℃,从而完成原料间发生的氧化、聚合反应;
(3).稳定熟化3小时后,经过板框过滤后,制成液体微生物营养液,存放暂储罐。
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CN110054303A (zh) * | 2019-04-30 | 2019-07-26 | 宁夏水投清水源水处理科技有限公司 | 一种污水处理微生物营养液的制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101033450A (zh) * | 2007-01-18 | 2007-09-12 | 赵志龙 | 一种废水处理用复合高效微生物制剂的制备方法 |
US20120305479A1 (en) * | 2011-06-01 | 2012-12-06 | David Falatko | Mixed substrates for anaerobic bioremediation in aquifers |
CN103865796A (zh) * | 2014-03-21 | 2014-06-18 | 杭州水询环保科技有限公司 | 一种废水生化处理微生物复合营养液 |
CN104118943A (zh) * | 2014-08-06 | 2014-10-29 | 南京大学 | 一种菹草发酵液在人工湿地脱氮中的应用 |
US20150024470A1 (en) * | 2012-01-19 | 2015-01-22 | National University Corporation Nagoya University | Microorganism belonging to yarrowia genus, and oil decomposition agent and oil decomposition/removal method using same |
CN106573811A (zh) * | 2014-06-17 | 2017-04-19 | 诺维信公司 | 从废水中去除生物磷 |
CN107162214A (zh) * | 2017-06-09 | 2017-09-15 | 四川金沙纳米技术有限公司 | 一种复合微生物耦合微米零价铁脱氮除磷的污水处理方法 |
-
2018
- 2018-06-30 CN CN201810703143.7A patent/CN108483681A/zh active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101033450A (zh) * | 2007-01-18 | 2007-09-12 | 赵志龙 | 一种废水处理用复合高效微生物制剂的制备方法 |
US20120305479A1 (en) * | 2011-06-01 | 2012-12-06 | David Falatko | Mixed substrates for anaerobic bioremediation in aquifers |
US20150024470A1 (en) * | 2012-01-19 | 2015-01-22 | National University Corporation Nagoya University | Microorganism belonging to yarrowia genus, and oil decomposition agent and oil decomposition/removal method using same |
CN103865796A (zh) * | 2014-03-21 | 2014-06-18 | 杭州水询环保科技有限公司 | 一种废水生化处理微生物复合营养液 |
CN106573811A (zh) * | 2014-06-17 | 2017-04-19 | 诺维信公司 | 从废水中去除生物磷 |
CN104118943A (zh) * | 2014-08-06 | 2014-10-29 | 南京大学 | 一种菹草发酵液在人工湿地脱氮中的应用 |
CN107162214A (zh) * | 2017-06-09 | 2017-09-15 | 四川金沙纳米技术有限公司 | 一种复合微生物耦合微米零价铁脱氮除磷的污水处理方法 |
Non-Patent Citations (2)
Title |
---|
张惠展等: "《DNA重组操作技术》", 31 May 2006, 上海交通大学出版社 * |
罗云波: "《食品生物技术导论》", 31 August 2016, 中国农业大学出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110054303A (zh) * | 2019-04-30 | 2019-07-26 | 宁夏水投清水源水处理科技有限公司 | 一种污水处理微生物营养液的制备方法 |
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